DE69507522D1 - Blockcopolymere aus monovinylaromatischem Monomer und konjugiertem Dien - Google Patents
Blockcopolymere aus monovinylaromatischem Monomer und konjugiertem DienInfo
- Publication number
- DE69507522D1 DE69507522D1 DE69507522T DE69507522T DE69507522D1 DE 69507522 D1 DE69507522 D1 DE 69507522D1 DE 69507522 T DE69507522 T DE 69507522T DE 69507522 T DE69507522 T DE 69507522T DE 69507522 D1 DE69507522 D1 DE 69507522D1
- Authority
- DE
- Germany
- Prior art keywords
- conjugated diene
- initiator
- block copolymers
- aromatic monomer
- monovinyl aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/216,725 US5438103A (en) | 1994-03-23 | 1994-03-23 | Block copolymers of monovinylaromatic and conjugated diene monomers |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69507522D1 true DE69507522D1 (de) | 1999-03-11 |
DE69507522T2 DE69507522T2 (de) | 1999-06-24 |
Family
ID=22808262
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69507522T Expired - Fee Related DE69507522T2 (de) | 1994-03-23 | 1995-03-22 | Blockcopolymere aus monovinylaromatischem Monomer und konjugiertem Dien |
Country Status (9)
Country | Link |
---|---|
US (1) | US5438103A (de) |
EP (1) | EP0673953B1 (de) |
JP (1) | JPH08143636A (de) |
KR (1) | KR100373544B1 (de) |
AT (1) | ATE176251T1 (de) |
CA (1) | CA2143598C (de) |
DE (1) | DE69507522T2 (de) |
ES (1) | ES2127957T3 (de) |
TW (1) | TW382633B (de) |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2134026C (en) * | 1993-11-15 | 1998-06-09 | William J. Trepka | Tapered block copolymers of monovinylarenes and conjugated dienes |
CN1036346C (zh) * | 1995-08-04 | 1997-11-05 | 中国石油化工总公司 | 丁苯嵌段共聚物热塑弹性体及制法 |
CN1037848C (zh) * | 1995-08-04 | 1998-03-25 | 北京燕山石油化工公司研究院 | 丁苯嵌段共聚物的制造方法 |
US6096828A (en) * | 1995-08-29 | 2000-08-01 | Phillips Petroleum Company | Conjugated diene/monovinylarene block copolymers, methods for preparing same, and polymer blends |
US6835778B2 (en) * | 1995-08-29 | 2004-12-28 | Chevron Phillips Chemical Company Lp | Conjugated diene/monovinylarene block copolymers blends |
US6143832A (en) * | 1997-05-22 | 2000-11-07 | Nippon Zeon Co., Ltd. | Aromatic vinyl-conjugated diene block copolymer and production process thereof |
US6359075B1 (en) * | 2001-01-09 | 2002-03-19 | Bridgestone/Firestone, Inc. | Means of producing high diblock content thermoplastic elastomers via chain transfer |
US6956084B2 (en) | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
KR100452813B1 (ko) * | 2002-05-15 | 2004-10-14 | 금호석유화학 주식회사 | 2조성 선형 블락 공중합체, 그 제조방법 및 용도 |
KR100458169B1 (ko) * | 2002-07-26 | 2004-11-20 | 금호석유화학 주식회사 | 비대칭 다중블록 sbs 중합체 및 이의 제조 방법 |
US20040115381A1 (en) * | 2002-12-12 | 2004-06-17 | Chevron Phillips Chemical Company, Lp | Method for manufacturing articles with materials containing tapered polymers |
JP4683928B2 (ja) | 2002-12-18 | 2011-05-18 | 株式会社ブリヂストン | クレイの剥離方法、該方法から得られた組成物、及び該組成物を含む変性ゴム |
US6875818B2 (en) | 2003-01-16 | 2005-04-05 | Bridgestone Corporation | Polymer nano-strings |
CN100386353C (zh) * | 2003-03-19 | 2008-05-07 | 电气化学工业株式会社 | 含有支链状嵌段共聚物的嵌段共聚物混合物 |
US7205370B2 (en) | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
DK1711558T3 (da) * | 2004-01-30 | 2008-09-22 | Renolit Ag | Syndiotaktisk polypropylensammensætning omfattende en termoplastisk elastomer |
US20050166551A1 (en) * | 2004-02-02 | 2005-08-04 | Keane J. A. | Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer |
US7112369B2 (en) * | 2004-03-02 | 2006-09-26 | Bridgestone Corporation | Nano-sized polymer-metal composites |
US8063142B2 (en) | 2004-03-02 | 2011-11-22 | Bridgestone Corporation | Method of making nano-particles of selected size distribution |
US7718737B2 (en) | 2004-03-02 | 2010-05-18 | Bridgestone Corporation | Rubber composition containing functionalized polymer nanoparticles |
US20050282956A1 (en) | 2004-06-21 | 2005-12-22 | Xiaorong Wang | Reversible polymer/metal nano-composites and method for manufacturing same |
US7998554B2 (en) | 2004-07-06 | 2011-08-16 | Bridgestone Corporation | Hydrophobic surfaces with nanoparticles |
US7572855B2 (en) | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
US7579398B2 (en) | 2005-02-02 | 2009-08-25 | Bridgestone Corporation | Nano-composite and compositions therefrom |
US7659342B2 (en) | 2005-02-03 | 2010-02-09 | Bridgestone Corporation | Polymer nano-particle with polar core and method for manufacturing same |
US9061900B2 (en) | 2005-12-16 | 2015-06-23 | Bridgestone Corporation | Combined use of liquid polymer and polymeric nanoparticles for rubber applications |
US7538159B2 (en) | 2005-12-16 | 2009-05-26 | Bridgestone Corporation | Nanoparticles with controlled architecture and method thereof |
US7884160B2 (en) | 2005-12-19 | 2011-02-08 | Bridgestone Corporation | Non-spherical nanoparticles made from living triblock polymer chains |
US8288473B2 (en) | 2005-12-19 | 2012-10-16 | Bridgestone Corporation | Disk-like nanoparticles |
US7601772B2 (en) | 2005-12-20 | 2009-10-13 | Bridgestone Corporation | Nano-composite and method thereof |
US8877250B2 (en) | 2005-12-20 | 2014-11-04 | Bridgestone Corporation | Hollow nano-particles and method thereof |
US7560510B2 (en) | 2005-12-20 | 2009-07-14 | Bridgestone Corporation | Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties |
US8697775B2 (en) | 2005-12-20 | 2014-04-15 | Bridgestone Corporation | Vulcanizable nanoparticles having a core with a high glass transition temperature |
US7935184B2 (en) | 2006-06-19 | 2011-05-03 | Bridgestone Corporation | Method of preparing imidazolium surfactants |
JP6096398B2 (ja) | 2006-07-28 | 2017-03-15 | 株式会社ブリヂストン | 重合体ナノ粒子、ゴム組成物及び使用 |
US7597959B2 (en) | 2006-12-19 | 2009-10-06 | Bridgestone Corporation | Core-shell fluorescent nanoparticles |
US7649049B2 (en) | 2006-12-20 | 2010-01-19 | Bridgestone Corporation | Rubber composition containing a polymer nanoparticle |
US7829624B2 (en) | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
KR101116750B1 (ko) * | 2008-10-31 | 2012-02-22 | 금호석유화학 주식회사 | 비대칭 스타 폴리머의 제조 방법 |
US8846819B2 (en) | 2008-12-31 | 2014-09-30 | Bridgestone Corporation | Core-first nanoparticle formation process, nanoparticle, and composition |
US9062144B2 (en) | 2009-04-03 | 2015-06-23 | Bridgestone Corporation | Hairy polymeric nanoparticles with first and second shell block polymer arms |
US20100272975A1 (en) * | 2009-04-23 | 2010-10-28 | Chevron Phillips Chemical Company Lp | System and method for the production and use of lamination films |
US9115222B2 (en) | 2009-12-29 | 2015-08-25 | Bridgestone Corporation | Well defined, highly crosslinked nanoparticles and method for making same |
US9428604B1 (en) | 2011-12-30 | 2016-08-30 | Bridgestone Corporation | Nanoparticle fillers and methods of mixing into elastomers |
MX362954B (es) | 2012-05-08 | 2019-02-27 | Denka Company Ltd | Composicion de copolimero de bloque y lamina. |
US9441090B1 (en) | 2015-03-12 | 2016-09-13 | Chevron Phillips Chemical Company Lp | Methods for controlling hardness of styrene-butadiene block copolymers |
US9598524B1 (en) | 2015-09-18 | 2017-03-21 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications |
US9540475B2 (en) | 2015-03-12 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers for tubing applications |
US9738781B2 (en) | 2015-09-03 | 2017-08-22 | Ineos Styrolution Group Gmbh | Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications |
US10023676B2 (en) | 2016-02-24 | 2018-07-17 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
US9828455B2 (en) | 2016-02-24 | 2017-11-28 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
GB201905379D0 (en) | 2019-04-16 | 2019-05-29 | Univ Durham | Method of epoxidation |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3670054A (en) * | 1969-10-29 | 1972-06-13 | Shell Oil Co | Block copolymers having reduced solvent sensitivity |
US3725368A (en) * | 1970-01-19 | 1973-04-03 | Lithium Corp | Preparation of polymers |
US4004070A (en) * | 1970-09-28 | 1977-01-18 | Phillips Petroleum Company | Viscosity reduction of organopolylithium-initiated polymer solutions |
US3937760A (en) * | 1974-04-29 | 1976-02-10 | The Firestone Tire & Rubber Company | Process for producing multiblock copolymer and products produced thereby |
US4133845A (en) * | 1974-12-05 | 1979-01-09 | Bayer Aktiengesellschaft | Polysegment copolymers |
US4248982A (en) * | 1979-04-30 | 1981-02-03 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
US4285751A (en) * | 1979-05-10 | 1981-08-25 | W. R. Grace & Co. | Method of forming an improved battery separator |
US4297451A (en) * | 1979-07-10 | 1981-10-27 | Phillips Petroleum Company | Dienyllithium initiated polymers |
US4584346A (en) * | 1984-02-29 | 1986-04-22 | Phillips Petroleum Company | Craze-resistant transparent resinous polymodal block copolymers |
IT1196517B (it) * | 1986-07-17 | 1988-11-16 | Montedipe Spa | Copolimeri a blocco radiali e bimodali aventi ottime proprieta' ottiche e reistenza agli urti e processo per la loro preparazione |
CA2028410C (en) * | 1990-01-02 | 1996-09-17 | William J. Trepka | Tapered block styrene/butadiene copolymers |
US5319033A (en) * | 1990-01-02 | 1994-06-07 | Phillips Petroleum Company | Tapered block monovinyl aromatic/conjugated diene copolymer |
US5256736A (en) * | 1991-05-08 | 1993-10-26 | Phillips Petroleum Company | Tapered block copolymers of conjugated dienes and monovinylarenes |
US5290875A (en) * | 1992-11-30 | 1994-03-01 | Phillips Petroleum Company | Conjugated diene/monovinylarene block copolymers with multiple tapered blocks |
-
1994
- 1994-03-23 US US08/216,725 patent/US5438103A/en not_active Expired - Fee Related
-
1995
- 1995-02-28 CA CA002143598A patent/CA2143598C/en not_active Expired - Fee Related
- 1995-03-22 AT AT95104209T patent/ATE176251T1/de not_active IP Right Cessation
- 1995-03-22 KR KR1019950006111A patent/KR100373544B1/ko not_active IP Right Cessation
- 1995-03-22 ES ES95104209T patent/ES2127957T3/es not_active Expired - Lifetime
- 1995-03-22 EP EP95104209A patent/EP0673953B1/de not_active Expired - Lifetime
- 1995-03-22 DE DE69507522T patent/DE69507522T2/de not_active Expired - Fee Related
- 1995-03-23 JP JP7102938A patent/JPH08143636A/ja not_active Abandoned
- 1995-04-17 TW TW084103751A patent/TW382633B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0673953A1 (de) | 1995-09-27 |
ES2127957T3 (es) | 1999-05-01 |
CA2143598A1 (en) | 1995-09-24 |
KR100373544B1 (ko) | 2003-04-26 |
TW382633B (en) | 2000-02-21 |
KR950032340A (ko) | 1995-12-20 |
US5438103A (en) | 1995-08-01 |
EP0673953B1 (de) | 1999-01-27 |
DE69507522T2 (de) | 1999-06-24 |
JPH08143636A (ja) | 1996-06-04 |
ATE176251T1 (de) | 1999-02-15 |
CA2143598C (en) | 2000-01-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |