DE69623107D1 - PARTICLE-SHAPED SILICONE-MODIFIED ACRYLIC RUBBER, PARTICLE-SHAPED GRAFT COPOLYMER BASED ON SILICONE-MODIFIED ACRYLIC RUBBER AND THERMOPLASTIC RESIN - Google Patents

PARTICLE-SHAPED SILICONE-MODIFIED ACRYLIC RUBBER, PARTICLE-SHAPED GRAFT COPOLYMER BASED ON SILICONE-MODIFIED ACRYLIC RUBBER AND THERMOPLASTIC RESIN

Info

Publication number
DE69623107D1
DE69623107D1 DE69623107T DE69623107T DE69623107D1 DE 69623107 D1 DE69623107 D1 DE 69623107D1 DE 69623107 T DE69623107 T DE 69623107T DE 69623107 T DE69623107 T DE 69623107T DE 69623107 D1 DE69623107 D1 DE 69623107D1
Authority
DE
Germany
Prior art keywords
acrylic rubber
silicone
weight
modified acrylic
particle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69623107T
Other languages
German (de)
Other versions
DE69623107T2 (en
Inventor
Nobuo Miyatake
Hiroki Yoshino
Hideki Hosoi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kaneka Corp
Original Assignee
Kaneka Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaneka Corp filed Critical Kaneka Corp
Application granted granted Critical
Publication of DE69623107D1 publication Critical patent/DE69623107D1/en
Publication of DE69623107T2 publication Critical patent/DE69623107T2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Silicon Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

To provide novel silicone-modified acrylic rubber particles prepared at a high conversion without using a special polymerization plant by graft-polymerizing (B) 45 to 5,000 parts by weight of a silicone rubber precursor comprising 99.9 to 80 % by weight of a low molecular weight organosiloxane, 0.1 to 10 % by weight of a polyfunctional silane compound and 0 to 10 % by weight of a reactive silane compound having a polymerizable unsaturated bond or a mercapto group in its molecule to (A) 100 parts by weight of acrylic rubber particles, and if necessary, thereto by graft-polymerizing (C) 0.1 to 5,000 parts by weight of an acrylic rubber precursor; graft copolymer particles of silicone-modified acrylic rubber which are prepared from the above-mentioned acrylic rubber particles and are capable of improving weather resistance and impact resistance of various thermoplastic resins; and a thermoplastic resin composition comprising the above-mentioned resin and the graft copolymer particles.
DE69623107T 1995-09-12 1996-09-09 PARTICLE-SHAPED SILICONE-MODIFIED ACRYLIC RUBBER, PARTICLE-SHAPED GRAFT COPOLYMER BASED ON SILICONE-MODIFIED ACRYLIC RUBBER AND THERMOPLASTIC RESIN Expired - Fee Related DE69623107T2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP23410895 1995-09-12
JP12871396 1996-05-23
PCT/JP1996/002566 WO1997010283A1 (en) 1995-09-12 1996-09-09 Particulate silicone-modified acrylic rubber, particulate graft copolymer based on silicone-modified acrylic rubber, and thermoplastic resin composition

Publications (2)

Publication Number Publication Date
DE69623107D1 true DE69623107D1 (en) 2002-09-26
DE69623107T2 DE69623107T2 (en) 2003-04-17

Family

ID=26464301

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69623107T Expired - Fee Related DE69623107T2 (en) 1995-09-12 1996-09-09 PARTICLE-SHAPED SILICONE-MODIFIED ACRYLIC RUBBER, PARTICLE-SHAPED GRAFT COPOLYMER BASED ON SILICONE-MODIFIED ACRYLIC RUBBER AND THERMOPLASTIC RESIN

Country Status (6)

Country Link
US (1) US5804655A (en)
EP (1) EP0791617B1 (en)
AT (1) ATE222591T1 (en)
DE (1) DE69623107T2 (en)
MY (1) MY113517A (en)
WO (1) WO1997010283A1 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE173486T1 (en) * 1994-08-05 1998-12-15 Goodrich Co B F CHLORINATED POLYVINYL CHLORIDE MATERIAL WITH IMPROVED TOUGHNESS AND STABILITY, AS WELL AS LOW SMOKE AND HEAT Emission
TWI222455B (en) * 1998-02-13 2004-10-21 Kanegafuchi Chemical Ind Aqueous emulsion containing silicone rubber particles and process for preparing the same
CN1325537C (en) * 1998-12-07 2007-07-11 通用电气公司 Emulsion polymerized silicone rubber-based impact modifiers, method for making, and blends thereof
US6703445B2 (en) * 2000-11-22 2004-03-09 Suzuka Fuji Xerox Co., Ltd. Molding thermoplastic resin material and a method for equal quality recycle of thermoplastic resin mold
CN1733964B (en) 2001-08-10 2011-06-15 三菱丽阳株式会社 Resin composition for direct vapor deposition, molded articles made by using the same, and surface-metallized lamp housing
KR100698821B1 (en) * 2003-04-11 2007-03-23 카네카 코포레이션 Polyorganosiloxane-containing graft copolymer, resin compositions containing the same and process for production of polyorganosiloxane emulsions
KR100528771B1 (en) * 2003-08-02 2005-11-15 주식회사 엘지화학 Acryl-silicones Complex Impact-Modifier and Method for Preparing the Same, and Vinyl Chloride Resin Composition Having the Same
DE102004022406A1 (en) * 2004-05-06 2005-12-15 Wacker-Chemie Gmbh Polysiloxane graft polymer
JP4732214B2 (en) * 2006-03-30 2011-07-27 エスケー化研株式会社 Painting method
JP4937629B2 (en) * 2006-03-31 2012-05-23 エスケー化研株式会社 Coating method
EP2129521B1 (en) 2007-02-26 2019-01-02 Hexcel Composites, Ltd. Improved surface finish for composite materials
CN102105532B (en) * 2008-07-23 2013-01-23 三菱工程塑料株式会社 Thermoplastic polyester resin composition
KR101282707B1 (en) * 2009-12-30 2013-07-05 제일모직주식회사 Silicone impact modifier having core-shell structure and thermoplastic composition having the same
KR102221306B1 (en) * 2020-09-02 2021-03-02 주식회사 뉴보텍 A double wall pipe

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3617267A1 (en) * 1986-05-23 1987-11-26 Bayer Ag NOTCH IMPACT TOE GRAFT POLYMERISATE
DE3629763A1 (en) * 1986-09-02 1988-03-03 Bayer Ag NOTCH IMPACT TOE SILICONE RUBBER GRAFT POLYMERISATE
JPH0611857B2 (en) * 1986-09-11 1994-02-16 三菱レイヨン株式会社 Polyphenylene ether resin composition
US5212236A (en) * 1986-09-11 1993-05-18 Mitsubishi Rayon Co., Ltd. Polyphenylene ether resin composition
DE3704657A1 (en) * 1987-02-14 1988-08-25 Bayer Ag PARTICULATE MULTI-PHASE POLYMERISATES
DE3720475A1 (en) * 1987-06-20 1988-12-29 Bayer Ag THERMOPLASTIC SILICONE RUBBER GRAFT POLYMERISATE (II)
AU604179B2 (en) * 1988-01-25 1990-12-06 Mitsubishi Rayon Company Limited Vinyl chloride resin composition
JP2608439B2 (en) * 1988-01-25 1997-05-07 三菱レイヨン株式会社 Impact resistant resin composition
DE3822667A1 (en) * 1988-07-05 1990-01-11 Bayer Ag TIEFTEMPERATURZAEHE PVC SILICONE RUBBER MOLDINGS
US5106900A (en) * 1990-11-15 1992-04-21 General Electric Company Method and organopolysiloxane/organic polymeric compositions obtained therefrom
JP2977605B2 (en) * 1990-11-28 1999-11-15 三菱レイヨン株式会社 Polyester resin composition
JPH0830102B2 (en) * 1990-12-14 1996-03-27 三菱レイヨン株式会社 Composite rubber-based graft copolymer particles
JP2684258B2 (en) * 1991-04-02 1997-12-03 三菱レイヨン株式会社 Method for producing polyorganosiloxane-based graft copolymer composition having excellent powder properties

Also Published As

Publication number Publication date
ATE222591T1 (en) 2002-09-15
EP0791617A4 (en) 1998-04-08
EP0791617A1 (en) 1997-08-27
DE69623107T2 (en) 2003-04-17
EP0791617B1 (en) 2002-08-21
US5804655A (en) 1998-09-08
MY113517A (en) 2002-03-30
WO1997010283A1 (en) 1997-03-20

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Legal Events

Date Code Title Description
8339 Ceased/non-payment of the annual fee