DE69101135D1 - Process for the preparation of 2- and 3-phenylalkanes using a catalyst based on a specific mordenite. - Google Patents

Process for the preparation of 2- and 3-phenylalkanes using a catalyst based on a specific mordenite.

Info

Publication number
DE69101135D1
DE69101135D1 DE91401831T DE69101135T DE69101135D1 DE 69101135 D1 DE69101135 D1 DE 69101135D1 DE 91401831 T DE91401831 T DE 91401831T DE 69101135 T DE69101135 T DE 69101135T DE 69101135 D1 DE69101135 D1 DE 69101135D1
Authority
DE
Germany
Prior art keywords
mordenite
phenylalkanes
catalyst based
preparation
specific
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE91401831T
Other languages
German (de)
Other versions
DE69101135T2 (en
Inventor
Bernard Juguin
Jean-Francois Joly
Francis Raatz
Germain Martino
Philippe Caullet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of DE69101135D1 publication Critical patent/DE69101135D1/en
Publication of DE69101135T2 publication Critical patent/DE69101135T2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08Silica
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10Magnesium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16Clays or other mineral silicates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Cosmetics (AREA)

Abstract

Process for the production of a mixture of 2-phenylalkanes and 3-phenylalkanes, in which benzene is reacted with a charge containing at least one linear olefin containing from 9 to 16 carbon atoms in its molecule, in contact with a catalyst based on a mordenite which has an overall Si/Al atomic ratio of between 6 and 100, preferably between 15 and 60, the said mordenite having been prepared from a mordenite synthesised in a fluoride medium. Use of the mixture of 2- and 3-phenylalkanes obtained as a basis for biodegradable detergents. <IMAGE>
DE91401831T 1990-07-31 1991-07-03 Process for the preparation of 2- and 3-phenylalkanes using a catalyst based on a specific mordenite. Expired - Fee Related DE69101135T2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9009878A FR2665436B1 (en) 1990-07-31 1990-07-31 PROCESS FOR PRODUCING 2- AND 3-PHENYLALCANES USING A CATALYST BASED ON A PARTICULAR MORDENITE.

Publications (2)

Publication Number Publication Date
DE69101135D1 true DE69101135D1 (en) 1994-03-17
DE69101135T2 DE69101135T2 (en) 1994-05-11

Family

ID=9399348

Family Applications (1)

Application Number Title Priority Date Filing Date
DE91401831T Expired - Fee Related DE69101135T2 (en) 1990-07-31 1991-07-03 Process for the preparation of 2- and 3-phenylalkanes using a catalyst based on a specific mordenite.

Country Status (6)

Country Link
EP (1) EP0469940B1 (en)
JP (1) JPH04243843A (en)
AT (1) ATE101110T1 (en)
DE (1) DE69101135T2 (en)
ES (1) ES2062723T3 (en)
FR (1) FR2665436B1 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2115015T3 (en) * 1991-12-23 1998-06-16 Uop Inc BENZENE RENTING PROCEDURE USING A SILICON-FLUORATED ALUMINA AND A LINEAR MONOOLEFINE C6 TO C20.
FR2697246B1 (en) * 1992-10-28 1995-01-06 Inst Francais Du Petrole Process for the production of phenylalkanes using a catalyst based on modified Y zeolite.
US5468407A (en) * 1994-11-03 1995-11-21 The Dow Chemical Company Dialkylbenzene monosulfonate collectors useful in ore flotation
CA2297010C (en) 1997-07-21 2003-04-15 Kevin Lee Kott Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof
EP1002030B1 (en) 1997-07-21 2003-05-21 The Procter & Gamble Company Detergent compositions containing mixtures of crystallinity-disrupted surfactants
CZ299604B6 (en) 1997-07-21 2008-09-17 The Procter & Gamble Company Alkylarylsulfonate surfactant system and hand dishwashing composition containing thereof
DE69814400T2 (en) 1997-07-21 2004-03-11 The Procter & Gamble Company, Cincinnati IMPROVED METHOD FOR PRODUCING ALKYLBENZENE SULFONATE TENSIDES AND PRODUCTS OBTAINED FROM THEM
PH11998001775B1 (en) 1997-07-21 2004-02-11 Procter & Gamble Improved alkyl aryl sulfonate surfactants
CN100339343C (en) * 1997-08-08 2007-09-26 普罗格特-甘布尔公司 Improved process for making surfactants via adsorptive separation and products thereof
HUP0104608A3 (en) 1998-10-20 2002-11-28 Procter & Gamble Tenzide mixture comprising modified alkylbenzene sulfonates and laundry detergents containing thereof, and process for preparation of the mixture and for use of the detergents
CN1331737A (en) 1998-10-20 2002-01-16 宝洁公司 Laundry detergents comprising modified alkylbenzene sulfonates
US6498134B1 (en) 1999-01-20 2002-12-24 The Procter & Gamble Company Dishwashing compositions containing alkylbenzenesulfonate surfactants
US6774099B1 (en) 1999-01-20 2004-08-10 The Procter & Gamble Company Dishwashing detergent compositions containing mixtures or crystallinity-disrupted surfactants
EP1022325A3 (en) 1999-01-20 2003-01-02 The Procter & Gamble Company Hard surface cleaning compositions comprising modified alkylbenzene sulfonates
EP1022326A1 (en) 1999-01-20 2000-07-26 The Procter & Gamble Company Hard surface cleaning compositions comprising modified alkylbenzene sulfonates
US7202205B1 (en) 1999-09-01 2007-04-10 Daniel Stedman Connor Processes for making surfactants via adsorptive separation and products thereof
DE10044352A1 (en) * 2000-09-07 2002-03-21 Basf Ag Continuous process for the production of acetals
FR2868418B1 (en) 2004-04-05 2008-08-29 Inst Francais Du Petrole PROCESS FOR THE PRODUCTION OF PHENYLALKANES USING A ZEOLITHIC CATALYST BASED ON SILICA-ALUMINA

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2112223B2 (en) * 1970-03-16 1973-12-20 Universal Oil Products Co., Des Plaines, Ill. (V.St.A.) Process for the production of synthetic mordenite and its use
US4301317A (en) * 1979-11-20 1981-11-17 Mobil Oil Corporation Preparation of 2-phenylalkanes
US4731497A (en) * 1986-12-29 1988-03-15 Atlantic Richfield Company Alkylation of aromatics with alpha-olefins
FR2638157B1 (en) * 1988-10-26 1991-04-19 Inst Francais Du Petrole PROCESS FOR PRODUCING ALKYLBENZENES USING A MODIFIED MORDENITE-BASED CATALYST

Also Published As

Publication number Publication date
EP0469940A1 (en) 1992-02-05
DE69101135T2 (en) 1994-05-11
JPH04243843A (en) 1992-08-31
FR2665436A1 (en) 1992-02-07
FR2665436B1 (en) 1992-10-16
ES2062723T3 (en) 1994-12-16
ATE101110T1 (en) 1994-02-15
EP0469940B1 (en) 1994-02-02

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee