DE4423260A1 - Reaction resin mortar, esp. for anchoring fixing bars in holes - Google Patents

Reaction resin mortar, esp. for anchoring fixing bars in holes

Info

Publication number
DE4423260A1
DE4423260A1 DE19944423260 DE4423260A DE4423260A1 DE 4423260 A1 DE4423260 A1 DE 4423260A1 DE 19944423260 DE19944423260 DE 19944423260 DE 4423260 A DE4423260 A DE 4423260A DE 4423260 A1 DE4423260 A1 DE 4423260A1
Authority
DE
Germany
Prior art keywords
weight
resin
resin mortar
reaction resin
esp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19944423260
Other languages
German (de)
Inventor
Christian Weber
Juergen Gruen
Regina Kolesko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Upat Max Langensiepen KG
Original Assignee
Upat Max Langensiepen KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upat Max Langensiepen KG filed Critical Upat Max Langensiepen KG
Priority to DE19944423260 priority Critical patent/DE4423260A1/en
Publication of DE4423260A1 publication Critical patent/DE4423260A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16BDEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
    • F16B13/00Dowels or other devices fastened in walls or the like by inserting them in holes made therein for that purpose
    • F16B13/14Non-metallic plugs or sleeves; Use of liquid, loose solid or kneadable material therefor
    • F16B13/141Fixing plugs in holes by the use of settable material
    • F16B13/143Fixing plugs in holes by the use of settable material using frangible cartridges or capsules containing the setting components
    • F16B13/145Fixing plugs in holes by the use of settable material using frangible cartridges or capsules containing the setting components characterised by the composition of the setting agents contained in the frangible cartridges or capsules
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/06Inhibiting the setting, e.g. mortars of the deferred action type containing water in breakable containers ; Inhibiting the action of active ingredients
    • C04B40/0641Mechanical separation of ingredients, e.g. accelerator in breakable microcapsules
    • C04B40/065Two or more component mortars
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06Unsaturated polyesters

Abstract

A reaction resin mortar (I) for a 2-component system, is esp. for use in twin-chamber cartridges with a static mixer, in which one chamber contains a pre-accelerated resin component (A) and the other contains the hardener (B), either or both of which also contain(s) a liq. thixotropic agent (II).

Description

Die Erfindung betrifft einen Reaktionsharzmörtel für Zweikomponenten­ systeme zur Herstellung eines Verbundkörpers, insbesondere für die Verankerung von Befestigungsmitteln im Befestigungsgrund.The invention relates to a reactive resin mortar for two-component Systems for producing a composite body, in particular for the Anchoring fasteners in the ground.

Die Qualität der Verankerung von Befestigungsmitteln im Befestigungsgrund ist durch die Verarbeitbarkeit der hierbei benutzten Mörtel bestimmt. Die Mörtelmassen, die mittels Kartuschen, Auspreßgerät und Statikmischer in ein Bohrloch appliziert werden, müssen ein entsprechendes Fließverhalten aufweisen, damit die Masse mit geringerem Strömungswiderstand aus einem Statikmischer von Hand ausgepreßt und die Harz- und Härterkomponente gut homogenisiert werden. In diesem Fall ist ein thixotropes Verhalten der Masse von großer Bedeutung. Die Thixotropie der Masse wird durch die Zugabe von pulverartigen Thixotropiermitteln wie z. B. pyrogene Kieselsäure, Magnesiumoxid, Aluminiumoxid oder dergleichen erreicht.The quality of anchoring fasteners in the ground is determined by the processability of the mortar used in this case. The Mortar compounds by means of cartridges, squeezing and static mixer in a Borehole be applied, must have a corresponding flow behavior so that the mass with less flow resistance from a Static mixer pressed by hand and the resin and hardener component good be homogenized. In this case, a thixotropic behavior of the mass of great importance. The thixotropy of the mass is determined by the addition of powdery thixotropic agents such. Fumed silica, Reached magnesium oxide, alumina or the like.

Die Praxis hat gezeigt, daß das Daruntermischen des pulverartigen Thixotropiermittels, wie pyrogene Kieselsäure, im Produktionsablauf einige Probleme bereitet. Practice has shown that the mixing in of the powdery Thixotropic agent, such as fumed silica, in the production process some Problems.  

Dadurch, daß die Schüttdichte der pyrogenen Kieselsäure klein ist, ist es notwendig, den Mischvorgang, d. h. das Einfügen der Kieselsäure, in das Harz und/oder in den Härter in einem relativ großen Mischbehälter durchzuführen. Das Thixotropiermittel muß in mehreren kleinen Portionen dosiert werden, um die notwendige Menge in die Komponente darunterzumischen. Infolgedessen dauern der Mischvorgang für die Herstellung einer fertigen Charge lange. Während der Dosierung des pulverartigen Thixotropiermittels entsteht am Arbeitsplatz Kieselsäurestaub, der für die Bedienungsperson gesundheits­ schädlich sein kann. Die mit pyrogene Kieselsäure thixotropierten Kompo­ nenten, gefüllt in einer Zweikammerkartusche, die dann mittels eines Statik­ mischer vermischt werden, weisen keine ausreichende Homogenität aus. Dies wirkt sich negativ auf die mechanischen Eigenschaften des Verbundkörpers aus.The fact that the bulk density of fumed silica is small, it is necessary, the mixing process, d. H. the insertion of the silica, in the resin and / or in the hardener in a relatively large mixing vessel. The thixotropic agent must be dosed in several small portions to to mix the necessary amount into the component below. Consequently The mixing process takes a long time to produce a finished batch. During the dosage of the powdery thixotropic agent arises on Workplace. Silica dust polluting for the operator can be harmful. The fumed with fumed silica Kompo Nenten, filled in a two-chamber cartridge, which then by means of a statics mixers are mixed, have no sufficient homogeneity. This has a negative effect on the mechanical properties of the composite out.

Die Aufgabe der Erfindung ist, einen Reaktionsharzmörtel zum Einsatz in Zweikammerkartuschen mit einem Statikmischer bereitzustellen, der ein gutes Fließverhalten aufweist, eine Verankerung mit hoher und dauerhafter Ver­ bundfestigkeit ermöglicht und unkompliziert hergestellt werden kann.The object of the invention is a reaction resin mortar for use in To provide two-chamber cartridges with a static mixer, a good Has flow behavior, anchoring with high and permanent Ver bundfestigkeit allows and can be easily produced.

Erfindungsgemäß wird diese Aufgabe durch die kennzeichnenden Merkmale des Anspruchs 1 gelöst.According to the invention this object is achieved by the characterizing features of claim 1.

Durch die Zugabe von flüssigem Thixotropiermittel zum Harz- und/oder Härterkomponente findet beim Mischvorgang im Statikmischer eine rapide Viskositätreduzierung statt. Dadurch wird ein besseres Fließverhalten beider Komponenten in dem Statikmischer ermöglicht und ein leichtes und gutes Homogenisieren der Masse erreicht. Dies erhöht die Benetzung der Bohr­ lochwandung mit der Masse und sichert einen kompakten und dauerhaften Verbund im Bohrloch. By adding liquid thixotropic agent to the resin and / or Hardener component finds a rapid during the mixing process in the static mixer Viscosity reduction takes place. This results in a better flow behavior of both Components in the static mixer allows and a light and good Homogenizing the mass achieved. This increases the wetting of the drill hole wall with the mass and ensures a compact and durable Composite in the borehole.  

Das flüssige Thixotropiermittel läßt sich leicht, unkompliziert und mit großer Genauigkeit der dosierten Menge in das Harz- und/oder Härterkomponente daruntermischen. Der Vorgang verläuft in einem wesentlich kürzeren Zeittakt in einem herkömmlichen Mischbehälter.The liquid thixotropic agent is easy, uncomplicated and with great Accuracy of the metered amount in the resin and / or hardener component Mix in. The process runs in a much shorter time cycle in a conventional mixing container.

Erfindungsgemäß wird als flüssiges Thixotropiermittel ein Harnstoffurethan in Form von einer 40-60%igen Lösung in N-Methylpyrrolidon verwendet.According to the invention is a urea urethane as a liquid thixotropic agent used in the form of a 40-60% solution in N-methylpyrrolidone.

Als radikalisch härtbares Harz kann ein aminvorbeschleunigtes, unge­ sättigtes Polyesterharz, Vinylesterharz, Vinylurethanharz, Acrylharze mit oder ohne Monomere, wobei das Monomer mindestens eine Methacrylgruppe und die Viskosität von 1-2200 m Pa·s bei Temp. 20°C aufweist, oder eine Mischung derselben verwendet werden. Für die Befestigungen in Innen­ räumen werden Harze bevorzugt verwendet, die kein Styrol als Monomer aufweisen. Als Beschleuniger sind beispielsweise Dimethylanilin, Diethylanilin, Dimethyl-p-toluidin u. dgl. verwendet. Als Härterkomponenten werden Diacylperoxide z. B. Dibenzoylperoxid (BP) oder Bis(4-chlor-benzoyl) peroxid (CL BP) verwendet.As the radically curable resin, an amine pre-accelerated, unge saturated polyester resin, vinyl ester resin, vinyl urethane resin, acrylic resins with or without monomers, wherein the monomer has at least one methacrylic group and the viscosity of 1-2200 m Pa · s at temp. 20 ° C, or a Mixture of the same can be used. For the fixings in the interior Resins are preferably used which do not contain styrene as a monomer respectively. Examples of accelerators are dimethylaniline, Diethylaniline, dimethyl-p-toluidine u. Like. Used. As hardener components are diacyl peroxides z. Dibenzoyl peroxide (BP) or bis (4-chloro-benzoyl) peroxide (CL BP) used.

Die folgenden Beispiele 1-6 und Tabelle 1 zeigen die Ausführung der vorliegenden Erfindung und beschreiben Eigenschaften des erreichten Kunstharzkörpers. The following Examples 1-6 and Table 1 show the embodiment of present invention and describe properties of the achieved Resin body.  

Harzkomponenteresin component

Beispiel 1example 1 - ungesättigtes Polysterharz, aminvorbeschleunigt, Viskosität 2100 m Pa·s bei 23°Cunsaturated polyester resin, amine preaccelerated, viscosity 2100 m Pa · s at 23 ° C. 49 Gew.-%49% by weight - Quarzsand Korngröße 0,08-0,2 mm- Quartz sand grain size 0.08-0.2 mm 50 Gew.-%50% by weight - Harnstoffurethan gelöst in N-Methylpyrrolidon (60%)Urea-urethane dissolved in N-methylpyrrolidone (60%) 1 Gew.-% 1% by weight 100 Gew.-%100% by weight

Beispiel 2Example 2 - Vinylesterharz, aminvorbeschleunigt, Viskosität 650 m Pa·s bei 23°C- Vinyl ester resin, amine-accelerated, viscosity 650 m Pa · s at 23 ° C. 38 Gew.-%38% by weight - Quarzsand Korngröße 0,1-0,25 mm- Quartz sand grain size 0.1-0.25 mm 60 Gew.-%60% by weight - Harnstoffurethanharz gelöst in N-Methylpyrrolidon (60%)Urea-urethane resin dissolved in N-methylpyrrolidone (60%) 2 Gew.-% 2% by weight 100 Gew.-%100% by weight

Beispiel 3Example 3 - Vinylurethanharz, aminvorbeschleunigt, Viskosität 1350 m Pa·s bei 23°C- Vinylurethane resin, amine preaccelerated, viscosity 1350 m Pa · s at 23 ° C. 45 Gew.-%45% by weight - Quarzsand Korngröße 0,08-0,2 mm- Quartz sand grain size 0.08-0.2 mm 45 Gew.-%45% by weight - Harnstoffurethan gelöst in N-Methylpyrrolidon (60%)Urea-urethane dissolved in N-methylpyrrolidone (60%) 10 Gew.-% 10% by weight 100 Gew.-%100% by weight

Beispiel 4Example 4 - Acrylharz, aminvorbeschleunigt Viskosität 250 m Pa·s bei 23°C- Acrylic resin, amine preaccelerated viscosity 250 m Pa · s at 23 ° C 35 Gew.-%35% by weight - Quarzsand Korngröße 0,04-0,15 mm- Quartz sand grain size 0.04-0.15 mm 60 Gew.-%60% by weight - Harnstoffurethan gelöst in N-Methylpyrrolidon (60%)Urea-urethane dissolved in N-methylpyrrolidone (60%) 5 Gew.-% 5% by weight 100 Gew.-%100% by weight

Härterkomponentehardener component

Beispiel 5Example 5 - Dibenzoylperoxid- Dibenzoyl peroxide 30 Gew.-%30% by weight - Dibutylphthalat- dibutyl phthalate 40 Gew.-%40% by weight - Wasser- Water 10 Gew.-%10% by weight - Emulgator- emulsifier 2 Gew.-%2% by weight - Hohlglaskugeln Korngröße max. 0,25 mm- hollow glass spheres grain size max. 0.25 mm 13 Gew.-%13% by weight - Harnstoffurethan gelöst in N-Methylpyrrolidon (60%)Urea-urethane dissolved in N-methylpyrrolidone (60%) 5 Gew.-% 5% by weight 100 Gew.-%100% by weight

Beispiel 6Example 6 - Dibenzoylperoxid- Dibenzoyl peroxide 15 Gew.-%15% by weight - Calciumcarbonat- Calcium carbonate 35 Gew.-%35% by weight - Expoxidharz, Viskosität 1200 m Pa·s bei 23°C- epoxy resin, viscosity 1200 m Pa · s at 23 ° C 46 Gew.-%46% by weight - Harnstoffurethan gelöst in N-Methylpyrrolidon (60%)Urea-urethane dissolved in N-methylpyrrolidone (60%) 4 Gew.-% 4% by weight 100 Gew.-%100% by weight

Claims (4)

1. Reaktionsharzmörtel für Zweikomponentensysteme insbesondere zum Einsatz in Zweikammerkartuschen mit einem Statikmischer, wobei in einer Kammer eine vorbeschleunigte Harzkomponente und in der anderen Kammer die Härterkomponente enthalten ist, dadurch gekennzeichnet, daß das Harz- und/oder die Härterkomponente ein flüssiges Thixotropier­ mittel enthält.1. reaction resin mortar for two-component systems in particular for use in two-chamber cartridges with a static mixer, wherein in one chamber a vorbeschleunigte resin component and in the other chamber containing the hardener component, characterized in that the resin and / or the hardener component contains a liquid thixotropic agent. 2. Reaktionsharzmörtel nach Anspruch 1, dadurch gekennzeichnet, daß als Thixotropiermittel Harnstoffurethan verwendet wird.2. Reaction resin mortar according to claim 1, characterized in that as Thixotropic urea urethane is used. 3. Reaktionsharzmörtel nach Anspruch 2, dadurch gekennzeichnet, daß das Harnstoffurethan als 40-60% Lösung in N-Methylpyrrolidon verwendet wird.3. Reaction resin mortar according to claim 2, characterized in that the Urea urethane used as a 40-60% solution in N-methylpyrrolidone becomes. 4. Reaktionsharzmörtel nach Anspruch 1, dadurch gekennzeichnet, daß das Harz und/oder Härterkomponente ein flüssiges Thixotropiermittel von 1-10 Gew.-% enthält.4. reaction resin mortar according to claim 1, characterized in that the Resin and / or hardener component a liquid thixotropic agent of Contains 1-10 wt .-%.
DE19944423260 1994-07-02 1994-07-02 Reaction resin mortar, esp. for anchoring fixing bars in holes Withdrawn DE4423260A1 (en)

Priority Applications (1)

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DE19944423260 DE4423260A1 (en) 1994-07-02 1994-07-02 Reaction resin mortar, esp. for anchoring fixing bars in holes

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10115587A1 (en) * 2001-03-29 2002-10-02 Fischer Artur Werke Gmbh Vinylester-urea
US6649706B1 (en) 1999-05-25 2003-11-18 Basf Coatings Ag Thixotroping agent
US6652915B1 (en) * 1999-05-25 2003-11-25 Basf Coatings Ag Coating material containing a mixture of silicic acids and urea and/or urea derivatives
US6652916B1 (en) 1999-05-25 2003-11-25 Basf Coatings Ag Coating material comprising a mixture that consists of at least one wetting agent and of ureas and/or urea derivatives serving as thixotropic agents
US6685985B2 (en) 2001-02-09 2004-02-03 Basf Corporation Method of improving the appearance of coated articles having both vertical and horizontal surfaces, and coating compositions for use therein
US7019042B2 (en) 2000-08-26 2006-03-28 Basf Coatings Ag Thixotropic agent that can be activated using actinic radiation, a method for its production and the use thereof
US8686090B2 (en) 2003-12-10 2014-04-01 Basf Coatings Gmbh Use of urea crystals for non-polymeric coatings
EP4177235A1 (en) * 2021-11-09 2023-05-10 HILTI Aktiengesellschaft Pulverized recycled materials as fillers for multicomponent systems for chemical fixation

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3347045A1 (en) * 1983-12-24 1985-07-04 Henkel KGaA, 4000 Düsseldorf TWO COMPONENT POLYURETHANE ADHESIVE
DE3523479A1 (en) * 1985-07-01 1987-01-08 Heinz Marohn METHOD FOR PRODUCING A REACTION RESIN-CEMENT BUILDING MATERIAL MIXTURE
GB2179932A (en) * 1985-09-05 1987-03-18 Aeci Ltd Settable plaster composition
DE3812814A1 (en) * 1988-04-16 1989-11-02 Hilti Ag USE OF TWO-COMPONENT REACTION RESIN FOR FASTENING PURPOSES
DE3940309A1 (en) * 1989-12-06 1991-06-13 Hilti Ag MOERTELMASSE
DE4231161A1 (en) * 1992-09-17 1994-03-24 Hilti Ag Mortar and device for fixing anchoring means in boreholes
DE4304824A1 (en) * 1993-02-17 1994-08-18 Upat Max Langensiepen Kg Reaction resin mortar for two-component systems

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3347045A1 (en) * 1983-12-24 1985-07-04 Henkel KGaA, 4000 Düsseldorf TWO COMPONENT POLYURETHANE ADHESIVE
DE3523479A1 (en) * 1985-07-01 1987-01-08 Heinz Marohn METHOD FOR PRODUCING A REACTION RESIN-CEMENT BUILDING MATERIAL MIXTURE
GB2179932A (en) * 1985-09-05 1987-03-18 Aeci Ltd Settable plaster composition
DE3812814A1 (en) * 1988-04-16 1989-11-02 Hilti Ag USE OF TWO-COMPONENT REACTION RESIN FOR FASTENING PURPOSES
DE3940309A1 (en) * 1989-12-06 1991-06-13 Hilti Ag MOERTELMASSE
DE4231161A1 (en) * 1992-09-17 1994-03-24 Hilti Ag Mortar and device for fixing anchoring means in boreholes
DE4304824A1 (en) * 1993-02-17 1994-08-18 Upat Max Langensiepen Kg Reaction resin mortar for two-component systems

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6649706B1 (en) 1999-05-25 2003-11-18 Basf Coatings Ag Thixotroping agent
US6652915B1 (en) * 1999-05-25 2003-11-25 Basf Coatings Ag Coating material containing a mixture of silicic acids and urea and/or urea derivatives
US6652916B1 (en) 1999-05-25 2003-11-25 Basf Coatings Ag Coating material comprising a mixture that consists of at least one wetting agent and of ureas and/or urea derivatives serving as thixotropic agents
US7019042B2 (en) 2000-08-26 2006-03-28 Basf Coatings Ag Thixotropic agent that can be activated using actinic radiation, a method for its production and the use thereof
US6685985B2 (en) 2001-02-09 2004-02-03 Basf Corporation Method of improving the appearance of coated articles having both vertical and horizontal surfaces, and coating compositions for use therein
DE10115587A1 (en) * 2001-03-29 2002-10-02 Fischer Artur Werke Gmbh Vinylester-urea
DE10115587B4 (en) * 2001-03-29 2017-06-14 Fischerwerke Gmbh & Co. Kg Use of a resin with certain hardenable urea derivatives for attachment by means of anchoring agents
US8686090B2 (en) 2003-12-10 2014-04-01 Basf Coatings Gmbh Use of urea crystals for non-polymeric coatings
EP4177235A1 (en) * 2021-11-09 2023-05-10 HILTI Aktiengesellschaft Pulverized recycled materials as fillers for multicomponent systems for chemical fixation

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