DE470287C - Process for dissolving casein hardened by formaldehyde - Google Patents
Process for dissolving casein hardened by formaldehydeInfo
- Publication number
- DE470287C DE470287C DEG68875D DEG0068875D DE470287C DE 470287 C DE470287 C DE 470287C DE G68875 D DEG68875 D DE G68875D DE G0068875 D DEG0068875 D DE G0068875D DE 470287 C DE470287 C DE 470287C
- Authority
- DE
- Germany
- Prior art keywords
- formaldehyde
- hardened
- casein
- dissolving casein
- dissolving
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
Verfahren zur Lösung von durch Formaldehyd gehärtetem Casein Die Verwertung der Abfälle bei der Verarbeitung von Kunsthorn aus formalingehärtetem Casein ist .ein bisher nur mangelhaft ;elöstes Problem. Das unplastisch und unlöslich gewordene gegerbte Casein läßt sich in wesentlichen Mengen nur mehr zu Düngezwecken verwerten.Process for dissolving casein hardened by formaldehyde Recovery the waste from processing artificial horn is made from formalin-hardened casein A problem that has so far only been poorly resolved. That which has become nonplastic and insoluble tanned casein can only be used for fertilization purposes in substantial quantities.
Es ist nun bereits ein Verfahren beschrilebe,n, das Formaldehyd,casein dadurch wieder plastisch zu machen, daß durch Vorbehandlung der Masse mit Proteinlösun.gsmittelneine Aufquellung bewirkt und durch Nachbehandlung mit Natriumbisulfit, das den Formaldehyd bindet, eine Entgerbung der Proteinsubstanz veranlaßt wird.A process has already been described, n, formaldehyde, casein to make it plastic again by pretreating the mass with protein solvents Swelling causes and after treatment with sodium bisulfite, which the formaldehyde binds, a tanning of the protein substance is caused.
Es ist also bekannt, daß schwache, z. B. 5prazentige Ammoniaklösungen selbst in der Wärme das Kunsthorn nicht aufschließen, d. h. nicht in Lösuaig bringen können.So it is known that weak, e.g. B. 5 percent ammonia solutions Do not unlock the artificial horn even in the warmth, d. H. do not dissolve can.
Dahingegen wurde nun die überraschende Beobachtung gemacht, daß bereits i oprozentige Ammoniaklösungen b .ei mittlerer Temperatur das Formaldehydcasein (gehärtetes Kunsthornl glatt auflösen. Das Ammoniak> läßt sich zum Teil durch andere Alkalien ersetzen. Die so erhaltenen Lösungen kann man nach dem Einengen und eventuellem Klären in bekannter Weise verwerten oder aus ihnen durch Caseinfällungsmittel die Eiweißmassen regenerieren.On the other hand, the surprising observation has now been made that already 100 percent ammonia solutions or formaldehyde casein at medium temperature (Dissolve hardened synthetic horn Replace alkalis. The solutions obtained in this way can be used after concentration and possibly Clarify in a known manner or utilize them by casein precipitants Regenerate protein masses.
Beispiele i. i kg Kunsthorn, grob zerkleinert, wird mit 5kg ioprozentigem wässerigen Ammoniak 2o bis 5o Stunden im Rührautoklaven bei etwa 7o' behandelt. Nach dieser Zeit ist vollkommene Lösung .entstanden.Examples i. i kg of synthetic horn, roughly chopped, is made with 5 kg of 10% aqueous ammonia treated in a stirred autoclave at about 70 'for 20 to 50 hours. After this time, the perfect solution has arisen.
z. 1 kg Kunsthorn wird mit 4. kg Ammoniak und i kg `Wasserglas von 38° W wie Oben aufgeschlossen.z. 1 kg of artificial horn is mixed with 4. kg of ammonia and 1 kg of water glass of 38 ° W open as above.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEG68875D DE470287C (en) | 1926-12-07 | 1926-12-07 | Process for dissolving casein hardened by formaldehyde |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEG68875D DE470287C (en) | 1926-12-07 | 1926-12-07 | Process for dissolving casein hardened by formaldehyde |
Publications (1)
Publication Number | Publication Date |
---|---|
DE470287C true DE470287C (en) | 1929-01-10 |
Family
ID=7134513
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEG68875D Expired DE470287C (en) | 1926-12-07 | 1926-12-07 | Process for dissolving casein hardened by formaldehyde |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE470287C (en) |
-
1926
- 1926-12-07 DE DEG68875D patent/DE470287C/en not_active Expired
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