DE588376C - Surface-active substances - Google Patents
Surface-active substancesInfo
- Publication number
- DE588376C DE588376C DEH133526D DEH0133526D DE588376C DE 588376 C DE588376 C DE 588376C DE H133526 D DEH133526 D DE H133526D DE H0133526 D DEH0133526 D DE H0133526D DE 588376 C DE588376 C DE 588376C
- Authority
- DE
- Germany
- Prior art keywords
- substances
- unsaponifiable
- residues
- active substances
- fatty acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000013543 active substance Substances 0.000 title claims 2
- 239000000126 substance Substances 0.000 claims description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- 238000004821 distillation Methods 0.000 claims description 6
- 238000005292 vacuum distillation Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000344 soap Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002674 ointment Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000021588 free fatty acids Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000002884 skin cream Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- -1 pomades Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000008257 shaving cream Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Description
Oberflächenaktive Stoffe Die Vakuumdestillation von durch Spaltung von Fetten gewonnenen Fettsäuren wird technisch in weitestem Maße ausgeübt. Für die bei dieser Destillation anfallenden Rückstände ist jedoch eine nutzbringende Verwendung in größeren Mengen bisher noch nicht gefunden worden; sie stellen im Gegenteil ein lästiges Abfallprodukt dar.Surfactants The vacuum distillation of by cleavage Fatty acids obtained from fats are practiced to the greatest extent technically. For the residue resulting from this distillation is, however, a beneficial one Use in larger quantities has not yet been found; they put in On the contrary, it is an annoying waste product.
Es wurde nun gefunden, daß die aus diesen Rückständen erhältlichen unverseifbaren Stoffe ein wertvolles Zusatzmittel zu kolloiden Massen darstellen. Solche Massen sind beispielsweise: Seifen, Seifenpulver, Rasierkreme, kosmetische Präparate, Hautkreme, Schmiermittel und ähnliche Emulsionen, ferner Bohnermassen, Poliermittel, Pomaden, Salben, Desinfektionsmittel, Schlichten, Appreturmittel, Klebstoffe u. dgl. It has now been found that those obtainable from these residues unsaponifiable substances represent a valuable additive to colloidal masses. Such masses are, for example: soaps, soap powder, shaving cream, cosmetic Preparations, skin creams, lubricants and similar emulsions, as well as polishing compounds, Polishing agents, pomades, ointments, disinfectants, sizing agents, finishing agents, Adhesives and the like
Der Zusatz der genannten unverseifbaren Stoffe wirkt sich in verschiedener Beziehung vorteilhaft aus. So besitzen die genannten Stoffe beispielsweise überfettende Eigenschaften, so daß sie von günstigem Einfluß auf die menschliche Haut sind. The addition of the mentioned unsaponifiable substances has different effects Relationship beneficial. The substances mentioned, for example, have excessively fatty substances Properties so that they have a beneficial influence on human skin.
Es wurde weiter ermittelt, daß die unverseifbaren Stoffe aus den Rückständen der Fettsäuredestillation in so bemerkenswertem Maße emulgierende und emulsionsstabilisierende Eigenschaften besitzer, daß es mit ihrer Hilfe gelingt, in weitgehendem Maße Stoffe, die sonst nicht oder nur schwer beispielsweise mit Wasser emulgierbar sind, in Emulsionen überzuführen. So sind die genannten Stoffe wegen ihres außerordentlich hohen Wasserbindungsvermögens unter anderem bei der Herstellung von Hautcremen, Bohnermassen, Poliermitteln, Pomaden, Salben usw. von besonderem Wert. It was further determined that the unsaponifiable substances from the Residues of fatty acid distillation to such a remarkable extent emulsifying and possesses emulsion-stabilizing properties that with their help it is possible to to a large extent substances that are otherwise difficult or impossible to use, for example Water can be emulsified to be converted into emulsions. So are the substances mentioned because of their extraordinarily high water-binding capacity, among other things in the Manufacture of skin creams, polishes, polishes, pomades, ointments, etc. by special value.
Die Verwendung der genannten Stoffe ist namentlich in wirtschaftlicher Beziehung von großer Bedeutung, ~weil auf diese Weise ein bisher wenig benutztes, lästiges Abfallprodukt zur Herstellung hochwertiger Präparate verwertet wird. The use of the substances mentioned is particularly economical Relationship of great importance, ~ because in this way a hitherto little used, annoying waste product is used for the production of high-quality preparations.
Die Herstellung der genannten Stoffgemische kann in einfacher Weise erfolgen, indem man den Massen zu einem beliebigen Zeitpunkt ihrer Zubereitung geeignete Mengen der unverseifbaren Stoffe aus den Destillationsrückständen einverleibt. Beispielsweise können diese Stoffe den Ausgangsstoffen beigegeben oder etwaigen Lösungsmitteln beigemengt werden. The above-mentioned mixtures of substances can be produced in a simple manner be done by adding the masses at any time of their preparation appropriate Incorporated quantities of unsaponifiable substances from the still residues. For example these substances can be added to the starting materials or any solvents be added.
Beispiele I. IOO Teile des aus den Destillationsrückständen gewonnenen Unverseifbaren werden unter gelindem Erwärmen mit 400 Teilen Unguentum Paraffini oder Vaseline gemischt und zu einer gleichmäßigen Paste verrieben. Examples I. 100 parts of that obtained from the still bottoms Unsaponifiables are made with 400 parts of Unguentum Paraffini by gentle heating or Vaseline mixed and rubbed into an even paste.
Durch Zusatz von Wasser lassen sich aus dieser Mischung Creme mit einem Wassergehalt von 50 01o und mehr herstellen.By adding water, this mixture can be turned into a cream produce a water content of 50 01o and more.
2. In eine normale Toiletteseife wird I 01o der aus den Fettsäuredestillationsrückständen gewonnenen unverseifbaren Bestandteile in üblicher Weise einpiliert. Die erhaltene Seife zeichnet sich durch einen dichten, sahnigen Schaum beim Waschen aus und besitzt eine angenehme kosmetische Wirkung auf die Haut. 2. In a normal toilet soap, I 01o is made from the fatty acid distillation residues obtained unsaponifiable constituents piled in in the usual way. The received Soap is characterized by a thick, creamy foam when washed and has a pleasant cosmetic effect on the skin.
3. Ein ausgezeichnetes Bohnerwachs unter Verwendung des Unverseifbaren aus den Fettsäuredestillationsrückständen wird nach folgendem Ansatz auf an sich bekannte Weise erhalten: 15 kg Paraffin, 7,5 kg Unverseifbares, o 7,5 5 kg Carnaubawachs, 35 kg Terpentinöl und 36 kg Sangajol. 3. An excellent floor wax using unsaponifiables the fatty acid distillation residues become per se according to the following approach known way: 15 kg paraffin, 7.5 kg unsaponifiable, o 7.5 5 kg carnauba wax, 35 kg turpentine oil and 36 kg sangajol.
Das fertige Wachs wird bei einer Temperatur von O ausgegossen. The finished wax is poured out at a temperature of 0.
Es ist bereits bekannt, Stearinpeche, -goudron u. dgl., die neben Asphalten noch Neutralfett, freie Fettsäuren mit hohem Gehalt an Oxysäure und deren Derivaten, ferner Ketone, Kohlenwasserstoffe, Fettalkohole u. dgl. enthalten, zur Herstellung von Dachpappen, Walzenfetten, Kabelisolierstoffen, Kautschukersatzstoffen, Tränkmassen, wasserdichten Anstrichmassen u. dgl. zu verwenden. Demgegenüber werden gemäß der vorliegenden Erfindung die unverseifbaren Stoffe aus den Rückständen, die sich bei der Vakuumdestillation von Fettsäuren ergeben, zur Herstellung anderer, hochwertiger Produkte verwe9det. It is already known, stearin pitch, goudron and the like Asphaltenes still neutral fat, free fatty acids with a high content of oxyacids and their Derivatives, also ketones, hydrocarbons, fatty alcohols and the like. Contain for Production of roofing felt, roller grease, cable insulation materials, rubber substitutes, To use impregnating compounds, waterproof coating compounds and the like. Be opposed to this according to the present invention the unsaponifiable substances from the residues, resulting from the vacuum distillation of fatty acids, for the production of other, high quality products.
Die unverseifbaren Stoffe können aus den Vakuumdestillationsrückständen der Fettsäuren z. B. dadurch erhalten werden, daß man die in den Rückständen enthaltenen verseifbaren Fettstoffe in die Kalksalze überführt und das Unverseifbare hieraus mittels an sich bekannter Lösungsmittel, so z. B. mit Aceton, auszieht. The unsaponifiable substances can be extracted from the vacuum distillation residues of fatty acids z. B. can be obtained by the fact that one contained in the residues saponifiable fatty substances are transferred into the lime salts and the unsaponifiable from this by means of known solvents, such. B. with acetone, takes off.
Die unverseifbaren Stoffe unterscheiden sich von den Destillationsrückständen der Fettsäuren durch ihre hellere Farbe und durch das Fehlen der freien Fettsäuren. Sie können daher vorteilhaft zur Herstellung hochwertiger Produkte verwendet werden. The unsaponifiable substances differ from the distillation residues of fatty acids due to their lighter color and the lack of free fatty acids. They can therefore be used advantageously for the production of high-quality products.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH133526D DE588376C (en) | 1932-10-06 | 1932-10-06 | Surface-active substances |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH133526D DE588376C (en) | 1932-10-06 | 1932-10-06 | Surface-active substances |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE588376C true DE588376C (en) | 1933-11-17 |
Family
ID=7176864
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEH133526D Expired DE588376C (en) | 1932-10-06 | 1932-10-06 | Surface-active substances |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE588376C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2444357A (en) * | 1944-11-25 | 1948-06-29 | Lockheed Aircraft Corp | Lubricant for drills and cutting tools |
-
1932
- 1932-10-06 DE DEH133526D patent/DE588376C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2444357A (en) * | 1944-11-25 | 1948-06-29 | Lockheed Aircraft Corp | Lubricant for drills and cutting tools |
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