DE66096C - Pay attention to alkaline solutions containing copper - Google Patents
Pay attention to alkaline solutions containing copperInfo
- Publication number
- DE66096C DE66096C DENDAT66096D DE66096DA DE66096C DE 66096 C DE66096 C DE 66096C DE NDAT66096 D DENDAT66096 D DE NDAT66096D DE 66096D A DE66096D A DE 66096DA DE 66096 C DE66096 C DE 66096C
- Authority
- DE
- Germany
- Prior art keywords
- copper
- chloride
- metallic
- solutions containing
- sulphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010949 copper Substances 0.000 title claims description 25
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 16
- 229910052802 copper Inorganic materials 0.000 title claims description 16
- 239000000460 chlorine Substances 0.000 claims description 8
- 239000005751 Copper oxide Substances 0.000 claims description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 7
- 229910000431 copper oxide Inorganic materials 0.000 claims description 7
- 235000002639 sodium chloride Nutrition 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- QLOLFVLPQSFYEU-UHFFFAOYSA-L C([O-])([O-])=O.[Cu+2]=O Chemical compound C([O-])([O-])=O.[Cu+2]=O QLOLFVLPQSFYEU-UHFFFAOYSA-L 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims description 2
- 239000012452 mother liquor Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 2
- 239000003518 caustics Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000003841 chloride salts Chemical class 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 230000001376 precipitating Effects 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- ORTQZVOHEJQUHG-UHFFFAOYSA-L Copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- -1 potassium chloride Chemical compound 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/04—Halides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
KAISERLIGHESKAISERLIGHES
PATENTAMT. \%PATENT OFFICE. \%
KLASSE 40: Hüttenwesen.CLASS 40: Metallurgy.
Um kupferhaltige Laugen, wie solche bei bekannten Hüttenprocessen gewonnen werden, zu verwerthen, verfährt man so:To alkaline solutions containing copper, such as those at known metallurgical processes are obtained, to utilize, one proceeds as follows:
Die Lauge wird, falls das Kupfer als Sulfat enthalten ist, mit einer äquivalenten Menge Kochsalz oder eines anderen Chlorides, wie Chlorkalium, versetzt.If the copper is contained as sulphate, the lye is mixed with an equivalent amount Table salt or another chloride, such as potassium chloride, is added.
Cu SO4 + 2NaCl= Na2 SO4 + Cu Cl2. Cu SO 4 + 2NaCl = Na 2 SO 4 + Cu Cl 2 .
Enthält sie dagegen überschüssiges Kochsalz, so wird sie mit einer diesem überschüssigen Kochsalz entsprechenden Menge Kupfervitriol oder eines analogen Metallsulfats versetzt.If, on the other hand, it contains excess table salt, it becomes excess with one of these Table salt is added to the corresponding amount of vitriol or an analogous metal sulfate.
Hierdurch wird bewirkt, dafs in der Lösung Kupferchlorid neben Glaubersalz ist. Diese Kupferchloridlösung wird nunmehr in einem Rührwerk mit metallischem Kupfer behandelt.This has the effect that copper chloride is in the solution in addition to Glauber's salt. These Copper chloride solution is now treated with metallic copper in a stirrer.
Es entsteht durch die Einwirkung des metallischen Kupfers unlösliches Kupferchlorür, gleichzeitig wird etwa in der Lösung vorhandenes Silber metallisch niedergeschlagen.At the same time, insoluble copper chlorine is created by the action of the metallic copper any silver present in the solution is deposited in a metallic manner.
Cu Cl2 +Cu= Cu2 Cl2 2 Ag Cl2 + 2 Cu = Cm2 Cl2 + 2 Ag. Cu Cl 2 + Cu = Cu 2 Cl 2 2 Ag Cl 2 + 2 Cu = Cm 2 Cl 2 + 2 Ag.
Die zurückbleibende Mutterlauge enthält nur Spuren von Kupfer, geringe Mengen Eisen, Nickel u. s. w. und ist zur Gewinnung von Glaubersalz geeignet. Durch Oxyde, Carbonate, Sulfide u. s. w. können diese Verunreinigungen entfernt und dadurch die Gewinnung eines reinen Salzes gesichert werden.The remaining mother liquor contains only traces of copper, small amounts of iron, Nickel etc. and is suitable for the extraction of Glauber's salt. By oxides, carbonates, Sulphides and the like can remove these impurities and thereby the recovery of a pure salt.
RCl2 RCl 2
Na2S =Na 2 S =
2Na Cl.2Na Cl.
Enthalten die Laugen freie Säure, so wird solche am zweckmäfsigsten durch Kupferoxyd oder Kupferoxydul abgestumpft.If the alkalis contain free acid, it is most expedient to use copper oxide or copper oxide blunted.
Zur Fällung des Kupfers aus den Chloridlaugen kann statt Kupfer auch Kupferoxydul
oder Kupferoxydulcarbonat ganz oder theilweise verwendet werden. Hierdurch werden
auch Eisen, Mangan und sonstige in der Lauge vorhandene Metalle gefällt.
Cu Cl2 + Cu2 (O H)2 = Cu (O H)2 + Cu2 Cl2
Fe Cl2 + Cu2 (O H)2 = Fe (O H)2 + Cu2 Cl2. For the precipitation of copper from the chloride liquors, copper oxide or copper oxide carbonate can also be used in whole or in part instead of copper. This also precipitates iron, manganese and other metals present in the lye.
Cu Cl 2 + Cu 2 (OH) 2 = Cu (OH) 2 + Cu 2 Cl 2 Fe Cl 2 + Cu 2 (OH) 2 = Fe (OH) 2 + Cu 2 Cl 2 .
Das erforderliche Kupferoxydul wird am einfachsten dadurch erzeugt, dafs Kupferchlorür mit Aetzkalk behandelt wird.The easiest way to produce the necessary copper oxide is to use copper chloride is treated with caustic lime.
Die in beschriebener Weise erhaltenen Niederschläge, welche Silber, Kupfer, Kupferoxydul, Kupferchlorür, Kupferoxyd u. s. w. enthalten können, werden in geeigneter Weise derart in Form von Kupferchlorür gelöst, dafs diese Lösung frei wird von Silber, Wismuth, Arsen-Antimon. Dieselbe wird sodann an den Kathoden eines elektrolytischen Bades auf reines Kupfer verarbeitet.The precipitates obtained in the manner described, which contain silver, copper, copper oxide, Copper chloride, copper oxide and the like are suitably used in this way in Dissolved in the form of copper chloride, so that this solution becomes free of silver, bismuth, arsenic-antimony. It is then applied to pure copper on the cathodes of an electrolytic bath processed.
Auch können die erhaltenen Kupferniederschläge bezw. deren Lösungen mit Aetzkalk behandelt und das erhaltene Oxyd oder Oxydul auf trockenem Wege zu Gute gemacht werden. Cm2 Cl2 + Ca (OH)2 — Cu2 (OH)2 + Ca Cl2. The copper deposits obtained can also bezw. the solutions of which are treated with quicklime and the oxide or oxide obtained is made good by dry means. Cm 2 Cl 2 + Ca (OH) 2 - Cu 2 (OH) 2 + Ca Cl 2 .
Selbstverständlich können die betreffenden Niederschläge oder deren Lösungen auch durch Eisen oder andere Metalle reducirt werden.Of course, the precipitates in question or their solutions can also through Iron or other metals are reduced.
Claims (1)
Bei diesem Verfahren der Entkupferung von Laugen die vollständige oder theilweise Ersetzung des als Fällungsmittel wirkenden metallischen Kupfers durch Kupferoxydul oder Kupferoxydulcarbonat.of table salt or other chlorides, e.g. B. potassium chloride, on the other hand, after an adverse effect of chloride (alkali chloride) was present, an equivalent amount of copper sulphate was added to the latter, the possibly present silver is precipitated metallic by metallic copper, the copper on the other hand is precipitated as chlorine, after which the remaining mother liquor, which can also be purified by oxides or sulphides and, in particular, made iron-free, so that the alkali sulphate contained therein can be processed.
In this process of copper removal from alkalis, the complete or partial replacement of the metallic copper, which acts as a precipitating agent, by copper oxide or copper oxide carbonate.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE66096C true DE66096C (en) | 1900-01-01 |
Family
ID=339832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT66096D Expired DE66096C (en) | Pay attention to alkaline solutions containing copper |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE66096C (en) |
-
0
- DE DENDAT66096D patent/DE66096C/en not_active Expired
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2629240C2 (en) | Process for the extraction of non-ferrous metals from sulphidic materials | |
| DE66096C (en) | Pay attention to alkaline solutions containing copper | |
| DE3402196A1 (en) | METHOD FOR RECOVERING SMALL BATTERIES | |
| US6861037B1 (en) | Method of removal of impurities from gold concentrate containing sulfides | |
| DE100242C (en) | ||
| DE432516C (en) | Process for opening up zinc blende | |
| DE366486C (en) | Process for the extraction of zinc in addition to lead, copper, silver, gold from poor zinc-lead ores etc. like | |
| DE395434C (en) | Process for the preparation of copper chlorine solution | |
| DE268142C (en) | ||
| DE3343541C2 (en) | Process for the separate extraction of metal chlorides from complex copper ores | |
| DE86543C (en) | ||
| DE356531C (en) | Process for the production of pure nickel from impure nickel vitriol | |
| DE543346C (en) | Process for dechlorinating lyes from chlorinated roasted gravel and similarly composed solutions with recovery of all metals and usable salts by means of a circular process | |
| DE62449C (en) | Process for precipitation respectively. Cementation of copper | |
| DE449635C (en) | Treatment of ores and concentrates | |
| DE138028C (en) | ||
| DE488582C (en) | Processing of lyes from sulfur pebbles and similar ores with recovery of the metals contained in the lyes | |
| DE165869C (en) | ||
| DE78159C (en) | Process for separating zinc sulphide from zinc and silver-containing galena | |
| DE633019C (en) | Process for the rusting off of sulphidic ores, preferably complex zinc and copper ores | |
| DE284741C (en) | ||
| AT66303B (en) | Process for sulphating sulphurous, oxidic, carbonic or other ores. | |
| AT50612B (en) | Process for separating copper and other metals from liquids obtained from wet metallurgical processes. | |
| DE508508C (en) | Extraction of copper and zinc from lyes of chlorinated roasted ores | |
| AT113661B (en) | Process for the extraction of the valuable components from chlorinating roasted gravel burns. |