DE550156C - Production of potassium bicarbonate or potassium carbonate - Google Patents
Production of potassium bicarbonate or potassium carbonateInfo
- Publication number
- DE550156C DE550156C DEA53017D DEA0053017D DE550156C DE 550156 C DE550156 C DE 550156C DE A53017 D DEA53017 D DE A53017D DE A0053017 D DEA0053017 D DE A0053017D DE 550156 C DE550156 C DE 550156C
- Authority
- DE
- Germany
- Prior art keywords
- potassium
- bicarbonate
- production
- carbonate
- potassium carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
- C01D7/02—Preparation by double decomposition
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Description
Herstellung von Kaliumbicarbonat bzw. Kaliumcarbonat Bekanntlich stellt man Kaliumcarbonat hauptsächlich nach dem Magnesiumverfahren oder aus mit Hilfe der Elektrolyse gewonnenem Ätzkali dar. Im folgenden wird ein neues Verfahren zur Erzeugung von Kaliumbicarbonat bzw. Kaliumcarbonat beschrieben.Production of potassium bicarbonate or potassium carbonate is known to represent one potassium carbonate mainly after the magnesium process or from with the help the electrolysis obtained caustic potash. The following is a new method for Described generation of potassium bicarbonate or potassium carbonate.
Läßt man Ammonbicarbonat oder Ammoncarbonat auf sekundäres Kaliumorthophosphat in wäßriger Lösung einwirken, so erhält man als Bodenkörper Kaliumbicarbonat und Kaliumcarbonat oder ein Gemisch dieser. Die miteinander reagierenden -Substanzen können auch als Bodenkörper vorhanden sein. Nach dem Absondern des entstandenen Bodenkörpers enthält die Mutterlauge alles P;; O, neben etwas Ammoniak und Kohlensäure. Diese Lauge kann in den im Patent 540 077 beschriebenen Prozeß eingeführt werden oder z. B. nach dem Eindampfen als Düngemittel Verwendung finden.If ammonium bicarbonate or ammonium carbonate is allowed to act on secondary potassium orthophosphate in aqueous solution, potassium bicarbonate and potassium carbonate or a mixture of these are obtained as the sediment. The substances that react with one another can also be present as soil bodies. After the resulting sediment has been separated off, the mother liquor contains all of the P ;; Oh, next to some ammonia and carbonic acid. This liquor can be introduced into the process described in patent 540 077 or e.g. B. can be used as fertilizer after evaporation.
Beispiel Mol sekundäres Kaliumorthophosphat wurde in 25 ccm Wasser von t$° C gelöst, '/", Mol Ammoniumbicarbonat zugegeben und gerührt. Nach einiger Zeit wurde der Bodenkörper abfiltriert. Sein Gewicht betrug etwa 5 g. Er bestand zu 9.4 °/" aus Kaliumbicarbonat und zu 6 "/" aus Pottasche. Das Kaliumbicarbonat kann auf bekannte Weise in Pottasche verwandelt werden. Der Umsatz verläuft etwa nach KZHP04 -f- (NHa)2COa -'t- 2 H20 - KHC03 --F KH,P04 + 2 NH40H, wobei die Bildung von K=C03 nicht berücksichtigt ist.Example mole of secondary potassium orthophosphate was added to 25 cc of water of t $ ° C dissolved, '/ ", mol of ammonium bicarbonate added and stirred. After a few Time the sediment was filtered off. Its weight was about 5 g. He passed 9.4 ° / "from potassium bicarbonate and 6" / "from potash. The potassium bicarbonate can be transformed into potash in a known way. The turnover is about according to KZHP04 -f- (NHa) 2COa -'t- 2 H20 - KHC03 --F KH, P04 + 2 NH40H, whereby the formation of K = C03 is not taken into account.
Man kann in geschlossenen oder offenen Gefäßen arbeiten und die etwa entweichenden, Ammoniak und Kohlensäure enthaltenden Gase und Dämpfe auffangen und verarbeiten. Auch kann man unter einem Überdruck von Kohlensäure oder Ammoniak arbeiten.You can work in closed or open vessels and that about collect escaping gases and vapors containing ammonia and carbonic acid and to process. You can also work under excess pressure of carbonic acid or ammonia.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEA53017D DE550156C (en) | 1928-01-18 | 1928-01-18 | Production of potassium bicarbonate or potassium carbonate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEA53017D DE550156C (en) | 1928-01-18 | 1928-01-18 | Production of potassium bicarbonate or potassium carbonate |
Publications (1)
Publication Number | Publication Date |
---|---|
DE550156C true DE550156C (en) | 1932-05-06 |
Family
ID=6938771
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEA53017D Expired DE550156C (en) | 1928-01-18 | 1928-01-18 | Production of potassium bicarbonate or potassium carbonate |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE550156C (en) |
-
1928
- 1928-01-18 DE DEA53017D patent/DE550156C/en not_active Expired
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