DE264243C - - Google Patents
Info
- Publication number
- DE264243C DE264243C DENDAT264243D DE264243DA DE264243C DE 264243 C DE264243 C DE 264243C DE NDAT264243 D DENDAT264243 D DE NDAT264243D DE 264243D A DE264243D A DE 264243DA DE 264243 C DE264243 C DE 264243C
- Authority
- DE
- Germany
- Prior art keywords
- printed
- printing ink
- acid
- anthraquinone
- etching
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 8
- 238000005530 etching Methods 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- RZVHIXYEVGDQDX-UHFFFAOYSA-N Anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 claims description 4
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 claims description 4
- AXZWODMDQAVCJE-UHFFFAOYSA-L Tin(II) chloride Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 claims description 4
- 235000002906 tartaric acid Nutrition 0.000 claims description 4
- 229960001367 tartaric acid Drugs 0.000 claims description 4
- 239000011975 tartaric acid Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 235000005985 organic acids Nutrition 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical compound [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 239000000984 vat dye Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000003638 reducing agent Substances 0.000 claims 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N Indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- QIJOTGQMDJOKJJ-UHFFFAOYSA-L [O-2].[Fe+4].S([O-])([O-])(=O)=O Chemical compound [O-2].[Fe+4].S([O-])([O-])(=O)=O QIJOTGQMDJOKJJ-UHFFFAOYSA-L 0.000 description 2
- QLRKASHXFNIPLZ-UHFFFAOYSA-M benzyl-dimethyl-phenylazanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[N+](C)(C)CC1=CC=CC=C1 QLRKASHXFNIPLZ-UHFFFAOYSA-M 0.000 description 2
- 235000019239 indanthrene blue RS Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- RODRRGLLKPAFKI-CCEZHUSRSA-N 2-amino-5-[(E)-(4-sulfophenyl)diazenyl]benzenesulfonic acid Chemical compound C1=C(OS(O)=O)C(N)=CC=C1\N=N\C1=CC=C(OS(O)=O)C=C1 RODRRGLLKPAFKI-CCEZHUSRSA-N 0.000 description 1
- 229940097275 Indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N Indigo Blue Chemical compound N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L Iron(II) sulfate Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N Iron(III) oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L Potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 229910000460 iron oxide Inorganic materials 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- -1 potassium sulfite Chemical class 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/155—Locally discharging the dyes with reductants
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- Ja 264243 KLASSE 8 ti. GRUPPE- Yes 264243 CLASS 8 ti. GROUP
MORITZ RIBBERT ACT.-GES.-in HOHENLIMBURG i.W.MORITZ RIBBERT ACT.-GES.-in HOHENLIMBURG i.W.
Verfahren zum Weiß- und Buntätzen indigogefärbter Gewebe mittels EisenoxydulsalzProcess for white and colored etching of indigo-dyed fabrics using iron oxide salt
und Alkalilauge.and alkali.
Patentiert im Deutschen Reiche vom 11. Oktober 1912 ab.Patented in the German Empire on October 11, 1912.
Es gibt ein Verfahren zum Ätzen von Indigo mittels Eisenoxydulsulfats unter Zugabe von Anthrachinon, Zinnsalz und Chlorzink und Durchnehmen durch Alkalilauge. Es gelingt in der Praxis nicht, brauchbare Resultate damit zu erzielen, da die Ätzung unvollkommen und außerdem noch sehr unsicher ist. Es wurde nun gefunden, daß man zu vollständig befriedigenden Resultaten gelangt,There is a method of etching indigo using ferrous sulfate with addition of anthraquinone, tin salt and zinc chloride and soaking through alkali. It succeeds in practice it is not possible to achieve useful results with it, since the etching is imperfect and is also very insecure. It has now been found that one too achieves completely satisfactory results,
ίο wenn man unter Weglassung von Chlorzink der Farbe die unter dem Namen Leukotrop W oder Primazol N in den Handel gebrachten Produkte (dimethylphenylbenzylammoniumhydroxydisulfosaures Natron oder auch andere quaternäre Alkarylammoniumverbindungen ähnlicher Zusammensetzung) nebst geringen Mengen organischer Säuren, wie Weinsäure, Oxalsäure, Essigsäure usw., zusetzt; auch können die organischen Säuren durch Sulfite, wie Kaliumsulfit, ersetzt werden; Eine Druckfarbe für ein dunkles Indigoblau setzt sich z. B. wie folgt zusammen:ίο if you omit zinc chloride the color of the products marketed under the name Leukotrop W or Primazol N (dimethylphenylbenzylammoniumhydroxydisulfosaures Soda or other quaternary alkarylammonium compounds are more similar Composition) together with small amounts of organic acids such as tartaric acid, oxalic acid, Acetic acid, etc., added; the organic acids can also be replaced by sulfites, such as potassium sulfite, be replaced; A printing ink for a dark indigo blue is e.g. B. how follows together:
Weißätze.White etching.
250 g Eisenoxydulsulfat,250 g iron oxide sulphate,
200 g Wasser,200 g water,
360 g Gummi verdickung 1Z1,360 g rubber thickening 1 Z 1 ,
40 g Anthrachinon 30 Prozent,
40 g Zinnsalz,40 g anthraquinone 30 percent,
40 g tin salt,
60 g Leukotrop W,60 g Leukotrope W,
50 g Weinsäure50 g of tartaric acid
1000 g.1000 g.
Nach dem Aufdruck wird getrocknet, eventuell kurz gedämpft, wodurch die Ätzwirkung bedeutend erhöht wird. Hierauf wird breit durch siedendes Natrorilaugebad 20 ° Be1. während 1J2 Minute passiert, gewaschen und zur Entfernung des Eisenoxyds gesäuert, gewaschen und getrocknet.After printing, it is dried, possibly briefly steamed, which significantly increases the etching effect. Then 20 ° Be 1 becomes wide through the boiling sodium hydroxide bath. happens during 1 J 2 minutes, washed and acidified to remove the ferric oxide, washed and dried.
Nachstehend folgt ein Beispiel einer Buntätzdruckfarbe (Ätzgelb).The following is an example of a color etching ink (Acid yellow).
60 g Indanthrengelb G pulv., 250 g Wasser,
250 g Eisenoxydulsulfat, 230 g Gummilösung 1J1,
60 g Zinnsalz,
60 g Leukotrop W,
40 g Anthrachinon 30 Prozent, 50 g Weinsäure60 g indanthrene yellow powder, 250 g water,
250 g iron oxide sulphate, 230 g rubber solution 1 J 1 , 60 g tin salt,
60 g Leukotrope W,
40 g anthraquinone 30 percent, 50 g tartaric acid
1000 g.1000 g.
Statt Indanthrengelb können auch andere blaue, grüne, rote usw. Küpenfarbstoffe Verwendung finden. Die Weiterbehandlung ist dieselbe wie oben angegeben.Instead of indanthrene yellow, other blue, green, red etc. vat dyes can also be used Find. Follow-up is the same as given above.
Claims (2)
Publications (1)
Publication Number | Publication Date |
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DE264243C true DE264243C (en) |
Family
ID=521575
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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DENDAT264243D Active DE264243C (en) |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE264243C (en) |
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0
- DE DENDAT264243D patent/DE264243C/de active Active
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