DE4129926C1 - - Google Patents
Info
- Publication number
- DE4129926C1 DE4129926C1 DE4129926A DE4129926A DE4129926C1 DE 4129926 C1 DE4129926 C1 DE 4129926C1 DE 4129926 A DE4129926 A DE 4129926A DE 4129926 A DE4129926 A DE 4129926A DE 4129926 C1 DE4129926 C1 DE 4129926C1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- surfactant
- tinting
- shampoo according
- alkylpolyglycoside
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000203 mixture Substances 0.000 claims abstract description 40
- 239000002453 shampoo Substances 0.000 claims abstract description 30
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 150000001412 amines Chemical class 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000000982 direct dye Substances 0.000 claims description 7
- 150000001447 alkali salts Chemical class 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 abstract description 6
- 239000000975 dye Substances 0.000 abstract description 4
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 229940071145 lauroyl sarcosinate Drugs 0.000 abstract 1
- -1 saccharide radical Chemical class 0.000 description 20
- 239000000194 fatty acid Substances 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 7
- 239000000654 additive Substances 0.000 description 5
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
- 229920006317 cationic polymer Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 230000037308 hair color Effects 0.000 description 4
- JHDBMHFWQRTXLV-UHFFFAOYSA-N 1-dodecoxydodecane;2-sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC JHDBMHFWQRTXLV-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 102000008186 Collagen Human genes 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- 244000208060 Lawsonia inermis Species 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- RFQSMLBZXQOMKK-UHFFFAOYSA-N [3-[(4,8-diamino-6-bromo-1,5-dioxonaphthalen-2-yl)amino]phenyl]-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)C1=CC=CC(NC=2C(C3=C(N)C=C(Br)C(=O)C3=C(N)C=2)=O)=C1 RFQSMLBZXQOMKK-UHFFFAOYSA-N 0.000 description 2
- HSWXSHNPRUMJKI-UHFFFAOYSA-N [8-[(2-methoxyphenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].COC1=CC=CC=C1N\N=C/1C2=CC([N+](C)(C)C)=CC=C2C=CC\1=O HSWXSHNPRUMJKI-UHFFFAOYSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229920001436 collagen Polymers 0.000 description 2
- ZXJXZNDDNMQXFV-UHFFFAOYSA-M crystal violet Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1[C+](C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 ZXJXZNDDNMQXFV-UHFFFAOYSA-M 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000000118 hair dye Substances 0.000 description 2
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 2
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 108700004121 sarkosyl Proteins 0.000 description 2
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 2
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NWKBFCIAPOSTKG-UHFFFAOYSA-M trimethyl-[3-[(3-methyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]phenyl]azanium;chloride Chemical compound [Cl-].CC1=NN(C=2C=CC=CC=2)C(=O)C1N=NC1=CC=CC([N+](C)(C)C)=C1 NWKBFCIAPOSTKG-UHFFFAOYSA-M 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 description 1
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 1
- BCPQALWAROJVLE-UHFFFAOYSA-N 4-(2,4-dinitroanilino)phenol Chemical compound C1=CC(O)=CC=C1NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O BCPQALWAROJVLE-UHFFFAOYSA-N 0.000 description 1
- JBDFNORUNVZONM-UHFFFAOYSA-N 4-octoxy-4-oxo-3-sulfobutanoic acid Chemical compound CCCCCCCCOC(=O)C(S(O)(=O)=O)CC(O)=O JBDFNORUNVZONM-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 1
- CMPPYVDBIJWGCB-UHFFFAOYSA-N [8-[(4-amino-3-nitrophenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].C12=CC([N+](C)(C)C)=CC=C2C=CC(=O)\C1=N\NC1=CC=C(N)C([N+]([O-])=O)=C1 CMPPYVDBIJWGCB-UHFFFAOYSA-N 0.000 description 1
- UXEAWNJALIUYRH-UHFFFAOYSA-N [8-[(4-aminophenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].C12=CC([N+](C)(C)C)=CC=C2C=CC(=O)\C1=N/NC1=CC=C(N)C=C1 UXEAWNJALIUYRH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- DSSYKIVIOFKYAU-UHFFFAOYSA-N camphor Chemical compound C1CC2(C)C(=O)CC1C2(C)C DSSYKIVIOFKYAU-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229940086555 cyclomethicone Drugs 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229940113124 polysorbate 60 Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
Description
Die vorliegende Erfindung betrifft ein färbendes Haarwaschmittel, das nicht nur eine gründliche und schonende Reinigung des Haares gewährleistet, sondern gleichzeitig auch noch eine exzellente haarfärbende Wirkung aufweist.The present invention relates to a coloring shampoo, Not only a thorough and gentle cleansing of the hair guaranteed, but at the same time also an excellent has hair coloring effect.
Haarwaschmittel mit färbenden Eigenschaften, sogenannte Tönungs-Shampoos, sind seit langem bekannt. Sie bestehen in der Regel aus einer Tensid-Grundlage und einem oder mehreren darin eingearbeiteten, direktziehenden Farbstoffen. Beispiele für solche Tönungs-Shampoos finden sich in den einschlägigen Handbüchern, beispielsweise bei K. Schrader, Grundlagen und Rezepturen der Kosmetika, 2. Auflage (Hüthig Buchverlag Heidelberg, 1989), S. 805 bis 806, 814.Shampoo having coloring properties, so-called tinting shampoos, have been known for a long time. They usually consist of a surfactant base and one or more incorporated therein, direct dyes. Examples of such tinting shampoos can be found in the relevant manuals, for example K. Schrader, basics and formulations of cosmetics, 2nd edition (Hüthig Verlag Heidelberg, 1989), pp. 805-806, 814th
Der Nachteil solcher Tönungs-Shampoos liegt darin, daß die mit ihnen erzielte Haarfärbung oftmals nicht intensiv genug ist und deshalb bereits nach relativ wenigen Haarwäschen wieder verblaßt bzw. ganz verschwindet.The disadvantage of such tinting shampoos is that the with Hair coloring they achieved is often not intense enough and Therefore, after a relatively few washes again faded or completely disappears.
Die Erfindung geht daher von der Aufgabenstellung aus, eine Zusammensetzung für ein Tönungs-Shampoo zu schaffen, das diese Nachteile nicht aufweist, d. h. das Haar nicht nur gründlich und schonend reinigt, sondern auch den direkten Farbstoff so aufziehen läßt, daß eine verbesserte und anhaltende Farbintensität gegeben ist. The invention is therefore based on the task, a composition to create a tinting shampoo that has these disadvantages does not have, d. H. not only the hair thoroughly and gently cleans, but also raise the direct dye so lets that give an improved and lasting color intensity is.
Die Lösung dieser Aufgabe besteht darin, ein Haartönungs-Shampoo zu verwenden, das mindestens einen direktziehenden Haarfarbstoff enthält und in einer ein Tensid-Gemisch umfassenden Grundlage auf wäßriger Basis vorliegt, wobei die Grundlage ein Tensid-Gemisch folgender Zusammensetzung enthält:The solution to this problem is a hair tinting shampoo to use at least one substantive hair dye contains and in a surfactant mixture comprehensive basis aqueous base, the basis being a surfactant mixture contains the following composition:
5-35 Gew.-% eines anionaktiven Tensids;
0,5-10 Gew.-% eines oberflächenaktiven Aminoxids;
2,5-15 Gew.-% eines Alkylpolyglycosids der allgemeinen
Formel RO(R¹O)tZx,5-35% by weight of an anionic surfactant;
0.5-10% by weight of a surface-active amine oxide;
2.5-15 wt .-% of an alkylpolyglycoside of the general formula RO (R¹O) t Z x ,
wobei Z einen reduzierenden Saccharid-Rest mit 5 bis 6 Kohlenstoffatomen,
R eine Alkylgruppe mit 8 bis 18 Kohlenstoffatomen, R¹
einen Ethylen- oder Propylen-Rest, t null bis zehn und x eins bis
fünf bedeuten,
und gegebenenfalls 0,5 bis 5 Gew.-% eines weiteren nichtionischen
Tensids.wherein Z is a reducing saccharide radical having 5 to 6 carbon atoms, R is an alkyl group having 8 to 18 carbon atoms, R¹ is an ethylene or propylene radical, t is zero to ten and x is one to five,
and optionally 0.5 to 5 wt .-% of a further nonionic surfactant.
Die genannten Prozentanteile beziehen sich jeweils auf die Gesamtzusammensetzung des Tönungs-Shampoos.The stated percentages in each case relate to the total composition Tinting Shampoo.
Aus der EP-A 1 37 178 sind bereits Haartönungs-Shampoos bekannt, die neben einem direktziehenden Farbstoff eine Shampoo-Grundlage enthalten, die ein anionisches Tensid und ein "Hilfs-Tensid", das ein kationisches und/oder Betain-Tensid sein soll, enthält. Jedoch auch diese Zusammensetzungen sind hinsichtlich der Vermittlung von optimalem Farbglanz und Farbtiefe nicht völlig zufriedenstellend. Hair tint shampoos are already known from EP-A 1 37 178. the next to a direct dye a shampoo foundation containing an anionic surfactant and an "auxiliary surfactant", the is a cationic and / or betaine surfactant. However, these compositions are also mediating of optimal color gloss and color depth not completely satisfactory.
Von einer anderen Aufgabenstellung geht die EP-A 3 67 926 aus, die ebenfalls Haarfärbe- bzw. Haartönungs-Mittel auf Basis mindestens eines direktziehenden Farbstoffs in einer aus Tensiden und üblichen Zusatzstoffen bestehenden Grundlage beschreibt, wobei diese folgende Stoffe enthält:From another task EP-A 3 67 926 is based, the also hair dyeing or hair tinting agent based on at least a direct dye in one of surfactants and conventional Describes additives existing basis, these being contains the following substances:
2,5-20 Gew.-% mindestens eines amphoteren Tensids;
1-10 Gew.-% mindestens eines oberflächenaktiven Aminoxids
und
1-10 Gew.-% mindestens eines nichtionischen Tensids.2.5-20% by weight of at least one amphoteric surfactant;
1-10 wt .-% of at least one surface-active amine oxide and
1-10% by weight of at least one nonionic surfactant.
Irgendwelche Anregungen zur erfindungsgemäßen Lösung der Aufgabe der Erfindung lassen sich dieser Druckschrift daher nicht entnehmen, insbesondere auch deshalb, als in dieser EP-A eindeutig ausgeführt wird, daß anionische Tenside, insbesondere Fettalkoholethersulfate, wenn überhaupt, nur in untergeordneten Mengen verwendet werden sollen.Any suggestions for solving the problem of the invention The invention can therefore not be found in this document, especially because of this, as clearly stated in this EP-A that anionic surfactants, especially fatty alcohol ether sulfates, if at all, only in subordinate quantities should be used.
Aus der EP-A 46 543 schließlich sind bereits Mittel zum gleichzeitigen Färben, Waschen und Konditionieren von menschlichen Haaren bekannt. Diese bekannten Mittel enthalten jedoch obligatorisch Oxidationsfarbstoffe, während erfindungsgemäß direktziehende Farbstoffe im Vordergrund stehen. Darüber hinaus unterscheiden sich die dort verwendeten Shampoo-Grundlagen hinsichtlich ihrer Tensid-Zusammensetzung grundlegend von den erfindungsgemäß zum Einsatz gelangenden. From EP-A 46 543 finally are already means for simultaneous Dyeing, washing and conditioning of human hair known. However, these known means are obligatory Oxidative dyes, while according to the invention substantive dyes stand in the foreground. In addition, they differ the shampoo bases used there with regard to their surfactant composition fundamentally used by the invention reaching.
Als im Rahmen der Erfindung geeignete anionische Tenside sind insbesondere Alkalisalze von Sulfobernsteinsäurehalbestern, insbesondere das Dinatriumsalz des Monooctylsulfosuccinats und Alkalisalze langkettiger Monoalkylethoxysulfosuccinate zu nennen.As in the invention suitable anionic surfactants are in particular Alkali salts of sulfosuccinic monoesters, in particular the disodium salt of monooctylsulfosuccinate and alkali salts to call long-chain monoalkylethoxysulfosuccinates.
Eine weitere bevorzugte Klasse anionischer Tenside sind langkettige Acylsarkosinate bzw. deren Alkalisalze, beispielsweise Natriumlauroylsarkosinat.Another preferred class of anionic surfactants are long chain Acylsarcosinates or their alkali metal salts, for example Natriumlauroylsarkosinat.
Wie bereits ausgeführt, beträgt der Anteil an anionischen Tensiden in den erfindungsgemäßen Zusammensetzungen etwa 5 bis etwa 35 Gew.-%, berechnet auf die Gesamtzusammensetzung des Tönungs-Shampoos. Als bevorzugter Bereich sind dabei etwa 8 bis etwa 25, vorzugsweise 10 bis 20 Gew.-% anionaktives Tensid zu nennen. Eine bevorzugte Tensid-Mischung besteht aus einem Alkalisalz eines Sulfosuccinats, beispielsweise dem Dinatriumlaurylethersulfosuccinat, und einem Acylaminocarbonsäuresalz, beispielsweise Natriumlauroylsarkosinat, vorzugsweise im Gewichtsverhältnis von etwa 5 : 1 bis 2 : 1, insbesondere 3 bis 4 : 1.As already stated, the proportion of anionic surfactants in the compositions of the invention about 5 to about 35% by weight, calculated on the total composition of the tinting shampoo. As a preferred range are about 8 to about 25, preferably 10 to 20 wt .-% anionic surfactant to call. A preferred surfactant mixture consists of an alkali salt of a Sulfosuccinate, for example disodium lauryl ether sulfosuccinate, and an acylaminocarboxylic acid salt, for example sodium lauroyl sarcosinate, preferably in a weight ratio of about 5: 1 to 2: 1, especially 3 to 4: 1.
Anstelle oder ergänzend zu den bevorzugt eingesetzten, oben definierten anionaktiven Tensiden können noch weitere anionaktive Tenside eingesetzt werden, beispielsweise die bekannten C₁₀-C₁₈-Alkylethersulfate, insbesondere die C₁₂-C₁₄-Alkylethersulfate bzw. Laurylethersulfat, insbesondere solche mit 1 bis 4 Ethylenoxid-Gruppen im Molekül.Instead of or in addition to the preferred, defined above Anionic surfactants may contain other anionic surfactants be used, for example, the well-known C₁₀-C₁₈-Alkylethersulfate, in particular the C₁₂-C₁₄-alkyl ether sulfates or Lauryl ether sulfate, especially those having 1 to 4 ethylene oxide groups in the molecule.
Weitere geeignete anionaktive Tenside sind Fettalkoholsulfate, beispielsweise Laurylsulfat, Monogylceridsulfate, Fettsäureamidsulfate, die durch Ethoxylierung und anschließende Sulfatierung von Fettsäuremonoalkanolamid hergestellt wurden, Alkylethercarbonsäuren und Alkalisalze langkettiger Alkylphosphate, die ebenfalls milde, besonders hautverträgliche Detergentien darstellen. Further suitable anionic surfactants are fatty alcohol sulfates, for example, lauryl sulfate, monoglyceride sulfates, fatty acid amide sulfates, by ethoxylation and subsequent sulfation of fatty acid monoalkanolamide, alkyl ether carboxylic acids and alkali salts of long chain alkyl phosphates, also mild, particularly skin-friendly detergents represent.
Im Gemisch mit anderen anionischen Tensiden ebenfalls einsetzbar sind Eiweiß-Fettsäure-Kondensationsprodukte an sich bekannter Struktur. Eine Übersicht über in Shampoos zum Einsatz gelangende anionaktive Tenside findet sich im übrigen in der bereits erwähnten Monographie von K. Schrader, S. 683 bis S. 691.Also usable in admixture with other anionic surfactants are protein-fatty acid condensation products known per se Structure. An overview of shampoos used Anionic surfactants are otherwise found in the already mentioned Monograph by K. Schrader, p. 683 to p. 691.
Ein weiterer Bestandteil der erfindungsgemäßen Zusammensetzung ist ein oberflächenaktives Aminoxid in einer Menge von etwa 0,5 bis etwa 10 Gew.-%, vorzugsweise 1 bis 5, insbesondere 1,5 bis 3 Gew.-% der Gesamtzusammensetzung.Another component of the composition according to the invention is a surface-active amine oxide in an amount of about 0.5 to about 10% by weight, preferably 1 to 5, in particular 1.5 to 3% by weight the overall composition.
Geeignete Aminoxide sind beispielsweise C₁₂-C₁₈-Alkyldimethylaminoxide, beispielsweise Lauryldimethylaminoxid oder Kokosdi-(hydroxyethyl)-aminoxid.Suitable amine oxides are, for example, C₁₂-C₁₈-alkyldimethylamine oxides, for example, lauryldimethylamine oxide or coco di (hydroxyethyl) amine oxide.
Der langkettige Alkylrest kann auch durch Amidgruppen substituiert sein, beispielsweise ein C₇-C₁₇-Alkoylamino-3-dimethylaminopropan-3-N-oxid. Auch polyoxethylierte Aminoxide sind geeignet, ebenso Aminoxide vom Typ Diethylaminopropylpalmitamid-N-oxid, etc.The long-chain alkyl radical can also be substituted by amide groups be, for example, a C₇-C₁₇-alkoylamino-3-dimethylaminopropan-3-N-oxide. Polyoxethylated amine oxides are also suitable, as well Amine oxides of the diethylaminopropyl palmitamide N-oxide type, etc.
Schließlich enthalten die erfindungsgemäßen Zusammensetzungen 2,5 bis 15 Gew.-% eines Alkylpolyglycosids der allgemeinen Formel RO(R¹O)tZx, wobei Z einen reduzierenden Saccharidrest mit 5 bis 6 Kohlenstoffatomen, R eine Alkylgruppe mit 8 bis 18 Kohlenstoffatomen, R¹ einen Ethylen- oder Propylenrest, t null bis zehn und x eins bis fünf bedeuten. Der bevorzugte Anteil liegt zwischen 5 und 10 Gew.-% der Gesamtzusammensetzung.Finally, the compositions according to the invention contain from 2.5 to 15% by weight of an alkylpolyglycoside of the general formula RO (R¹O) t Z x , where Z is a reducing saccharide radical having 5 to 6 carbon atoms, R is an alkyl group having 8 to 18 carbon atoms, R¹ is ethylene or propylene radical, t is zero to ten and x is one to five. The preferred proportion is between 5 and 10% by weight of the total composition.
Gemische aus anionaktiven Tensiden und Alkylpolygylcosiden sowie deren Verwendung in Haarwaschmitteln sind an sich bereits bekannt, beispielsweise aus der EP-A 70 074. Mixtures of anionic surfactants and alkylpolyglycosides as well their use in shampoos are already known per se, For example, from EP-A 70 074.
Die dort beschriebenen Alkylpolyglycoside sind prinzipiell auch im Rahmen der vorliegenden Erfindung geeignet; allerdings wird erfindungsgemäß als besonders bevorzugtes Alkylpolyglycosid ein solches mit etwa 9 bis 11 Kohlenstoffatomen in der Alkylkette und einem Kondensationsgrad von weniger als 1,4, vorzugsweise etwa 1,35, eingesetzt.The alkylpolyglycosides described there are also in principle Within the scope of the present invention; however, according to the invention as particularly preferred alkylpolyglycoside such with about 9 to 11 carbon atoms in the alkyl chain and one Degree of condensation of less than 1.4, preferably about 1.35, used.
Auch Gemische aus Sulfosuccinaten und Alkylpolyglycosiden sind aus der EP-A 3 58 216 bereits bekannt; die dort beschriebenen Gemische eignen sich ebenfalls vorzüglich zum Einsatz in den erfindungsgemäßen Zusammensetzungen.Mixtures of sulfosuccinates and alkylpolyglycosides are also out EP-A 3 58 216 already known; the mixtures described there are also excellent for use in the invention Compositions.
Gemäß einer bevorzugten Ausführungsform enthalten die erfindungsgemäßen Zusammensetzungen auch 0,5 bis 10, vorzugsweise 1 bis 5 Gew.-%, bezogen auf die Gesamtzusammensetzung, eines oder mehrerer amphoterer Tenside. Als solche sind insbesondere die verschiedenen bekannten Betaine wie Fettsäureamidoalkylbetaine, langkettige Alkylaminopropionate sowie vorzugsweise Sulfobetaine geeignet. Ein besonders geeignetes Betain ist in diesem Zusammenhang das Laurylhydroxysulfobetain.According to a preferred embodiment, the inventive Compositions also 0.5 to 10, preferably 1 to 5% by weight, based on the total composition, of one or more amphoteric surfactants. As such, in particular the various known betaines such as Fettsäureamidoalkylbetaine, long-chain Alkylaminopropionate and preferably sulfobetaines suitable. A particularly suitable betaine is in this context the lauryl hydroxy sulfobetaine.
Auch für Shampoos geeignete amphotere Tenside sind bei Schrader, l.c., S. 598-600, beschrieben.Also suitable for shampoos amphoteric surfactants are in Schrader, l.c., pp. 598-600.
Ein weiterer bevorzugter fakultativer Bestandteil der erfindungsgemäßen Zusammensetzungen sind weitere nichtionische Tenside, vorzugsweise in einer Menge von etwa 0,5 bis etwa 5,0, vorzugsweise 1 bis 3 Gew.-%, bezogen auf die Gesamtzusammensetzung. Another preferred optional ingredient of the invention Compositions are other nonionic surfactants, preferably in an amount of about 0.5 to about 5.0, preferably 1 to 3 wt .-%, based on the total composition.
Solche nichtionischen Tenside sind beispielsweise die verschiedenen Sorbitanester, beispielsweise Polyethylenglycolsorbitanstearinsäureester wie Polyoxyethylensorbitanmonostearat mit 20 bis 60 Ethylenoxid-Einheiten, Fettsäurepolyglykcolester oder Fettsäureglyceridoxyethylate, Fettalkoholpolyglycolether und auch Mischkondensate aus Ethylenoxid und Propylenoxid, wie sie beispielsweise unter der Handelsbezeichnung "Pluronics" im Verkehr sind.Such nonionic surfactants are, for example, the various Sorbitan esters, for example Polyethylenglycolsorbitanstearinsäureester such as polyoxyethylene sorbitan monostearate with 20 to 60 ethylene oxide units, fatty acid polyglycol ester or fatty acid glyceride oxyethylate, Fatty alcohol polyglycol ethers and also mixed condensates from ethylene oxide and propylene oxide, as for example under the trade name "Pluronics".
Als weitere nichtionische Tensid-Bestandteile können die erfindungsgemäßen Tönungs-Shampoos beispielsweise langkettige Fettsäuremono- und -dialkanolamide enthalten, beispielsweise Kokosfettsäuremonoethanolamid oder Myristinfettsäurediethanolamid. Der Anteil dieser Alkanolamide liegt vorzugsweise zwischen etwa 0,2 und 2,5, insbesondere 0,5 und 2 Gew.-% der Gesamtzusammensetzung. Solche Gemische aus Alkylpolyglycosiden und Fettsäurealkanolamiden sind beispielsweise Gegenstand der EP-A 70 076.As further nonionic surfactant components, the inventive Tinting shampoos, for example, long-chain fatty acid mono- and dialkanolamides, for example, coconut fatty acid monoethanolamide or myristic fatty acid diethanolamide. The Proportion of these alkanolamides is preferably between about 0.2 and 2.5, in particular 0.5 and 2 wt .-% of the total composition. Such mixtures of alkyl polyglycosides and fatty acid alkanolamides are for example the subject of EP-A 70 076.
Die erfindungsgemäßen Haartönungs-Shampoos können selbstverständlich alle üblichen, in solchen Mitteln zum Einsatz gelangende Stoffe enthalten. Als solche seien Komplexbildner, weitere Farbstoffe zur Färbung des Shampoos selbst, Konservierungsmittel, pH-Regler, Viskositätsregler, wie anorganische Salze, soweit sie nicht ohnehin in den Tensid-Ausgangsmischungen enthalten sind, Duftstoffe, Perlglanzmittel, Verdickungsmittel, etc. genannnt. Eine Auflistung solcher Zusatzstoffe findet sich beispielsweise bei Schrader, l.c., S. 695 bis 722. The hair coloring shampoos according to the invention can of course all the usual ones used in such means Contain substances. As such, are complexing agents, other dyes for coloring the shampoo itself, preservative, pH regulator, Viscosity regulators, such as inorganic salts, as far as they are concerned are not contained in the starting surfactant mixtures anyway, Fragrances, pearlescing agents, thickeners, etc. genannnt. A list of such additives can be found, for example in Schrader, l.c., pp. 695 to 722.
Besonders geeignete Zusatzstoffe sind haarkonditionierende Mittel. Als solche werden insbesondere kationische Polymere, vorzugsweise in einer Menge zwischen 0,1 bis 1,5, insbesondere 0,25 bis 1,0 Gew.-% der Gesamtzusammensetzung, eingesetzt.Particularly suitable additives are hair conditioning agents. As such, in particular cationic polymers, preferably in an amount between 0.1 to 1.5, in particular 0.25 to 1.0 wt .-% of the total composition used.
Aus der EP-A 3 37 354 ist die Verwendung von kationischen Polymeren mit Alkylpolysaccharid-Tensidpräparaten an sich bereits bekannt; die dort auf S. 3 bis 7 aufgezählten kationischen Polymeren eignen sich auch als konditionierende Zusätze in den erfindungsgemäßen Zusammensetzungen.From EP-A 3 37 354 is the use of cationic polymers already known with alkyl polysaccharide surfactant preparations per se; the cationic polymers enumerated on pages 3 to 7 are suitable also as conditioning additives in the invention Compositions.
Weitere haarkonditionierende Zusätze sind die bekannten Eiweißhydrolysate, beispielsweise in einer Menge von 0,25 bis 5 Gew.-%, vorzugsweise 0,5 bis 2,5 Gew.-% der Gesamtzusammensetzung.Further hair-conditioning additives are the known protein hydrolysates, for example, in an amount of 0.25 to 5 wt .-%, preferably 0.5 to 2.5% by weight of the total composition.
Weiterhin geeignet sind auch wasserlösliches Collagen bzw. wasserlösliche Collagen-Derivate.Also suitable are water-soluble collagen or water-soluble Collagen derivatives.
Schließlich können auch, wie ebenfalls bereits bekannt, die verschiedenen Polysiloxane als konditionierende Mittel in den erfindungsgemäßen Haartönungs-Shampoos mit verwendet werden. Der bevorzugte Anteil liegt dabei zwischen etwa 0,5 und etwa 7,5, insbesondere 1 bis 5 Gew.-% der Gesamtzusammensetzung. Geeignet sind sowohl leichtflüchtige als auch schwerflüchtige cyclische oder lineare Polysiloxane, beispielsweise die unter den Trivialnamen "Dimethicone" bzw. "Phenyldimethicone" sowie "Cyclomethicone" bekannten Siliconöle.Finally, as also already known, the various Polysiloxanes as conditioning agents in the inventive Hair tint shampoos to be used with. The preferred one Share is between about 0.5 and about 7.5, in particular 1 to 5 wt .-% of the total composition. Are suitable both volatile and nonvolatile cyclic or linear Polysiloxanes, for example, the trivial names Dimethicone or "Phenyldimethicone" and "Cyclomethicone" known Silicone oils.
Ein essentieller Bestandteil der erfindungsgemäßen Haartönungs-Shampoos sind natürlich die an sich bekannten direktziehenden Haarfarbstoffe.An essential component of the hair tint shampoos according to the invention are of course the known substantive ones Hair dyes.
Deren Auswahl und Konzentration ist selbstverständlich abhängig von der gewünschten Farbnuance, weshalb die folgende Aufzählung nur als beispielhaft anzusehen ist: Their selection and concentration is of course dependent of the desired color shade, which is why the following list only to be considered as an example is:
Besonders geeignet sind die sogenannten Arianor-Farbstoffe wie Basic Brown 17, C.I. (Colour Index)-No. 12,251, Basic Brown 16, C.I.-No. 12,250, Basic Red 76, C.I.-No. 12,245, Basic Yellow 57, C.I.-No. 12, 719, Basic Blue 99, C.I.-No. 56,059, Basic Violet, C.I.-No. 45,170 bzw. Basic Violet 1, C.I.-No. 42,535 und Basic Violet 3, C.I.-No. 42,555, Acid Yellow 1, C.I.-No. 10,316, Acid Yellow 9, C.I.-No. 13,015, Disperse Yellow 3, C.I.-No. 11,855, und Disperse Yellow 1, C.I.-No. 10,345.Particularly suitable are the so-called Arianor dyes such Basic Brown 17, C.I. (Color Index) -No. 12.251, Basic Brown 16, C.I. 12.250, Basic Red 76, C.I. no. 12.245, Basic Yellow 57, C.I. 12, 719, Basic Blue 99, C.I. 56,059, Basic Violet, C.I. 45.170 or Basic Violet 1, C.I. 42,535 and Basic Violet 3, C.I. 42,555, Acid Yellow 1, C.I. 10.316, Acid Yellow 9, C.I. 13.015, Disperse Yellow 3, C.I. 11,855, and Disperse Yellow 1, C.I. 10.345.
Eine Aufzählung direktziehender Haarfarben findet sich ebenfalls bei Schrader, l.c., S. 800-805.A list of direct hair colors is also found in Schrader, l.c., pp. 800-805.
Selbstverständlich können auch direktziehende Naturfarbstoffe wie beispielsweise Henna mitverwendet werden.Of course, direct dyes such as natural for example, henna be used.
In den folgenden Beispielen wird eine Illustration der Erfindung gegeben.In the following examples will become an illustration of the invention given.
Die Benutzung dieses Tönungs-Shampoos verleiht dem Haar einen ausdrucksfähigen, dauerhaften intensiven Rotton. The use of this tinting shampoo gives the hair an expressive, permanent intense shade of red.
Bei der Wäsche mit diesem Tönungs-Shampoo wurde ein glänzender hellblonder Farbton erhalten.When washing with this tinting shampoo was a shiny get light blond color.
Claims (8)
- a) 5-35 Gew.-% mindestens eines anionaktiven Tensids;
- b) 0,5-10 Gew.-% eines oberflächenaktiven Aminoxids;
- c) 2,5-15 Gew.-% eines Alkylpolyglycosids der allgemeinen Formel RO(R¹O)tZx,
- a) 5-35% by weight of at least one anionic surfactant;
- b) 0.5-10% by weight of a surface-active amine oxide;
- c) 2.5-15% by weight of an alkylpolyglycoside of the general formula RO (R¹O) t Z x ,
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4129926A DE4129926C1 (en) | 1991-09-09 | 1991-09-09 | |
| JP4196903A JP2799803B2 (en) | 1991-09-09 | 1992-07-23 | Coloring shampoo composition |
| AT92115352T ATE98470T1 (en) | 1991-09-09 | 1992-09-08 | HAIR TONING SHAMPOOS. |
| EP92115352A EP0531943B1 (en) | 1991-09-09 | 1992-09-08 | Hair tinting shampoo |
| US08/135,656 US5422031A (en) | 1991-09-09 | 1993-10-14 | Hair tinting shampoo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4129926A DE4129926C1 (en) | 1991-09-09 | 1991-09-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4129926C1 true DE4129926C1 (en) | 1992-07-23 |
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ID=6440193
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4129926A Expired - Fee Related DE4129926C1 (en) | 1991-09-09 | 1991-09-09 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5422031A (en) |
| EP (1) | EP0531943B1 (en) |
| JP (1) | JP2799803B2 (en) |
| AT (1) | ATE98470T1 (en) |
| DE (1) | DE4129926C1 (en) |
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| DE102014223938A1 (en) | 2014-11-25 | 2016-05-25 | Henkel Ag & Co. Kgaa | An agent for coloring keratinic fibers containing at least one dimeric, dicationic azo dye and at least one nonionic surfactant |
| DE102014223936A1 (en) | 2014-11-25 | 2016-05-25 | Henkel Ag & Co. Kgaa | Agent for dyeing keratinic fibers, containing at least one dimeric, dicationic azo dye with a special substitution pattern |
| DE102014223935A1 (en) * | 2014-11-25 | 2016-05-25 | Henkel Ag & Co. Kgaa | Agent for dyeing keratinic fibers, containing at least one dimeric, dicationic azo dye and at least one anionic and / or cationic surfactant |
| DE102014223939A1 (en) | 2014-11-25 | 2016-05-25 | Henkel Ag & Co. Kgaa | A composition for dyeing keratinic fibers containing at least one dimeric, dicationic azo dye and at least one anionic surfactant |
| DE102014223937A1 (en) | 2014-11-25 | 2016-05-25 | Henkel Ag & Co. Kgaa | Agent for changing the color of keratinic fibers containing at least one dimeric ring-bridged azo dye |
| WO2019074123A1 (en) * | 2017-10-13 | 2019-04-18 | ロート製薬株式会社 | Shampoo composition |
| JP7103706B1 (en) * | 2022-03-16 | 2022-07-20 | 株式会社ナンバースリー | Hair dyeing agent and hair dyeing method |
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| EP0070074A2 (en) * | 1981-07-13 | 1983-01-19 | THE PROCTER & GAMBLE COMPANY | Foaming surfactant compositions |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0544495A1 (en) * | 1991-11-27 | 1993-06-02 | Hoechst Celanese Corporation | Improved azo pigment compositions and process for their preparation |
| WO1994004124A1 (en) * | 1992-08-22 | 1994-03-03 | Henkel Kommanditgesellschaft Auf Aktien | Alkyl glycosides in dyeing agents |
| DE4430521C1 (en) * | 1994-08-27 | 1995-12-14 | Kao Corp Gmbh | Hair dye compsn. contg. an oxidisable dye precursor |
| DE4430522A1 (en) * | 1994-08-27 | 1996-02-29 | Kao Corp Gmbh | Hair colour or toner with colour intensity and conditioning |
| DE4430522C2 (en) * | 1994-08-27 | 1998-08-06 | Kao Corp | Means for coloring and tinting human hair |
| DE19640831C2 (en) * | 1996-10-02 | 2002-11-21 | Kao Corp | Means for dyeing and tinting human hair |
| DE19651482C2 (en) * | 1996-12-11 | 2002-05-02 | Wella Ag | Means for dyeing and tinting hair |
| DE19713696C5 (en) * | 1997-04-03 | 2004-01-15 | Kpss-Kao Professional Salon Services Gmbh | Process for simultaneously tinting and washing human hair |
| EP1762220A3 (en) * | 2005-09-09 | 2010-06-09 | Henkel AG & Co. KGaA | Composition for dyeing keratinous fibres comprising polymers of low molecular weight |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2799803B2 (en) | 1998-09-21 |
| EP0531943B1 (en) | 1993-12-15 |
| US5422031A (en) | 1995-06-06 |
| EP0531943A1 (en) | 1993-03-17 |
| ATE98470T1 (en) | 1994-01-15 |
| JPH05194159A (en) | 1993-08-03 |
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| 8100 | Publication of patent without earlier publication of application | ||
| D1 | Grant (no unexamined application published) patent law 81 | ||
| 8363 | Opposition against the patent | ||
| 8365 | Fully valid after opposition proceedings | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: KAO CORP., TOKIO/TOKYO, JP |
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Free format text: HOFFMANN, EITLE & PARTNER PATENT- UND RECHTSANWAELTE, 81925 MUENCHEN |
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| 8339 | Ceased/non-payment of the annual fee |