DE3374684D1 - A method to trap the enolate ion of the malonic acid or its derivatives - Google Patents
A method to trap the enolate ion of the malonic acid or its derivativesInfo
- Publication number
- DE3374684D1 DE3374684D1 DE8383108542T DE3374684T DE3374684D1 DE 3374684 D1 DE3374684 D1 DE 3374684D1 DE 8383108542 T DE8383108542 T DE 8383108542T DE 3374684 T DE3374684 T DE 3374684T DE 3374684 D1 DE3374684 D1 DE 3374684D1
- Authority
- DE
- Germany
- Prior art keywords
- trap
- derivatives
- malonic acid
- enolate ion
- enolate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 title 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/62—Halogen-containing esters
- C07C69/65—Halogen-containing esters of unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/716—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15100882A JPS5939849A (en) | 1982-08-31 | 1982-08-31 | Fluorine-containing aliphatic group-substituted alkylated or alkenylated malonic ester or its derivative |
JP15100782A JPS5939854A (en) | 1982-08-31 | 1982-08-31 | Trapping of enolate ion of fluorine-containing group- substituted malonic ester |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3374684D1 true DE3374684D1 (en) | 1988-01-07 |
Family
ID=26480410
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8383108542T Expired DE3374684D1 (en) | 1982-08-31 | 1983-08-30 | A method to trap the enolate ion of the malonic acid or its derivatives |
Country Status (3)
Country | Link |
---|---|
US (1) | US4578503A (en) |
EP (1) | EP0103233B1 (en) |
DE (1) | DE3374684D1 (en) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5350878A (en) * | 1989-07-26 | 1994-09-27 | Dow Corning Corporation | Fluorinated compounds containing hetero atoms and polymers thereof |
US5493049A (en) * | 1993-02-10 | 1996-02-20 | Dow Corning Corporation | Fluorinated compounds containing hetero atoms and polymers thereof |
GB9512546D0 (en) * | 1995-06-20 | 1995-08-23 | Bnfl Fluorchem Ltd | A process for the preparation of esters |
US7683071B2 (en) * | 2000-07-26 | 2010-03-23 | Taro Pharmaceuticals Industries Ltd. | Composition and method for improved bioavailability and enhanced brain delivery of 5,5-diphenyl barbituric acid |
US6756379B2 (en) * | 2001-07-26 | 2004-06-29 | Taro Pharmaceutical Industries Ltd. | Non-sedating barbiturate compounds as neuroprotective agents |
US6939873B2 (en) * | 2000-07-26 | 2005-09-06 | Taro Pharmaceuticals Industries Limited | Non-sedating barbituric acid derivatives |
JP4739760B2 (en) | 2002-12-11 | 2011-08-03 | タロー・ファーマシューティカル・インダストリーズ・リミテッド | Method for treating movement disorders using barbituric acid derivatives |
US7947253B2 (en) * | 2004-01-15 | 2011-05-24 | Aposense Ltd. | Perturbed membrane-binding compounds and methods of using the same |
US7270799B2 (en) * | 2004-01-15 | 2007-09-18 | Nst Neurosurvival Technologies Ltd. | Perturbed membrane-binding compounds and methods of using the same |
CA2572797A1 (en) * | 2004-07-02 | 2006-01-12 | Daniella Gutman | A process for preparing 1-methoxymethyl-5,5-diphenylbarbituric acid |
EP2081576A4 (en) * | 2006-11-14 | 2010-06-30 | Taro Pharmaceuticals North Ame | Method of improving bioavailability for non-sedating barbiturates |
US20100035296A1 (en) * | 2007-01-04 | 2010-02-11 | Anat Shirvan | Compounds and methods for detection of cells |
US9249265B1 (en) | 2014-09-08 | 2016-02-02 | Sirrus, Inc. | Emulsion polymers including one or more 1,1-disubstituted alkene compounds, emulsion methods, and polymer compositions |
US9279022B1 (en) | 2014-09-08 | 2016-03-08 | Sirrus, Inc. | Solution polymers including one or more 1,1-disubstituted alkene compounds, solution polymerization methods, and polymer compositions |
RU2013122684A (en) | 2010-10-20 | 2014-11-27 | Биоформикс Инк. | SYNTHESIS OF METHYLMENALONATES USING QUICK EXTRACTION IN THE PRESENCE OF AN ENERGY TRANSFER |
US10414839B2 (en) | 2010-10-20 | 2019-09-17 | Sirrus, Inc. | Polymers including a methylene beta-ketoester and products formed therefrom |
US9828324B2 (en) | 2010-10-20 | 2017-11-28 | Sirrus, Inc. | Methylene beta-diketone monomers, methods for making methylene beta-diketone monomers, polymerizable compositions and products formed therefrom |
EP2768917B1 (en) | 2011-10-19 | 2018-12-05 | Sirrus, Inc. | Multifunctional monomers and methods for making them |
EP2831125B1 (en) | 2012-03-30 | 2016-10-05 | Sirrus, Inc. | Methods for activating polymerizable compositions, polymerizable systems, and products formed thereby |
EP2831124B1 (en) | 2012-03-30 | 2016-10-05 | Sirrus, Inc. | Composite and laminate articles and polymerizable systems for producing the same |
EP3848402A1 (en) | 2012-03-30 | 2021-07-14 | Sirrus, Inc. | Ink and coating formulations and polymerizable systems for producing the same |
US10047192B2 (en) | 2012-06-01 | 2018-08-14 | Sirrus, Inc. | Optical material and articles formed therefrom |
WO2014078689A1 (en) | 2012-11-16 | 2014-05-22 | Bioformix Inc. | Plastics bonding systems and methods |
WO2014085570A1 (en) | 2012-11-30 | 2014-06-05 | Bioformix, Inc. | Composite compositions for electronics applications |
EP2943462B1 (en) | 2013-01-11 | 2018-06-27 | Sirrus, Inc. | Method to obtain methylene malonate via bis(hydroxymethyl) malonate pathway |
US9416091B1 (en) | 2015-02-04 | 2016-08-16 | Sirrus, Inc. | Catalytic transesterification of ester compounds with groups reactive under transesterification conditions |
US9315597B2 (en) | 2014-09-08 | 2016-04-19 | Sirrus, Inc. | Compositions containing 1,1-disubstituted alkene compounds for preparing polymers having enhanced glass transition temperatures |
US10501400B2 (en) | 2015-02-04 | 2019-12-10 | Sirrus, Inc. | Heterogeneous catalytic transesterification of ester compounds with groups reactive under transesterification conditions |
US9334430B1 (en) | 2015-05-29 | 2016-05-10 | Sirrus, Inc. | Encapsulated polymerization initiators, polymerization systems and methods using the same |
US9217098B1 (en) | 2015-06-01 | 2015-12-22 | Sirrus, Inc. | Electroinitiated polymerization of compositions having a 1,1-disubstituted alkene compound |
US9518001B1 (en) | 2016-05-13 | 2016-12-13 | Sirrus, Inc. | High purity 1,1-dicarbonyl substituted-1-alkenes and methods for their preparation |
US10196481B2 (en) | 2016-06-03 | 2019-02-05 | Sirrus, Inc. | Polymer and other compounds functionalized with terminal 1,1-disubstituted alkene monomer(s) and methods thereof |
US10428177B2 (en) | 2016-06-03 | 2019-10-01 | Sirrus, Inc. | Water absorbing or water soluble polymers, intermediate compounds, and methods thereof |
US9567475B1 (en) | 2016-06-03 | 2017-02-14 | Sirrus, Inc. | Coatings containing polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes |
US9617377B1 (en) | 2016-06-03 | 2017-04-11 | Sirrus, Inc. | Polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3578701A (en) * | 1967-07-26 | 1971-05-11 | Du Pont | Fluorinated acids and esters |
US3478116A (en) * | 1967-07-26 | 1969-11-11 | Du Pont | Fluorinated alcohols |
FR2480742A1 (en) * | 1980-04-18 | 1981-10-23 | Ugine Kuhlmann | PROCESS FOR THE PREPARATION OF PRODUCTS HAVING A PERFLUOROALKYL GROUP IN THE PRESENCE OF ZINC IN ACIDIC ENVIRONMENT |
JPS6034940B2 (en) * | 1980-11-13 | 1985-08-12 | ダイキン工業株式会社 | Fluoromalonic acid derivatives and their production method |
-
1983
- 1983-08-30 EP EP83108542A patent/EP0103233B1/en not_active Expired
- 1983-08-30 DE DE8383108542T patent/DE3374684D1/en not_active Expired
- 1983-08-31 US US06/528,134 patent/US4578503A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US4578503A (en) | 1986-03-25 |
EP0103233A3 (en) | 1985-06-19 |
EP0103233A2 (en) | 1984-03-21 |
EP0103233B1 (en) | 1987-11-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE3374684D1 (en) | A method to trap the enolate ion of the malonic acid or its derivatives | |
CS222279B2 (en) | Method of making the derivative of the 2-penem-3-carboxyle acid | |
GB2072642B (en) | Process for the preparation of sulfuric acid | |
JPS552674A (en) | Separation of tyralcarboxylic acid antipode | |
JPS5714570A (en) | Preparation of n-benzyloxycarbonylaspartic acid | |
JPS5385797A (en) | Method of concentrating phosphoric acid | |
ZA813537B (en) | Process for the preparation of diacetone-ketogulonic acid | |
JPS5753438A (en) | Manufacture of 2-aryloxy-acrylic acid compound | |
JPS5448747A (en) | Method of separating 11aminoo44 bromoanthraquinonee22sulfonic acid or its alkali metal salt | |
GB2090594B (en) | Fluoromethylthioacetic acid compounds | |
JPS56130289A (en) | Method of evaporating water | |
JPS56169644A (en) | Manufacture of alkoxyalkanoic acid | |
JPS5589244A (en) | Ammonium salt of alphaaketocarboxylic acid | |
JPS5448748A (en) | Method of separating 11aminoo44 bromoanthraquinonee22sulfonic acid or its alkali metal salt | |
JPS56140968A (en) | Manufacture of carbamoylsulfonic acid derivative salt | |
DE3163621D1 (en) | Process for the preparation of compounds of 2-aryloxy-2-halogen-propionic acid | |
JPS56104858A (en) | Manufacture of styrylsulfonic acid derivative | |
CS221993B2 (en) | Method of preparation of the derivatives of the 15-acetoxy-9-oxoprostadien acid | |
JPS5567127A (en) | Method of manufacturing nonnpolarized solid electrolytic condenser | |
JPS5550618A (en) | Method of manufacturing chipplike solid electrolytic condenser | |
ZA813397B (en) | Process for the preparation of diacetoneketogulonic acid | |
JPS57130951A (en) | Manufacture of dienoic acid | |
JPS56104848A (en) | Manufacture of 11nitrobenzenee22carboxylic acid alkylesterr55carboxylic acid | |
JPS5793925A (en) | Manufacture of 2-methoxyalkanoic acid | |
JPS5791956A (en) | Manufacture of hypohalogen acid alkyl |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |