DE3063622D1 - Oxidation catalysts and process for the preparation of methacrolein by vapour phase oxidation - Google Patents
Oxidation catalysts and process for the preparation of methacrolein by vapour phase oxidationInfo
- Publication number
- DE3063622D1 DE3063622D1 DE8080303546T DE3063622T DE3063622D1 DE 3063622 D1 DE3063622 D1 DE 3063622D1 DE 8080303546 T DE8080303546 T DE 8080303546T DE 3063622 T DE3063622 T DE 3063622T DE 3063622 D1 DE3063622 D1 DE 3063622D1
- Authority
- DE
- Germany
- Prior art keywords
- oxidation
- methacrolein
- preparation
- vapour phase
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/084,254 US4280928A (en) | 1979-10-12 | 1979-10-12 | Catalyst compositions and their use for the preparation of methacrolein |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3063622D1 true DE3063622D1 (en) | 1983-07-07 |
Family
ID=22183785
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8080303546T Expired DE3063622D1 (en) | 1979-10-12 | 1980-10-09 | Oxidation catalysts and process for the preparation of methacrolein by vapour phase oxidation |
Country Status (6)
Country | Link |
---|---|
US (1) | US4280928A (de) |
EP (1) | EP0027351B1 (de) |
JP (1) | JPS5695339A (de) |
CA (1) | CA1128918A (de) |
DE (1) | DE3063622D1 (de) |
ES (1) | ES495892A0 (de) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5715842A (en) * | 1980-06-30 | 1982-01-27 | Nitto Chem Ind Co Ltd | Manufacture of highly active fluid catalyst from coarse grained catalyst |
DE3030243A1 (de) * | 1980-08-09 | 1982-03-18 | Basf Ag, 6700 Ludwigshafen | Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein |
US4347163A (en) * | 1980-10-03 | 1982-08-31 | Standard Oil Company | Te-containing methacrolein oxidation catalysts and their use |
JPS57130548A (en) * | 1981-02-05 | 1982-08-13 | Mitsubishi Chem Ind Ltd | Catalyst composition |
JPS5811041A (ja) * | 1981-07-13 | 1983-01-21 | Nitto Chem Ind Co Ltd | アンチモン含有金属酸化物触媒の製法 |
US4537874A (en) * | 1982-10-22 | 1985-08-27 | Nippon Shokubai Kagaku Kogyo Co Ltd | Catalyst for production of unsaturated aldehydes |
JPS59115750A (ja) * | 1982-12-22 | 1984-07-04 | Nippon Shokubai Kagaku Kogyo Co Ltd | メタクリル酸合成用触媒 |
US4568596A (en) * | 1984-07-18 | 1986-02-04 | Hercules Incorporated | Nonwoven fabric |
JP2720215B2 (ja) * | 1989-10-25 | 1998-03-04 | 三菱レイヨン株式会社 | メタクリル酸製造用触媒の調整法 |
US7361791B2 (en) * | 2003-03-31 | 2008-04-22 | Saudi Basic Industries Corporation | Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
US7232788B2 (en) * | 2003-03-31 | 2007-06-19 | Saudi Basic Industries Corporation | Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
CN100342968C (zh) * | 2003-12-03 | 2007-10-17 | 三菱化学株式会社 | 生产不饱和醛和不饱和羧酸的催化剂以及此催化剂的制备方法 |
US7649112B2 (en) | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon |
US7851397B2 (en) | 2005-07-25 | 2010-12-14 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
US7732367B2 (en) | 2005-07-25 | 2010-06-08 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
US7649111B2 (en) | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same |
US8921257B2 (en) | 2011-12-02 | 2014-12-30 | Saudi Basic Industries Corporation | Dual function partial oxidation catalyst for propane to acrylic acid conversion |
US8722940B2 (en) | 2012-03-01 | 2014-05-13 | Saudi Basic Industries Corporation | High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
WO2015190754A1 (ko) * | 2014-06-10 | 2015-12-17 | 주식회사 엘지화학 | 다성분계 복합금속산화물 촉매의 제조방법 |
DE102018200841A1 (de) * | 2018-01-19 | 2019-07-25 | Basf Se | Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen |
Family Cites Families (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3313856A (en) * | 1967-04-11 | Preparation of acrolein or methacrolein | ||
DE1125901B (de) * | 1959-12-19 | 1962-03-22 | Knapsack Ag | Verfahren zur Herstellung von Acrolein |
US3238254A (en) * | 1961-02-20 | 1966-03-01 | Petro Tex Chem Corp | Oxidation of alpha, beta unsaturated aldehydes in the presence of a catalyst containing v, p, cu and o |
FR1426166A (fr) * | 1964-09-14 | 1966-01-28 | Aquitaine Petrole | Catalyseur d'oxydation d'hydrocarbures oléfiniques |
FR1425301A (fr) * | 1964-09-15 | 1966-01-24 | Aquitaine Petrole | Catalyseur perfectionné pour l'oxydation d'hydrocarbures |
NL135123C (de) * | 1964-10-06 | |||
NL6512930A (de) * | 1964-10-06 | 1966-04-07 | ||
BE672279A (de) * | 1964-11-13 | |||
US3471556A (en) * | 1964-12-07 | 1969-10-07 | Nippon Kayaku Kk | Production of unsaturated aliphatic acids |
GB1156544A (en) * | 1966-10-01 | 1969-06-25 | Shorrock Dev | Improvements in or relating to a Message Transmission Apparatus |
US3959384A (en) * | 1969-05-02 | 1976-05-25 | Nippon Kayaku Kabushiki Kaisha | Oxidation catalyst and process for oxidation of olefins to unsaturated aldehydes |
BE757476A (fr) * | 1969-10-17 | 1971-03-16 | Nippon Kayaku Kk | Procede d'oxydeshydrogenation |
CA939676A (en) * | 1970-03-24 | 1974-01-08 | David Naden | Catalytic oxidation |
JPS494441B1 (de) * | 1970-11-07 | 1974-02-01 | ||
JPS4852713A (de) * | 1971-10-29 | 1973-07-24 | ||
US3925464A (en) * | 1971-12-14 | 1975-12-09 | Asahi Glass Co Ltd | Process for preparing unsaturated carboxylic acids from the corresponding unsaturated aldehydes |
US3966802A (en) * | 1972-03-09 | 1976-06-29 | Nippon Kayaku Kabushiki Kaisha | Process for preparing acrylic acid and oxidation catalyst |
NL171440C (nl) * | 1973-05-10 | 1983-04-05 | Japan Synthetic Rubber Co Ltd | Werkwijze voor het bereiden van methacroleien door katalytische oxydatie van isobuteen. |
US4111984A (en) * | 1973-06-11 | 1978-09-05 | Mitsubishi Rayon Co., Ltd. | Process for producing unsaturated aldehydes, and unsaturated fatty acids |
US3972920A (en) * | 1973-06-11 | 1976-08-03 | Mitsubishi Rayon Co., Ltd. | Process for producing unsaturated aldehydes, unsaturated fatty acids or conjugated dienes |
US3875220A (en) * | 1973-10-11 | 1975-04-01 | Standard Oil Co Ohio | Process for the preparation of methacrylic acid from methacrolein |
US3932551A (en) * | 1973-10-12 | 1976-01-13 | The Standard Oil Company | Process for the preparation of diolefins from olefins |
US4111983A (en) * | 1973-10-18 | 1978-09-05 | Union Carbide Corporation | Oxidation of unsaturated aldehydes to unsaturated acids |
US4075244A (en) * | 1973-11-22 | 1978-02-21 | Nippon Zeon Co. Ltd. | Process for preparing methacrylic acid |
GB1481039A (en) * | 1973-11-26 | 1977-07-27 | Nippon Zeon Co | Process for preparing unsaturated carboxylic acids and catalyst for use therein |
IT1045704B (it) * | 1973-11-28 | 1980-06-10 | Sir Soc Italiana Resine Spa | Perfezionamenti nel procedimento di preparazione dell acido acrilico |
IT1001977B (it) * | 1973-11-28 | 1976-04-30 | Sir Soc Italiana Resine Spa | Procedimento per la preparazione di acrilato di metile o di miscele di acrilato di metile ed acido acri lico |
IT1001978B (it) * | 1973-11-28 | 1976-04-30 | Sir Soc Italiana Resine Spa | Procedimento per la produzione di metilacrilato o di miscele di que sto con acido acrilico |
US4083804A (en) * | 1974-02-09 | 1978-04-11 | Nitto Chemical Industry Co., Ltd. | Catalyst for use in and process for preparing acrylonitrile |
US3956377A (en) * | 1974-06-17 | 1976-05-11 | The Standard Oil Company (Ohio) | Production of unsaturated acids from the corresponding aldehydes |
US4162234A (en) * | 1974-07-22 | 1979-07-24 | The Standard Oil Company | Oxidation catalysts |
JPS5242552B2 (de) * | 1974-08-01 | 1977-10-25 | ||
US4124634A (en) * | 1974-10-23 | 1978-11-07 | Asahi Glass Company, Ltd. | Process for producing methacrylic acid from isobutylene by two step oxidation |
JPS5341648B2 (de) * | 1974-12-06 | 1978-11-06 | ||
GB1490683A (en) * | 1975-03-12 | 1977-11-02 | Mitsubishi Rayon Co | Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene |
US4111985A (en) * | 1975-03-12 | 1978-09-05 | Mitsubishi Rayon Co., Ltd. | Process for producing unsaturated aldehydes and unsaturated carboxylic acids |
JPS51115414A (en) * | 1975-04-03 | 1976-10-12 | Mitsubishi Rayon Co Ltd | Process for preparation of unsaturated fatty acids |
US4136110A (en) * | 1975-08-18 | 1979-01-23 | The Standard Oil Company | Process for the preparation of unsaturated acids from unsaturated aldehydes |
US4051180A (en) * | 1976-01-02 | 1977-09-27 | The Standard Oil Company | Preparation of acrylic acid and methacrylic acid |
US4052332A (en) * | 1976-04-20 | 1977-10-04 | E. I. Du Pont De Nemours And Company | Catalyst regeneration with impregnation of bismuth and molybdenum |
US4335264A (en) * | 1976-07-07 | 1982-06-15 | E. I. Du Pont De Nemours And Company | High yield, low byproduct α, β-unsaturated aldehydes from olefins |
US4065507A (en) * | 1976-08-02 | 1977-12-27 | Standard Oil Company | Preparation of methacrylic derivatives from tertiary butyl-containing compounds |
JPS5319188A (en) * | 1976-08-06 | 1978-02-22 | Nippon Zeon Co Ltd | Olefin oxidation catalyst |
DE2735414A1 (de) * | 1976-08-06 | 1978-02-09 | Nippon Zeon Co | Oxydation von olefinen |
US4110369A (en) * | 1976-10-19 | 1978-08-29 | The Standard Oil Company | Process for the preparation of unsaturated acids from unsaturated aldehydes |
US4148758A (en) * | 1977-08-23 | 1979-04-10 | Exxon Research & Engineering Co. | Reforming with multimetallic catalysts |
-
1979
- 1979-10-12 US US06/084,254 patent/US4280928A/en not_active Expired - Lifetime
-
1980
- 1980-09-29 CA CA361,187A patent/CA1128918A/en not_active Expired
- 1980-10-09 EP EP80303546A patent/EP0027351B1/de not_active Expired
- 1980-10-09 DE DE8080303546T patent/DE3063622D1/de not_active Expired
- 1980-10-09 JP JP14189780A patent/JPS5695339A/ja active Granted
- 1980-10-13 ES ES495892A patent/ES495892A0/es active Granted
Also Published As
Publication number | Publication date |
---|---|
ES8201117A1 (es) | 1981-12-01 |
EP0027351B1 (de) | 1983-06-01 |
CA1128918A (en) | 1982-08-03 |
US4280928A (en) | 1981-07-28 |
EP0027351A1 (de) | 1981-04-22 |
JPS5695339A (en) | 1981-08-01 |
ES495892A0 (es) | 1981-12-01 |
JPH0149542B2 (de) | 1989-10-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8339 | Ceased/non-payment of the annual fee |