DE2509792B2 - TRANSFER COLOR - Google Patents

TRANSFER COLOR

Info

Publication number
DE2509792B2
DE2509792B2 DE19752509792 DE2509792A DE2509792B2 DE 2509792 B2 DE2509792 B2 DE 2509792B2 DE 19752509792 DE19752509792 DE 19752509792 DE 2509792 A DE2509792 A DE 2509792A DE 2509792 B2 DE2509792 B2 DE 2509792B2
Authority
DE
Germany
Prior art keywords
parts
dye
formula
transfer printing
print
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19752509792
Other languages
German (de)
Other versions
DE2509792C3 (en
DE2509792A1 (en
Inventor
Guenter Dipl.-Chem. Dr.; Preuss Guenter Ing.(grad.); 6700 Ludwigshafen Meyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority claimed from DE19752509792 external-priority patent/DE2509792C3/en
Priority to DE19752509792 priority Critical patent/DE2509792C3/en
Priority to IT48134/76A priority patent/IT1053859B/en
Priority to CH266976A priority patent/CH588594A5/xx
Priority to BE164817A priority patent/BE839144A/en
Priority to FR7606134A priority patent/FR2303056A1/en
Priority to GB8651/76A priority patent/GB1530531A/en
Priority to JP51023346A priority patent/JPS51111834A/en
Publication of DE2509792A1 publication Critical patent/DE2509792A1/en
Publication of DE2509792B2 publication Critical patent/DE2509792B2/en
Publication of DE2509792C3 publication Critical patent/DE2509792C3/en
Application granted granted Critical
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/28—Dyes with amino groups substituted by hydrocarbon radicals substituted by alkyl, aralkyl or cyclo alkyl groups
    • C09B1/285—Dyes with no other substituents than the amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D06P5/004—Transfer printing using subliming dyes
    • D06P5/006—Transfer printing using subliming dyes using specified dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)

Description

Die Erfindung betrifft die Verwendung des Farbstoffes der Formel IThe invention relates to the use of the dye of the formula I.

O NHQH,(n)O NHQH, (n)

O NHQHe(n)O NHQHe (n)

für den Transferdruck insbesondere auf Polyamid.for transfer printing, especially on polyamide.

Die Eignung des Farbstoffs der angegebenen Formel zur Färbung von Mineralölprodukten ist bekanntThe suitability of the dye of the formula given for coloring mineral oil products is known

Überraschenderweise eignet er sich ebenfalls vorzüglich für das Transferdruckverfahren z. B. für Polyester, insbesondere jedoch für Polyamid, wobei man blaue Drucke von vorzüglicher Licht- und Naßechtheit erhältSurprisingly, it is also ideally suited for the transfer printing process, for. B. for polyester, but especially for polyamide, which gives blue prints of excellent light and wet fastness

Das Transferdruckverfahren ist z. B. aus der französischen Patentschrift 12 23 330 und der DT-OS 17 69 757 bekannt, Farbstoffzubereitungen dafür sind beispielsweise in der DT-OS 17 71813 und entsprechende Hilfsträger in der DT-OS 17 71 812 beschrieben.The transfer printing process is z. B. from the French Patent specification 12 23 330 and DT-OS 17 69 757 known, dye preparations are for example in DT-OS 17 71813 and corresponding auxiliary carriers in DT-OS 17 71 812.

Aus der DT-OS 21 00 783 ist die Verwendung von z.B. 1,4-Di-isobutylaminoanthrachinon für den Transferdruck bekanntFrom DT-OS 21 00 783 the use of e.g. 1,4-di-isobutylaminoanthraquinone for transfer printing known

Überraschenderweise zeigt der Farbstoff der Formel I in den zumeist als Bindemittel verwendeten Cellulosederivaten, speziell Äthylceüulose, eine sehr viel bessere Dispergierbarkeit und Beständigkeit der damit hergestellten Druckfarben. Auch das SublimatJonsverhalten ist gegenüber dem bekannten Farbstoff sehr viel S besser, so daß man farbtiefere Drucke herstellen kann.Surprisingly, the dye of the formula I shows in the cellulose derivatives mostly used as binders, especially ethyl cellulose, a lot better dispersibility and resistance of the with it manufactured printing inks. Also the sublimate / consonant behavior S is much better than the known dye, so that prints with deeper colors can be produced.

Bei der nahen Verwandtschaft der beiden Verbindungen waren diese Effekte weder vorhersehbar noch zu erwarten.Given the close relationship between the two compounds, these effects were neither predictable nor possible expect.

In den folgenden Beispielen beziehen sich Angaben über Teile und Prozente, sofern nicht anders vermerkt, auf das GewichtIn the following examples, parts and percentages relate, unless otherwise stated, on weight

Beispiel 1example 1

Man bedruckt ein Umdruckpapier in einem geis wünschten Muster im Offsetdruck mit einer Farbe, die aus 7 Teilen des Farbstoffes der Formel I und 93 Teilen eines Firnis besteht, der sich wie folgt zusammensetzt:
40 Teile phenolmodifiziertes Kolophoniumharz,
20 TeQe vegetabilisch trocknende öle,
10 Teile langöliges Alkydharz,
25 Teile Mineralöl und
5TeileAerosiLA transfer paper is printed in a desired pattern in offset printing with an ink that consists of 7 parts of the dye of the formula I and 93 parts of a varnish, which is composed as follows:
40 parts of phenol modified rosin resin,
20 TeQe vegetable drying oils,
10 parts long oil alkyd resin,
25 parts mineral oil and
5PartsAerosil

Der getrocknete Druck wird mit der Druckseite auf ein Polyamidgewebe gelegt und auf einer Blattpresse 25 Sekunden bei 195°C behandelt Man erhält einen licht- und naßechten blauen Druck auf weißem Grund.The dried print is placed with the print side on a polyamide fabric and on a leaf press 25 Treated for seconds at 195 ° C. A lightfast and wetfast blue print on a white background is obtained.

Beispiel 2Example 2

Man bedruckt ein Papier im Tiefdruck mit einer Farbe, die aus 10 Teilen des Farbstoffes der Formel I und 90 Teilen eines Firnis besteht, der sich wie folgt zusammensetzt:A paper is printed by gravure printing with an ink composed of 10 parts of the dye of the formula I. and 90 parts of a varnish, which is composed as follows:

10 Teile Äthylcellulose,
75 Teile Äthylalkohol
20 Teile Äthylacetat und10 parts ethyl cellulose,
75 parts of ethyl alcohol
20 parts of ethyl acetate and

5TeileÄthylglykoL5 parts Ethyl GlycoL

Das getrocknete Papier läßt man, mit der bedruckten Seite auf einem Polyamidgewebe liegend, gemeinsam mit diesem 30 Sekunden bei 1900C durch einen Kalander laufen. Dabei wird der Farbstoff auf das Polyamidgewebe übertragen. Man erhält einen licht- und waschechten Druck auf weißem Grund.The dried paper is allowed to run, with the printed side on a polyamide fabric, together with this for 30 seconds at 190 ° C. through a calender. The dye is transferred to the polyamide fabric. A lightfast and washfast print is obtained on a white background.

Beispiel 3Example 3

Man bedruckt ein Papier im Rotationsfilmdruck mit einer Farbe, die aus 20 Teilen des Farbstoffes der Formel I, 280 Teilen Wasser und 700 Teilen einer 8%igen Kernmehlätherverdickung besteht und trocknet den Druck. Dann überträgt man das Papierdruckmuster auf die im Beispiel 2 beschriebene Weise in 30 Sekunden bei 205° C auf ein Polyestergewebe. Man erhält einen naßechten blauen Druck auf weißem GrundA paper is printed using rotary film printing with an ink composed of 20 parts of the dye Formula I, 280 parts of water and 700 parts of an 8% corn flour ether thickening consists and dries the pressure. The paper print pattern is then transferred to FIG. 30 in the manner described in Example 2 Seconds at 205 ° C on a polyester fabric. A wet-fast blue print on white is obtained reason

Claims (3)

Patentansprüche:
L Die Verwendung des Farbstoffes der FormelPatent claims:
L The use of the dye of the formula NHQH9(I1)NHQH 9 (I 1 ) für den Transferdruck.for transfer printing. 2. Druckfarben für den Transferdruck, enthaltend neben üblichen Bestandteilen den Farbstoff gemäß Anspruch 1.2. Printing inks for transfer printing, containing In addition to the usual constituents, the dye according to claim 1. 3. Hilfeträger für den Transferdruck, enthaltend als färbenden Bestandteil des Druckes den Farbstoff gemäß Anspruch 1.3. Auxiliary carrier for transfer printing, containing the dye as the coloring component of the print according to claim 1.
DE19752509792 1975-03-06 1975-03-06 Transfer dye Expired DE2509792C3 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE19752509792 DE2509792C3 (en) 1975-03-06 Transfer dye
IT48134/76A IT1053859B (en) 1975-03-06 1976-02-17 DYE FOR TRANSFER
CH266976A CH588594A5 (en) 1975-03-06 1976-03-03
BE164817A BE839144A (en) 1975-03-06 1976-03-03 COLORANT FOR TRANSFER PRINTING
FR7606134A FR2303056A1 (en) 1975-03-06 1976-03-04 COLORANT FOR TRANSFER PRINTING
GB8651/76A GB1530531A (en) 1975-03-06 1976-03-04 Transfer printing
JP51023346A JPS51111834A (en) 1975-03-06 1976-03-05 Dyes for transfer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19752509792 DE2509792C3 (en) 1975-03-06 Transfer dye

Publications (3)

Publication Number Publication Date
DE2509792A1 DE2509792A1 (en) 1976-09-16
DE2509792B2 true DE2509792B2 (en) 1977-03-31
DE2509792C3 DE2509792C3 (en) 1977-11-17

Family

ID=

Also Published As

Publication number Publication date
IT1053859B (en) 1981-10-10
BE839144A (en) 1976-09-03
FR2303056A1 (en) 1976-10-01
FR2303056B3 (en) 1978-12-01
GB1530531A (en) 1978-11-01
DE2509792A1 (en) 1976-09-16
CH588594A5 (en) 1977-06-15
JPS51111834A (en) 1976-10-02

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
E77 Valid patent as to the heymanns-index 1977
8330 Complete disclaimer