DE502908C - Process for the production of gases rich in hydrogen sulfide from aqueous solutions of alkali carbonate, bicarbonate and sulfhydrate - Google Patents
Process for the production of gases rich in hydrogen sulfide from aqueous solutions of alkali carbonate, bicarbonate and sulfhydrateInfo
- Publication number
- DE502908C DE502908C DEO18194A DEO0018194A DE502908C DE 502908 C DE502908 C DE 502908C DE O18194 A DEO18194 A DE O18194A DE O0018194 A DEO0018194 A DE O0018194A DE 502908 C DE502908 C DE 502908C
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen sulfide
- sulfhydrate
- bicarbonate
- carbon dioxide
- aqueous solutions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/167—Separation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/12—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
- C10K1/122—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors containing only carbonates, bicarbonates, hydroxides or oxides of alkali-metals (including Mg)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
Description
Verfahren zur Gewinnung von an Schwefelwasserstoff reichen Gasen an wässerigen Lösungen von Alkalicarbonat, -bicarbonat und -sulfhydrat Gegenstand der Erfindung ist ein Verfahren zur Gewinnung von an Schwefelwasserstoff reichen Gasen aus wässerigen Lösungen von Alkalicarbonat, -bicarbonat und -sulfhydrat. Derartige Lösungen fallen beispielsweise an, wenn schwefelwasserstoffhaltige Gase mit einer Alkalicarbonatlösung behandelt werden; zur restlosen Ausscheidung des Schwefelwasserstoffes ist naturgemäß ein gewisser Überschuß von Alkalicarbonat erforderlich, so daß nach der Umsetzung des Schwefelwasserstoffes mit dem Alkalicarbonat zu Alkalibicarbonat und -sulfhydrat noch unverbrauchtes -carbonat vorhanden ist. Es ist zwar bekannt, aus Alkalisulfhydrat enthaltenden wässerigen Lösungen durch Behandeln finit Kohlendioxyd den Schwefelwasserstoff zu gewinnen, da sich das Alkalisulfhydrat mit dem Kohlendioxyd zu Alkalibicarbonat und Schwefelwasserstoff umsetzt. Diese Umsetzung findet jedoch erst dann vollständig statt, wenn das gesamte noch vorhandene Carbonat durch Reaktion mit dem Kohlendioxyd in Bicarbonat übergeführt worden ist. Die Umwandlung des Sulfhydrates mittels Kohlendioxyd zu Schwefelwasserstoff- erfordert gemäß dem Massenwirkungsgesetz einen großen Überschuß von Kohlendioxyd, so daß der Schwefelwasserstoff nur stark mit Kohlensäure verdünnt anfällt. Die theoretisch vorhandene Möglichkeit, aus einem derartigen Gasgemisch den Schwefelwasserstoff durch Oxydation zu verarbeiten, hat sich bisher als praktisch undurchführbar erwiesen (vgl. z. B. G 1 u u d , Handbuch der Kokerei, Bd.II, Seite 98).Process for the production of gases rich in hydrogen sulphide aqueous solutions of alkali carbonate, bicarbonate and sulfhydrate are the subject of Invention is a process for the recovery of gases rich in hydrogen sulfide from aqueous solutions of alkali carbonate, bicarbonate and sulfhydrate. Such Solutions arise, for example, when gases containing hydrogen sulfide with a Alkali carbonate solution to be treated; for the complete elimination of the hydrogen sulfide a certain excess of alkali metal carbonate is naturally required, so that after the conversion of the hydrogen sulfide with the alkali carbonate to alkali bicarbonate and sulfhydrate is still unused carbonate. It is well known from aqueous solutions containing alkali sulfhydrate by treating finite carbon dioxide to win the hydrogen sulfide, since the alkali sulfhydrate with the carbon dioxide converts to alkali bicarbonate and hydrogen sulfide. However, this implementation takes place only takes place completely when all of the carbonate still present has reacted has been converted into bicarbonate with the carbon dioxide. The conversion of the sulfhydrate by means of carbon dioxide to hydrogen sulfide - required according to the law of mass action a large excess of carbon dioxide, so that the hydrogen sulfide is only strong is obtained diluted with carbonic acid. The theoretically available possibility of a such a gas mixture to process the hydrogen sulfide by oxidation have so far proven to be practically impracticable (cf. e.g. G 1 u u d, manual der Kokerei, Vol. II, page 98).
Die Erfindung bezweckt, aus den eingangs genannten Lösungen ein an Schwefelwasserstoff reiches Gas zu erzeugen; die Erfindung besteht im wesentlichen darin, dal5 die genannten Lösungen zunächst mit einem Teilstrom des Endgases behandelt werden; wobei infolge der größeren Reaktionsgeschwindigkeit das in der Lösung vorhandene Carbonat sich im wesentlichen nur mit dein Schwefelwasserstoff des Gases zu Bicarbonat und Sulfhydrat umsetzt, und daß die nunmehr nur noch aus Bicarbonat und Sulfhydrat bestehende Lösung in einer zweiten Stufe mit Kohlendioxyd behandelt wird, wobei sich das gesamte Sulfhydrat zu Schwefelwasserstoff und Bicarbonat umsetzt. Aus dieser Stufe wird daher eine reine Bicarbonatlösung und ein an Schwefelwasserstoff reiches Gas gewonnen. Von diesem Endgas wird, wie vorstehend geschildert ist, ein Teil in der ersten Verfahrensstufe verwendet, der restliche Teil kann ohne Schwierigkeiten aufbereitet werken. Besonders zweckmäßig ist es hierbei, auch das in der ersten Stufe erzeugte kohlendioxydreiche Gas neben dem frisch zugeführten Kohlendioxyd in der zweiten Stufe zu verwenden, wobei das frisch zugeführte Kohlendioxyd zuletzt mit der Lösung in Berührung gebracht wird.The aim of the invention is to provide one of the solutions mentioned at the outset Generate hydrogen sulfide rich gas; the invention essentially consists in that the solutions mentioned are initially treated with a partial flow of the end gas will; where, as a result of the greater reaction rate, that which is present in the solution Carbonate essentially only converts to bicarbonate with the hydrogen sulfide in the gas and sulfhydrate converts, and that now only consists of bicarbonate and sulfhydrate existing solution is treated with carbon dioxide in a second stage, wherein the entire sulfhydrate converts to hydrogen sulfide and bicarbonate. From this The second stage therefore becomes a pure bicarbonate solution and one rich in hydrogen sulphide Gas won. As described above, a part of this end gas is in the first stage of the process is used, the remaining part can be used without difficulty work processed. It is particularly useful here, including that in the first Stage produced carbon dioxide-rich gas in addition to the freshly supplied carbon dioxide in the second stage to use, with the freshly supplied carbon dioxide is finally brought into contact with the solution.
Claims (2)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEO18194A DE502908C (en) | 1929-05-14 | 1929-05-14 | Process for the production of gases rich in hydrogen sulfide from aqueous solutions of alkali carbonate, bicarbonate and sulfhydrate |
GB14720/30A GB345873A (en) | 1929-05-14 | 1930-05-13 | Process for obtaining sulphuretted hydrogen from aqueous solutions of alkali carbonate, alkali bicarbonate and alkali hydrosulphide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEO18194A DE502908C (en) | 1929-05-14 | 1929-05-14 | Process for the production of gases rich in hydrogen sulfide from aqueous solutions of alkali carbonate, bicarbonate and sulfhydrate |
Publications (1)
Publication Number | Publication Date |
---|---|
DE502908C true DE502908C (en) | 1930-07-18 |
Family
ID=43500210
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEO18194A Expired DE502908C (en) | 1929-05-14 | 1929-05-14 | Process for the production of gases rich in hydrogen sulfide from aqueous solutions of alkali carbonate, bicarbonate and sulfhydrate |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE502908C (en) |
GB (1) | GB345873A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1061613B (en) * | 1955-07-14 | 1959-07-16 | Stora Kopparbergs Bergslags Ab | Process for the regeneration of alkali sulphite or alkali bisulphite pulp waste liquors |
DE1196489B (en) * | 1959-05-04 | 1965-07-08 | Babcock & Wilcox Co | Process for the recovery of chemicals from a lye containing alkali, especially sodium salts of sulphurous acid |
DE2741613A1 (en) * | 1976-09-15 | 1978-03-16 | Rockwell International Corp | PROCESS FOR PROCESSING AN ALKALIMETAL SULFIDE SOLUTION |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2567867A (en) * | 1946-10-04 | 1951-09-11 | West End Chemical Company | Process for desulfurizing of searles lake brine |
US2611682A (en) * | 1949-12-07 | 1952-09-23 | Mannbro Nils Viktor | Methods of recovering hydrogen sulfide from sulfide containing soda liquors obtainedin cellulose production |
US3653829A (en) * | 1970-01-29 | 1972-04-04 | Catalytic Construction Co | Recovery of sulfur values from brine |
-
1929
- 1929-05-14 DE DEO18194A patent/DE502908C/en not_active Expired
-
1930
- 1930-05-13 GB GB14720/30A patent/GB345873A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1061613B (en) * | 1955-07-14 | 1959-07-16 | Stora Kopparbergs Bergslags Ab | Process for the regeneration of alkali sulphite or alkali bisulphite pulp waste liquors |
DE1196489B (en) * | 1959-05-04 | 1965-07-08 | Babcock & Wilcox Co | Process for the recovery of chemicals from a lye containing alkali, especially sodium salts of sulphurous acid |
DE2741613A1 (en) * | 1976-09-15 | 1978-03-16 | Rockwell International Corp | PROCESS FOR PROCESSING AN ALKALIMETAL SULFIDE SOLUTION |
Also Published As
Publication number | Publication date |
---|---|
GB345873A (en) | 1931-04-02 |
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