DE3276807D1 - Triazinyllactames, process for their preparation, their use as stabilisators for synthetic organic polymers and polymers stabilised by them - Google Patents

Triazinyllactames, process for their preparation, their use as stabilisators for synthetic organic polymers and polymers stabilised by them

Info

Publication number
DE3276807D1
DE3276807D1 DE8282108750T DE3276807T DE3276807D1 DE 3276807 D1 DE3276807 D1 DE 3276807D1 DE 8282108750 T DE8282108750 T DE 8282108750T DE 3276807 T DE3276807 T DE 3276807T DE 3276807 D1 DE3276807 D1 DE 3276807D1
Authority
DE
Germany
Prior art keywords
group
formula
see diagramm
alkyl
substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8282108750T
Other languages
German (de)
Inventor
Hartmut Dr Wiezer
Gerhard Dr Pfahler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to DE8282108750T priority Critical patent/DE3276807D1/en
Application granted granted Critical
Publication of DE3276807D1 publication Critical patent/DE3276807D1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyethers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1. Claims for the Contracting States : BE, CH, DE, FR, GB, IT, LI, NL, SE A compound of the formula (I) see diagramm : EP0075849,P13,F1 in which m is 0 or 1, n is also 0 or 1 and A is C4 to C11 alkylene, R**1 , when m is 0, has the meaning of hydrogen, of C1 to C18 alkyl, of C3 to C21 alkoxyalkyl, of C5 to C12 cycloalkyl, which can be substituted by C1 to C4 alkyl, or phenyl or naphthyl, which can be substituted by up to two Cl or C1 to C4 alkyl radicals or by one C1 to C4 alkoxy or C1 to C2 carboalkoxy group, of C7 to C14 phenylalkyl or of a group of the formula (II) see diagramm : EP0075849,P13,F2 wherein R**3 is hydrogen or methyl and R**4 is hydrogen, C1 to C4 alkyl, or is 2,3-epoxypropyl, allyl or benzyl, R**1 and R**2 , when m is 1, are identical or different and represent hydrogen, C1 to C18 alkyl, C5 to C12 cycloalkyl, which can be substituted by up to four C1 to C4 alkyl groups, phenyl, which can be substituted by up to two C1 to C4 alkyl radicals, C7 to C14 phenylalkyl or a group of the formula (II), X1 and X2 , when n is 0, are identical or different and represent halogen, phenyl or a group of the formulae (III), (IV) or (V) see diagramm : EP0075849,P13,F3 see diagramm : EP0075849,P13,F4 -DR**9 (V) but when n is 1, X2 is always a group of the formula see diagramm : EP0075849,P14,F1 with A being C4 to C11 alkylene, wherein, in the formulae (III), (IV) and (V), R**5 and R**6 are identical or different and represent radicals listed for R**2 and R**6 additionally has the meaning of C3 to C21 alkoxyalkyl, or R**5 and R**6 together with the N atom connecting them, also represent a pyrrolidine ring or a piperidine, morpholine or hexamethyleneimine ring which is unsubstituted or substituted by up to four C1 to C4 alkyl groups, r, s and t are identical or different whole numbers from 2 to 6 and v is from 0 to 3, R**7 and R**8 represent identical of different radicals with the meanings indicated for R**2 , T has the meaning of a group of the formula (VI) see diagramm : EP0075849,P14,F2 with X3 and X4 being identical or different radicals of the formulae (III), (IV) or (V), R**9 is one of the radicals mentioned under R**1 , when m is 0, and Y represents C2 to C18 alkylene, C2 to C12 bis(propyloxy)alkylene, monocycloalkylene, dicycloalkylene or tricycloalkylene having 6 to 18 C atoms, which can be substituted by up to four methyl groups and in which up to two C atoms can be replaced by N atoms which can carry propylene groups, or Y represents C6 to C18 arylene, or C7 to C14 aralkylene, or a piperazinylene radical can also take the place of the group see diagramm : EP0075849,P14,F3 or C5 to C6 azamonocycloalkylene or azadicycloalkylene radicals, substituted by up to four methyl groups, can take the place of the group see diagramm : EP0075849,P14,F4 or see diagramm : EP0075849,P14,F5 and in formula (I), at least one group of the formula (II) is present, preferably at least one group of the formula (II) per triazine ring. 1. Claims for the Contracting State : AT A process for the preparation of triazinyllactames of the formula (I) see diagramm : EP0075849,P15,F2 in which m is 0 or 1, n is also 0 or 1 and A is C4 to C11 alkylene, R**1 , when m is 0, has the meaning of hydrogen, of C1 to C18 alkyl, of C3 to C21 alkoxyalkyl, of C5 to C12 cycloalkyl, which can be substituted by C1 to C4 alkyl, or phenyl or naphthyl, which can be substituted by up to two Cl or C1 to C4 alkyl radicals or by one C1 to C4 alkoxy or C1 to C2 carboalkoxy group, of C7 to C14 phenylalkyl or of a group of the formula (II) see diagramm : EP0075849,P16,F1 wherein R**3 is hydrogen or methyl and R**4 is hydrogen, C1 to C4 alkyl, or is 2,3-epoxypropyl, allyl or benzyl, R**1 and R**2 , when m is 1, are identical or different and represent hydrogen, C1 to C18 alkyl, C5 to C12 cycloalkyl, which can be substituted by up to four C1 to C4 alkyl groups phenyl, which can be substituted by up to two C1 to C4 alkyl radicals C7 to C14 phenylalkyl or a group of the formula (II), X1 and X2 , when n is 0, are identical or different and represent halogen, phenyl or a group of the formulae (III), (IV) or (V) see diagramm : EP0075849,P16,F2 see diagramm : EP0075849,P16,F3 -DR**9 (V) but when n is 1, X2 is always a group of the formula see diagramm : EP0075849,P16,F4 with A being C4 to C11 alkylene, wherein, in the formulae (III), (IV) and (V), R**5 and R**6 are identical or different and represent radicals listed for R**2 and R**6 additionally has the meaning of C3 to C21 alkoxyalkyl, or R**5 and R**6 , together with the N atom connecting them, also represent a pyrrolidine ring or a piperidine, morpholine or hexamethyleneimine ring which is unsubstituted or substituted by up to four C1 to C4 alkyl groups, r, s, and t are identical or different whole numbers from 2 to 6 and v is from 0 to 3, R**7 and R**8 represent identical of different radicals with the meanings indicated for R**2 , T has the meaning of a group of the formula (VI) see diagramm : EP0075849,P16,F5 with X3 and X4 being identical or different radicals of the formulae (III), (IV) or (V), R**9 is one of the radicals mentioned under R**1 , when m is 0, and Y represents C2 to C18 alkylene, C2 to C12 bis(propyloxy)alkylene, monocycloalkylene, dicycloalkylene or tricycloalkylene having 6 to 18 C atoms, which can be substituted by up to four methyl groups and in which up to two C atoms can be replaced by N atoms which can carry propylene groups, or Y represents C6 to C18 arylene, or C7 to C14 aralkylene, or a piperazinylene radical can also take the place of the group see diagramm : EP0075849,P17,F1 or C5 to C9 azamonocycloalkylene or azadicycloalkylene radicals, substituted by up to four methyl groups, can take the place of the group see diagramm : EP0075849,P17,F2 or see diagramm : EP0075849,P17,F3 and in formula (I), at least one group of the formula (II) is present, preferably at least one group of the formula (II) per triazine ring, which comprises reacting a compound of the formula (VII) see diagramm : EP0075849,P17,F4 in which R**1 , R**2 , X1 , X2 , Y, m and n have the meanings indicated above and Hal is preferably chlorine, in an inert organic solvent at 100 to 200 degrees C with 1.0 to 1.05 times the equivalent amount, relative to the halogen atoms envisaged for the reaction, of the alkali metal salt of a lactam having 4 to 11 methylene groups.
DE8282108750T 1981-09-26 1982-09-22 Triazinyllactames, process for their preparation, their use as stabilisators for synthetic organic polymers and polymers stabilised by them Expired DE3276807D1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE8282108750T DE3276807D1 (en) 1981-09-26 1982-09-22 Triazinyllactames, process for their preparation, their use as stabilisators for synthetic organic polymers and polymers stabilised by them

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19813138343 DE3138343A1 (en) 1981-09-26 1981-09-26 TRIAZINYL LACTAME, METHOD FOR THE PRODUCTION THEREOF, THEIR USE AS STABILIZERS FOR SYNTHETIC ORGANIC POLYMERS AND THE POLYMERS STABILIZED WITH THEM
DE8282108750T DE3276807D1 (en) 1981-09-26 1982-09-22 Triazinyllactames, process for their preparation, their use as stabilisators for synthetic organic polymers and polymers stabilised by them

Publications (1)

Publication Number Publication Date
DE3276807D1 true DE3276807D1 (en) 1987-08-27

Family

ID=6142673

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19813138343 Withdrawn DE3138343A1 (en) 1981-09-26 1981-09-26 TRIAZINYL LACTAME, METHOD FOR THE PRODUCTION THEREOF, THEIR USE AS STABILIZERS FOR SYNTHETIC ORGANIC POLYMERS AND THE POLYMERS STABILIZED WITH THEM
DE8282108750T Expired DE3276807D1 (en) 1981-09-26 1982-09-22 Triazinyllactames, process for their preparation, their use as stabilisators for synthetic organic polymers and polymers stabilised by them

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE19813138343 Withdrawn DE3138343A1 (en) 1981-09-26 1981-09-26 TRIAZINYL LACTAME, METHOD FOR THE PRODUCTION THEREOF, THEIR USE AS STABILIZERS FOR SYNTHETIC ORGANIC POLYMERS AND THE POLYMERS STABILIZED WITH THEM

Country Status (4)

Country Link
EP (1) EP0075849B1 (en)
AT (1) ATE28456T1 (en)
DE (2) DE3138343A1 (en)
ZA (1) ZA827040B (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3417079A (en) * 1966-10-19 1968-12-17 Gaf Corp 2-alkylamino-4-halogeno-6-n-lactam-s-triazine derivatives
DE2933078A1 (en) * 1979-08-16 1981-03-26 Hoechst Ag, 65929 Frankfurt NEW TRIAZINE DERIVATIVES, THEIR PRODUCTION AND THEIR USE AS STABILIZERS FOR SYNTHETIC POLYMERS

Also Published As

Publication number Publication date
ZA827040B (en) 1983-08-31
EP0075849A3 (en) 1984-02-22
ATE28456T1 (en) 1987-08-15
EP0075849A2 (en) 1983-04-06
DE3138343A1 (en) 1983-04-07
EP0075849B1 (en) 1987-07-22

Similar Documents

Publication Publication Date Title
RO85264B (en) Process for preparing triazoline derivatives
ATE19630T1 (en) POLY-BIS-TRIAZINYLAMINES, PROCESS FOR THEIR PRODUCTION, THEIR USE IN STABILIZING SYNTHETIC POLYMERS AND THE POLYMERS SO STABILIZED.
ATE58525T1 (en) PYRROL DERIVATIVES, PROCESSES FOR THEIR PRODUCTION AND THEIR USE AS PESTICIDES.
DE3477195D1 (en) 1,6-naphthyridinone derivatives, process for their preparation, and medicaments containing them
EP0244098A3 (en) Thiazolotriazole herbicides
ES8800285A1 (en) A process for preparing thermically stable olefinic polymers.
GB1489595A (en) Bis-(triazinyl-amino)-stilbene-disulphonic acid derivatives
ATE38839T1 (en) PROCESS FOR THE PRODUCTION OF NUCLEOSIDALKYL, ARALKYL AND ARYLPHOSPHONITES AND PHOSPHONATES.
DE3276807D1 (en) Triazinyllactames, process for their preparation, their use as stabilisators for synthetic organic polymers and polymers stabilised by them
DE2963244D1 (en) Substituted bisbenzimidazole derivatives, their preparation and antiprotozoic and antiviral agents
KR850001907A (en) Insecticidal compounds and methods of making the compositions
TW222268B (en)
US3197463A (en) Certain aziridine compounds
ES423489A1 (en) Phthalocyanines, compositions derived therefrom and processes for their preparation
HUT34193A (en) Process for the production of substituted 6-aryl-1,2,4-triazolo/4,3-b/-pyridazin-derivatives and of pharmaceutic products containing such compounds
ES8202030A1 (en) Rifamycin XII derivatives, their preparation and anti-bacterial compositions thereof
EG13962A (en) Novel phenoxy-phenoxy-propionic acid amides,process for their manufacture and their use as herbicidal compositions
US2875235A (en) Production of bicyclo heterocyclic phosphoramides and thionophosphoramides
ES2024332A6 (en) New sulfonamides as antifungal agents.
IL59127A (en) Imidazo-and pyrimido-pyridoindolones,their preparation and pharmaceutical compositions containing them
FR2551751B1 (en) NOVEL PROCESS FOR PREPARING A PYROGLUTAMIC DERIVATIVE, NOVEL PYROGLUTAMIC DERIVATIVES, NOVEL SYNTHESIS FOR PREPARING THE SAME AND USE OR APPLICATION OF PYROGLUTAMIC DERIVATIVES AS ANTIBACTERIAL OR ANTIFUNGAL AGENTS
GB1008174A (en) Phosphorus esters containing a heterocyclic ring and having pesticidal properties
EP0281326A3 (en) Norbornadiene derivatives
GB1043502A (en) New betaines and process for their manufacture
RO82862B1 (en) 5-carbamoyloxymethyl-3, 7-dioxa-1-azabicyclo(3.3,0)octanic derivatives and process for preparing the same

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee