DE428878C - Soap containing compounds containing active oxygen - Google Patents

Soap containing compounds containing active oxygen

Info

Publication number
DE428878C
DE428878C DEF57389D DEF0057389D DE428878C DE 428878 C DE428878 C DE 428878C DE F57389 D DEF57389 D DE F57389D DE F0057389 D DEF0057389 D DE F0057389D DE 428878 C DE428878 C DE 428878C
Authority
DE
Germany
Prior art keywords
soap
active oxygen
persalts
containing compounds
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEF57389D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
L C KELBER DR
Original Assignee
L C KELBER DR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L C KELBER DR filed Critical L C KELBER DR
Priority to DEF57389D priority Critical patent/DE428878C/en
Priority claimed from GB2955925A external-priority patent/GB265714A/en
Application granted granted Critical
Publication of DE428878C publication Critical patent/DE428878C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D13/00Making of soap or soap solutions in general; Apparatus therefor
    • C11D13/14Shaping
    • C11D13/20Shaping in the form of small particles, e.g. powder or flakes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/42Per-compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Description

Seife mit Gehalt an aktiven Sauerstoff enthaltenden Verbindungen. Die bekannten Seifenpulver mit einem Gehalt an Sauerstoff enthaltenden Verbindungen, insbesondere mit einem Gehalt an Persalzen, werden in der Weise hergestellt, daß trockene, feingepulverte Seife und pulverförmige Persalze mit oder ohne Zusatz von sonstigen trockenen pulverförmigen Waschmitteln gemischt werden.Soap containing compounds containing active oxygen. The known soap powder with a content of oxygen-containing compounds, in particular with a content of persalts are produced in such a way that dry, finely powdered soap and powdered persalts with or without the addition of other dry powder detergents can be mixed.

Diese Seifenpulvcr aus getrockneter Seife und Persalzen entmischen sich leicht, da die Korngrößen und das spczifische Gewicht der Bestandteile verschieden sind. Bei der üblichen Art des Gebrauchs zum Waschen löst sich die pulverförmige Seife schneller als das Persalz, und es entsteht so die Gefahr, daß die schwerlöslichen und spezifisch schweren Persalze sich auf die Gewebe setzen und daß durch nachträgliche Bildung konzentrierter Lösungen auf und in denselben eine starke örtliche Einwirkung und dadurch eine Schädigung der Gewebe hervorgerufen wird.Separate these soap powders from dried soap and persalts Easily because the grain sizes and the specific weight of the components are different are. With the usual type of use for washing, the powdery one dissolves Soap faster than the persalt, and there is a risk that the poorly soluble and specifically heavy persalts settle on the tissue and that by subsequent Formation of concentrated solutions on and in them a strong local influence and thereby causing tissue damage.

Man hat bereits vorgeschlagen, vollkommen entwässerte, pulverförmige Seife mit Persalzen zu mischen und das Gemisch unter hohem Druck zu einem einheitlichen Ganzen zu verpressen. Man erhält nach diesem Verfahren harte Stücke oder auch Blöcke, die in Stücke geteilt werden können; sie sind zwar haltbar, aber sehr schwer im Wasser löslich. In der Industrie wird das Verfahren zur Herstellung solcher Seifenstücke mit Gehalt an Persalzen nicht -benutzt und ist völlig unbekannt; nach demselben hergestellte Erzeugnisse sind nicht im Handel. Das erklärt sich in einfacher Weise dadurch, daß einerseits die Herstellungsweise zu teuer und unwirtschaftlich ist, anderseits eine solche Seife in der Verwendung- unzweckmäßig sein würde. Denn um aus dieser fast steinharten, schwer löslichen Seife eine Waschlauge herzustellen, müßte das Stück erst mit einem Hammer zertrümmert werden, damit es in eine leichter lösliche Form gebracht wird.It has already been proposed that they be completely dehydrated, powdery Mix soap with persalts and apply high pressure to make the mixture a uniform To press the whole thing. This process produces hard pieces or blocks, that can be divided into pieces; they are durable, but very heavy in the Water soluble. In industry, the process of making such bars of soap is used with content of persalts not used and is completely unknown; after the same manufactured products are not on the market. This can be explained in a simple way in that on the one hand the production method is too expensive and uneconomical, on the other hand, such a soap would be inexpedient to use. Because around to make a detergent solution from this almost rock-hard, sparingly soluble soap, the piece would have to be smashed with a hammer so that it becomes easier soluble form is brought.

Aus dem pulverförmigen Gemisch von vollkommen entwässerter Seife und Persalzen lassen sich leicht lösliche Flocken nicht herstellen, da es technisch unmöglich ist, mittels Walzen aus diesem Gut Flocken oder dünne Bänder zu erzeugen; das Pulver fällt von der Walze so wieder ab, wie es aufgebracht ist.From the powdery mixture of completely drained soap and Easily soluble flakes cannot be produced from persalts because it is technical it is impossible to produce flakes or thin ribbons from this material by means of rollers; the powder falls off the roller as it is applied.

Es lag für den Fachmann nicht nahe, unter Benutzung von wasserhaltiger Seife Versuche anzustellen zur Herstellung von persalzhaltigen Seifenflocken oder Seifenbändern; denn nach einfacher Überlegung kam man zu dem Schluß, daß bei einem genügenden Wassergehalt, auch wenn dieser nur 8 bis 1q. Prozent betragen würde, infolge der durch den Walzendruck entstehenden nicht unerheblichen Wärme schon bei der Herstellung selbst Zersetzungen in dem Persalz-Seife-Gemisch eintreten würden. Für den Fachmann lag ferner der Schluß nahe, daß ein Gemisch von Seife mit diesem Wassergehalt und dem sonst üblichen Gehalt an Perborat oder einem anderen Persalz viel zu sprcde sein würde für die Formung zu dünnen Bändern und Blättchen oder Flocken, zumal eine Seife reit diesem Wassergehalt schon an sich außerordentlich spröde ist.It was not obvious to the expert to use water-based Soap to make experiments for the production of soap flakes containing persalt or Soap ribbons; because after a simple reflection one came to the conclusion that with one sufficient water content, even if this is only 8 to 1q. Percent would be due to the not inconsiderable heat generated by the roller pressure the production itself would cause decomposition in the persalt-soap mixture. For the person skilled in the art it was also obvious that a mixture of soap with this Water content and the usual perborate or other persalt content would be much too brittle for the formation of ribbons and leaves or flakes that are too thin especially since a soap with this water content is extremely brittle in and of itself.

Überraschenderweise haben die angestellten Versuche aber ein ganz anderes Ergebnis gehabt; dieses führte zu der Verfahrenserfindung, für welche das Patent nachgesucht wird.Surprisingly, the staff try but had a completely different result; this led to the process invention, for which the patent is sought.

Wasserarme Seife mit einem Gehalt von etwa 8 bis 14 Prozent Wasser wird mit pulverförmigen, aktiven Sauerstoff enthaltenden Verbindungen, insbesondere mit Persalzen, innig vermischt, das Gemisch durch Walzmaschinen dünn ausgewalzt und dann durch Schneidemaschinen in kleine, flockenförmige Blättchen übergeführt. Das Wesentliche des vorliegenden Verfahrens besteht darin, daB Mischungen von wasserarmer Seife mit Persalzen in die Form haltbarer Flocken übergeführt werden, bei denen ein Entmischen der Bestandtei:e und damit die Gefahr einer Schädigung der Wäsche ausgeschlossen und eine leichte Löslichkeit gesichert ist.Low-water soap with a water content of around 8 to 14 percent is used with powdered, active oxygen-containing compounds, in particular with persalts, intimately mixed, the mixture rolled out thinly by rolling machines and then cut into small, flaky leaves by cutting machines. The essence of the present process is that mixtures of water-poor Soap with persalts can be converted into the form of durable flakes in which segregation of the components and thus the risk of damage to the laundry excluded and easy solubility is ensured.

Claims (1)

PATENTANSPRUCH: Seife mit Gehalt an aktiven Sauerstoff enthaltenden Verbindungen, dadurch gekennzeichnet, daß die aus wasserarmer, etwa 8 bis i4; Prozent Wasser enthaltender Seife und den Sauerstoff abgebenden Verbindungen bestehende Mischung die Form von dünnen Blättchen besitzt.PATENT CLAIM: Soap with active oxygen content Compounds, characterized in that the low-water, about 8 to i4; percent Soap containing water and the oxygen-releasing compounds Mixture is in the form of thin leaflets.
DEF57389D 1924-11-20 1924-11-21 Soap containing compounds containing active oxygen Expired DE428878C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEF57389D DE428878C (en) 1924-11-20 1924-11-21 Soap containing compounds containing active oxygen

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
DE1810759X 1924-11-20
DEF57389D DE428878C (en) 1924-11-20 1924-11-21 Soap containing compounds containing active oxygen
US69488A US1810759A (en) 1924-11-20 1925-11-16 Manufacture of soap
GB2955925A GB265714A (en) 1925-11-23 1925-11-23 Improvements in the manufacture of soap
US129656A US1717553A (en) 1924-11-20 1926-08-16 Manufacture of soap
US129657A US1824809A (en) 1924-11-20 1926-08-16 Manufacture of soap
US129654A US1715999A (en) 1924-11-20 1926-08-16 Manufacture of soap
US129655A US1716000A (en) 1924-11-20 1926-08-16 Manufacture of soap

Publications (1)

Publication Number Publication Date
DE428878C true DE428878C (en) 1926-05-12

Family

ID=27561724

Family Applications (4)

Application Number Title Priority Date Filing Date
DEF57389D Expired DE428878C (en) 1924-11-20 1924-11-21 Soap containing compounds containing active oxygen
DEF58599D Expired DE472047C (en) 1924-11-20 1925-04-12 Process for the production of transparent flakes or ribbons from mixtures of soaps with active oxygen-releasing compounds
DEF59929D Expired DE453457C (en) 1924-11-20 1925-10-01 Process for the production of translucent flakes or ribbons from soap with salts that release oxygen
DEF60931D Expired DE447626C (en) 1924-11-20 1926-02-27 Soap containing compounds containing active oxygen

Family Applications After (3)

Application Number Title Priority Date Filing Date
DEF58599D Expired DE472047C (en) 1924-11-20 1925-04-12 Process for the production of transparent flakes or ribbons from mixtures of soaps with active oxygen-releasing compounds
DEF59929D Expired DE453457C (en) 1924-11-20 1925-10-01 Process for the production of translucent flakes or ribbons from soap with salts that release oxygen
DEF60931D Expired DE447626C (en) 1924-11-20 1926-02-27 Soap containing compounds containing active oxygen

Country Status (4)

Country Link
US (5) US1810759A (en)
DE (4) DE428878C (en)
FR (1) FR618298A (en)
NL (1) NL17876C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE740891C (en) * 1939-04-30 1943-10-30 Ig Farbenindustrie Ag Disinfectant supply form
US2876200A (en) * 1955-04-08 1959-03-03 Procter & Gamble Making perborate containing detergents

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2423449A (en) * 1941-04-17 1947-07-08 Colgate Palmolive Peet Co Preparation of spray dried soap particles having only slight dustforming tendencies
US2423450A (en) * 1941-04-17 1947-07-08 Colgate Palmolive Peet Co Preparation of synthetic organic detergent particles having only slight dust-forming tendencies
US2463680A (en) * 1945-03-31 1949-03-08 Wyandotte Chemicals Corp Process of making a dust-free alkaline detergent product
US2575179A (en) * 1947-12-15 1951-11-13 Monsanto Chemicals Water treating compositions
US2937147A (en) * 1955-09-28 1960-05-17 Lever Brothers Ltd Stabilized germicidal soaps and process of making the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE740891C (en) * 1939-04-30 1943-10-30 Ig Farbenindustrie Ag Disinfectant supply form
US2876200A (en) * 1955-04-08 1959-03-03 Procter & Gamble Making perborate containing detergents

Also Published As

Publication number Publication date
US1810759A (en) 1931-06-16
US1824809A (en) 1931-09-29
DE447626C (en) 1927-08-01
US1717553A (en) 1929-06-18
US1715999A (en) 1929-06-04
DE453457C (en) 1927-12-08
DE472047C (en) 1929-02-22
US1716000A (en) 1929-06-04
FR618298A (en) 1927-03-07
NL17876C (en)

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