DE595014C - Process for the production of phenol-aldehyde resins which harden faster in the cold - Google Patents

Process for the production of phenol-aldehyde resins which harden faster in the cold

Info

Publication number
DE595014C
DE595014C DE1930595014D DE595014DA DE595014C DE 595014 C DE595014 C DE 595014C DE 1930595014 D DE1930595014 D DE 1930595014D DE 595014D A DE595014D A DE 595014DA DE 595014 C DE595014 C DE 595014C
Authority
DE
Germany
Prior art keywords
phenol
cold
production
aldehyde resins
harden
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE1930595014D
Other languages
German (de)
Inventor
Dr Karl Dietz
Dipl-Ing Karl Frank
Dr Franz Privinsky
Dr Emil Thiel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority claimed from DEI45176D external-priority patent/DE596409C/en
Application granted granted Critical
Publication of DE595014C publication Critical patent/DE595014C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Description

Verfahren zur Herstellung von in der Kälte schnellerhärtenden Phenol-Aldehyd-Harzen Es ist bekannt. Ph enol-Alclehyd-Harze, welche :erst so weit kondensiert sind, daß sie sich noch il flüssigem Zustand befinden, zu säurefesten Aüslleidungen und Bekleidungen von Apparateei und zur Herstellung von Säurebauten -und Anstrichfarben zu verwenden. Bisher wurden diese flüssigen Kunstharze entweder durch Wärme oder durch Säure oder saure Salze gehärtet bzw. zu Ende kondensiert. Auch die Verwendung von basischen Stoffen als Zusatzstoffe für Phen.ol-Aldehyd-Harze, um deren Erhärten in der Kälte herbeizuführen, ist bereits bekannt.Process for the production of phenol-aldehyde resins which harden faster in the cold It is known. Ph enol-Alclehyd resins, which: are only condensed so far that they are still in a liquid state, to acid-resistant clothes and garments of apparatus and for the production of acidic structures and paints to be used. Up until now, these liquid synthetic resins were produced either by heat or by acid or acid salts hardened or condensed to the end. Also the use of basic Substances as additives for phenol-aldehyde resins, in order to harden them in the cold to bring about is already known.

Es wurde nun gefunden, daß man diese flüssigen Kunstharze auch durch Zusatz von gegen, Wasser neutral reagierenden Metalldioxyden, in der Kälte härten kann. Dies ist vor allen Dingen für die Herstellung von säurefesten Auskleidungen und Bauten wertvoll, da man: hierfür naturgemäß keine so säureempfindlichen Materialien, wie basische Zusatzstoffe benutzen kann und andererseits das Arbeiten mit neutralen kondensationsmitteln keine Belästigung für Arbeiter und keine Beschädigung des zu schützenden Materials durch Säuren mit sich bringt.It has now been found that these liquid synthetic resins can also be used Addition of metal dioxides, which react neutrally to water, harden in the cold can. This is especially important for the production of acid-proof linings and buildings are valuable because: naturally there are no materials that are so sensitive to acid, how to use basic additives and on the other hand working with neutral ones condensation agents no nuisance to workers and no damage to the too protective material by acids.

Die neutralen Metalldioxyde werden entweder für sich allein oder in Verbindung mit Füllstoffen, gegebenenfalls. außerdem -noch unter Zusatz gut wärmeleitender Materialien, wie beispielsweise Silicium, Siliciumlegierungen und Graphit den flüssigen Phenol-Aldehyd-Harzen beigemischt. Die Erhärtung der Masseil erfolgt bei gewöhnlicher Temperatur und wird bereits; durch verhältnismäßig geringe Mengen der Zusatzstoffe erreicht. Die mit solchen Massen hergestellten Kittangen, oder Verputze sind fest, hart und widerstandsfähig gegen Druck, Reibung und gegen Säureangriff. Ein besonderer Vorteil. gegenüber den, durch saure Zusatzstoffe erhärtenden Kunstmassen besteht darin, daß mit diesen: neuen Mischungen auch auf Metallflächen gearbeitet werden kann, da diese nicht angegriffen. werden.The neutral metal dioxides are either on their own or in Connection with fillers, if appropriate. in addition, with the addition of good thermal conductivity Materials such as silicon, silicon alloys and graphite are the liquid ones Phenol-aldehyde resins mixed in. The hardening of the masseil takes place with ordinary Temperature and is already; due to relatively small amounts of the additives achieved. The putty bars or plasters made with such masses are solid, hard and resistant to pressure, friction and acid attack. A special Advantage. compared to the synthetic masses hardened by acidic additives in the fact that these new mixtures can also be used on metal surfaces can, as this is not attacked. will.

Beispiel. z5 Teile Bleidioxyd oder Mangandioxyd, ¢o Teile feine amorphe Kieselerde und ¢o Teile Quarzmehl werden zusammengemischt und dann. mit flüssigem Phenol-Aldehyd-Harz zu einer plastischen, gut verarbeitbaren Mörtelmasse vermengt, die zuverlässig innerhalb 48 Stunden erstarrt.Example. z5 parts lead dioxide or manganese dioxide, ¢ o parts fine amorphous Silica and ¢ o parts of quartz flour are mixed together and then. with liquid Phenol-aldehyde resin mixed into a plastic, easily workable mortar mass, which solidifies reliably within 48 hours.

Claims (2)

PATENTANSPRÜCHE -. t. Verfahren zur Herstellung von in der Kälte schnell erhärtenden Phenol-Aldehyd-Harzen, dadurch gekennzeichnet, daß man gegen Wasser neutral reagierende Metalldioxyde einem Phenol-Aldehyd-Harz zusetzt, welches erst so weit kondensiert ist, daß es sich noch in flüssigem Zustand befindet. PATENT CLAIMS -. t. Method of making in the cold quickly hardening phenol-aldehyde resins, characterized in that man Adds metal dioxides that react neutrally to water to a phenol-aldehyde resin, which has only condensed so far that it is still in a liquid state. 2. Verfahren nach Anspruch r, dadurch gekennzeichnet, daß den Metalldioxyden noch säurefeste Füllstoffe, welche gegebenenfalls auch wärmeleitend sind, beigemengt werden.2. The method according to claim r, characterized in that the metal dioxides still acid-resistant fillers, which are optionally also thermally conductive, added will.
DE1930595014D 1930-06-07 1930-06-07 Process for the production of phenol-aldehyde resins which harden faster in the cold Expired DE595014C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE595014T 1930-06-07
DEI45176D DE596409C (en) 1930-06-07 1930-07-22 Process for the production of phenol-aldehyde resins which harden quickly in the cold

Publications (1)

Publication Number Publication Date
DE595014C true DE595014C (en) 1934-03-26

Family

ID=41009822

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1930595014D Expired DE595014C (en) 1930-06-07 1930-06-07 Process for the production of phenol-aldehyde resins which harden faster in the cold

Country Status (1)

Country Link
DE (1) DE595014C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE748697C (en) * 1935-02-01 1944-11-09 Hermann Frenkel Fa Method of painting wood using phenol-formaldehyde synthetic resin paints
DE865197C (en) * 1937-11-25 1953-01-29 Hoechst Ag Process for the production of masses that harden in the cold
DE964476C (en) * 1935-07-19 1957-05-23 Elastic Stop Nut Corp Pressed reflector, especially for traffic signs

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE748697C (en) * 1935-02-01 1944-11-09 Hermann Frenkel Fa Method of painting wood using phenol-formaldehyde synthetic resin paints
DE964476C (en) * 1935-07-19 1957-05-23 Elastic Stop Nut Corp Pressed reflector, especially for traffic signs
DE865197C (en) * 1937-11-25 1953-01-29 Hoechst Ag Process for the production of masses that harden in the cold

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