DE60208907D1 - Neuer mehrkerniger halbmetallocen-katalysator und herstellung von styrolpolymeren unter dessen anwendung - Google Patents

Neuer mehrkerniger halbmetallocen-katalysator und herstellung von styrolpolymeren unter dessen anwendung

Info

Publication number
DE60208907D1
DE60208907D1 DE60208907T DE60208907T DE60208907D1 DE 60208907 D1 DE60208907 D1 DE 60208907D1 DE 60208907 T DE60208907 T DE 60208907T DE 60208907 T DE60208907 T DE 60208907T DE 60208907 D1 DE60208907 D1 DE 60208907D1
Authority
DE
Germany
Prior art keywords
catalyst
preparing
ligand
half metallocene
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60208907T
Other languages
English (en)
Other versions
DE60208907T2 (de
Inventor
Min-Hyung Lee
You-Mi Jeong
Jin-Young Ryu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Chem Ltd
Original Assignee
LG Chem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Publication of DE60208907D1 publication Critical patent/DE60208907D1/de
Application granted granted Critical
Publication of DE60208907T2 publication Critical patent/DE60208907T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE60208907T 2001-07-11 2002-07-11 Neuer mehrkerniger halbmetallocen-katalysator und herstellung von styrolpolymeren unter dessen anwendung Expired - Fee Related DE60208907T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-2001-0041580A KR100440482B1 (ko) 2001-07-11 2001-07-11 새로운 다중핵 반쪽 메탈로센 촉매
KR2001041580 2001-07-11
PCT/KR2002/001317 WO2003006473A1 (en) 2001-07-11 2002-07-11 Novel multinuclear half metallocene catalyst and preparation of styrene polymer using the same

Publications (2)

Publication Number Publication Date
DE60208907D1 true DE60208907D1 (de) 2006-04-13
DE60208907T2 DE60208907T2 (de) 2006-09-21

Family

ID=36089193

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60208907T Expired - Fee Related DE60208907T2 (de) 2001-07-11 2002-07-11 Neuer mehrkerniger halbmetallocen-katalysator und herstellung von styrolpolymeren unter dessen anwendung

Country Status (8)

Country Link
US (1) US6894129B2 (de)
EP (1) EP1404690B1 (de)
JP (1) JP4157033B2 (de)
KR (1) KR100440482B1 (de)
CN (1) CN1203082C (de)
AT (1) ATE316534T1 (de)
DE (1) DE60208907T2 (de)
WO (1) WO2003006473A1 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100503359B1 (ko) * 2002-10-16 2005-07-26 주식회사 엘지화학 스티렌 중합체 제조용 메탈로센 촉매 및 이를 이용한스티렌 중합체의 제조방법
EP1582536A1 (de) * 2004-03-31 2005-10-05 Total Petrochemicals Research Feluy Herstellung von Styrol-Homopolymeren und Styrol-Ethylen-Copolymeren
KR100771351B1 (ko) * 2004-08-12 2007-10-29 주식회사 엘지화학 새로운 반쪽 메탈로센 촉매 및 이를 이용한 신디오탁틱폴리스티렌 제조방법
CN101088178B (zh) * 2004-12-30 2010-09-29 E.I.内穆尔杜邦公司 有机金属配合物
CN1955200B (zh) * 2005-10-26 2011-08-31 Lg化学株式会社 多核半金属茂催化剂和使用该多核半金属茂催化剂制备间同立构聚苯乙烯的方法
US7592401B2 (en) 2005-10-27 2009-09-22 Lg Chem, Ltd. Multinuclear half metallocene catalyst and method for preparing syndiotatic polystyrene using the same
US8470208B2 (en) 2006-01-24 2013-06-25 E I Du Pont De Nemours And Company Organometallic complexes
TW201033327A (en) * 2008-12-12 2010-09-16 Du Pont Photoactive composition and electronic device made with the composition
US8617720B2 (en) 2009-12-21 2013-12-31 E I Du Pont De Nemours And Company Electroactive composition and electronic device made with the composition
KR101788558B1 (ko) * 2017-06-14 2017-10-23 주식회사 유피케미칼 4 족 금속 원소-함유 알콕시 화합물, 이의 제조 방법, 이를 포함하는 막 증착용 전구체 조성물, 및 이를 이용하는 막의 증착 방법
CN109957054A (zh) * 2019-03-25 2019-07-02 广州大学 一种粒径可控的单分散性纳米级聚苯乙烯微球的制备方法

Family Cites Families (14)

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Publication number Priority date Publication date Assignee Title
CA1276748C (en) 1985-07-29 1990-11-20 Michitake Uoi Styrene polymers
JP2911501B2 (ja) 1989-09-29 1999-06-23 出光興産株式会社 スチレン系重合体の製造方法
JPH04314790A (ja) 1991-04-12 1992-11-05 Nippon Oil Co Ltd 食品機械用油脂組成物
US5972822A (en) * 1994-08-02 1999-10-26 The Dow Chemical Company Biscyclopentadienyldiene complex containing addition polymerization catalysts
US6010972A (en) 1996-04-15 2000-01-04 Kimberly-Clark Worldwide, Inc. Oil-resistant disposable absorbent product
KR19980072719A (ko) 1997-03-07 1998-11-05 박홍기 스티렌 중합용 탄소 및/또는 규소 다리화 두금속 메탈로센 촉매, 및 이를 이용한 스티렌 중합방법
US6235917B1 (en) 1998-08-28 2001-05-22 The Dow Chemical Company Dinuclear complexes and polymerization catalysts therefrom
KR100301135B1 (ko) * 1998-02-04 2001-10-27 유현식 스티렌중합용신규메탈로센촉매및그제조방법
KR100287955B1 (ko) 1998-06-08 2001-05-02 유현식 올레핀계 또는 스티렌계 중합용 신규 메탈로센 촉매 및 이를 이용한 중합방법
US6228790B1 (en) * 1998-06-29 2001-05-08 Industrial Technology Research Institute Dinuclear metallocene catalyst for preparing high molecular weight olefin polymer
KR100367463B1 (ko) * 1999-03-03 2003-01-14 주식회사 엘지화학 메탈로센 화합물 및 이를 이용한 올레핀 중합
KR100354290B1 (ko) * 1999-06-22 2002-09-28 주식회사 엘지화학 담지 메탈로센 촉매 및 이를 이용한 올레핀 중합
KR100365869B1 (ko) * 2000-08-05 2002-12-27 호남석유화학 주식회사 메탈로센 화합물 및 이를 사용하는 중합방법
KR100422940B1 (ko) * 2000-12-23 2004-03-12 주식회사 엘지화학 하프 메탈로센 촉매 및 이를 이용한 입체규칙성을 가진비닐 방향족 중합체의 제조방법

Also Published As

Publication number Publication date
KR100440482B1 (ko) 2004-07-14
CN1203082C (zh) 2005-05-25
US20040048737A1 (en) 2004-03-11
DE60208907T2 (de) 2006-09-21
US6894129B2 (en) 2005-05-17
EP1404690B1 (de) 2006-01-25
JP2004536124A (ja) 2004-12-02
JP4157033B2 (ja) 2008-09-24
CN1464879A (zh) 2003-12-31
EP1404690A1 (de) 2004-04-07
KR20030006040A (ko) 2003-01-23
WO2003006473A1 (en) 2003-01-23
ATE316534T1 (de) 2006-02-15

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Legal Events

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8339 Ceased/non-payment of the annual fee