DE69217997T2 - Pyrazolcarboxamilide als fungizide - Google Patents
Pyrazolcarboxamilide als fungizideInfo
- Publication number
- DE69217997T2 DE69217997T2 DE69217997T DE69217997T DE69217997T2 DE 69217997 T2 DE69217997 T2 DE 69217997T2 DE 69217997 T DE69217997 T DE 69217997T DE 69217997 T DE69217997 T DE 69217997T DE 69217997 T2 DE69217997 T2 DE 69217997T2
- Authority
- DE
- Germany
- Prior art keywords
- carboxamilides
- pyrazolic
- fungicides
- pyrazolic carboxamilides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/06—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D233/08—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms
- C07D233/12—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D233/18—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/20—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D233/22—Radicals substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US80297891A | 1991-12-06 | 1991-12-06 | |
US87790792A | 1992-05-01 | 1992-05-01 | |
US07/967,417 US5223526A (en) | 1991-12-06 | 1992-11-05 | Pyrazole carboxanilide fungicides and use |
PCT/US1992/010509 WO1993011117A1 (en) | 1991-12-06 | 1992-12-04 | Pyrazole carboxanilide fungicides |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69217997D1 DE69217997D1 (de) | 1997-04-10 |
DE69217997T2 true DE69217997T2 (de) | 1997-09-04 |
Family
ID=27419994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69217997T Expired - Fee Related DE69217997T2 (de) | 1991-12-06 | 1992-12-04 | Pyrazolcarboxamilide als fungizide |
Country Status (22)
Country | Link |
---|---|
US (1) | US5223526A (de) |
EP (1) | EP0623113B1 (de) |
JP (1) | JPH07501549A (de) |
CN (1) | CN1078234A (de) |
AR (1) | AR248397A1 (de) |
AT (1) | ATE149490T1 (de) |
AU (1) | AU657598B2 (de) |
BR (1) | BR9206869A (de) |
CA (1) | CA2123122A1 (de) |
CZ (1) | CZ126094A3 (de) |
DE (1) | DE69217997T2 (de) |
HU (1) | HUT67795A (de) |
IL (1) | IL103988A0 (de) |
MD (1) | MD940085A (de) |
MX (1) | MX9207038A (de) |
MY (1) | MY131288A (de) |
NZ (1) | NZ246269A (de) |
SI (1) | SI9200352A (de) |
SK (1) | SK67894A3 (de) |
TR (1) | TR26592A (de) |
WO (1) | WO1993011117A1 (de) |
ZW (1) | ZW18792A1 (de) |
Families Citing this family (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL103614A (en) * | 1991-11-22 | 1998-09-24 | Basf Ag | Carboxamides for controlling botrytis and certain novel such compounds |
DE4231517A1 (de) * | 1992-09-21 | 1994-03-24 | Basf Ag | Carbonsäureanilide, Verfahren zu ihrer Herstellung und sie enthaltende Mittel zur Bekämpfung von Schadpilzen |
JP3307026B2 (ja) * | 1993-11-04 | 2002-07-24 | 住友化学工業株式会社 | 農園芸用殺菌組成物 |
TW305743B (de) * | 1993-11-04 | 1997-05-21 | Sumitomo Chemical Co | |
US5498624A (en) * | 1995-05-03 | 1996-03-12 | Monsanto Company | Selected pyrazolyl derivatives |
TW349094B (en) * | 1995-09-05 | 1999-01-01 | Basf Ag | Compositions and methods for controlling harmful fungi |
TW384208B (en) | 1995-09-22 | 2000-03-11 | Basf Ag | Compositions and methods for controlling harmful fungi |
US5739140A (en) * | 1995-11-03 | 1998-04-14 | Monsanto Company | Selected novel aryl acrylics |
DE19544800A1 (de) * | 1995-12-01 | 1997-06-05 | Bayer Ag | Verfahren zur Herstellung von 1,3-Dimethyl-5-fluor-pyrazol-4-carboxaniliden |
CA2193714A1 (en) * | 1995-12-21 | 1997-06-22 | Wilhelm Rademacher | Encapsulated plant growth regulator formulations and applications |
US5935906A (en) * | 1995-12-21 | 1999-08-10 | Basf Corporation | Aminoethoxyvinylglycine in combination with mepiquat chloride |
US5837653A (en) * | 1995-12-21 | 1998-11-17 | Basf Corporation | Encapsulated plant growth regulator formulations |
AU1373797A (en) * | 1995-12-21 | 1997-07-17 | Basf Corporation | Low rate application of inhibitors of ethylene biosynthesis or action |
DE19615977A1 (de) * | 1996-04-22 | 1997-10-23 | Basf Ag | Mittel und Verfahren zur Bekämpfung von Schadpilzen |
DE19615976A1 (de) * | 1996-04-22 | 1997-10-23 | Basf Ag | Mittel und Verfahren zur Bekämpfung von Schadpilzen |
DE19629825A1 (de) * | 1996-07-24 | 1998-01-29 | Bayer Ag | Dihydrofuran-carboxamide |
DE19629828A1 (de) | 1996-07-24 | 1998-01-29 | Bayer Ag | Carbanilide |
DE19629826A1 (de) * | 1996-07-24 | 1998-01-29 | Bayer Ag | 1,3-Dimethyl-5-fluor-pyrazol-4-carboxamide |
CA2270983A1 (en) | 1996-12-20 | 1998-07-02 | Charles W. Finch | Plant growth regulators in pyrrolidone solvents |
TW460460B (en) * | 1997-11-04 | 2001-10-21 | Chugai Pharmaceutical Co Ltd | Heterocyclic compounds having NOS inhibitory activities |
DE19840322A1 (de) | 1998-09-04 | 2000-03-09 | Bayer Ag | Pyrazol-carboxanilide |
WO2001023358A1 (fr) * | 1999-09-27 | 2001-04-05 | Sagami Chemical Research Center | Derives pyrazole, intermediaires pour la preparation de ces derives, procedes de preparation des derives et intermediaires, et herbicides dont ces derives sont le principe actif |
CN1227235C (zh) * | 1999-12-09 | 2005-11-16 | 辛根塔参与股份公司 | 作为杀菌剂的吡唑羧酰胺和吡唑硫代羧酰胺 |
GB0001447D0 (en) | 2000-01-21 | 2000-03-08 | Novartis Ag | Organic compounds |
WO2002008197A1 (de) | 2000-07-24 | 2002-01-31 | Bayer Cropscience Ag | Biphenylcarboxamide |
HUP0301189A3 (en) | 2000-07-24 | 2003-11-28 | Bayer Cropscience Ag | Pyrazolyl biphenyl carboxamides, intermediates, preparation and use thereof for controlling undesired microorganisms |
KR20030022396A (ko) * | 2000-08-16 | 2003-03-15 | 닛뽕소다 가부시키가이샤 | 피라졸 화합물의 제조방법 |
CA2426033A1 (en) | 2000-11-08 | 2002-05-16 | Syngenta Participations Ag | Pyrrolcarboxamides and pyrrolcarbothioamides and their agrochemical uses |
EP1275301A1 (de) * | 2001-07-10 | 2003-01-15 | Bayer CropScience S.A. | Trisubstituierte heterocyclische Verbindungen und ihre Verwendung als Fungizide |
DE10136065A1 (de) * | 2001-07-25 | 2003-02-13 | Bayer Cropscience Ag | Pyrazolylcarboxanilide |
MXPA04001286A (es) | 2001-08-15 | 2004-05-27 | Du Pont | Arilamidas orto-heterociclicas sustituidas para controlar plagas de invertebrados. |
EP1829865A3 (de) * | 2002-03-05 | 2007-09-19 | Syngeta Participations AG | O-Cyclopropyl-carboxanilide und ihre Verwendung als Fungizide |
DE10219035A1 (de) | 2002-04-29 | 2003-11-13 | Bayer Cropscience Ag | Biphenylcarboxamide |
DE10258314A1 (de) * | 2002-12-13 | 2004-06-24 | Bayer Cropscience Ag | Biphenyloximether |
DE10303589A1 (de) * | 2003-01-29 | 2004-08-12 | Bayer Cropscience Ag | Pyrazolylcarboxanilide |
JP4722829B2 (ja) | 2003-02-14 | 2011-07-13 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | オキサチンカルボキサミド |
EP1628962B1 (de) | 2003-05-21 | 2014-10-01 | Bayer Intellectual Property GmbH | Iodpyrazolylcarboxanilide |
WO2004103953A1 (de) * | 2003-05-21 | 2004-12-02 | Bayer Cropscience Aktiengesellschaft | Difluormethylbenzanilide und deren verwendung zur bekämpfung bon mikroorganismen, sowie zwischen produkte und deren herstellung |
WO2005003077A1 (de) | 2003-07-01 | 2005-01-13 | Bayer Cropscience Aktiengesellschaft | Verfahren zum herstellen von difluoracetessigsäurealkylestern |
DE10331496A1 (de) * | 2003-07-01 | 2005-01-27 | Bayer Cropscience Ag | Verfahren zum Herstellen von Difluoracetessigsäurealkylestern |
EP1656020A2 (de) * | 2003-07-10 | 2006-05-17 | Bayer CropScience AG | Pyridinylanilide |
DE10349502A1 (de) | 2003-10-23 | 2005-05-25 | Bayer Cropscience Ag | 1,3-Dimethylbutylcarboxanilide |
DE10349500A1 (de) * | 2003-10-23 | 2005-06-02 | Bayer Cropscience Ag | Verfahren zum Herstellen von 2-Dihalogenacyl-3-amino-acrylsäureestern und 3-Dihalogenmethyl-pyrazol-4-carbonsäureestern |
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JP2006076990A (ja) | 2004-03-12 | 2006-03-23 | Bayer Cropscience Ag | 殺虫性ベンゼンジカルボキサミド類 |
DE102004012901A1 (de) * | 2004-03-17 | 2005-10-06 | Bayer Cropscience Ag | Silylierte Carboxamide |
KR101274879B1 (ko) | 2004-12-20 | 2013-06-14 | 에자이 알앤드디 매니지먼트 가부시키가이샤 | 1-시클로프로필메틸-4-[2-(3,3,5,5-테트라메틸시클로헥실)페닐]피페라진의 염 및 결정 |
DE102005009457A1 (de) | 2005-03-02 | 2006-09-07 | Bayer Cropscience Ag | Verfahren zum Herstellen von Alkylaniliden |
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AR056882A1 (es) | 2006-02-01 | 2007-10-31 | Bayer Cropscience Sa | Derivados del fungicida n- cicloalquil- bencil- amida |
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KR20110031501A (ko) | 2008-07-21 | 2011-03-28 | 바스프 에스이 | 1,3-이치환된 피라졸카르복실산 에스테르의 제조 방법 |
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CN103360313A (zh) * | 2013-07-12 | 2013-10-23 | 雅本化学股份有限公司 | 3-氟代烷基-1-取代吡唑-4-羧酸及其制备方法 |
WO2015039877A1 (en) * | 2013-09-20 | 2015-03-26 | Bayer Cropscience Ag | Process for preparing 5-fluoro-1-alkyl-3-fluoroalkyl-1h-pyrazole-4-carbaldehyde |
ITMI20132201A1 (it) | 2013-12-23 | 2015-06-24 | Isagro Spa | Processo per la sintesi regioselettiva di pirazoli |
WO2015155713A1 (en) | 2014-04-09 | 2015-10-15 | Isagro S.P.A. | Process for the regioselective synthesis of 1,3, 4 -substituted pyrazoles |
CN106187893B (zh) * | 2015-05-06 | 2019-11-12 | 沈阳中化农药化工研发有限公司 | 一种吡唑酰胺类化合物及其用途 |
WO2017054112A1 (zh) * | 2015-09-28 | 2017-04-06 | 常州市卜弋科研化工有限公司 | 3-氟代烷基-1-甲基吡唑-4-羧酸的制备方法 |
CN108059614B (zh) * | 2016-11-09 | 2020-09-01 | 沈阳中化农药化工研发有限公司 | 吡唑酰胺类化合物及其应用 |
CN108409684B (zh) * | 2018-04-26 | 2022-04-12 | 上海晓明检测技术服务有限公司 | 一种n-(2-环己氧基苯基)酰胺类化合物及其制备方法和应用 |
CN108383791A (zh) * | 2018-04-27 | 2018-08-10 | 上海泰禾国际贸易有限公司 | 一种酰胺类化合物及其制备方法和用途 |
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Publication number | Priority date | Publication date | Assignee | Title |
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AU508225B2 (en) * | 1976-01-14 | 1980-03-13 | Commonwealth Scientific And Industrial Research Organisation | Pyrazole fungicides |
US4134987A (en) * | 1976-01-14 | 1979-01-16 | Huppatz John L | Compounds and compositions |
US4214090A (en) * | 1976-01-14 | 1980-07-22 | Commonwealth Scientific And Industrial Research Organization | Fungicidal carboxamidopyrazoles |
BR8506974A (pt) * | 1984-10-29 | 1986-12-23 | Sumitomo Chemical Co | Derivado pirazolcarboxamida,processo para o seu preparo e fungicida contendo o mesmo como substancia atuante |
JPS62249975A (ja) * | 1986-04-22 | 1987-10-30 | Sumitomo Chem Co Ltd | アニリド誘導体およびそれを有効成分とする殺菌剤 |
US5049575A (en) * | 1988-11-10 | 1991-09-17 | Sumitomo Chemical Company | Substituted carboxylic acid, fungicidal compositions and use |
AU626402B2 (en) * | 1989-04-19 | 1992-07-30 | Sumitomo Chemical Company, Limited | An amide compound and its production and use |
US5093347A (en) * | 1991-01-28 | 1992-03-03 | Monsanto Company | 3-difluoromethylpyrazolecarboxamide fungicides, compositions and use |
IL103614A (en) * | 1991-11-22 | 1998-09-24 | Basf Ag | Carboxamides for controlling botrytis and certain novel such compounds |
-
1992
- 1992-11-05 US US07/967,417 patent/US5223526A/en not_active Expired - Fee Related
- 1992-12-01 SI SI19929200352A patent/SI9200352A/sl unknown
- 1992-12-04 WO PCT/US1992/010509 patent/WO1993011117A1/en active IP Right Grant
- 1992-12-04 CA CA002123122A patent/CA2123122A1/en not_active Abandoned
- 1992-12-04 JP JP5510373A patent/JPH07501549A/ja active Pending
- 1992-12-04 MY MYPI92002233A patent/MY131288A/en unknown
- 1992-12-04 AR AR92323828A patent/AR248397A1/es active
- 1992-12-04 IL IL103988A patent/IL103988A0/xx unknown
- 1992-12-04 TR TR92/1170A patent/TR26592A/xx unknown
- 1992-12-04 MX MX9207038A patent/MX9207038A/es unknown
- 1992-12-04 HU HU9401693A patent/HUT67795A/hu unknown
- 1992-12-04 NZ NZ246269A patent/NZ246269A/en unknown
- 1992-12-04 CZ CZ941260A patent/CZ126094A3/cs unknown
- 1992-12-04 SK SK678-94A patent/SK67894A3/sk unknown
- 1992-12-04 ZW ZW187/92A patent/ZW18792A1/xx unknown
- 1992-12-04 AT AT93900895T patent/ATE149490T1/de active
- 1992-12-04 AU AU32407/93A patent/AU657598B2/en not_active Ceased
- 1992-12-04 DE DE69217997T patent/DE69217997T2/de not_active Expired - Fee Related
- 1992-12-04 EP EP93900895A patent/EP0623113B1/de not_active Expired - Lifetime
- 1992-12-04 BR BR9206869A patent/BR9206869A/pt not_active Application Discontinuation
-
1993
- 1993-01-02 CN CN93100017A patent/CN1078234A/zh active Pending
- 1993-12-30 MD MD94-0085A patent/MD940085A/ro not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
SK67894A3 (en) | 1995-02-08 |
CN1078234A (zh) | 1993-11-10 |
MY131288A (en) | 2007-07-31 |
HU9401693D0 (en) | 1994-09-28 |
CZ126094A3 (en) | 1995-02-15 |
ATE149490T1 (de) | 1997-03-15 |
AR248397A1 (es) | 1995-08-18 |
HUT67795A (en) | 1995-04-28 |
DE69217997D1 (de) | 1997-04-10 |
MD940085A (ro) | 1995-06-30 |
BR9206869A (pt) | 1995-11-28 |
EP0623113A1 (de) | 1994-11-09 |
MX9207038A (es) | 1993-06-01 |
WO1993011117A1 (en) | 1993-06-10 |
AU657598B2 (en) | 1995-03-16 |
SI9200352A (en) | 1993-06-30 |
CA2123122A1 (en) | 1993-06-10 |
US5223526A (en) | 1993-06-29 |
NZ246269A (en) | 1995-07-26 |
ZW18792A1 (en) | 1993-05-12 |
JPH07501549A (ja) | 1995-02-16 |
TR26592A (tr) | 1995-03-15 |
EP0623113B1 (de) | 1997-03-05 |
AU3240793A (en) | 1993-06-28 |
IL103988A0 (en) | 1993-05-13 |
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