DE19960918A1

DE19960918A1 - Synergistic herbicidal combinations of active ingredients

Info

Publication number: DE19960918A1
Application number: DE19960918A
Authority: DE
Inventors: Mathias Kremer; Dieter Feucht; Arndt Wellmann; Peter Dahmen; Birgit Krauskopf
Original assignee: Bayer AG
Current assignee: Bayer CropScience AG
Priority date: 1999-11-18
Filing date: 1999-12-17
Publication date: 2001-05-23
Also published as: ZA200202759B

Abstract

The invention relates to novel herbicidal synergistic active substance combinations which comprise tritosulfuron and conventional herbicidally effective compounds and, optionally, compounds that improve the compatibility of cultivated plants. The inventive synergistic herbicidal active substance combinations can be used with particularly good success in selectively killing weeds in different useful plant crops, especially in crops consisting of cereals and corn.

Description

Die Erfindung betrifft neue synergistische, herbizide Wirkstoffkombinationen, die Tritosulfuron und bekannte, herbizid wirksame Verbindungen und gegebenenfalls die Kulturpflanzenverträglichkeit verbessernde Verbindungen umfassen, und mit be sonders gutem Erfolg zur selektiven Unkrautbekämpfung in verschiedenen Nutz pflanzenkulturen verwendet werden können.The invention relates to new synergistic, herbicidal combinations of active ingredients Tritosulfuron and known herbicidally active compounds and optionally the Crop tolerance improving compounds include, and with be particularly good success for selective weed control in various uses plant crops can be used.

Tritosulfuron (N-[[[4-methoxy-6-(trifluormethyl)-1,3,5-triazin-2-yl]amino]carbonyl]-2- trifluormethyl)-benzensulfonamid) ist als breit wirksames Herbizid Gegenstand einer Reihe von Patentanmeldungen (vgl. DE-A 40 38 430, WO-A 97/10714). Dieser Wirk stoff weist jedoch Wirkungslücken auf.Tritosulfuron (N - [[[4-methoxy-6- (trifluoromethyl) -1,3,5-triazin-2-yl] amino] carbonyl] -2- trifluoromethyl) -benzenesulfonamide) is the subject of a broadly active herbicide Series of patent applications (see. DE-A 40 38 430, WO-A 97/10714). This effect However, substance has gaps in effectiveness.

Überraschenderweise wurde nun gefunden, dass Tritosulfuron bei gemeinsamer An wendung mit bekannten, herbizid wirksamen Verbindungen aus verschiedenen Stoff klassen ausgesprochen synergistische Effekte hinsichtlich der Wirkung gegen Un kräuter zeigt, und dass solche breit wirksamen Kombinationspräparate besonders vorteilhaft zur selektiven Bekämpfung von Unkräutern in Nutzpflanzenkulturen, wie z. B. Weizen und Mais, verwendet werden können.Surprisingly, it has now been found that tritosulfuron when An Use with known, herbicidally active compounds from various substances Classes extremely synergistic effects with regard to the action against Un herbs shows, and that such broadly effective combination preparations especially advantageous for the selective control of weeds in crops such as e.g. B. wheat and corn can be used.

Überraschenderweise wurde ebenfalls gefunden, dass man mit Mischungen von Trito sulfuron mit weiteren bekannten, herbizid wirksamen Verbindungen bei gemeinsamer Anwendung mit den im weiteren beschriebenen, die Kulturpflanzenverträglichkeit ver bessernden Verbindungen (Safenern/Antidots) gegebenenfalls zusätzliche vorteilhafte Effekte erzielen kann.Surprisingly, it was also found that mixtures with Trito sulfuron with other known herbicidally active compounds together Use with the ver described below, the crop tolerance improving compounds (safeners / antidots), if necessary, additional advantageous Can achieve effects.

Gegenstand der Erfindung sind Mittel, gekennzeichnet durch einen synergistisch wirk samen Gehalt an einer Wirkstoffkombination umfassend
The invention relates to agents characterized by a synergistically active content of an active ingredient combination comprising

a) Tritosulfurona) Tritosulfuron

und
and

a) eine oder mehrere Verbindungen aus einer Gruppe von Herbiziden, welche die nachstehend genannten Wirkstoffe enthält:
(5-Trifluormethyl-1,3,4-thiadiazol-2-yl-oxy)-essigsäure-N-isopropyl-N-(4- fluorphenyl)-amid (Flufenacet, DE-A-38 21 600), 2-(2-Methoxycarbonyl phenylsulfonylaminocarbonyl)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4- triazol-3-on oder das Natriumsalz dieser Verbindung (Propoxycarba zone(-sodium), EP-A-507 171), 2-(2-Trifluormethoxy-phenylsulfonylamino carbonyl)-4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazol-3-on oder das Natriumsalz dieser Verbindung (Flucarbazone(-sodium), EP-A-507 171), N- (3,4-dichlorphenyl)propanamid (Propanil, DE-A-10 39 779), N-2-benzothia zolyl-N,N'-dimethylharnstoff (Methabenzthiazuron, GB-A-1085430), 4- Amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-on (Metri buzin, DE-A-17 95 784), 4-(2-Chlorphenyl)-N-cyclohexyl-N-ethyl-4,5-dihy dro-5-oxo-1H-tetrazol-1-carboxamid (Fentrazamide, EP-A-612 735), 4- Amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)-on (Metamitron, DE-A- 21 38 031), 2-(2-Benzothiazolyloxy)-N-methyl-N-phenylacetamid (Mefenacet, DE-A-28 22 155), 4-Amino-6-(1,1-dimethylethyl)-3-(ethylthio)- 1,2,4-triazin-5(4H)-on (Ethiozin, DE-A-15 42 873), 1-Methylethyl 5-[4- brom-1-methyl-5-(trifluormethyl)-1 H-pyrazol-3-yl]-2-chlor-4-fluorbenzoat (Fluazolate, WO-A-92/06 962)
("Wirkstoffe der Gruppe 1")a) one or more compounds from a group of herbicides which contains the active compounds mentioned below:
(5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) acetic acid-N-isopropyl-N- (4-fluorophenyl) -amide (Flufenacet, DE-A-38 21 600), 2- ( 2-methoxycarbonyl phenylsulfonylaminocarbonyl) -4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one or the sodium salt of this compound (Propoxycarba zone (-sodium), EP- A-507 171), 2- (2-trifluoromethoxy-phenylsulfonylamino carbonyl) -4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazol-3-one or the sodium salt of this compound ( Flucarbazone (-sodium), EP-A-507 171), N- (3,4-dichlorophenyl) propanamide (Propanil, DE-A-10 39 779), N-2-benzothiazolyl-N, N'-dimethylurea ( Methabenzthiazuron, GB-A-1085430), 4-amino-6- (1,1-dimethylethyl) -3- (methylthio) -1,2,4-triazin-5 (4H) -one (Metri buzin, DE-A -17 95 784), 4- (2-chlorophenyl) -N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamide, EP-A-612 735) , 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5 (4H) -one (Metamitron, DE-A-21 38 031), 2- (2-benzothiazolyloxy) -N-methyl -N-phenylacetamide (Mefenacet, DE-A-28 22 155), 4-amino-6- (1,1-dimethylethyl) -3- (ethylthio) - 1,2,4-triazin-5 (4H) -one (ethiozine, DE-A-15 42 873), 1 -Methylethyl 5- [4-bromo-1-methyl-5- (trifluoromethyl) -1 H-pyrazol-3-yl] -2-chloro-4-fluorobenzoate (fluazolates, WO-A-92/06 962)
("Active substances of group 1")

sowie gegebenenfalls
and if necessary

a) eine oder mehrere Verbindungen aus einer zweiten Gruppe von Herbiziden, welche die nachstehend genannten Wirkstoffe enthält:
2-Chlor-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamid (Aceto chlor), 5-(2-Chlor-4-trifluormethyl-phenoxy)-2-nitro-benzoesäure-Natrium salz (Acifluorfen-sodium), 2-Chlor-6-nitro-3-phenoxy-benzenamin (Aclonifen), 2-Chlor-N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-acetamid (Alachlor), N-Ethyl-N'-i-propyl-6-methylthio-1,3,5-triazin-2,4-diamin (Ametryn), 4-Amino-N-(1,1-Dimethyl-ethyl)-4,5-dihydro-3-(1-methyl-ethyl)- 5-oxo-1H-1,2,4-triazol-1-carboxamid (Amicarbazone), N-(4,6-Dimethoxy pyrimidin-2-yl)-N'-(N-methyl-N-methylsulfonyl-sulfamoyl)-harnstoff (Amidosulfuron), 1H-1,2,4-Triazol-3-amin (Amitrole), 6-Chlor-4-ethyl amino-2-isopropylamino-1,3,5-triazin (Atrazin), 2-[2,4-Dichlor-5-(2-prop inyloxy)-phenyl]-5,6,7,8-tetrahydro-1,2,4-triazolo-[4,3-a]-pyridin-3(2H)-on (Azafenidin), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-[1-methyl-4-(2-methyl- 2H-tetrazol-5-yl)-1H-pyrazol-5-ylsulfonyl]-harnstoff (Azimsulfuron), N- Benzyl-2-(4-fluor-3-trifluormethyl-phenoxy)-butanamid (Beflubutamid), 4- Chlor-2-oxo-3(2H)-benzthiazolessigsäure (Benazolin), N-Butyl-N-ethyl-2,6- dinitro-4-trifluormethyl-benzenamin (Benfluralin), N-(4,6-Dimethoxy-pyri midin-2-yl)-N'-(2-methoxycarbonyl-phenylmethylsulfonyl)-harnstoff (Ben sulfuron), 2-[2-[4-(3,6-Dihydro-3-methyl-2,6-dioxo-4-trifluormethyl-1(2H)- pyrimidinylphenoxymethyl]-5-ethyl-phenoxy-propansäure-methylester (Benzfendizone), 3-(2-Chlor-4-methylsulfonyl-benzoyl)-4-phenylthio-bi cyclo-[3.2.1]-oct-3-en-2-on (Benzobicyclon), Ethyl N-benzoyl-N-(3,4-di chlor-phenyl)-DL-alaninat (Benzoylprop-ethyl), 3-i-Propyl-1H-2,1,3-benzo thiadiazin-4(3H)-on (Bentazon), Methyl-5-(2,4-dichlor-phenoxy)-2-nitro benzoat (Bifenox), 2,6-Bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoesäure- Natriumsalz (Bispyribac-sodium), 2-Brom-3,3-dimethyl-N-(1-methyl-1- phenyl-ethyl)-butanamid (Bromobutide), 3,5-Dibrom-4-hydroxy-benz aldehyd-O-(2,4-dinitro-phenyl)-oxim (Bromofenoxim), 3,5-Dibrom-4-hy droxy-benzonitril (Bromoxynil), N-Butoxymethyl-2-chlor-N-(2,6-diethyl phenyl)-acetamid (Butachlor), 2-Chlor-5-(3,6-dihydro-3-methyl-2,6-dioxo-4- trifluormethyl-1(2H)-pyrimidinyl)-benzoesäure-[1,1-dimethyl-2-oxo-2-(2- propenyloxy)]-ethylester (Butafenacil-allyl), 2-(1-Ethoximino-propyl)-3- hydroxy-5-[2,4,6-trimethyl-3-(1-oxo-butyl)-phenyl]-2-cyclohexen-1-on (But roxydim), S-Ethyl-bis-(2-methyl-propyl)-thiocarbamat (Butylate), N,N- Diethyl-3-(2,4,6-trimethyl-phenylsulfonyl)-1H-1,2,4-triazol-1-carboxamid (Cafenstrole), 2-[1-[(3-Chlor-2-propenyl)-oxy-imino]-propyl]-3-hydroxy-5- (tetrahydro-2H-pyran-4-yl)-2-cyclohexen-1-on (Caloxydim, Tepraloxydim), 2-(4-Chlor-2-fluor-5-(2-chlor-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluor methyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-on (Carfentrazone-ethyl), 2,4-Dichlor-1-(3-methoxy-4-nitro-phenoxy)-benzol (Chlomethoxyfen), 3- Amino-2,5-dichlor-benzoesäure (Chloramben), N-(4-Chlor-6-methoxy-pyri midin-2-yl)-N'-(2-ethoxycarbonyl-phenylsulfonyl)-harnstoff (Chlorimuron ethyl), 1,3,5-Trichlor-2-(4-nitro-phenoxy)-benzol (Chlornitrofen), N-(4- Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-chlor-phenylsulfonyl)-harnstoff (Chlorsulfuron), N'-(3-Chlor-4-methyl-phenyl)-N,N-dimethyl-harnstoff (Chlortoluron), 2-Chlor-3-[2-chlor-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H- isoindol-2-yl)-phenyl]-2-propansäure-ethylester (Cinidon-ethyl), N-(4,6-Di methoxy-1,3,5-triazin-2-yl)-N'-(2-(2-methoxy-ethoxy)-phenylsulfonyl)-harn stoff (Cinosulfuron), 2-[1-[2-(4-Chlor-phenoxy)-propoxyaminobutyl]-5- (tetrahydro-2H-thiopyran-3-yl)-1,3-cyclohexandion (Clefoxydim), (E,E)-(+)- 2-[1-[[(3-Chlor-2-propenyl)-oxy]-imino]-propyl]-3-hydroxy-2-cyclohexen-1- on (Clethodim), (R)-(2-Propinyl)-2-[4-(5-chlor-3-fluor-pyridin-2-yl-oxy)- phenoxy-propanoat (Clodinafop-propargyl), 3,6-Dichlor-pyridin-2-carbon säure (Clopyralid), Methyl-3-chloro-2-[(5-ethoxy-7-fluor[1,2,4]triazolo[1,5- c]pyrimidin-2-yl-sulfonyl)-amino]-benzoat (Cloransulam-methyl), 2-Chlor-4- ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazin (Cyanazine), N- (4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2-cyclopropylcarbonyl-phenylsulfonyl)- harnstoff (Cyclosulfamuron), 2-(1-Ethoximinobutyl)-3-hydroxy-5-(tetra hydro-2H-thiopyran-3-yl)-2-cyclohexen-1-on (Cycloxydim), (R)-2-[4-(4- Cyano-2-fluor-phenoxy)-phenoxy]-propansäure-butylester (Cyhalofop-butyl), 2,4-Dichlor-phenoxyessigsäure (2,4-D), 3,6-Dichlor-2-methoxy-benzoesäure (Dicamba), (R)-2-(2,4-Dichlor-phenoxy)-propansäure (Dichlorprop-P), Methyl-2-[4-(2,4-dichlor-phenoxy)-phenoxy]-propanoat (Diclofop-methyl), N-(2,6-Dichlor-phenyl)-5-ethoxy-7-fluor-[1,2,4]-triazolo-[1,5-c]-pyrimidin-2- sulfonamid (Diclosulam), 1,2-Dimethyl-3,5-diphenyl-1H-pyrazolium-methyl sulfat (Difenzoquat), N-(2,4-Difluor-phenyl)-2-(3-trifluormethyl-phenoxy)- pyridin-3-carboxamid (Diflufenican), 2-[1-[(3,5-Difluor-phenyl)-amino carbonyl-hydrazono]-ethyl]-pyridin-3-carbonsäure (Diflufenzopyr), S-(1- Methyl-1-phenyl-ethyl)-1-piperidin-carbothioat (Dimepiperate), (S-) 2-Chlor- N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-acetamid (S-) (Di methenamid), 2-Amino-4-(1-fluor-1-methyl-ethyl)-6-(1-methyl-2-(3,5-di methyl-phenoxy)-ethylamino)-1,3,5-triazin (Dimexyflam), N3,N3-Diethyl- 2,4-dinitro-6-trifluormethyl-1,3-diamino-benzol (Dinitramine), 6,7-Dihydro dipyrido[1,2-a:2',1'-c]pyrazindüum (Diquat), S,S-Dimethyl-2-difluormethyl- 4-i-butyl-6-trifluormethyl-pyridin-3,5-dicarbothioat (Dithiopyr), N'-(3,4-Di chlor-phenyl)-N,N-dimethyl-harnstoff (Diuron), 2-[2-(3-Chlor-phenyl)- oxiranylmethyl]-2-ethyl-1-H-inden-1,3(2H)-dion (Epropodan), S-Ethyl-di propylthiocarbamat (EPTC), S-(Phenylmethyl)-N-ethyl-N-(1,2-dimethyl propyl)-thiocarbamat (Esprocarb), N-Ethyl-N-(2-methyl-2-propenyl)-2,6-di nitro-4-trifluormethyl-benzenamin (Ethalfluralin), (S)-(2-Ethoxy-1-methyl-2- oxoethyl)-2-chlor-5-(2-chlor-4-trifluormethyl-phenoxy)-benzoat (Ethoxyfen), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2-ethoxy-phenoxysulfonyl)-harnstoff (Ethoxysulfuron), (R)-Ethyl-2-[4-(6-chlor-benzoxazol-2-yl-oxy)-phenoxy]- propanoat (Fenoxaprop-(P)-ethyl), 4-(2-Chlor-phenyl)-N-cyclohexyl-N-ethyl- 4,5-dihydro-5-oxo-1H-tetrazol-1-carboxamid (Fentrazamide), Isopropyl-N- benzoyl-N-(3-chlor-4-fluro-phenyl)-DL-alaninat (Flamprop-isopropyl), Iso propyl-N-benzoyl-N-(3-chlor-4-fluro-phenyl)-L-alaninat (Flamprop-iso propyl-L), Methyl-N-benzoyl-N-(3-chlor-4-fluor-phenoxy)-DL-alaninat (Flamprop-methyl), N-(2,6-Difluor-phenyl)-8-fluor-5-methoxy-[1,2,4]- triazolo-[1,5-c]-pyrimidin-2-sulfonamid (Florasulam), (R)-2-[4-(5-Trifluor methyl-pyridin-2-yl-oxy)-phenoxy]-propansäure-butylester (Fluazifop, -butyl, -P-butyl), 5-(4-Brom-1-methyl-5-trifluormethyl-1H-pyrazol-3-yl)-2-chlor-4- fluor-benzoesäure-i-propylester (Fluazolate), 4,5-Dihydro-3-methoxy-4- methyl-S-oxo-N-[(2-trifluormethoxy-phenyl)-sulfonyl]-1-H-1,2,4-triazol-1- carboxamid-Natriumsalz (Flucarbazone-sodium), N-(4-Fluor-phenyl)-N-i- propyl-2-(5-trifluormethyl-1,3,4-thiadiazol-2-yl-oxy)-acetamid (Flufenacet), N-(2,6-Difluor-phenyl)-5-methyl-1,2,4-triazolo[1,5-a]-pyrimidin-2-sulfon amid (Flumetsulam), Pentyl-[2-chlor-4-fluor-5-(1,3,4, 5,6, 7-hexahydro-1,3- dioxo-2H-isoindol-2-yl)-phenoxy]-acetat (Flumiclorac-pentyl), 2-[7-Fluor- 3,4-dihydro-3-oxo-4-(2-propinyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetra hydro-1H-isoindol-1,3-dion (Flumioxazin), 2-[4-Chlor-2-fluor-5-[(1-methyl- 2-propinyl)-oxy]-phenyl]-4,5,6,7-tetrahydro-1H-isoindol-1,3(2H)-dion (Flumipropyn), 3-Chlor-4-chlormethyl-1-(3-trifluormethyl-phenyl)-2-pyrroli dinon (Fluorochloridone), 5-(2-Chlor-4-trifluormethyl-phenoxy)-2-nitro benzoesäure-ethoxycarbonylmethylester (Fluoroglycofen-ethyl), 1-(4-Chlor- 3-(2,2,3,3,3-pentafluor-propoxymethyl)-phenyl)-5-phenyl-1H-1,2,4-triazol-3 - carboxamid (Flupoxam), 1-Isopropyl-2-chlor-5-(3,6-dihydro-3-methyl-2,6-di oxo-4-trifluormethyl-1(2H)-pyrimidyl)-benzoat (Flupropacil), N-(4,6-Di methoxy-pyrimidin-2-yl)-N'-(3-methoxycarbonyl-6-trifluormethyl-pyridin-2- yl-sulfonyl)-harnstoff-Natriumsalz (Flupyrsulfuron-methyl-sodium), 9- Hydroxy-9H-fluoren-9-carbonsäure (Flurenol), (4-Amino-3,5-dichlor-6-fluor pyridin-2-yl-oxy)-essigsäure (-2-butoxy-1-methyl-ethylester, -1-methyl heptylester) (Fluroxypyr, -butoxypropyl, -meptyl), 5-Methylamino-2-phenyl- 4-(3-trifluormethyl-phenyl)-3(2H)-furanon (Flurtamone), Methyl-[(2-chlor-4- fluor-5-(tetrahydro-3-oxo-1 H,3H-[1,3,4]-thiadiazolo-[3,4-a]-pyridazin-1- yliden)-amino-phenyl]-thio-acetat (Fluthiacet-methyl), 5-(2-Chlor-4-trifluor methyl-phenoxy)-N-methylsulfonyl-2-nitro-benzamid (Fomesafen), 2- [[[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino)-sulfonyl)-4- formylamino-N,N-dimethyl-benzamid (Foramsulfuron), 2-Amino-4- (hydroxymethylphosphinyl)-butansäure (-ammoniumsalz) (Glufosinate (-ammonium)), N-Phosphonomethyl-glycin (-isopropylammmoniumsalz), (Glyphosate, -isopropylammonium), (R)-2-[4-(3-Chlor-5-trifluormethyl pyridin-2-yl-oxy)-phenoxy]-propansäure (-methylester, -2-ethoxy-ethylester, -butylester) (Haloxyfop, -methyl, -P-methyl, -ethoxyethyl, -butyl), 3-Cyclo hexyl-6-dimethylamino-1-methyl-1,3,5-triazin-2,4(1H,3H)-dion (Hexazin one), Methyl-2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)- 4-methyl-benzoat (Imazamethabenz-methyl), 2-(4,5-Dihydro-4-methyl-4-iso propyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridin-3-carbonsäure (Imaza methapyr), 2-(4,5-Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5- methoxymethyl-pyridin-3-carbonsäure (Imazamox), 2-(4,5-Dihydro-4- methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-chinolin-3-carbonsäure (Imaza quin), 2-(4,5-Dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl)-5-ethyl pyridin-3-carbonsäure (Imazethapyr), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'- (2-chlor-imidazo[1,2-a]-pyridin-3-yl-sulfonyl)-harnstoff (Imazosulfuron), N- (4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(5-iod-2-methoxycarbonyl phenylsulfonyl)-harnstoff-Natriumsalz (Iodosulfuron-methyl-sodium), 4-Hy droxy-3,5-diiod-benzonitril (Ioxynil), N,N-Dimethyl-N'-(4-isopropyl phenyl)-harnstoff (Isoproturon), N-(3-(1-Ethyl-1-methyl-propyl)-isoxazol-5- yl)-2,6-dimethoxy-benzamid (Isoxaben), (4-Chlor-2-methylsulfonyl-phenyl)- (5-cyclopropyl-isoxazol-4-yl)-methanon (Isoxachlortole), (5-Cyclopropyl isoxazol-4-yl)-(2-methylsulfonyl-4-trifluormethyl-phenyl)-methanon (Isoxa flutole), 2-[2-[4-[3,5-Dichlor-2-pyridinyl)-oxy]-phenoxy]-1-oxo-propyl]-is oxazolidin (Isoxapyrifop), (2-Ethoxy-1-methyl-2-oxo-ethyl)-5-(2-chlor-4-tri fluormethyl-phenoxy)-2-nitro-benzoat (Lactofen), N'-(3,4-dichlor-phenyl)-N- methoxy-N-methyl-harnstoff (Linuron), (4-Chlor-2-methyl-phenoxy)-essig säure (MCPA), 2-(4-Chlor-2-methyl-phenoxy)-propionsäure (Mecoprop), 2- (2-Benzthiazolyloxy)-N-methyl-N-phenyl-acetamid (Mefenacet), 2-(4- Methylsulfonyl-2-nitro-benzoyl)-1,3-cyclohexandion (Mesotrione), 4-Amino- 3-methyl-6-phenyl-1,2,4-triazin-5(4H)-on (Metamitron), 2-Chlor-N-(2,6-di methyl-phenyl)-N-(1H-pyrazol-1-yl-methyl)-acetamid (Metazachlor), N-(4- (3,4-Dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy)- phenyl)-N-methoxy-N-methyl-harnstoff (Metobenzuron), N'-(4-Brom phenyl)-N-methoxy-N-methylharnstoff (Metobromuron), (S)-2-Chlor-N-(2- ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-acet-amid (Metola chlor, S-Metolachlor), N-(2,6-Dichlor-3-methyl-phenyl)-5,7-dimethoxy- 1,2,4-triazolo[1,5-a]-pyrimidin-2-sulfonamid (Metosulam), N'-(3-Chlor-4- methoxy-phenyl)-N,N-dimethyl-harnstoff (Metoxuron), 4-Amino-6-tert.- butyl-3-methylthio-1,2,4-triazin-5(4H)-on (Metribuzin), N-(4-Methoxy-6- methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Metsulfuron-methyl), S-Ethyl-hexahydro-1H-azepin-1-carbothioat (Moli nate), 2-(2-Naphthyloxy)-N-phenyl-propanamid (Naproanilide), N-Butyl-N'- (3,4-dichlor-phenyl)-N-methyl-harnstoff (Neburon), N-(4,6-Dimethoxy-pyri midin-2-yl)-N'-(3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl)-harnstoff (Nico sulfuron), S-(2-Chlor-benzyl)-N,N-diethyl-thiocarbamat (Orbencarb), 4-Di propylamino-3,5-dinitro-benzensulfonamid (Oryzalin), 3-[2,4-Dichlor-5-(2- propinyloxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)-on (Oxadiargyl), 3- [2,4-Dichlor-5-(1-methyl-ethoxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)- on (Oxadiazon), N-(4,6-Dimethyl-pyrimidin-2-yl)-N'-(2-oxetan-3-yl-oxy carbonyl-phenylsulfonyl)-harnstoff (Oxasulfuron), 3-[1-(3,5-Dichlor-phenyl)- 1-i-propyl]-2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-on (Oxaziclo mefone), 2-Chlor-1-(3-ethoxy-4-nitro-phenoxy)-4-trifluormethyl-benzen (Oxyfluorfen), 1,1'-Dimethyl-4,4'-bipyridinium (Paraquat), 1-Amino-N-(1- ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzol (Pendimethalin), 4-(t-Butyl)-N- (1-ethyl-propyl)-2,6-dinitro-benzenamin (Pendralin), 4-Amino-3,5,6-trichlor pyridin-2-carbonsäure (Picloram), 2-Chlor-N-(2,6-diethyl-phenyl)-N-(2-prop oxy-ethyl)-acetamid (Pretilachlor), N-(4,6-Bis-difluormethoxy-pyrimidin-2- yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Primisulfuron methyl), 1-Chlor-N-[2-chlor-4-fluor-5-[(6S,7aR)-6-fluor-tetrahydro-1,3-di oxo-1H-pyrrolo[1,2-c]imidazol-2(3H)-yl]-phenyl]-methansulfonamid (Proflu azol), 2-Chlor-N-isopropyl-N-phenyl-acetamid (Propachlor), N-(3,4-Dichlor phenyl)-propanamid (Propanil), (R)-[2-[[(1-Methyl-ethyliden)-amino]-oxy]- ethyl]-2-[4-(6-chlor-2-chinoxalinyloxy)-phenoxy]-propanoat (Propaquizafop), 2-Chlor-N-(2-ethyl-6-methyl-phenyl)-N-[(1-methyl-ethoxy)-methyl]-acet amid (Propisochlor), 2-[[[(4,5-Dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4- triazol-1-yl)-carbonyl]-amino]-sulfonyl]-benzoesäure-methylester-Natrium salz (Propoxycarbazone-sodium), S-Phenylmethyl-N,N-dipropyl-thiocarb amat (Prosulfocarb), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-(3,3,3- trifluor-propyl)-phenylsulfonyl)-harnstoff (Prosuliron), Ethyl-[2-Chlor-5-(4- chlor-5-difluormethoxy-1-methyl-1H-pyrazol-3-yl)-4-fluor-phenoxy]-acetat (Pyraflufen-ethyl), 1-(3-Chlor-4,5,6,7-tetrahydro-pyrazolo[1,5-a]pyridin-2- yl)-5-(methyl-2-propinylamino)-1H-pyrazol-4-carbonitril (Pyrazogyl), 4-(2,4- Dichlor-benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulfonyloxy)-pyrazol (Pyr azolate), 4-(2,4-Dichlor-benzoyl)-1,3-dimethyl-5-(phenylcarbonylmethoxy)- pyrazol (Pyrazoxyfen), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(4-ethoxy carbonyl-1-methyl-pyrazol-5-yl-sulfonyl)-harnstoff (Pyrazosulfuron-ethyl), Diphenylmethanon-O-[2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoyl]- oxim (Pyribenzoxim), 6-Chlor-3-phenyl-4-pyridazinol (Pyridafol), O-(6- Chlor-3-phenyl-pyridazin-4-yl)-S-octyl-thiocarbonat (Pyridate), 6-Chlor-3- phenyl-pyridazin-4-ol (Pyridatol), 7-[(4,6-Dimethoxy-2-pyrimidinyl)-thio]-3- methyl-1(3H)-isobenzofuranon (Pyriftalid), 2-(4,6-Dimethoxy-pyrimidin-2- yl-oxy)-benzoesäure-methylester (Pyriminobac-methyl), 2-Chlor-6-(4,6-di methoxy-pyrimidin-2-ylthio)-benzoesäure-Natriumsalz (Pyrithiobac-sodium), 3,7-Dichlor-chinolin-8-carbonsäure (Quinchlorac), 7-Chlor-3-methyl chinolin-8-carbonsäure (Quinmerac), 2-[4-(6-Chlor-2-chinoxalinyloxy)-phen oxy]-propansäure (-ethylester, -tetrahydro-2-furanyl-methylester) (Quizalo fop, -ethyl, -P-ethyl, -P-tefuryl), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(3- ethylsulfonyl-pyridin-2-yl-sulfonyl)-harnstoff (Rimsulfuron), 2-(1-Ethox iminobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-2-cyclohexen-1-on (Sethoxy dim), 6-Chlor-2,4-bis-ethylamino-1,3,5-triazin (Simazin), 2-(2-Chlor-4- methylsulfonyl-benzoyl)-cyclohexan-1,3-dion (Sulcotrione), 2-(2,4-Dichlor- 5-methylsulfonylamino-phenyl)-4-difluormethyl-5-methyl-2,4-dihydro-3H- 1,2,4-triazol-3-on (Sulfentrazone), N-Phosphonomethyl-glycin-trimethyl sulfonium (Sulfosate), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2-ethyl sulfonyl-imidazo[1,2-a]pyridin-3-sulfonamid (Sulfosulfuron), 6-Chlor-4- ethylamino-2-tert-butylamino-1,3,5-triazin (Terbuthylazine), 2-tert.-Butyl amino-4-ethylamino-6-methylthio-1,3,5-triazin (Terbutryn), 2-Chlor-N-(2,6- dimethyl-phenyl)-N-(3-methoxy-2-thienyl-methyl)-acetamid (Thenylchlor), 2-Difluormethyl-5-(4,5-dihydro-thiazol-2-yl)-4-(2-methyl-propyl)-6-trifluor methyl-pyridin-3-carbonsäure-methylester (Thiazopyr), 6-(6,7-Dihydro-6,6- dimethyl-3H,5H-pyrrolo[2,1-c]-1,2,4-thiadiazol-3-ylidenamino)-7-fluor-4-(2- propinyl)-2H-1,4-benzoxazin-3(4H)-on (Thidiazimin), N-(4-Methoxy-6- methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-thien-3-yl-sulfonyl)-harn stoff (Thifensulfuron-methyl), 2-(Ethoximino-propyl)-3-hydroxy-5-(2,4,6-tri methyl-phenyl)-2-cyclohexen-1-on (Tralkoxydim), S-(2,3,3-Trichlor-2- propenyl)-diisopropylcarbamothioat (Triallate), N-(4-Methoxy-6-methyl- 1,3,5-triazin-2-yl)-N'-[2-(2-chlor-ethoxy)-phenylsulfonyl]-harnstoff (Triasul furon), N-Methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxy carbonyl-phenylsulfonyl)-harnstoff (Tribenuron-methyl), (3,5,6-Trichlor)- pyridin-2-yl-oxy-essigsäure (Triclopyr), 2-(3,5-Dichlor-phenyl)-2-(2,2,2-tri chlor-ethyl)-oxiran (Tridiphane), N-[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]- carbonyl]-3-(2,2,2-trifluor-ethoxy)-2-pyridinsulfonamid-Natriumsalz (Tri floxysulfuron), 1-Amino-2,6-dinitro-N,N-dipropyl-4-trifluormethyl-benzol (Trifluralin), N-[4-Dimethylamino-6-(2,2,2-trifluor-ethoxy)-1,3,5-triazin-2- yl]-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Triflusulfuron methyl), N-[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3-(N-methyl- N-methylsulfonyl-amino])-2-pyridinsulfonamid, (vgl. WO-A-92/10 660), 2- [[[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]-4- [[(methylsulfonyl)-amino]methyl]-benzoesäure-methylester (vgl. DE-A- 43 35 297), 4-[4,5-Dihydro-4-methyl-5-oxo-(3-trifluormethyl)-1H-1,2,4-tri azol-1-yl]-2-[(ethylsulfonyl)amino]-5-fluor-benzencarbothioamid (vgl. WO- A-95/30 661)
("Wirkstoffe der Gruppe 2"),a) one or more compounds from a second group of herbicides which contains the active compounds mentioned below:
2-chloro-N- (ethoxymethyl) -N- (2-ethyl-6-methyl-phenyl) -acetamide (aceto chlorine), 5- (2-chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoic acid- Sodium salt (Acifluorfen-sodium), 2-chloro-6-nitro-3-phenoxy-benzenamine (Aclonifen), 2-chloro-N- (methoxymethyl) -N- (2,6-diethyl-phenyl) -acetamide (alachlor ), N-ethyl-N'-i-propyl-6-methylthio-1,3,5-triazine-2,4-diamine (ametryn), 4-amino-N- (1,1-dimethyl-ethyl) - 4,5-dihydro-3- (1-methyl-ethyl) - 5-oxo-1H-1,2,4-triazole-1-carboxamide (amicarbazone), N- (4,6-dimethoxy pyrimidin-2-yl ) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), 1H-1,2,4-triazol-3-amine (amitrole), 6-chloro-4-ethyl amino-2- isopropylamino-1,3,5-triazine (atrazine), 2- [2,4-dichloro-5- (2-propynyloxy) phenyl] -5,6,7,8-tetrahydro-1,2,4- triazolo- [4,3-a] pyridin-3 (2H) -one (azafenidin), N- (4,6-dimethoxypyrimidin-2-yl) -N '- [1-methyl-4- (2nd -methyl- 2H-tetrazol-5-yl) -1H-pyrazol-5-ylsulfonyl] urea (azimsulfuron), N-benzyl-2- (4-fluoro-3-trifluoromethyl-phenoxy) -butanamide (beflubutamide), 4 - chlorine 2-oxo-3 (2H) -benzthiazole acetic acid (benazoline), N-butyl-N-ethyl-2,6-dinitro-4-trifluoromethyl-benzenamine (benfluralin), N- (4,6-dimethoxy-pyrimidine-2 -yl) -N '- (2-methoxycarbonylphenylmethylsulfonyl) urea (ben sulfuron), 2- [2- [4- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl- 1 (2H) -pyrimidinylphenoxymethyl] -5-ethyl-phenoxypropanoic acid methyl ester (benzfendizone), 3- (2-chloro-4-methylsulfonyl-benzoyl) -4-phenylthio-bi cyclo- [3.2.1] -oct- 3-en-2-one (benzobicyclone), ethyl N-benzoyl-N- (3,4-di chlorophenyl) -DL-alaninate (benzoylprop-ethyl), 3-i-propyl-1H-2,1, 3-benzothiadiazin-4 (3H) -one (bentazone), methyl 5- (2,4-dichlorophenoxy) -2-nitro benzoate (bifenox), 2,6-bis- (4,6-dimethoxy- pyrimidin-2-yl-oxy) -benzoic acid sodium salt (bispyribac-sodium), 2-bromo-3,3-dimethyl-N- (1-methyl-1-phenyl-ethyl) -butanamide (bromobutide), 3.5 -Dibromo-4-hydroxy-benzaldehyde-O- (2,4-dinitro-phenyl) -oxime (bromofenoxime), 3,5-dibromo-4-hy droxy-benzonitrile (bromoxynil), N-butoxymethyl-2-chlorine -N- (2,6-diethylphenyl) aceta mid (butachlor), 2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) -benzoic acid- [1,1-dimethyl-2 -oxo-2- (2-propenyloxy)] ethyl ester (butafenacil-allyl), 2- (1-ethoximino-propyl) -3-hydroxy-5- [2,4,6-trimethyl-3- (1-oxo -butyl) -phenyl] -2-cyclohexen-1-one (butoxydim), S-ethyl-bis- (2-methyl-propyl) -thiocarbamate (butylate), N, N-diethyl-3- (2.4 , 6-trimethyl-phenylsulfonyl) -1H-1,2,4-triazole-1-carboxamide (cafenstrole), 2- [1 - [(3-chloro-2-propenyl) -oxy-imino] -propyl] -3 -hydroxy-5- (tetrahydro-2H-pyran-4-yl) -2-cyclohexen-1-one (caloxydim, tepraloxydim), 2- (4-chloro-2-fluoro-5- (2-chloro-2- ethoxycarbonyl-ethyl) -phenyl) -4-difluoro methyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (Carfentrazone-ethyl), 2,4-dichloro-1- (3-methoxy-4-nitro-phenoxy) benzene (chloromethoxyfen), 3-amino-2,5-dichloro-benzoic acid (chlorambene), N- (4-chloro-6-methoxy-pyrimidin-2-yl) -N '- (2-ethoxycarbonyl-phenylsulfonyl) urea (chlorimuron ethyl), 1,3,5-trichloro-2- (4-nitro-phenoxy) benzene (chloronitrofen), N- (4th - methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-chlorophenylsulfonyl) urea (chlorosulfuron), N' - (3-chloro-4-methylphenyl) -N, N-dimethyl-urea (chlorotoluron), 2-chloro-3- [2-chloro-5- (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindole- Ethyl 2-yl) -phenyl] -2-propanoate (cinidon-ethyl), N- (4,6-dimethoxy-1,3,5-triazin-2-yl) -N '- (2- (2nd -methoxy-ethoxy) -phenylsulfonyl) urea (cinosulfuron), 2- [1- [2- (4-chlorophenoxy) propoxyaminobutyl] -5- (tetrahydro-2H-thiopyran-3-yl) -1, 3-cyclohexanedione (clefoxydim), (E, E) - (+) - 2- [1 - [[(3-chloro-2-propenyl) -oxy] -imino] -propyl] -3-hydroxy-2-cyclohexene -1- one (clethodim), (R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yl-oxy) phenoxy propanoate (clodinafop propargyl), 3,6-dichloropyridine-2-carboxylic acid (clopyralide), methyl-3-chloro-2 - [(5-ethoxy-7-fluoro [1,2,4] triazolo [1,5-c] pyrimidine- 2-yl-sulfonyl) amino] benzoate (chlorosulam-methyl), 2-chloro-4-ethylamino-6- (1-cyano-1-methyl-ethylamino) -1,3,5-triazine (cyanazine), N- (4,6-Dimethoxypyrimidin-2-yl) -N '- (2-cyc lopropylcarbonylphenylsulfonyl) urea (cyclosulfamuron), 2- (1-ethoximinobutyl) -3-hydroxy-5- (tetra hydro-2H-thiopyran-3-yl) -2-cyclohexen-1-one (cycloxydim), (R. ) -2- [4- (4- Cyano-2-fluorophenoxy) phenoxy] propanoic acid butyl ester (cyhalofop butyl), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6- Dichloro-2-methoxy-benzoic acid (Dicamba), (R) -2- (2,4-dichlorophenoxy) propanoic acid (dichloroprop-P), methyl 2- [4- (2,4-dichlorophenoxy) -phenoxy] propanoate (diclofop-methyl), N- (2,6-dichlorophenyl) -5-ethoxy-7-fluoro [1,2,4] triazolo [1,5-c] pyrimidine -2-sulfonamide (diclosulam), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methyl sulfate (difenzoquat), N- (2,4-difluorophenyl) -2- (3-trifluoromethylphenoxy ) - pyridine-3-carboxamide (diflufenican), 2- [1 - [(3,5-difluorophenyl) amino carbonyl hydrazono] ethyl] pyridine-3-carboxylic acid (diflufenzopyr), S- (1- Methyl 1-phenyl-ethyl) -1-piperidine carbothioate (dimepiperate), (S-) 2-chloro-N- (2,4-dimethyl-3-thienyl) -N- (2-methoxy-1-methyl -ethyl) -acetamide (S-) (dimethenamid), 2-A mino-4- (1-fluoro-1-methyl-ethyl) -6- (1-methyl-2- (3,5-dimethyl-phenoxy) -ethylamino) -1,3,5-triazine (dimexyflam), N3, N3-diethyl-2,4-dinitro-6-trifluoromethyl-1,3-diamino-benzene (dinitramine), 6,7-dihydro dipyrido [1,2-a: 2 ', 1'-c] pyrazine ( Diquat), S, S-dimethyl-2-difluoromethyl-4-i-butyl-6-trifluoromethyl-pyridine-3,5-dicarbothioate (dithiopyr), N '- (3,4-di chlorophenyl) -N, N-dimethyl-urea (diuron), 2- [2- (3-chlorophenyl) oxiranylmethyl] -2-ethyl-1-H-indene-1,3 (2H) -dione (epropodane), S-ethyl -di propylthiocarbamate (EPTC), S- (phenylmethyl) -N-ethyl-N- (1,2-dimethylpropyl) -thiocarbamate (Esprocarb), N-ethyl-N- (2-methyl-2-propenyl) -2 , 6-di nitro-4-trifluoromethylbenzamine (ethalfluralin), (S) - (2-ethoxy-1-methyl-2-oxoethyl) -2-chloro-5- (2-chloro-4-trifluoromethylphenoxy) -benzoate (ethoxyfen), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (2-ethoxyphenoxysulfonyl) urea (ethoxysulfuron), (R) -ethyl-2- [4- ( 6-chloro-benzoxazol-2-yl-oxy) phenoxy] propanoate (fenoxaprop- (P) -ethyl), 4- (2-chlorophenyl) -N-cyclohexyl- N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamide), isopropyl-N-benzoyl-N- (3-chloro-4-fluro-phenyl) -DL-alaninate (Flamprop -isopropyl), isopropyl-N-benzoyl-N- (3-chloro-4-fluro-phenyl) -L-alaninate (Flamprop-iso propyl-L), methyl-N-benzoyl-N- (3-chloro 4-fluoro-phenoxy) -DL-alaninate (Flamprop-methyl), N- (2,6-difluorophenyl) -8-fluoro-5-methoxy- [1,2,4] - triazolo- [1,5 -c] -pyrimidine-2-sulfonamide (florasulam), (R) -2- [4- (5-trifluoromethyl-pyridin-2-yl-oxy) -phenoxy] -propanoic acid butyl ester (fluazifop, -butyl, - P-butyl), 5- (4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl) -2-chloro-4-fluoro-benzoic acid i-propyl ester (fluazolates), 4,5- Dihydro-3-methoxy-4-methyl-S-oxo-N - [(2-trifluoromethoxyphenyl) sulfonyl] -1-H-1,2,4-triazole-1-carboxamide sodium salt (Flucarbazone-sodium) , N- (4-fluorophenyl) -ni-propyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (flufenacet), N- (2,6-difluoro -phenyl) -5-methyl-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (flumetsulam), pentyl- [2-chloro-4-fluoro-5- ( 1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenoxy] acetate (flumiclorac-pentyl), 2- [7-fluoro-3,4- dihydro-3-oxo-4- (2-propynyl) -2H-1,4-benzoxazin-6-yl] -4,5,6,7-tetra hydro-1H-isoindole-1,3-dione (flumioxazin) , 2- [4-chloro-2-fluoro-5 - [(1-methyl-2-propynyl) -oxy] phenyl] -4,5,6,7-tetrahydro-1H-isoindole-1,3 (2H ) -dione (flumipropyn), 3-chloro-4-chloromethyl-1- (3-trifluoromethyl-phenyl) -2-pyrrolidinone (fluorochloridone), 5- (2-chloro-4-trifluoromethyl-phenoxy) -2-nitro benzoic acid ethoxycarbonylmethyl ester (fluoroglycofen-ethyl), 1- (4-chloro-3- (2,2,3,3,3-pentafluoropropoxymethyl) phenyl) -5-phenyl-1H-1,2,4-triazole -3 - carboxamide (flupoxam), 1-isopropyl-2-chloro-5- (3,6-dihydro-3-methyl-2,6-di oxo-4-trifluoromethyl-1 (2H) -pyrimidyl) -benzoate ( Flupropacil), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl) urea sodium salt (flupyrsulfuron-methyl-sodium ), 9-hydroxy-9H-fluoren-9-carboxylic acid (flurenol), (4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) -es acetic acid (-2-butoxy-1-methyl-ethyl ester, -1-methyl heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 5-methylamino-2-phenyl-4- (3-trifluoromethyl-phenyl) -3 (2H ) furanon (flurtamone), methyl - [(2-chloro-4-fluoro-5- (tetrahydro-3-oxo-1 H, 3H- [1,3,4] -thiadiazolo- [3,4-a] -pyridazin-1-ylidene) -amino-phenyl] -thio-acetate (Fluthiacet-methyl), 5- (2-chloro-4-trifluoromethyl-phenoxy) -N-methylsulfonyl-2-nitro-benzamide (Fomesafen), 2- [[[[(4,6-Dimethoxy-2-pyrimidinyl) amino] carbonyl] amino) sulfonyl) -4-formylamino-N, N-dimethyl-benzamide (foramsulfuron), 2-amino-4 - (hydroxymethylphosphinyl) butanoic acid (ammonium salt) (glufosinate (ammonium)), N-phosphonomethylglycine (isopropyl ammonium salt), (glyphosate, isopropyl ammonium), (R) -2- [4- (3-chloro-5 -trifluoromethyl pyridin-2-yl-oxy) -phenoxy] -propanoic acid (-methyl ester, -2-ethoxy-ethyl ester, -butyl ester) (haloxyfop, -methyl, -P-methyl, -ethoxyethyl, -butyl), 3-cyclo hexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4 (1H, 3H) -dione (Hexazin one), methyl-2- (4,5-di hydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) - 4-methyl-benzoate (imazamethabenz-methyl), 2- (4,5-dihydro-4-methyl-4-iso propyl-5-oxo-1H-imidazol-2-yl) -5-methyl-pyridine-3-carboxylic acid (Imaza methapyr), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo 1H-imidazol-2-yl) -5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl ) -quinoline-3-carboxylic acid (Imaza quin), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -5-ethyl pyridin-3 -carboxylic acid (imazethapyr), N- (4,6-dimethoxy-pyrimidin-2-yl) -N'- (2-chloro-imidazo [1,2-a] pyridin-3-yl-sulfonyl) urea ( Imazosulfuron), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (5-iodo-2-methoxycarbonyl phenylsulfonyl) urea sodium salt (iodosulfuron-methyl-sodium ), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), N, N-dimethyl-N '- (4-isopropylphenyl) urea (isoproturon), N- (3- (1-ethyl-1 -methyl-propyl) -isoxazol-5-yl) -2,6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methylsulfonyl-phenyl) - (5-cyc lopropyl-isoxazol-4-yl) methanone (isoxachlorotole), (5-cyclopropyl isoxazol-4-yl) - (2-methylsulfonyl-4-trifluoromethyl-phenyl) methanone (isoxa flutole), 2- [2- [4 - [3,5-dichloro-2-pyridinyl) -oxy] -phenoxy] -1-oxo-propyl] -is oxazolidine (isoxapyrifop), (2-ethoxy-1-methyl-2-oxo-ethyl) -5- (2-chloro-4-tri fluoromethyl-phenoxy) -2-nitro-benzoate (lactofen), N '- (3,4-dichlorophenyl) -N-methoxy-N-methyl-urea (Linuron), (4th - Chloro-2-methylphenoxy) acetic acid (MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (mecoprop), 2- (2-benzothiazolyloxy) -N-methyl-N-phenyl -acetamide (Mefenacet), 2- (4-methylsulfonyl-2-nitro-benzoyl) -1,3-cyclohexanedione (mesotrione), 4-amino-3-methyl-6-phenyl-1,2,4-triazine-5 (4H) -one (metamitron), 2-chloro-N- (2,6-dimethylphenyl) -N- (1H-pyrazol-1-ylmethyl) acetamide (metazachlor), N- (4- (3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy) -phenyl) -N-methoxy-N-methyl-urea (metobenzuron), N ' - (4-Bromophenyl) -N-methoxy-N-methylurea (metobromuron), (S) -2-chloro-N- (2-eth yl-6-methyl-phenyl) -N- (2-methoxy-1-methyl-ethyl) -acet-amide (Metola chlor, S-Metolachlor), N- (2,6-dichloro-3-methyl-phenyl) -5,7-dimethoxy-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (metosulam), N '- (3-chloro-4-methoxy-phenyl) -N, N- dimethyl urea (metoxuron), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin), N- (4-methoxy-6-methyl -1,3,5-triazin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (metsulfuron-methyl), S-ethyl-hexahydro-1H-azepine-1-carbothioate (Moli nate), 2- (2-naphthyloxy) -N-phenyl-propanamide (naproanilide), N-butyl-N'- (3,4-dichlorophenyl) -N-methyl-urea (neburon), N- (4,6- Dimethoxy-pyrimidine-2-yl) -N '- (3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl) urea (Nico sulfuron), S- (2-chloro-benzyl) -N, N-diethyl-thiocarbamate (Orbencarb), 4-di propylamino-3,5-dinitro-benzenesulfonamide (oryzalin), 3- [2,4-dichloro-5- (2-propynyloxy) phenyl] -5- (t-butyl) -1, 3,4-oxadiazol-2 (3H) -one (oxadiargyl), 3- [2,4-dichloro-5- (1-methylethoxy) phenyl] -5- (t-butyl) -1,3, 4-ox adiazol-2 (3H) - one (oxadiazon), N- (4,6-dimethyl-pyrimidin-2-yl) -N '- (2-oxetan-3-yl-oxycarbonylphenylsulfonyl) urea (oxasulfuron) , 3- [1- (3,5-dichlorophenyl) -1-i-propyl] -2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-one (oxaziclo mefone), 2-chloro-1- (3-ethoxy-4-nitro-phenoxy) -4-trifluoromethyl-benzene (oxyfluorfen), 1,1'-dimethyl-4,4'-bipyridinium (paraquat), 1-amino -N- (1-ethyl-propyl) -3,4-dimethyl-2,6-dinitro-benzene (pendimethalin), 4- (t-butyl) -N- (1-ethyl-propyl) -2,6- dinitro-benzene amine (pendralin), 4-amino-3,5,6-trichloropyridine-2-carboxylic acid (picloram), 2-chloro-N- (2,6-diethyl-phenyl) -N- (2-prop oxy -ethyl) -acetamide (pretilachlor), N- (4,6-bis-difluoromethoxy-pyrimidin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) -urea (primisulfuron methyl), 1-chloro-N- [2-chloro-4-fluoro-5 - [(6S, 7aR) -6-fluoro-tetrahydro-1,3-di oxo-1H-pyrrolo [1,2-c] imidazole-2 (3H) -yl] -phenyl] methanesulfonamide (proflu azole), 2-chloro-N-isopropyl-N-phenyl-acetamide (propachlor), N- (3,4-dichlorophenyl) propanamide (propanil), (R) - [2 - [[(1-methylethylidene) amino] oxy] ethyl] -2- [4- (6-chloro-2-quinoxalinyloxy) phenoxy] propanoate (propaquizafop), 2 -Chlor-N- (2-ethyl-6-methyl-phenyl) -N - [(1-methyl-ethoxy) -methyl] -acetamide (propisochlor), 2 - [[[(4,5-dihydro-4 -methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino] sulfonyl] benzoic acid methyl ester sodium salt (propoxycarbazone sodium), S-phenylmethyl -N, N-dipropyl-thiocarb amate (prosulfocarb), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2- (3,3,3- trifluoropropyl) phenylsulfonyl) urea (prosulirone), ethyl [2-chloro-5- (4-chloro-5-difluoromethoxy-1-methyl-1H-pyrazol-3-yl) -4-fluorophenoxy] acetate (pyraflufen-ethyl), 1- (3-chloro-4,5,6,7-tetrahydro-pyrazolo [1,5-a] pyridin-2-yl) -5- (methyl-2-propynylamino) - 1H-pyrazole-4-carbonitrile (pyrazogyl), 4- (2,4-dichlorobenzoyl) -1,3-dimethyl-5- (4-methylphenylsulfonyloxy) pyrazole (pyr azolate), 4- (2, 4-dichlorobenzoyl) -1,3-dimethyl-5- (phenylcarbonylmethoxy) pyrazole (pyrazoxyfen), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (4-eth oxy carbonyl-1-methyl-pyrazol-5-yl-sulfonyl) urea (pyrazosulfuron-ethyl), diphenylmethanone-O- [2,6-bis- (4,6-dimethoxy-pyrimidin-2-yl-oxy) - benzoyl] - oxime (pyribenzoxime), 6-chloro-3-phenyl-4-pyridazinol (pyridafol), O- (6-chloro-3-phenyl-pyridazin-4-yl) -S-octyl-thiocarbonate (pyridates), 6-chloro-3-phenyl-pyridazin-4-ol (pyridatol), 7 - [(4,6-dimethoxy-2-pyrimidinyl) thio] -3-methyl-1 (3H) -isobenzofuranone (pyriftalid), 2 - (4,6-Dimethoxy-pyrimidin-2-yl-oxy) -benzoic acid methyl ester (Pyriminobac-methyl), 2-chloro-6- (4,6-di methoxy-pyrimidin-2-ylthio) -benzoic acid sodium salt (Pyrithiobac-sodium), 3,7-dichloro-quinoline-8-carboxylic acid (Quinchlorac), 7-chloro-3-methyl quinoline-8-carboxylic acid (Quinmerac), 2- [4- (6-chloro-2-quinoxalinyloxy ) -phen oxy] -propanoic acid (-ethyl ester, -tetrahydro-2-furanyl-methyl ester) (Quizalo fop, -ethyl, -P-ethyl, -P-tefuryl), N- (4,6-dimethoxy-pyrimidine-2 -yl) -N '- (3-ethylsulfonyl-pyridin-2-yl-sulfonyl) urea (rimsulfuron), 2- (1-ethoximinobutyl) -5- (2-ethylthiopropyl) -3- hydroxy-2-cyclohexen-1-one (Sethoxy dim), 6-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazine), 2- (2-chloro-4-methylsulfonyl-benzoyl) -cyclohexane-1,3-dione (sulcotrione), 2- (2,4-dichloro-5-methylsulfonylamino-phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro-3H- 1,2,4- triazol-3-one (sulfentrazone), N-phosphonomethyl-glycine-trimethyl sulfonium (sulfosate), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (2-ethyl sulfonyl-imidazo [1, 2-a] pyridine-3-sulfonamide (sulfosulfuron), 6-chloro-4-ethylamino-2-tert-butylamino-1,3,5-triazine (terbuthylazine), 2-tert.-butyl amino-4-ethylamino- 6-methylthio-1,3,5-triazine (terbutryn), 2-chloro-N- (2,6-dimethyl-phenyl) -N- (3-methoxy-2-thienyl-methyl) -acetamide (thenylchlor), Methyl 2-difluoromethyl-5- (4,5-dihydro-thiazol-2-yl) -4- (2-methyl-propyl) -6-trifluoromethyl-pyridine-3-carboxylate (thiazopyr), 6- (6 , 7-dihydro-6,6-dimethyl-3H, 5H-pyrrolo [2,1-c] -1,2,4-thiadiazol-3-ylidenamino) -7-fluoro-4- (2-propynyl) -2H -1,4-benzoxazin-3 (4H) -one (thidiazimin), N- (4-methoxy-6-methyl-1,3,5-triazi n-2-yl) -N '- (2-methoxycarbonyl-thien-3-yl-sulfonyl) urea (thifensulfuron-methyl), 2- (ethoximino-propyl) -3-hydroxy-5- (2,4 , 6-tri methyl-phenyl) -2-cyclohexen-1-one (tralkoxydim), S- (2,3,3-trichloro-2-propenyl) -diisopropylcarbamothioate (triallate), N- (4-methoxy-6- methyl-1,3,5-triazin-2-yl) -N '- [2- (2-chloroethoxy) phenylsulfonyl] urea (triasul furon), N-methyl-N- (4-methoxy-6 -methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonylphenylsulfonyl) urea (tribenuron-methyl), (3,5,6-trichloro) pyridin-2-yl -oxyacetic acid (triclopyr), 2- (3,5-dichlorophenyl) -2- (2,2,2-tri chloroethyl) oxirane (tridiphane), N - [[(4,6-dimethoxy -2-pyrimidinyl) amino] - carbonyl] -3- (2,2,2-trifluoro-ethoxy) -2-pyridinesulfonamide sodium salt (tri-floxysulfuron), 1-amino-2,6-dinitro-N, N- dipropyl-4-trifluoromethyl-benzene (trifluralin), N- [4-dimethylamino-6- (2,2,2-trifluoro-ethoxy) -1,3,5-triazin-2-yl] -N '- (2nd -methoxycarbonyl-phenylsulfonyl) urea (triflusulfuron methyl), N - [[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl ] -3- (N-methyl-N-methylsulfonylamino]) - 2-pyridinesulfonamide, (cf. WO-A-92/10 660), 2- [[[[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -4- [[(methylsulfonyl) amino] methyl] -benzoic acid methyl ester (cf. DE-A-43 35 297), 4- [4,5-dihydro-4-methyl-5-oxo (3-trifluoromethyl) -1H-1,2,4-tri azol-1-yl] -2 - [(ethylsulfonyl) amino] -5-fluorobenzenecarbothioamide (cf. WO-A-95/30 661)
("Active substances of group 2"),

und/oder gegebenenfallsand / or if necessary

a) eine die Kulturpflanzenverträglichkeit verbessernde Verbindung aus der folgenden Gruppe von Verbindungen:
4-Dichloracetyl-1-oxa-4-aza-spiro[4.5]-decan (AD-67), 1-Dichloracetyl-hexa hydro-3,3,8a-trimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-on (BAS-145138), 4- Dichloracetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazin (Benoxacor), 5- Chlor-chinoxalin-8-oxy-essigsäure-(1-methyl-hexylester) (Cloquintocet mexyl), α-(Cyanomethoximino)-phenylacetonitril (Cyometrinil), 2,4-Dichlor phenoxy-essigsäure (2,4-D), 2,2-Dichlor-N-(2-oxo-2-(2-propenylamino)- ethyl)-N-(2-propenyl)-acetamid (DKA-24), 2,2-Dichlor-N,N-di-2-propenyl acetamid (Dichlormid), N-(4-Methyl-phenyl)-N'-(1-methyl-1-phenyl-ethyl)- harnstoff (Dymron), 4,6-Dichlor-2-phenyl-pyrimidin (Fenclorim), 1-(2,4-Di chlor-phenyl)-5-trichlormethyl-1H-1,2,4-triazol-3-carbonsäure-ethylester (Fenchlorazol-ethyl), 2-Chlor-4-trifluormethyl-thiazol-5-carbonsäure-phenyl methylester (Flurazole), 4-Chlor-N-(1,3-dioxolan-2-yl-methoxy)-α-trifluor acetophenonoxim (Fluxofenim), 3-Dichloracetyl-5-(2-furanyl)-2,2-dimethyl oxazolidin (Furilazole, MON-13900), Ethyl-4,5-dihydro-5,5-diphenyl-3- isoxazolcarboxylat (Isoxadifen-ethyl), (4-Chlor-2-methyl-phenoxy)-essig säure (MCPA), (+-)-2-(4-Chlor-2-methylphenoxy)propansäure (Mecoprop), Diethyl-I-(2,4-dichlorphenyl)-4,5-dihydro-5-methyl-1H-pyrazol-3,5-di carboxylat (Mefenpyr-diethyl) 2-Dichlormethyl-2-methyl-1,3-dioxolan (MG- 191), 1,8-Naphthalsäureanhydrid, α-(1,3-Dioxolan-2-yl-methoximino)- phenylacetonitril (Oxabetrinil), 2,2-Dichlor-N-(1,3-dioxolan-2-yl-methyl)-N- (2-propenyl)-acetamid (PPG-1292) und 3-Dichloracetyl-2,2,5-trimethyl oxazolidin (R-29148)
("Wirkstoffe der Gruppe 3").a) a compound which improves crop plant tolerance from the following group of compounds:
4-dichloroacetyl-1-oxa-4-aza-spiro [4.5] -decane (AD-67), 1-dichloroacetyl-hexa hydro-3,3,8a-trimethylpyrrolo [1,2-a] pyrimidine-6 ( 2H) -one (BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (Benoxacor), 5-chloro-quinoxaline-8-oxyacetic acid- (1- methyl hexyl ester) (Cloquintocet mexyl), α- (cyanomethoximino) phenylacetonitrile (Cyometrinil), 2,4-dichlorophenoxyacetic acid (2,4-D), 2,2-dichloro-N- (2-oxo-2 - (2-propenylamino) - ethyl) -N- (2-propenyl) -acetamide (DKA-24), 2,2-dichloro-N, N-di-2-propenyl acetamide (dichlormid), N- (4- Methyl-phenyl) -N '- (1-methyl-1-phenyl-ethyl) urea (Dymron), 4,6-dichloro-2-phenyl-pyrimidine (Fenclorim), 1- (2,4-di chloro) phenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid ethyl ester (fenchlorazole-ethyl), 2-chloro-4-trifluoromethyl-thiazole-5-carboxylic acid-phenyl methyl ester (flurazole), 4- Chloro-N- (1,3-dioxolan-2-yl-methoxy) -α-trifluoroacetophenone oxime (fluxofenim), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyl oxazolidine (furilazole, MON-13900 ), Ethyl-4,5-dih ydro-5,5-diphenyl-3-isoxazole carboxylate (isoxadifen-ethyl), (4-chloro-2-methylphenoxy) acetic acid (MCPA), (+ -) - 2- (4-chloro-2-methylphenoxy ) propanoic acid (mecoprop), diethyl-I- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole-3,5-di carboxylate (mefenpyr-diethyl) 2-dichloromethyl-2-methyl -1,3-dioxolane (MG-191), 1,8-naphthalic anhydride, α- (1,3-dioxolan-2-yl-methoximino) - phenylacetonitrile (oxabetrinil), 2,2-dichloro-N- (1, 3-dioxolan-2-ylmethyl) -N- (2-propenyl) acetamide (PPG-1292) and 3-dichloroacetyl-2,2,5-trimethyl oxazolidine (R-29148)
("Active substances of group 3").

Als Mischungskomponenten aus den Wirkstoffen der Gruppe 2 werden besonders hervorgehoben:
2-Chlor-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamid (Acetochlor), 2- Chlor-N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-acetamid (Alachlor), 4-Amino-N- (1,1-Dimethyl-ethyl)-4,5-dihydro-3-(1-methyl-ethyl)-5-oxo-1H-1,2,4-triazol-1- carboxamid (Amicarbazone), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(N-methyl-N- methylsulfonyl-sulfamoyl)-harnstoff (Amidosulfuron), 6-Chlor-4-ethylamino-2-iso propylamino-1,3,5-triazin (Atrazin), N-Benzyl-2-(4-fluor-3-trifluormethyl-phenoxy)- butanamid (Beflubutamid), 3-i-Propyl-1H-2,1,3-benzothiadiazin-4(3H)-on (Bentazon), Methyl-5-(2,4-dichlor-phenoxy)-2-nitro-benzoat (Bifenox), 2,6-Bis-(4,6- dimethoxy-pyrimidin-2-yl-oxy)-benzoesäure-Natriumsalz (Bispyribac-sodium), 3,5- Dibrom-4-hydroxy-benzonitril (Bromoxynil), 2-Chlor-5-(3,6-dihydro-3-methyl-2,6- dioxo-4-trifluormethyl-1(2H)-pyrimidinyl)-benzoesäure-[1,1-dimethyl-2-oxo-2-(2- propenyloxy)]-ethylester (Butafenacil-allyl), 2-(4-Chlor-2-fluor-5-(2-chlor-2-ethoxy carbonyl-ethyl)-phenyl)-4-difluormethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-on (Carfentrazone-ethyl), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-chlor phenylsulfonyl)-harnstoff (Chlorsulfuron), N'-(3-Chlor-4-methyl-phenyl)-N,N-di methyl-harnstoff (Chlortoluron), 2-Chlor-3-[2-chlor-5-(1,3,4,5,6,7-hexahydro-1,3- dioxo-2H-isoindol-2-yl)-phenyl]-2-propansäure-ethylester (Cinidon-ethyl), (R)-(2- Propinyl)-2-[4-(5-chlor-3-fluor-pyridin-2-yl-oxy)-phenoxy-propanoat (Clodinafop propargyl), 3,6-Dichlor-pyridin-2-carbonsäure (Clopyralid), 2-Chlor-4-ethylamino-6- (1-cyano-1-methyl-ethylamino)-1,3,5-triazin (Cyanazine), N-(4,6-Dimethoxy-py rimidin-2-yl)-N'-(2-cyclopropylcarbonyl-phenylsulfonyl)-harnstoff (Cyclosulfam uron), 2,4-Dichlor-phenoxyessigsäure (2,4-D), 3,6-Dichlor-2-methoxy-benzoesäure (Dicamba), (R)-2-(2,4-Dichlor-phenoxy)-propansäure (Dichlorprop-P), Methyl-2-[4- (2,4-dichlor-phenoxy)-phenoxy]-propanoat (Diclofop-methyl), 1,2-Dimethyl-3,5-di phenyl-1H-pyrazolium-methylsulfat (Difenzoquat), N-(2,4-Difluor-phenyl)-2-(3-tri fluormethyl-phenoxy)-pyridin-3-carboxamid (Diflufenican), 2-[1-[(3,5-Difluor phenyl)-aminocarbonyl-hydrazono]-ethyl]-pyridin-3-carbonsäure (Diflufenzopyr), (S-) 2-Chlor-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-acetamid (S-)(Di methenamid), S-Ethyl-dipropylthiocarbamat (EPTC), (S)-(2-Ethoxy-1-methyl-2- oxoethyl)-2-chlor-5-(2-chlor-4-trifluormethyl-phenoxy)-benzoat (Ethoxyfen), N-(4,6- Dimethoxy-pyrimidin-2-yl)-N'-(2-ethoxy-phenoxysulfonyl)-harnstoff (Ethoxy sulfuron), (R)-Ethyl-2-[4-(6-chlor-benzoxazol-2-yl-oxy)-phenoxy]-propanoat (Fen oxaprop-(P)-ethyl), Isopropyl-N-benzoyl-N-(3-chlor-4-fluro-phenyl)-DL-alaninat (Flamprop-isopropyl), Isopropyl-N-benzoyl-N-(3-chlor-4-fluro-phenyl)-L-alaninat (Flamprop-isopropyl-L), Methyl-N-benzoyl-N-(3-chlor-4-fluor-phenoxy)-DL- alaninat (Flamprop-methyl), N-(2,6-Difluor-phenyl)-8-fluor-5-methoxy-[1,2,4]- triazolo-[1,5-c]-pyrimidin-2-sulfonamid (Florasulam), 5-(4-Brom-1-methyl-5-tri fluormethyl-1H-pyrazol-3-yl)-2-chlor-4-fluor-benzoesäure-i-propylester (Fluazolate), 4,5-Dihydro-3-methoxy-4-methyl-5-oxo-N-[(2-trifluormethoxy-phenyl)-sulfonyl]-1- H-1,2,4-triazol-1-carboxamid-Natriumsalz (Flucarbazone-sodium), N-(4-Fluor phenyl)-N-i-propyl-2-(5-trifluormethyl-1,3,4-thiadiazol-2-yl-oxy)-acetamid (Flufen acet), N-(2,6-Difluor-phenyl)-5-methyl-1,2,4-triazolo[1,5-a]-pyrimidin-2-sulfonamid (Flumetsulam), 5-(2-Chlor-4-trifluormethyl-phenoxy)-2-nitro-benzoesäure-ethoxy carbonylmethylester (Fluoroglycofen-ethyl), 1-(4-Chlor-3-(2, 2,3,3,3-pentafluor-prop oxymethyl)-phenyl)-5-phenyl-1H-1,2,4-triazol-3-carboxamid (Flupoxam), N-(4,6- Dimethoxy-pyrimidin-2-yl)-N'-(3-methoxycarbonyl-6-trifluormethyl-pyridin-2-yl- sulfonyl)-harnstoff-Natriumsalz (Flupyrsulfuron-methyl-sodium), 9-Hydroxy-9H- fluoren-9-carbonsäure (Flurenol), (4-Amino-3,5 -dichlor-6-fluor-pyridin-2-yl-oxy)- essigsäure (-2-butoxy-1-methyl-ethylester, -1-methyl-heptylester) (Fluroxypyr, -butoxypropyl, -meptyl), 5-Methylamino-2-phenyl-4-(3-trifluormethyl-phenyl)- 3(2H)-furanon (Flurtamone), Methyl-[(2-chlor-4-fluor-5-(tetrahydro-3-oxo-1H,3H- [1,3,4]-thiadiazolo-[3,4-a]-pyridazin-1-yliden)-amino-phenyl]-thio-acetat (Fluthiacet methyl), 2-[[[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]-4- formylamino-N,N-dimethyl-benzamid (Foramsulfuron), 2-Amino-4-(hydroxymethyl phosphinyl)-butansäure (-ammoniumsalz) (Glufosinate (-ammonium)), N-Phos phonomethyl-glycin (-isopropylammoniumsalz), (Glyphosate, -isopropylam monium), Methyl-2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4- methyl-benzoat (Imazamethabenz-methyl), 2-(4,5-Dihydro-4-methyl-4-isopropyl-5- oxo-1H-imidazol-2-yl)-5-methyl-pyridin-3-carbonsäure (Imazamethapyr), 2-(4,5-Di hydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl-pyridin-3- carbonsäure (Imazamox), 2-(4,5-Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol- 2-yl)-chinolin-3-carbonsäure (Imazaquin), 2-(4,5-Dihydro-4-methyl-4-i-propyl-5- oxo-1H-imidazol-2-yl)-5-ethyl-pyridin-3-carbonsäure (Imazethapyr), N-(4-Methoxy- 6-methyl-1,3,5-triazin-2-yl)-N'-(5-iod-2-methoxycarbonyl-phenylsulfonyl)-harn stoff-Natriumsalz (Iodosulfuron-methyl-sodium), 4-Hydroxy-3,5-diiod-benzonitril (Ioxynil), N,N-Dimethyl-N'-(4-isopropyl-phenyl)-harnstoff (Isoproturon), N-(3-(1- Ethyl-1-methyl-propyl)-isoxazol-5-yl)-2,6-dimethoxy-benzamid (Isoxaben), (4- Chlor-2-methylsulfonyl-phenyl)-(5-cyclopropyl-isoxazol-4-yl)-methanon (Isoxa chlortole), (5-Cyclopropylisoxazol-4-yl)-(2-methylsulfonyl-4-trifluormethyl phenyl)-methanon (Isoxaflutole), (4-Chlor-2-methyl-phenoxy)-essigsäure (MCPA), 2-(4-Chlor-2-methyl-phenoxy)-propionsäure (Mecoprop), 2-(4-Methylsulfonyl-2- nitro-benzoyl)-1,3-cyclohexandion (Mesotrione), 2-Chlor-N-(2,6-dimethyl-phenyl)- N-(1H-pyrazol-1-yl-methyl)-acetamid (Metazachlor), (S)-2-Chlor-N-(2-ethyl-6- methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-acet-amid (Metolachlor, S-Metola chlor), N-(2,6-Dichlor-3-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo[1,5-a]- pyrimidin-2-sulfonamid (Metosulam), 4-Amino-6-tert-butyl-3-methylthio-1,2,4- triazin-5(4H)-on (Metribuzin), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2- methoxycarbonyl-phenylsulfonyl)-harnstoff (Metsulfuron-methyl), N-(4,6-Di methoxy-pyrimidin-2-yl)-N'-(3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl)-harnstoff (Nicosulfuron), 1-Amino-N-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzol (Pendi methalin), N-(4,6-Bis-difluormethoxy-pyrimidin-2-yl)-N'-(2-methoxycarbonyl phenylsulfonyl)-harnstoff (Primisulfuronmethyl), 2-Chlor-N-isopropyl-N-phenyl acetamid (Propachlor), N-(3,4-Dichlor-phenyl)-propanamid (Propanil), 2-[[[(4,5-Di hydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl)-carbonyl]-amino]-sulfonyl]- benzoesäure-methylester-Natriumsalz (Propoxycarbazone-sodium), S-Phenylmethyl- N,N-dipropyl-thiocarbamat (Prosulfocarb), N-(4-Methoxy-6-methyl-1,3,5-triazin-2- yl)-N'-(2-(3,3,3-trifluor-propyl)-phenylsulfonyl)-harnstoff (Prosulfuron), Ethyl-[2- Chlor-S-(4-chlor-5-difluormethoxy-1-methyl-1H-pyrazol-3-yl)-4-fluor-phenoxy] - acetat (Pyraflufen-ethyl), O-(6-Chlor-3-phenyl-pyridazin-4-yl)-S-octyl-thiocarbonat (Pyridate), 7-Chlor-3-methylchinolin-8-carbonsäure (Quinmerac), N-(4,6-Dimeth oxy-pyrimidin-2-yl)-N'-(3-ethylsulfonyl-pyridin-2-yl-sulfonyl)-harnstoff (Rimsul furon), 2-(1-Ethoximinobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-2-cyclohexen-1-on (Sethoxydim), 6-Chlor-2,4-bis-ethylamino-1,3,5-triazin (Simazin), 2-(2-Chlor-4- methylsulfonyl-benzoyl)-cyclohexan-1,3-dion (Sulcotrione), N-Phosphonomethyl glycin-trimethylsulfonium (Sulfosate), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2- ethylsulfonyl-imidazo[1,2-a]pyridin-3-sulfonamid (Sulfosulfuron), 6-Chlor-4-ethyl amino-2-tert-butylamino-1,3,5-triazin (Terbuthylazine), 2-tert-Butylamino-4-ethyl amino-6-methylthio-1,3,5-triazin (Terbutryn), N-(4-Methoxy-6-methyl-1,3,5-triazin- 2-yl)-N'-(2-methoxycarbonyl-thien-3-yl-sulfonyl)-harnstoff (Thifensulfuron-methyl), 2-(Ethoximino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen-1-on (Tralkoxydim), S-(2,3,3-Trichlor-2-propenyl)-diisopropylcarbamothioat (Triallate), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-[2-(2-chlor-ethoxy)-phenylsulfonyl]- harnstoff (Triasulfuron), N-Methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'- (2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Tribenuron-methyl), 2-(3,5-Dichlor phenyl)-2-(2,2,2-trichlor-ethyl)-oxiran (Tridiphane), N-[[(4,6-Dimethoxy-2-pyri midinyl)-amino]-carbonyl]-3-(2,2,2-trifluor-ethoxy)-2-pyridinsulfonamid-Natrium salz (Trifloxysulfuron), 1-Amino-2,6-dinitro-N,N-dipropyl-4-trifluormethyl-benzol (Trifluralin).The following are particularly emphasized as mixture components from the active ingredients of group 2:
2-chloro-N- (ethoxymethyl) -N- (2-ethyl-6-methyl-phenyl) -acetamide (acetochlor), 2-chloro-N- (methoxymethyl) -N- (2,6-diethyl-phenyl) -acetamide (alachlor), 4-amino-N- (1,1-dimethyl-ethyl) -4,5-dihydro-3- (1-methyl-ethyl) -5-oxo-1H-1,2,4- triazol-1-carboxamide (amicarbazone), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), 6-chloro-4 -ethylamino-2-iso-propylamino-1,3,5-triazine (atrazine), N-benzyl-2- (4-fluoro-3-trifluoromethyl-phenoxy) -butanamide (beflubutamide), 3-i-propyl-1H- 2,1,3-benzothiadiazin-4 (3H) -one (bentazone), methyl 5- (2,4-dichlorophenoxy) -2-nitro-benzoate (bifenox), 2,6-bis- (4, 6- dimethoxy-pyrimidin-2-yl-oxy) -benzoic acid sodium salt (bispyribac-sodium), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), 2-chloro-5- (3,6-dihydro- 3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) -benzoic acid- [1,1-dimethyl-2-oxo-2- (2-propenyloxy)] - ethyl ester (butafenacil-allyl) , 2- (4-chloro-2-fluoro-5- (2-chloro-2-ethoxycarbonyl-ethyl) -phenyl) -4-difluoromethyl-5- methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (Carfentrazone-ethyl), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-chlorophenylsulfonyl) urea (chlorosulfuron), N' - (3-chloro-4-methylphenyl) -N, N-di methylurea (chlorotoluron), 2-chloro-3- [ Ethyl 2-chloro-5- (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenyl] -2-propanoate (cinidon-ethyl), (R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yloxy) phenoxy propanoate (Clodinafop propargyl), 3,6-dichloropyridine-2 -carboxylic acid (clopyralide), 2-chloro-4-ethylamino-6- (1-cyano-1-methyl-ethylamino) -1,3,5-triazine (cyanazine), N- (4,6-dimethoxy-py rimidin -2-yl) -N '- (2-cyclopropylcarbonylphenylsulfonyl) urea (cyclosulfam uron), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxybenzoic acid ( Dicamba), (R) -2- (2,4-dichlorophenoxy) propanoic acid (dichloroprop-P), methyl 2- [4- (2,4-dichlorophenoxy) phenoxy] propanoate (diclofop- methyl), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methyl sulfate (difenzoquate), N- (2,4-difluorophenyl) -2 - (3-tri fluoromethyl-phenoxy) pyridine-3-carboxamide (diflufenican), 2- [1 - [(3,5-difluorophenyl) aminocarbonylhydrazono] ethyl] pyridine-3-carboxylic acid (diflufenzopyr) , (S-) 2-chloro-N- (2,4-dimethyl-3-thienyl) -N- (2-methoxy-1-methyl-ethyl) -acetamide (S -) (dimethenamide), S-ethyl -dipropylthiocarbamate (EPTC), (S) - (2-ethoxy-1-methyl-2-oxoethyl) -2-chloro-5- (2-chloro-4-trifluoromethyl-phenoxy) -benzoate (ethoxyfen), N- ( 4,6-dimethoxy-pyrimidin-2-yl) -N '- (2-ethoxy-phenoxysulfonyl) urea (ethoxy sulfurone), (R) -ethyl-2- [4- (6-chloro-benzoxazol-2- yl-oxy) phenoxy] propanoate (fen oxaprop- (P) -ethyl), isopropyl-N-benzoyl-N- (3-chloro-4-fluro-phenyl) -DL-alaninate (flamprop-isopropyl), isopropyl -N-benzoyl-N- (3-chloro-4-fluro-phenyl) -L-alaninate (Flamprop-isopropyl-L), methyl-N-benzoyl-N- (3-chloro-4-fluorophenoxy) - DL-alaninate (Flamprop-methyl), N- (2,6-difluorophenyl) -8-fluoro-5-methoxy- [1,2,4] - triazolo- [1,5-c] pyrimidine-2 -sulfonamide (florasulam), 5- (4-bromo-1-methyl-5-tri fluoromethyl-1H-pyrazol-3-yl) -2-chloro-4-fluoro-b enzoic acid i-propyl ester (fluazolates), 4,5-dihydro-3-methoxy-4-methyl-5-oxo-N - [(2-trifluoromethoxyphenyl) sulfonyl] -1- H-1,2,4 -triazol-1-carboxamide sodium salt (Flucarbazone-sodium), N- (4-fluorophenyl) -Ni-propyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (Flufen acet), N- (2,6-difluorophenyl) -5-methyl-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (flumetsulam), 5- (2- Chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoic acid-ethoxy carbonylmethyl ester (fluoroglycofen-ethyl), 1- (4-chloro-3- (2, 2,3,3,3-pentafluoropropoxy oxymethyl) phenyl ) -5-phenyl-1H-1,2,4-triazole-3-carboxamide (flupoxam), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-methoxycarbonyl-6-trifluoromethyl -pyridin-2-yl-sulfonyl) -urea sodium salt (flupyrsulfuron-methyl-sodium), 9-hydroxy-9H-fluoren-9-carboxylic acid (flurenol), (4-amino-3,5-dichloro-6-fluor -pyridin-2-yl-oxy) - acetic acid (-2-butoxy-1-methyl-ethyl ester, -1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 5-methylamino-2-phenyl-4- (3-trifluoromethyl-phenyl) - 3 (2H) -furanone (Flurtamone), methyl - [(2-chloro-4-fluoro-5- (tetrahydro-3-oxo-1H, 3H- [1,3,4] thiadiazolo- [3,4 -a] -pyridazin-1-ylidene) -amino-phenyl] -thio-acetate (Fluthiacet methyl), 2 - [[[[(4,6-Dimethoxy-2-pyrimidinyl) -amino] -carbonyl] -amino] -sulfonyl] -4- formylamino-N, N-dimethyl-benzamide (foramsulfuron), 2-amino-4- (hydroxymethyl phosphinyl) -butanoic acid (-ammonium salt) (glufosinate (-ammonium)), N-phos phonomethyl-glycine ( -isopropylammonium salt), (glyphosate, -isopropylam monium), methyl 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -4-methyl-benzoate ( Imazamethabenz-methyl), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methyl-pyridine-3-carboxylic acid (imazamethapyr), 2- (4,5-di hydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2- (4,5-dihydro -4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -quinolin-3-carboxylic acid (imazaquin), 2- (4,5-dihydro-4-methyl-4-i-propyl- 5-oxo-1H-imidazol-2-yl) -5-ethyl-pyridine-3-carboxylic acid e (imazethapyr), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (5-iodo-2-methoxycarbonyl-phenylsulfonyl) urea sodium salt (iodosulfuron -methyl-sodium), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), N, N-dimethyl-N '- (4-isopropyl-phenyl) -urea (isoproturon), N- (3- (1 - Ethyl-1-methyl-propyl) -isoxazol-5-yl) -2,6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methylsulfonyl-phenyl) - (5-cyclopropyl-isoxazol-4-yl ) -methanone (isoxa chlorotole), (5-cyclopropylisoxazol-4-yl) - (2-methylsulfonyl-4-trifluoromethylphenyl) -methanone (isoxaflutole), (4-chloro-2-methylphenoxy) acetic acid (MCPA) , 2- (4-chloro-2-methylphenoxy) propionic acid (mecoprop), 2- (4-methylsulfonyl-2-nitro-benzoyl) -1,3-cyclohexanedione (mesotrione), 2-chloro-N- ( 2,6-dimethyl-phenyl) - N- (1H-pyrazol-1-yl-methyl) -acetamide (metazachlor), (S) -2-chloro-N- (2-ethyl-6-methyl-phenyl) - N- (2-methoxy-1-methyl-ethyl) -acetamide (metolachlor, S-metola chlorine), N- (2,6-dichloro-3-methylphenyl) -5,7-dimethoxy-1, 2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (Metos ulam), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin), N- (4-methoxy-6-methyl-1,3, 5-triazin-2-yl) -N '- (2-methoxycarbonylphenylsulfonyl) urea (metsulfuron-methyl), N- (4,6-dimethoxy-pyrimidin-2-yl) -N' - (3- dimethylcarbamoyl-pyridin-2-yl-sulfonyl) urea (nicosulfuron), 1-amino-N- (1-ethyl-propyl) -3,4-dimethyl-2,6-dinitro-benzene (Pendi methalin), N- (4,6-bis-difluoromethoxypyrimidin-2-yl) -N '- (2-methoxycarbonyl phenylsulfonyl) urea (primisulfuronmethyl), 2-chloro-N-isopropyl-N-phenyl acetamide (propachlor), N- ( 3,4-dichlorophenyl) propanamide (propanil), 2 - [[[(4,5-di hydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazole-1 -yl) -carbonyl] -amino] -sulfonyl] - methyl benzoate sodium salt (propoxycarbazone-sodium), S-phenylmethyl-N, N-dipropyl-thiocarbamate (prosulfocarb), N- (4-methoxy-6-methyl- 1,3,5-triazin-2-yl) -N '- (2- (3,3,3-trifluoropropyl) phenylsulfonyl) urea (prosulfuron), ethyl- [2-chloro-S- (4th -chloro-5-difluoromethoxy-1-methyl-1H-pyrazol-3-yl) -4-fluorophen oxy] - acetate (Pyraflufen-ethyl), O- (6-chloro-3-phenyl-pyridazin-4-yl) -S-octyl-thiocarbonate (Pyridate), 7-chloro-3-methylquinoline-8-carboxylic acid (Quinmerac ), N- (4,6-Dimethoxypyrimidin-2-yl) -N '- (3-ethylsulfonyl-pyridin-2-yl-sulfonyl) urea (Rimsul furon), 2- (1-ethoximinobutyl) - 5- (2-ethylthiopropyl) -3-hydroxy-2-cyclohexen-1-one (sethoxydim), 6-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazine), 2- (2nd -Chlor-4-methylsulfonyl-benzoyl) -cyclohexane-1,3-dione (Sulcotrione), N-phosphonomethylglycine-trimethylsulfonium (sulfosate), N- (4,6-dimethoxy-pyrimidin-2-yl) -N'- (2-ethylsulfonyl-imidazo [1,2-a] pyridine-3-sulfonamide (sulfosulfuron), 6-chloro-4-ethyl amino-2-tert-butylamino-1,3,5-triazine (terbuthylazine), 2- tert-Butylamino-4-ethyl amino-6-methylthio-1,3,5-triazine (terbutryn), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N ' - (2-methoxycarbonyl-thien-3-yl-sulfonyl) urea (thifensulfuron-methyl), 2- (ethoximino-propyl) -3-hydroxy-5- (2,4,6-trimethyl-phenyl) -2- cyclohexen-1-one (tralkoxydim), S- (2,3,3-T richlor-2-propenyl) diisopropyl carbamothioate (triallate), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- [2- (2-chloroethoxy) - phenylsulfonyl] urea (triasulfuron), N-methyl-N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N'- (2-methoxycarbonyl-phenylsulfonyl) urea (tribenuron -methyl), 2- (3,5-dichlorophenyl) -2- (2,2,2-trichloro-ethyl) -oxirane (tridiphane), N - [[(4,6-dimethoxy-2-pyrimidinyl) -amino] -carbonyl] -3- (2,2,2-trifluoro-ethoxy) -2-pyridinesulfonamide sodium salt (trifloxysulfuron), 1-amino-2,6-dinitro-N, N-dipropyl-4-trifluoromethyl -benzene (trifluralin).

Als Mischungskomponenten aus den Wirkstoffen der Gruppe 3 werden besonders her vorgehoben:
5-Chlor-chinoxalin-8-oxy-essigsäure-(1-methylhexylester) (Cloquintocet), 1-(2,4-Di chlor-phenyl)-5-trichlormethyl-1H-1,2,4-triazol-3-carbonsäure-ethylester (Fenchlora zol-ethyl), Ethyl-4,5-dihydro-5,5-diphenyl-3-isoxazolcarboxylat (Isoxadifen-ethyl), Diethyl-1-(2,4-dichlorphenyl)-4,5-dihydro-5-methyl-1 H-pyrazol-3,5-dicarboxylat (Mefenpyr-diethyl) und 2,4-Dichlorphenoxyessigsäure (2,4-D) sowie dessen Derivate.The following are particularly emphasized as mixture components from the active ingredients of group 3:
5-chloro-quinoxaline-8-oxyacetic acid (1-methylhexyl ester) (cloquintocet), 1- (2,4-di chlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3- carboxylic acid ethyl ester (fenchlorazole ethyl), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazole carboxylate (isoxadifen-ethyl), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro -5-methyl-1 H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl) and 2,4-dichlorophenoxyacetic acid (2,4-D) and their derivatives.

Die Verbindungen Diethyl-1-(2,4-dichlorphenyl)-4,5-dihydro-5-methyl-1H-pyrazol- 3,5-dicarboxylat (Mefenpyr-diethyl), (1-Methylhexyl)-[(5-chlor-8-quinolinyl)oxy]- acetat (Cloquintocet-methyl) und Ethyl-1-(2,4-dichlorphenyl)-5-(trichlormethyl)-1H- 1,2,4-triazol-3-carboxylat (Fenchlorazole-ethyl) sind in den folgenden Patentan meldungen beschrieben: DE-A-39 39 503, EP-A-191 736 bzw. DE-A-35 25 205. 2,4-D ist ein bekanntes Herbizid. The compounds diethyl-1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole- 3,5-dicarboxylate (mefenpyr-diethyl), (1-methylhexyl) - [(5-chloro-8-quinolinyl) oxy] - acetate (cloquintocet-methyl) and ethyl 1- (2,4-dichlorophenyl) -5- (trichloromethyl) -1H- 1,2,4-triazole-3-carboxylate (fenchlorazole-ethyl) are disclosed in the following patents described: DE-A-39 39 503, EP-A-191 736 and DE-A-35 25 205. 2,4-D is a well-known herbicide.

Es wurde nun überraschend gefunden, dass die oben definierten Wirkstoffkom binationen aus Tritosulfuron und den oben angeführten Wirkstoffen der Gruppe 1 ge gebenenfalls in Kombination mit Wirkstoffen der Gruppe 2 und/oder Wirkstoffen der Gruppe 3, bei sehr guter Nutzpflanzenverträglichkeit eine besonders hohe herbizide Wirksamkeit aufweisen und in verschiedenen Kulturen, insbesondere in Weizen, da neben aber auch in Mais und Gerste zur selektiven Unkrautbekämpfung verwendet werden können.It has now surprisingly been found that the active ingredient com combinations of tritosulfuron and the active ingredients of group 1 listed above optionally in combination with active substances of group 2 and / or active substances of Group 3, with very good crop tolerance, a particularly high herbicide Have effectiveness and in different crops, especially in wheat, because but also used in maize and barley for selective weed control can be.

Überraschenderweise ist die herbizide Wirksamkeit der erfindungsgemäßen Wirkstoff kombinationen aus Tritosulfuron und Verbindungen der oben aufgeführten Gruppe 1 erheblich höher als die Summe der Wirkungen der einzelnen Wirkstoffe.Surprisingly, the herbicidal activity of the active ingredient according to the invention combinations of tritosulfuron and compounds from group 1 above considerably higher than the sum of the effects of the individual active ingredients.

Es liegt somit ein nicht vorhersehbarer synergistischer Effekt vor und nicht nur eine Wirkungsergänzung. Die neuen Wirkstoffkombinationen sind in vielen Kulturen gut verträglich, wobei die neuen Wirkstoffkombinationen auch sonst schwer bekämpfbare Unkräuter gut bekämpfen. Die neuen Wirkstoffkombinationen stellen somit eine wert volle Bereicherung der Selektivherbizide dar.There is therefore an unforeseeable synergistic effect and not just one Addition of effects. The new drug combinations are good in many cultures tolerated, whereby the new active ingredient combinations are otherwise difficult to control Control weeds well. The new combinations of active ingredients therefore represent a value full enrichment of selective herbicides.

Es wurde außerdem überraschend gefunden, dass die oben definierten Wirkstoffkombi nationen aus Tritosulfuron und einem Safener/Antidot ("Wirkstoffe der Gruppe 3") in Kombination mit einem oder mehreren der oben angeführten Wirkstoffe der Gruppe 1 bei sehr guter Nutzpflanzenverträglichkeit eine besonders hohe herbizide Wirksamkeit aufweisen und in verschiedenen Kulturen, insbesondere in Getreide, vor allem Weizen, aber auch in Soja, Kartoffeln, Mais und Reis zur selektiven Unkrautbekämpfung verwendet werden können.It was also surprisingly found that the combination of active ingredients defined above nations from tritosulfuron and a safener / antidote ("active substances of group 3") in Combination with one or more of the group 1 active ingredients listed above with very good crop tolerance, a particularly high herbicidal activity and in different cultures, especially in cereals, especially wheat, but also in soy, potatoes, corn and rice for selective weed control can be used.

Überraschenderweise wurde zudem gefunden, dass auch die herbizid wirksame Sub stanz 2,4-Dichlorphenoxy-essigsäure (2,4-D) und ihre Derivate die oben beschriebene Safeneraufgabe übernehmen können. Surprisingly, it was also found that the herbicidally active sub punch 2,4-dichlorophenoxy-acetic acid (2,4-D) and its derivatives as described above Can take over safener task.

Als überraschend ist weiterhin anzusehen, dass aus einer Vielzahl von bekannten Safenern oder Antidots, die befähigt sind, die schädigende Wirkung eines Herbizids auf die Kulturpflanzen zu antagonisieren, gerade die oben aufgeführten Verbindungen der Gruppe 3 geeignet sind, die schädigende Wirkung von Tritosulfuron in Kombination mit einem oder mehreren der oben angeführten Wirkstoffe der Gruppe 1, auf die Kulturpflanzen annähernd vollständig aufzuheben, ohne dabei die herbizide Wirk samkeit gegenüber den Unkräutern zu beeinträchtigen.It is also surprising that from a large number of known Safeners or antidotes that are capable of the harmful effects of a herbicide to antagonize the crops, just the compounds listed above Group 3 are suitable, the harmful effects of tritosulfuron in combination with one or more of the group 1 active ingredients listed above, to which Cultivating crops almost completely, without losing the herbicidal effect affect weedliness.

Hervorgehoben sei hierbei die besonders vorteilhafte Wirkung der besonders bevor zugten Kombinationspartner aus der Gruppe 3, insbesondere hinsichtlich der Schonung von Getreidepflanzen, wie z. B. Reis, Weizen, Gerste und Roggen, als Kulturpflanzen.The particularly advantageous effect of the especially before should be emphasized here combination partners from group 3, especially with regard to the Protection of cereal plants, such as. B. rice, wheat, barley and rye, as Crops.

Ganz besonders hervorgehoben werden Mischungen von Tritosulfuron und Propoxy carbazone(-sodium) in Kombination mit einem oder mehreren der folgenden Wirk stoffe:
N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(N-methyl-N-methylsulfonyl-sulfamoyl)- harnstoff (Amidosulfuron), 2,6-Bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoe säure-Natriumsalz (Bispyribac-sodium), 2-(4-Chlor-2-fluor-5-(2-chlor-2-ethoxy carbonyl-ethyl)-phenyl)-4-difluormethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-on (Carfentrazone-ethyl), 2-Chlor-3-[2-chlor-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H- isoindol-2-yl)-phenyl]-2-propansäure-ethylester (Cinidon-ethyl), 2,4-Dichlor-phen oxyessigsäure (2,4-D), (R)-2-(2,4-Dichlor-phenoxy)-propansäure (Dichlorprop-P), N-(2,4-Difluor-phenyl)-2-(3-trifluormethyl-phenoxy)-pyridin-3-carboxamid (Diflu fenican), N-(4-Fluor-phenyl)-N-i-propyl-2-(5-trifluormethyl-1,3,4-thiadiazol-2-yl- oxy)-acetamid (Flufenacet), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(3-methoxy carbonyl-6-trifluormethyl-pyridin-2-yl-sulfonyl)-harnstoff-Natriumsalz (Flupyrsul furon-methyl-sodium), (4-Amino-3,5-dichlor-6-fluor-pyridin-2-yl-oxy)-essigsäure (-2-butoxy-1-methyl-ethylester, -1-methyl-heptylester) (Fluroxypyr, -butoxypropyl, -meptyl), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(5-iod-2-methoxycarbonyl phenylsulfonyl)-harnstoff-Natriumsalz (Iodosulfuron-methyl-sodium), N,N-Di methyl-N'-(4-isopropyl-phenyl)-harnstoff (Isoproturon), 2-(4-Chlor-2-methyl-phen oxy)-propionsäure (Mecoprop), 4-Amino-6-tert-butyl-3-methylthio-1,2,4-triazin- 5(4H)-on (Metribuzin), N-[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl)-3- (2,2,2-trifluor-ethoxy)-2-pyridinsulfonamid-Natriumsalz (Trifloxysulfuron).Mixtures of tritosulfuron and propoxy carbazone (sodium) are particularly emphasized in combination with one or more of the following active ingredients:
N- (4,6-Dimethoxy-pyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), 2,6-bis (4,6-dimethoxypyrimidine -2-yl-oxy) -benzoic acid sodium salt (bispyribac-sodium), 2- (4-chloro-2-fluoro-5- (2-chloro-2-ethoxy carbonyl-ethyl) -phenyl) -4-difluoromethyl -5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (Carfentrazone-ethyl), 2-chloro-3- [2-chloro-5- (1,3,4, 5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenyl] -2-propanoic acid ethyl ester (cinidon-ethyl), 2,4-dichlorophen oxyacetic acid (2,4- D), (R) -2- (2,4-dichlorophenoxy) propanoic acid (dichloroprop-P), N- (2,4-difluorophenyl) -2- (3-trifluoromethylphenoxy) pyridine- 3-carboxamide (Diflu fenican), N- (4-fluoro-phenyl) -Ni-propyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (Flufenacet), N - (4,6-Dimethoxy-pyrimidin-2-yl) -N '- (3-methoxy carbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl) urea sodium salt (Flupyrsul furon-methyl-sodium), ( 4-Amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) -acetic acid (-2-butoxy-1-methyl-ethyl ester, -1-methy l-heptyl ester) (fluroxypyr, butoxypropyl, meptyl), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (5-iodo-2-methoxycarbonyl phenylsulfonyl ) urea sodium salt (iodosulfuron-methyl-sodium), N, N-dimethyl-N '- (4-isopropyl-phenyl) -urea (isoproturon), 2- (4-chloro-2-methyl-phen oxy) -propionic acid (mecoprop), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5 (4H) -one (metribuzin), N - [[(4,6-dimethoxy-2 -pyrimidinyl) -amino] -carbonyl) -3- (2,2,2-trifluoro-ethoxy) -2-pyridinesulfonamide sodium salt (trifloxysulfuron).

Weiterhin werden ganz besonders Mischungen von Tritosulfuron und Flucarbazone(-sodium) in Kombination mit einem oder mehreren der folgenden Wirkstoffen hervorgehoben:
2,6-Bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoesäure-Natriumsalz (Bispyribac sodium), 3,5-Dibrom-4-hydroxy-benzonitril (Bromoxynil), 2-(4-Chlor-2-fluor-5-(2- chlor-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluormethyl-5-methyl-2,4-dihydro-3H- 1,2,4-triazol-3-on (Carfentrazone-ethyl), 2-Chlor-3-[2-chlor-5-(1,3,4,5,6,7-hexa hydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl]-2-propansäure-ethylester (Cinidon-ethyl), (R)-(2-Propinyl)-2-[4-(5-chlor-3-fluor-pyridin-2-yl-oxy)-phenoxy-propanoat (Clo dinafop-propargyl), 3,6-Dichlor-pyridin-2-carbonsäure (Clopyralid), 2,4-Dichlor phenoxyessigsäure (2,4-D), 3,6-Dichlor-2-methoxy-benzoesäure (Dicamba), (R)- Ethyl-2-[4-(6-chlor-benzoxazol-2-yl-oxy)-phenoxy]-propanoat (Fenoxaprop-(P)- ethyl), N-(2,6-Difluor-phenyl)-8-fluor-5-methoxy-[1,2,4]-triazolo-[1,5-c]-pyrimidin- 2-sulfonamid (Florasulam), N-(4-Fluor-phenyl)-N-i-propyl-2-(5-trifluormethyl-1,3,4- thiadiazol-2-yl-oxy)-acetamid (Flufenacet), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'- (3-methoxycarbonyl-6-trifluormethyl-pyridin-2-yl-sulfonyl)-harnstoff-Natriumsalz (Flupyrsulfuron-methyl-sodium), (4-Amino-3,5-dichlor-6-fluor-pyridin-2-yl-oxy)- essigsäure (-2-butoxy-1-methyl-ethylester, -1-methyl-heptylester) (Fluroxypyr, -butoxypropyl, -meptyl), Methyl-2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H- imidazol-2-yl)-4-methyl-benzoat (Imazamethabenz-methyl), 2-(4,5-Dihydro-4- methyl-4-isopropyl-5-oxo-1 H-imidazol-2-yl)-5-methoxymethyl-pyridin-3-carbon säure (Imazamox), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(5-iod-2-methoxy carbonyl-phenylsulfonyl)-harnstoff-Natriumsalz (Iodosulfuron-methyl-sodium), N,N-Dimethyl-N'-(4-isopropyl-phenyl)-harnstoff (Isoproturon), (4-Chlor-2-methyl phenoxy)-essigsäure (MCPA), 2-(4-Chlor-2-methyl-phenoxy)-propionsäure (Meco prop), 4-Amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-on (Metribuzin), 2- [[[(4,5-Dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl)-carbonyl]-amino]- sulfonyl]-benzoesäure-methylester-Natriumsalz (Propoxycarbazone-sodium), Ethyl- [2-Chlor-5-(4-chlor-5-difluormethoxy-1-methyl-1 H-pyrazol-3-yl)-4-fluor-phenoxy]- acetat (Pyraflufen-ethyl), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2-ethylsulfonyl imidazo[1,2-a]pyridin-3-sulfonamid (Sulfosulfuron), N-(4-Methoxy-6-methyl-1,3,5- triazin-2-yl)-N'-(2-methoxycarbonyl-thien-3-yl-sulfonyl)-harnstoff (Thifensulfuron methyl), 2-(Ethoximino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen- 1-on (Tralkoxydim), S-(2,3,3-Trichlor-2-propenyl)-diisopropylcarbamothioat (Tri allate), N-[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3-(2,2,2-trifluor ethoxy)-2-pyridinsulfonamid-Natriumsalz (Trifloxysulfuron).Mixtures of tritosulfuron and flucarbazone (sodium) in combination with one or more of the following active ingredients are also particularly emphasized:
2,6-bis- (4,6-dimethoxy-pyrimidin-2-yl-oxy) -benzoic acid sodium salt (bispyribac sodium), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), 2- (4- Chloro-2-fluoro-5- (2-chloro-2-ethoxycarbonyl-ethyl) phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (Carfentrazone-ethyl), 2-chloro-3- [2-chloro-5- (1,3,4,5,6,7-hexa hydro-1,3-dioxo-2H-isoindol-2-yl) - phenyl] -2-propanoic acid ethyl ester (cinidon-ethyl), (R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yl-oxy) phenoxy propanoate (Clo dinafop-propargyl), 3,6-dichloropyridine-2-carboxylic acid (clopyralid), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (dicamba) , (R) - ethyl 2- [4- (6-chloro-benzoxazol-2-yl-oxy) phenoxy] propanoate (fenoxaprop- (P) - ethyl), N- (2,6-difluorophenyl ) -8-fluoro-5-methoxy- [1,2,4] triazolo- [1,5-c] pyrimidine-2-sulfonamide (Florasulam), N- (4-fluoro-phenyl) -Ni-propyl -2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (flufenacet), N- (4,6-dimethoxypyrimidin-2-yl) -N'- (3- methoxycarbonyl-6-trifluo rmethyl-pyridin-2-yl-sulfonyl) urea sodium salt (flupyrsulfuron-methyl-sodium), (4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) acetic acid (-2 -butoxy-1-methyl-ethyl ester, -1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), methyl-2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H - imidazol-2-yl) -4-methyl-benzoate (imazamethabenz-methyl), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1 H -imidazol-2-yl) - 5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (5-iodo-2-methoxy carbonyl -phenylsulfonyl) -urea sodium salt (iodosulfuron-methyl-sodium), N, N-dimethyl-N '- (4-isopropyl-phenyl) -urea (isoproturon), (4-chloro-2-methylphenoxy) -acetic acid ( MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (Meco prop), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5 (4H) - on (metribuzin), 2- [[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino] - sulfonyl] -benzoic acid methyl ester sodium salt (Propoxycarbazone-sodium), ethyl 1- [2-chloro-5- (4-chloro-5-difluoromethoxy-1-methyl-1 H -pyrazol-3-yl) -4-fluoro-phenoxy] acetate (Pyraflufen-ethyl), N- (4th , 6-Dimethoxypyrimidin-2-yl) -N '- (2-ethylsulfonylimidazo [1,2-a] pyridine-3-sulfonamide (sulfosulfuron), N- (4-methoxy-6-methyl-1,3 , 5- triazin-2-yl) -N '- (2-methoxycarbonyl-thien-3-yl-sulfonyl) urea (thifensulfuron methyl), 2- (ethoximino-propyl) -3-hydroxy-5- (2, 4,6-trimethyl-phenyl) -2-cyclohexen- 1-one (tralkoxydim), S- (2,3,3-trichloro-2-propenyl) diisopropylcarbamothioate (tri allate), N - [[(4.6 -Dimethoxy-2-pyrimidinyl) amino] carbonyl] -3- (2,2,2-trifluoroethoxy) -2-pyridinesulfonamide sodium salt (trifloxysulfuron).

Die erfindungsgemäßen Wirkstoffkombinationen können z. B. bei den folgenden Pflan zen verwendet werden:
Dikotyle Unkräuter der Gattungen: Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Cirsium, Carduus, Sonchus, Solanum, Rorippa, Rotala, Lindemia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxacum.The active compound combinations according to the invention can, for. B. used in the following plants:
Dicotyledon weeds of the genera: Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Cirsium, Carduippum, Sonuanum , Rotala, Lindemia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxacum.

Dikotyle Kulturen der Gattungen: Gossypium, Glycine, Beta, Daucus, Phaseolus, Pisum, Solanum, Linum, Ipomoea, Vicia, Nicotiana, Lycopersicon, Arachis, Brassica, Lactuca, Cucumis, Cuburbita.Dicot cultures of the genera: Gossypium, Glycine, Beta, Daucus, Phaseolus, Pisum, Solanum, Linum, Ipomoea, Vicia, Nicotiana, Lycopersicon, Arachis, Brassica, Lactuca, cucumis, cuburbita.

Monokotyle Unkräuter der Gattungen: Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, Sorghum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischaemum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus, Apera, Phalaris. Monocotyledonous weeds of the genera: Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, Sorghum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischaemum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus, Apera, phalaris.

Monokotyle Kulturen der Gattungen: Oryza, Zea, Triticum, Hordeum, Avena, Secale, Sorghum, Panicum, Saccharum, Ananas, Asparagus, Allium.Monocot cultures of the genera: Oryza, Zea, Triticum, Hordeum, Avena, Secale, Sorghum, Panicum, Saccharum, Pineapple, Asparagus, Allium.

Die Verwendung der erfindungsgemäßen Wirkstoffkombinationen ist jedoch keines wegs auf diese Gattungen beschränkt, sondern erstreckt sich in gleicher Weise auch auf andere Pflanzen.However, the use of the active compound combinations according to the invention is not one wegs limited to these genera, but extends in the same way other plants.

Erfindungsgemäß können alle Pflanzen und Pflanzenteile behandelt werden. Unter Pflanzen werden hierbei alle Pflanzen und Pflanzenpopulationen verstanden, wie er wünschte und unerwünschte Wildpflanzen oder Kulturpflanzen (einschließlich natürlich vorkommender Kulturpflanzen). Kulturpflanzen können Pflanzen sein, die durch konventionelle Züchtungs- und Optimierungsmethoden oder durch biotechno logische und gentechnologische Methoden oder Kombinationen dieser Methoden erhalten werden können, einschließlich der transgenen Pflanzen und einschließlich der durch Sortenschutzrechte schützbaren oder nicht schützbaren Pflanzensorten. Unter Pflanzenteilen sollen alle oberirdischen und unterirdischen Teile und Organe der Pflanzen, wie Spross, Blatt, Blüte und Wurzel verstanden werden, wobei bei spielhaft Blätter, Nadeln, Stengel, Stämme, Blüten, Fruchtkörper, Früchte und Samen sowie Wurzeln, Knollen und Rhizome aufgeführt werden. Zu den Pflanzenteilen gehört auch Erntegut sowie vegetatives und generatives Vermehrungsmaterial, bei spielsweise Stecklinge, Knollen, Rhizome, Ableger und Samen.According to the invention, all plants and parts of plants can be treated. Under Plants are understood here as all plants and plant populations desired and undesirable wild plants or crops (including naturally occurring crops). Cultivated plants can be plants that by conventional breeding and optimization methods or by biotechno logical and genetic engineering methods or combinations of these methods can be obtained, including the transgenic plants and inclusive plant varieties that can or cannot be protected by plant breeders' rights. Plant parts should include all above-ground and underground parts and organs the plants, such as sprout, leaf, flower and root are understood, with playful leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds as well as roots, tubers and rhizomes. To the plant parts also includes crops and vegetative and generative propagation material for example cuttings, tubers, rhizomes, cuttings and seeds.

Die erfindungsgemäße Behandlung der Pflanzen und Pflanzenteile mit den Wirk stoffen erfolgt direkt oder durch Einwirkung auf deren Umgebung, Lebensraum oder Lagerraum nach den üblichen Behandlungsmethoden, z. B. durch Tauchen, Sprühen, Verdampfen, Vernebeln, Streuen, Aufstreichen und bei Vermehrungsmaterial, insbe sondere bei Samen, weiterhin durch ein- oder mehrschichtiges Umhüllen.The treatment according to the invention of the plants and parts of plants with the active ingredients substances takes place directly or by influencing their surroundings, living space or Storage room according to the usual treatment methods, e.g. B. by diving, spraying, Evaporation, misting, scattering, spreading and in the case of propagation material, in particular especially in the case of seeds, still by wrapping them in one or more layers.

Der synergistische Effekt der erfindungsgemäßen Wirkstoffkombinationen ist bei be stimmten Konzentrationsverhältnissen besonders stark ausgeprägt. Jedoch können die Gewichtsverhältnisse der Wirkstoffe in den Wirkstoffkombinationen in relativ großen Bereichen variiert werden. Im allgemeinen entfallen auf 1 Gewichtsteil Tritosulfuron 0,01 bis 1000 Gewichtsteile, vorzugsweise 0,05 bis 500 Gewichtsteile und besonders bevorzugt 0,1 bis 100 Gewichtsteile Wirkstoff der Gruppe 1.The synergistic effect of the active compound combinations according to the invention is in be certain concentration ratios are particularly pronounced. However, they can Weight ratios of the active ingredients in the active ingredient combinations in relatively large Ranges can be varied. In general, 1 part by weight of tritosulfuron 0.01 to 1000 parts by weight, preferably 0.05 to 500 parts by weight and particularly preferably 0.1 to 100 parts by weight of active ingredient of group 1.

Der vorteilhafte Effekt der Kulturpflanzenverträglichkeit der erfindungsgemäßen Wirk stofflcombinationen ist bei bestimmten Konzentrationsverhältnissen ebenfalls beson ders stark ausgeprägt. Jedoch können die Gewichtsverhältnisse der Wirkstoffe in den Wirkstoffkombinationen in relativ großen Bereichen variiert werden. Im allgemeinen entfallen auf 1 Gewichtsteil Tritosulfuron oder dessen Mischungen mit Wirkstoffen der Gruppe 1 und gegebenenfalls mit Wirkstoffen der Gruppe 2 0,001 bis 1000 Gewichts teile, vorzugsweise 0,01 bis 100 Gewichtsteile und besonders bevorzugt 0,1 bis 10 Ge wichtsteile Wirkstoff der Gruppe 3.The advantageous effect of crop tolerance of the active compound according to the invention Material combinations are also special at certain concentration ratios very pronounced. However, the weight ratios of the active ingredients in the Drug combinations can be varied in relatively large areas. In general account for 1 part by weight of tritosulfuron or its mixtures with active ingredients of Group 1 and optionally with active ingredients of group 2 0.001 to 1000 weight parts, preferably 0.01 to 100 parts by weight and particularly preferably 0.1 to 10 Ge important parts of active ingredient of group 3.

Die Wirkstoffkombinationen können in die üblichen Formulierungen übergeführt werden, wie Lösungen, Emulsionen, Spritzpulver, Suspensionen, Pulver, Stäubemittel, Pasten, lösliche Pulver, Granulate, Suspensions-Emulsions-Konzentrate, Wirkstoff imprägnierte Natur- und synthetische Stoffe sowie Feinstverkapselungen in polymeren Stoffen.The active substance combinations can be converted into the usual formulations such as solutions, emulsions, wettable powders, suspensions, powders, dusts, Pastes, soluble powders, granules, suspension emulsion concentrates, active ingredient impregnated natural and synthetic materials as well as very fine encapsulation in polymers Fabrics.

Diese Formulierungen werden in bekannter Weise hergestellt, z. B. durch Vermischen der Wirkstoffe mit Streckmitteln, also flüssigen Lösungsmitteln und/oder festen Trä gerstoffen, gegebenenfalls unter Verwendung von oberflächenaktiven Mitteln, also Emulgiermitteln und/oder Dispergiermitteln und/oder schaumerzeugenden Mitteln.These formulations are prepared in a known manner, e.g. B. by mixing of the active ingredients with extenders, i.e. liquid solvents and / or solid carriers gerstoffe, optionally using surfactants, so Emulsifiers and / or dispersants and / or foaming agents.

Im Falle der Benutzung von Wasser als Streckmittel können z. B. auch organische Lö sungsmittel als Hilfslösungsmittel verwendet werden. Als flüssige Lösungsmittel kom men im wesentlichen in Frage: Aromaten, wie Xylol, Toluol, oder Alkylnaphthaline, chlorierte Aromaten und chlorierte aliphatische Kohlenwasserstoffe, wie Chlorbenzole, Chlorethylene oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z. B. Erdölfraktionen, mineralische und pflanzliche Öle, Alkohole, wie Butanol oder Glykol sowie deren Ether und Ester, Ketone wie Aceton, Methyl ethylketon, Methylisobutylketon oder Cyclohexanon, stark polare Lösungsmittel, wie Dimethylformamid und Dimethylsulfoxid, sowie Wasser.In the case of the use of water as an extender, e.g. B. also organic Lö be used as auxiliary solvents. Com as liquid solvent essentially in question: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, Chlorethylene or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. B. petroleum fractions, mineral and vegetable oils, alcohols, such as Butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as Dimethylformamide and dimethyl sulfoxide, as well as water.

Als feste Trägerstoffe kommen in Frage:
z.B. Ammoniumsalze und natürliche Gesteinsmehle, wie Kaoline, Tonerden, Talkum, Kreide, Quarz, Attapulgit, Montmorillonit oder Diatomeenerde und synthetische Ge steinsmehle, wie hochdisperse Kieselsäure, Aluminiumoxid und Silikate, als feste Trä gerstoffe für Granulate kommen in Frage: z. B. gebrochene und fraktionierte natürliche Gesteine wie Calcit, Marmor, Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Material wie Sägemehl, Kokosnussschalen, Maiskolben und Tabakstengeln; als Emulgier- und/oder schaumerzeugende Mittel kommen in Frage: z. B. nichtionogene und anio nische Emulgatoren, wie Polyoxyethylen-Fettsäure-Ester, Polyoxyethylen-Fettalkohol- Ether, z. B. Alkylarylpolyglykolether, Alkylsulfonate, Alkylsulfate, Arylsulfonate sowie Eiweißhydrolysate; als Dispergiermittel kommen in Frage: z. B. Lignin-Sulfitab laugen und Methylcellulose.The following are suitable as solid carriers:
For example, ammonium salts and natural rock powders, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders, such as highly disperse silica, aluminum oxide and silicates, as solid carriers for granules are possible: z. B. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stems; as emulsifying and / or foam-generating agents come into question: z. B. nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for. B. alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates; as dispersants come into question: z. B. lignin sulfitab lye and methyl cellulose.

Es können in den Formulierungen Haftmittel wie Carboxymethylcellulose, natürliche und synthetische pulvrige, körnige oder latexförmige Polymere verwendet werden, wie Gummiarabicum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospholipide, wie Kephaline und Lecithine und synthetische Phospholipide. Weitere Additive können mineralische und vegetabile Öle sein.Adhesives such as carboxymethyl cellulose, natural, can be used in the formulations and synthetic powdery, granular or latex-shaped polymers can be used, such as Gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids, such as cephalins and lecithins and synthetic phospholipids. Other additives can mineral and vegetable oils.

Es können Farbstoffe wie anorganische Pigmente, z. B. Eisenoxid, Titanoxid, Ferro cyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyaninfarb stoffe und Spurennährstoffe wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink verwendet werden. Dyes such as inorganic pigments, e.g. B. iron oxide, titanium oxide, ferro cyan and organic dyes such as alizarin, azo and metal phthalocyanine substances and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, Molybdenum and zinc can be used.

Die Formulierungen enthalten im allgemeinen zwischen 0,1 und 95 Gewichtsprozent an Wirkstoffen einschließlich der Safener, vorzugsweise zwischen 0,5 und 90%.The formulations generally contain between 0.1 and 95 percent by weight of active ingredients including safeners, preferably between 0.5 and 90%.

Die erfindungsgemäßen Wirkstoffkombinationen werden im allgemeinen in Form von Fertigformulierungen zur Anwendung gebracht. Die in den Wirkstoffkombinationen enthaltenen Wirkstoffe können aber auch in Einzelformulierungen bei der Anwendung gemischt, d. h. in Form von Tankmischungen zur Anwendung gebracht werden.The active compound combinations according to the invention are generally in the form of Ready formulations applied. The one in the drug combinations Active ingredients contained can also be used in individual formulations mixed, d. H. be used in the form of tank mixes.

Die neuen Wirkstoffkombinationen können als solche oder in ihren Formulierungen weiterhin auch in Mischung mit anderen bekannten Herbiziden Verwendung finden, wobei wiederum Fertigformulierungen oder Tankmischungen möglich sind. Auch eine Mischung mit anderen bekannten Wirkstoffen, wie Fungiziden, Insektiziden, Akari ziden, Nematiziden, Schutzstoffen gegen Vogelfraß, Wuchsstoffen, Pflanzennährstof fen und Bodenstrukturverbesserungsmitteln ist möglich. Für bestimmte Anwendungs zwecke, insbesondere im Nachauflauf-Verfahren, kann es ferner vorteilhaft sein, in die Formulierungen als weitere Zusatzstoffe pflanzenverträgliche mineralische oder vege tabilische Öle (z. B. das Handelspräparat "Oleo DuPont 11E") oder Ammoniumsalze wie z. B. Ammoniumsulfat oder Ammoniumrhodanid aufzunehmen.The new drug combinations can be used as such or in their formulations continue to be used in a mixture with other known herbicides, ready formulations or tank mixes are possible. Also one Mixture with other known active ingredients, such as fungicides, insecticides, Akari ziden, nematicides, bird repellants, growth agents, plant nutrients fen and soil structure improvers is possible. For certain application purposes, especially in the post-emergence process, it may also be advantageous to use the Formulations as additional additives plant-compatible mineral or vege stable oils (e.g. the commercial preparation "Oleo DuPont 11E") or ammonium salts such as B. include ammonium sulfate or ammonium rhodanide.

Die neuen Wirkstoftkombinationen können als solche, in Form ihrer Formulierungen oder der daraus durch weiteres Verdünnen bereiteten Anwendungsformen, wie ge brauchsfertige Lösungen, Suspensionen, Emulsionen, Pulver, Pasten und Granulate an gewandt werden. Die Anwendung geschieht in üblicher Weise, z. B. durch Gießen, Spritzen, Sprühen, Stäuben oder Streuen.The new active substance combinations can be used as such, in the form of their formulations or the use forms prepared therefrom by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules be turned. The application is done in the usual way, e.g. B. by pouring, Spraying, spraying, dusting or sprinkling.

Die erfindungsgemäßen Wirkstoflkombinationen können vor und nach dem Auflaufen der Pflanzen appliziert werden, also im Vorauflauf- und Nachauflauf-Verfahren. Sie können auch vor der Saat in den Boden eingearbeitet werden. The active compound combinations according to the invention can be used before and after emergence of the plants are applied, i.e. pre- and post-emergence. she can also be worked into the soil before sowing.

Ein synergistischer Effekt liegt bei Herbiziden immer dann vor, wenn die herbizide Wirkung der Wirkstoffkombination größer ist als die der einzelnen applizierten Wirk stoffe.A herbicide always has a synergistic effect if the herbicide Effect of the combination of active substances is greater than that of the individual active compound applied fabrics.

Die zu erwartende Wirkung für eine gegebene Kombination zweier Herbizide kann wie folgt berechnet werden (vgl. COLBY, S. R.: "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, Seiten 20-22, 1967):
Wenn X = % Schädigung durch Herbizid A (Wirkstoff der Formel I) bei p kg/ha Aufwandmenge
und Y = % Schädigung durch Herbizid B (Wirkstoff der Formel II) bei q kg/ha Aufwandmenge
und E = die erwartete Schädigung der Herbizide A und B bei p und q kg/ha Aufwandmenge,
dann ist E = X + Y - (X . Y/100).The expected effect for a given combination of two herbicides can be calculated as follows (cf. COLBY, SR: "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, pages 20-22, 1967):
If X =% damage by herbicide A (active ingredient of formula I) at p kg / ha application rate
and Y =% damage by herbicide B (active ingredient of the formula II) at q kg / ha application rate
and E = the expected damage to herbicides A and B at p and q kg / ha application rate,
then E = X + Y - (X. Y / 100).

Ist die tatsächliche Schädigung größer als berechnet, so ist die Kombination in ihrer Wirkung überadditiv, das heißt, sie zeigt einen synergistischen Effekt.If the actual damage is greater than calculated, the combination is in its Effect superadditive, that is, it shows a synergistic effect.

Claims

1. Herbizide Mittel, gekennzeichnet durch einen synergistischen wirksamen Gehalt an einer Wirkstoffkombination, umfassend

a) Tritosulfuron

1. Herbicidal agents, characterized by a synergistic effective content of an active ingredient combination, comprising

a) Tritosulfuron

und

a) eine oder mehrere Verbindungen aus einer zweiten Gruppe von Herbizi den, welche die nachstehend genannten Wirkstoffe enthält:
(5-Trifluormethyl-1,3,4-thiadiazol-2-yl-oxy)-essigsäure-N-isopropyl-N-(4- fluorphenyl)-amid (Flufenacet), 2-(2-Methoxycarbonyl-phenylsulfonylamino carbonyl)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-on oder das Natriumsalz dieser Verbindung (Propoxycarbazone(-sodium), 2-(2- Trifluormethoxy-phenylsulfonylaminocarbonyl)-4-methyl-5-methoxy-2,4- dihydro-3H-1,2,4-triazol-3-on oder das Natriumsalz dieser Verbindung (Flucarbazone(-sodium), N-(3,4-dichlorphenyl)propanamid (Propanil), N-2- benzothiazolyl-N,N'-dimethylharnstoff (Methabenzthiazuron), 4-Amino-6- (1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-on (Metribuzin), 4-(2- Chlorphenyl)-N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1 H-tetrazol-1-carbox amid (Fentrazamide), 4-Amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)-on (Metamitron), 2-(2-Benzothiazolyloxy)-N-methyl-N-phenylacetamid (Mefenacet), 4-Amino-6-(1,1-dimethylethyl)-3-(ethylthio)-1,2,4-triazin- 5(4H)-on (Ethiozin), 1-Methylethyl 5-[4-brom-1-methyl-5-(trifluormethyl)- 1H-pyrazol-3-yl]-2-chlor-4-fluorbenzoat (Fluazolate)

sowie gegebenenfalls

a) eine oder mehrere Verbindungen aus einer zweiten Gruppe von Herbiziden, welche die nachstehend genannten Wirkstoffe enthält:
2-Chlor-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamid (Aceto chlor), 5-(2-Chlor-4-trifluormethyl-phenoxy)-2-nitro-benzoesäure-Natrium salz (Acifluorfen-sodium), 2-Chlor-6-nitro-3-phenoxy-benzenamin (Aclonifen), 2-Chlor-N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-acetamid (Alachlor), N-Ethyl-N'-i-propyl-6-methylthio-1,3,5-triazin-2,4-diamin (Ametryn), 4-Amino-N-(1,1-Dimethyl-ethyl)-4,5-dihydro-3-(1-methyl-ethyl)- 5-oxo-1H-1,2,4-triazol-1-carboxamid (Amicarbazone), N-(4,6-Dimethoxy pyrimidin-2-yl)-N'-(N-methyl-N-methylsulfonyl-sulfamoyl)-harnstoff (Amidosulfuron), 1H-1,2,4-Triazol-3-amin (Amitrole), 6-Chlor-4-ethyl amino-2-isopropylamino-1,3,5-triazin (Atrazin), 2-[2,4-Dichlor-5-(2-prop inyloxy)-phenyl]-5,6,7,8-tetrahydro-1,2,4-triazolo-[4,3-a]-pyridin-3(2H)-on (Azafenidin), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-[1-methyl-4-(2-methyl- 2H-tetrazol-5-yl)-1H-pyrazol-5-ylsulfonyl]-harnstoff (Azimsulftiron), N- Benzyl-2-(4-fluor-3-trifluormethyl-phenoxy)-butanamid (Beflubutamid), 4- Chlor-2-oxo-3(2H)-benzthiazolessigsäure (Benazolin), N-Butyl-N-ethyl-2,6- dinitro-4-trifluormethyl-benzenamin (Benfluralin), N-(4,6-Dimethoxy pyrimidin-2-yl)-N'-(2-methoxycarbonyl-phenylmethylsulfonyl)-harnstoff (Bensulfuron), 2-[2-[4-(3,6-Dihydro-3-methyl-2,6-dioxo-4-trifluormethyl- 1(2H)-pyrimidinylphenoxymethyl]-5-ethyl-phenoxy-propansäure-methylester (Benzfendizone), 3-(2-Chlor-4-methylsulfonyl-benzoyl)-4-phenylthio-bi cyclo-[3.2.1]-oct-3-en-2-on (Benzobicyclon), Ethyl N-benzoyl-N-(3,4-di chlor-phenyl)-DL-alaninat (Benzoylprop-ethyl), 3-i-Propyl-1H-2,1,3-benzo thiadiazin-4(3H)-on (Bentazon), Methyl-5-(2,4-dichlor-phenoxy)-2-nitro benzoat (Bifenox), 2,6-Bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoesäure- Natriumsalz (Bispyribac-sodium), 2-Brom-3,3-dimethyl-N-(1-methyl-1- phenyl-ethyl)-butanamid (Bromobutide), 3,5-Dibrom-4-hydroxy-benz aldehyd-O-(2,4-dinitro-phenyl)-oxim (Bromofenoxim), 3,5-Dibrom-4-hy droxy-benzonitril (Bromoxynil), N-Butoxymethyl-2-chlor-N-(2,6-diethyl phenyl)-acetamid (Butachlor), 2-Chlor-5-(3,6-dihydro-3-methyl-2,6-dioxo-4- trifluormethyl-1(2H)-pyrimidinyl)-benzoesäure-[1,1-dimethyl-2-oxo-2-(2- propenyloxy)]-ethylester (Butafenacil-allyl), 2-(1-Ethoximino-propyl)-3- hydroxy-5-[2,4,6-trimethyl-3-(1-oxo-butyl)-phenyl]-2-cyclohexen-1-on (But roxydim), S-Ethyl-bis-(2-methyl-propyl)-thiocarbamat (Butylate), N,N- Diethyl-3-(2,4,6-trimethyl-phenylsulfonyl)-1H-1,2,4-triazol-1-carboxamid (Cafenstrole), 2-[1-[(3-Chlor-2-propenyl)-oxy-imino]-propyl]-3-hydroxy-5- (tetrahydro-2H-pyran-4-yl)-2-cyclohexen-1-on (Caloxydim, Tepraloxydim), 2-(4-Chlor-2-fluor-5-(2-chlor-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluor methyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-on (Carfentrazone-ethyl), 2,4-Dichlor-1-(3-methoxy-4-nitro-phenoxy)-benzol (Chlomethoxyfen), 3- Amino-2,5-dichlor-benzoesäure (Chloramben), N-(4-Chlor-6-methoxy-pyri midin-2-yl)-N'-(2-ethoxycarbonyl-phenylsulfonyl)-harnstoff (Chlorimuron ethyl), 1,3,5-Trichlor-2-(4-nitro-phenoxy)-benzol (Chlornitrofen), N-(4- Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-chlor-phenylsulfonyl)-harnstoff (Chlorsulfuron), N'-(3-Chlor-4-methyl-phenyl)-N,N-dimethyl-harnstoff (Chlortoluron), 2-Chlor-3-[2-chlor-5-(1, 3, 4,5,6,7-hexahydro-1,3-dioxo-2H- isoindol-2-yl)-phenyl]-2-propansäure-ethylester (Cinidon-ethyl), N-(4,6- Dimethoxy-1,3,5-triazin-2-yl)-N'-(2-(2-methoxy-ethoxy)-phenylsulfonyl)- harnstoff (Cinosulfuron), 2-[1-[2-(4-Chlor-phenoxy)-propoxyaminobutyl]-5- (tetrahydro-2H-thiopyran-3-yl)-1,3-cyclohexandion (Clefoxydim), (E,E)-(+)- 2-[1-[[(3-Chlor-2-propenyl)-oxy]-imino]-propyl]-3-hydroxy-2-cyclohexen-1- on (Clethodim), (R)-(2-Propinyl)-2-[4-(5-chlor-3-fluor-pyridin-2-yl-oxy)- phenoxy-propanoat (Clodinafop-propargyl), 3,6-Dichlor-pyridin-2-carbon säure (Clopyralid), Methyl-3-chloro-2-[(5-ethoxy-7-fluor[1,2, 4]triazolo[1,5- c]pyrimidin-2-yl-sulfonyl)-amino]-benzoat (Cloransulam-methyl), 2-Chlor-4- ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazin (Cyanazine), N- (4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2-cyclopropylcarbonyl-phenylsulfonyl)- harnstoff (Cyclosulfamuron), 2-(1-Ethoximinobutyl)-3-hydroxy-5-(tetra hydro-2H-thiopyran-3-yl)-2-cyclohexen-1-on (Cycloxydim), (R)-2-[4-(4- Cyano-2-fluor-phenoxy)-phenoxy]-propansäure-butylester (Cyhalofop-butyl), 2,4-Dichlor-phenoxyessigsäure (2,4-D), 3,6-Dichlor-2-methoxy-benzoesäure (Dicamba), (R)-2-(2,4-Dichlor-phenoxy)-propansäure (Dichlorprop-P), Methyl-2-[4-(2,4-dichlor-phenoxy)-phenoxy]-propanoat (Diclofop-methyl), N-(2,6-Dichlor-phenyl)-5-ethoxy-7-fluor-[1,2,4]-triazolo-[1,5-c]-pyrimidin-2- sulfonamid (Diclosulam), 1,2-Dimethyl-3,5-diphenyl-1H-pyrazolium-methyl sulfat (Difenzoquat), N-(2,4-Difluor-phenyl)-2-(3-trifluormethyl-phenoxy)- pyridin-3-carboxamid (Diflufenican), 2-[1-[(3,5-Difluor-phenyl)-amino carbonyl-hydrazono]-ethyl]-pyridin-3-carbonsäure (Diflufenzopyr), S-(1- Methyl-1-phenyl-ethyl)-1-piperidin-carbothioat (Dimepiperate), (S-)2-Chlor- N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-acetamid (S-) (Di methenamid), 2-Amino-4-(1-fluor-1-methyl-ethyl)-6-(1-methyl-2-(3,5-di methyl-phenoxy)-ethylamino)-1,3,5-triazin (Dimexyflam), N3,N3-Diethyl- 2,4-dinitro-6-trifluormethyl-1,3-diamino-benzol (Dinitramine), 6,7-Dihydro dipyrido[1,2-a:2',1'-c]pyrazindiium (Diquat), S,S-Dimethyl-2-difluormethyl- 4-i-butyl-6-trifluormethyl-pyridin-3,5-dicarbothioat (Dithiopyr), N' -(3,4-Di chlor-phenyl)-N,N-dimethyl-harnstoff (Diuron), 2-[2-(3-Chlor-phenyl)- oxiranylmethyl]-2-ethyl-111-inden-1,3(2H)-dion (Epropodan), S-Ethyl-dipro pylthiocarbamat (EPTC), S-(Phenylmethyl)-N-ethyl-N-(1,2-dimethylpropyl)- thiocarbamat (Esprocarb), N-Ethyl-N-(2-methyl-2-propenyl)-2, 6-dinitro-4-tri fluormethyl-benzenamin (Ethalfluralin), (S)-(2-Ethoxy-1-methyl-2-oxoethyl)- 2-chlor-5-(2-chlor-4-trifluormethyl-phenoxy)-benzoat (Ethoxyfen), N-(4,6- Dimethoxy-pyrimidin-2-yl)-N'-(2-ethoxy-phenoxysulfonyl)-harnstoff (Ethoxysulfuron), (R)-Ethyl-2-[4-(6-chlor-benzoxazol-2-yl-oxy)-phenoxy]- propanoat (Fenoxaprop-(P)-ethyl), 4-(2-Chlor-phenyl)-N-cyclohexyl-N-ethyl- 4,5-dihydro-5-oxo-1H-tetrazol-1-carboxamid (Fentrazamide), Isopropyl-N- benzoyl-N-(3-chlor-4-fluro-phenyl)-DL-alaninat (Flamprop-isopropyl), Iso propyl-N-benzoyl-N-(3-chlor-4-fluro-phenyl)-L-alaninat (Flamprop-iso propyl-L), Methyl-N-benzoyl-N-(3-chlor-4-fluor-phenoxy)-DL-alaninat (Flamprop-methyl), N-(2,6-Difluor-phenyl)-8-fluor-5-methoxy-[1,2,4]- triazolo-[1,5-c]-pyrimidin-2-sulfonamid (Florasulam), (R)-2-[4-(5-Trifluor methyl-pyridin-2-yl-oxy)-phenoxy]-propansäure-butylester (Fluazifop, -butyl, -P-butyl), 5-(4-Brom-1-methyl-5-trifluormethyl-1H-pyrazol-3-yl)-2-chlor-4- fluor-benzoesäure-i-propylester (Fluazolate), 4,5-Dihydro-3-methoxy-4- methyl-5-oxo-N-[(2-trifluormethoxy-phenyl)-sulfonyl]-1-H-1,2,4-triazol-1- carboxamid-Natriumsalz (Flucarbazone-sodium), N-(4-Fluor-phenyl)-N-i- propyl-2-(5-trifluormethyl-1,3,4-thiadiazol-2-yl-oxy)-acetamid (Flufenacet), N-(2,6-Difluor-phenyl)-5-methyl-1,2,4-triazolo[1,5-a]-pyrimidin-2-sulfon amid (Flumetsulam), Pentyl-[2-chlor-4-fluor-5-(1,3,4,5,6,7-hexahydro-1,3- dioxo-2H-isoindol-2-yl)-phenoxy]-acetat (Flumiclorac-pentyl), 2-[7-Fluor- 3,4-dihydro-3-oxo-4-(2-propinyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetra hydro-1H-isoindol- 1,3-dion (Flumioxazin), 2-[4-Chlor-2-fluor-5-[(1-methyl- 2-propinyl)-oxy]-phenyl]-4,5,6,7-tetrahydro-1H-isoindol-1,3(2H)-dion (Flumipropyn), 3-Chlor-4-chlormethyl-1-(3-trifluormethyl-phenyl)-2-pyrroli dinon (Fluorochloridone), 5-(2-Chlor-4-trifluormethyl-phenoxy)-2-nitro benzoesäure-ethoxycarbonylmethylester (Fluoroglycofen-ethyl), 1-(4-Chlor- 3-(2, 2,3,3,3-pentafluor-propoxy methyl)-phenyl)-5-phenyl-1H-1,2,4-triazol-3- carboxamid (Flupoxam), 1-Isopropyl-2-chlor-5-(3,6-dihydro-3-methyl-2,6-di oxo-4-trifluormethyl-1(2H)-pyrimidyl)-benzoat (Flupropacil), N-(4,6-Di methoxy-pyrimidin-2-yl)-N'-(3-methoxycarbonyl-6-trifluormethyl-pyridin-2- yl-sulfonyl)-harnstoff-Natriumsalz (Flupyrsulfuron-methyl-sodium), 9- Hydroxy-9H-fluoren-9-carbonsäure (Flurenol), (4-Amino-3,5-dichlor-6-fluor pyridin-2-yl-oxy)-essigsäure (-2-butoxy-1-methyl-ethylester, -1-methyl heptylester) (Fluroxypyr, -butoxypropyl, -meptyl), 5-Methylamino-2-phenyl- 4-(3-trifluormethyl-phenyl)-3(2H)-furanon (Flurtamone), Methyl-[(2-chlor-4- fluor-5-(tetrahydro-3-oxo-1H,3H-[1,3,4]-thiadiazolo-[3,4-a]-pyridazin-1- yliden)-amino-phenyl]-thio-acetat (Fluthiacet-methyl), 5-(2-Chlor-4-trifluor methyl-phenoxy)-N-methylsulfonyl-2-nitro-benzamid (Fomesafen), 2- [[[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]-4- formylamino-N,N-dimethyl-benzamid (Foramsulfuron), 2-Amino-4-(hy droxymethylphosphinyl)-butansäure (-ammoniumsalz) (Glufosinate (-am monium)), N-Phosphonomethyl-glycin (-isopropylammoniumsalz), (Gly phosate, -isopropylammonium), (R)-2-[4-(3-Chlor-5-trifluormethyl-pyridin-2- yl-oxy)-phenoxy]-propansäure (-methylester, -2-ethoxy-ethylester, -butyl ester) (Haloxyfop, -methyl, -P-methyl, -ethoxyethyl, -butyl), 3-Cyclohexyl-6- dimethylamino-1-methyl-1,3,5-triazin-2,4(1H,3H)-dion (Hexazinone), Methyl-2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4- methyl-benzoat (Imazamethabenz-methyl), 2-(4,5-Dihydro-4-methyl-4-iso propyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridin-3-carbonsäure (Imaza methapyr), 2-(4,5-Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5- methoxymethyl-pyridin-3-carbonsäure (Imazamox), 2-(4,5-Dihydro-4- methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-chinolin-3-carbonsäure (Imaza quin), 2-(4,5-Dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl)-5-ethyl pyridin-3-carbonsäure (Imazethapyr), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'- (2-chlor-imidazo[1,2-a]-pyridin-3-yl-sulfonyl)-harnstoff (Imazosulfuron), N- (4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(5-iod-2-methoxycarbonyl phenylsulfonyl)-harnstoff-Natriumsalz (Iodosulfuron-methyl-sodium), 4- Hydroxy-3,5-diiod-benzonitril (Ioxynil), N,N-Dimethyl-N'-(4-isopropyl phenyl)-harnstoff (Isoproturon), N-(3-(1-Ethyl-1-methyl-propyl)-isoxazol-5- yl)-2,6-dimethoxy-benzamid (Isoxaben), (4-Chlor-2-methylsulfonyl-phenyl)- (5-cyclopropyl-isoxazol-4-yl)-methanon (Isoxachlortole), (5-Cyclopropyl isoxazol-4-yl)-(2-methylsulfonyl-4-trifluormethyl-phenyl)-methanon (Isoxa flutole), 2-[2-[4-[3,5-Dichlor-2-pyridinyl)-oxy]-phenoxy]-1-oxo-propyl]-is oxazolidin (Isoxapyrifop), (2-Ethoxy-1-methyl-2-oxo-ethyl)-5-(2-chlor-4-tri fluormethyl-phenoxy)-2-nitro-benzoat (Lactofen), N'-(3,4-dichlor-phenyl)-N- methoxy-N-methyl-harnstoff (Linuron), (4-Chlor-2-methyl-phenoxy)-essig säure (MCPA), 2-(4-Chlor-2-methyl-phenoxy)-propionsäure (Mecoprop), 2- (2-Benzthiazolyloxy)-N-methyl-N-phenyl-acetamid (Mefenacet), 2-(4- Methylsulfonyl-2-nitro-benzoyl)-1,3-cyclohexandion (Mesotrione), 4-Amino- 3-methyl-6-phenyl-1,2,4-triazin-5(4H)-on (Metamitron), 2-Chlor-N-(2,6-di methyl-phenyl)-N-(1H-pyrazol-1-yl-methyl)-acetamid (Metazachlor), N'-(4- (3,4-Dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy)- phenyl)-N-methoxy-N-methyl-harnstoff (Metobenzuron), N'-(4-Brom phenyl)-N-methoxy-N-methylharnstoff (Metobromuron), (S)-2-Chlor-N-(2- ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-acet-amid (Metola chlor, S-Metolachlor), N-(2,6-Dichlor-3-methyl-phenyl)-5,7-dimethoxy- 1,2,4-triazolo[1,5-a]-pyrimidin-2-sulfonamid (Metosulam), N'-(3-Chlor-4- methoxy-phenyl)-N,N-dimethyl-harnstoff (Metoxuron), 4-Amino-6-tert- butyl-3-methylthio-1,2,4-triazin-5(4H)-on (Metribuzin), N-(4-Methoxy-6- methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Metsulfuron-methyl), S-Ethyl-hexahydro-1H-azepin-1-carbothioat (Moli nate), 2-(2-Naphthyloxy)-N-phenyl-propanamid (Naproanilide), N-Butyl-N'- (3,4-dichlor-phenyl)-N-methyl-harnstoff (Neburon), N-(4,6-Dimethoxy-pyri midin-2-yl)-N'-(3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl)-harnstoff (Nico sulfuron), S-(2-Chlor-benzyl)-N,N-diethyl-thiocarbamat (Orbencarb), 4-Di propylamino-3,5-dinitro-benzensulfonamid (Oryzalin), 3-[2,4-Dichlor-5-(2- propinyloxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)-on (Oxadiargyl), 3- [2,4-Dichlor-5-(1-methyl-ethoxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)- on (Oxadiazon), N-(4,6-Dimethyl-pyrimidin-2-yl)-N'-(2-oxetan-3-yl-oxy carbonyl-phenylsulfonyl)-harnstoff (Oxasulfuron), 3-[1-(3,5-Dichlor-phenyl)- 1-i-propyl]-2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-on (Oxaziclo mefone), 2-Chlor-1-(3-ethoxy-4-nitro-phenoxy)-4-trifluormethyl-benzen (Oxyfluorfen), 1,1'-Dimethyl-4,4'-bipyridinium (Paraquat), 1-Amino-N-(1- ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzol (Pendimethalin), 4-(t-Butyl)-N- (1-ethyl-propyl)-2,6-dinitro-benzenamin (Pendralin), 4-Amino-3,5,6-trichlor pyridin-2-carbonsäure (Picloram), 2-Chlor-N-(2,6-diethyl-phenyl)-N-(2-prop oxy-ethyl)-acetamid (Pretilachlor), N-(4,6-Bis-difluormethoxy-pyrimidin-2- yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Primisulfuron methyl), 1-Chlor-N-[2-chlor-4-fluor-5-[(6S,7aR)-6-fluor-tetrahydro-1,3-di oxo-1H-pyrrolo[1,2-c]imidazol-2(3H)-yl]-phenyl]-methansulfonamid (Proflu azol), 2-Chlor-N-isopropyl-N-phenyl-acetamid (Propachlor), N-(3,4-Dichlor phenyl)-propanamid (Propanil), (R)-[2-[[(1-Methyl-ethyliden)-amino]-oxy]- ethyl]-2-[4-(6-chlor-2-chinoxalinyloxy)-phenoxy]-propanoat (Propaquizafop), 2-Chlor-N-(2-ethyl-6-methyl-phenyl)-N-[(1-methyl-ethoxy)-methyl]-acet amid (Propisochlor), 2-[[[(4,5-Dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4- triazol-1-yl)-carbonyl]-amino]-sulfonyl]-benzoesäure-methylester-Natrium salz (Propoxycarbazone-sodium), S-Phenylmethyl-N,N-dipropyl-thiocarb amat (Prosulfocarb), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-(3,3,3- trifluor-propyl)-phenylsulfonyl)-harnstoff (Prosulfuron), Ethyl-[2-Chlor-5-(4- chlor-5-difluormethoxy-1-methyl-1 H-pyrazol-3-yl)-4-fluor-phenoxy]-acetat (Pyraflufen-ethyl), 1-(3-Chlor-4,5,6,7-tetrahydro-pyrazolo[1,5-a]pyridin-2- yl)-5-(methyl-2-propinylamino)-1H-pyrazol-4-carbonitril (Pyrazogyl), 4-(2,4- Dichlor-benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulfonyloxy)-pyrazol (Pyr azolate), 4-(2,4-Dichlor-benzoyl)-1,3-dimethyl-S-(phenylcarbonylmethoxy)- pyrazol (Pyrazoxyfen), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(4-ethoxy carbonyl-1-methyl-pyrazol-5-yl-sulfonyl)-harnstoff (Pyrazosulfuron-ethyl), Diphenylmethanon-O-[2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoyl]- oxim (Pyribenzoxim), 6-Chlor-3-phenyl-4-pyridazinol (Pyridafol), O-(6- Chlor-3-phenyl-pyridazin-4-yl)-S-octyl-thiocarbonat (Pyridate), 6-Chlor-3- phenyl-pyridazin-4-ol (Pyridatol), 7-[(4,6-Dimethoxy-2-pyrimidinyl)-thio]-3- methyl-1(3H)-isobenzofuranon (Pyriftalid), 2-(4,6-Dimethoxy-pyrimidin-2- yl-oxy)-benzoesäure-methylester (Pyriminobac-methyl), 2-Chlor-6-(4,6-di methoxy-pyrimidin-2-ylthio)-benzoesäure-Natriumsalz (Pyrithiobac-sodium), 3,7-Dichlor-chinolin-8-carbonsäure (Quinchlorac), 7-Chlor-3-methyl chinolin-8-carbonsäure (Quinmerac), 2-[4-(6-Chlor-2-chinoxalinyloxy)-phen oxy]-propansäure (-ethylester, -tetrahydro-2-furanyl-methylester) (Quizalo fop, -ethyl, -P-ethyl, -P-tefuryl), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(3- ethylsulfonyl-pyridin-2-yl-sulfonyl)-harnstoff (Rimsulfuron), 2-(1-Ethox iminobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-2-cyclohexen-1-on (Sethoxy dim), 6-Chlor-2,4-bis-ethylamino-1,3,5-triazin (Simazin), 2-(2-Chlor-4- methylsulfonyl-benzoyl)-cyclohexan-1,3-dion (Sulcotrione), 2-(2,4-Dichlor- 5-methylsulfonylamino-phenyl)-4-difluormethyl-5-methyl-2,4-dihydro-3H- 1,2,4-triazol-3-on (Sulfentrazone), N-Phosphonomethyl-glycin-trimethyl sulfonium (Sulfosate), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2-ethyl sulfonyl-imidazo[1,2-a]pyridin-3-sulfonamid (Sulfosulfuron), 6-Chlor-4- ethylamino-2-tert-butylamino-1,3,5-triazin (Terbuthylazine), 2-tert-Butyl amino-4-ethylamino-6-methylthio-1,3,5-triazin (Terbutryn), 2-Chlor-N-(2,6- dimethyl-phenyl)-N-(3-methoxy-2-thienyl-methyl)-acetamid (Thenylchlor), 2-Difluormethyl-S-(4,5-dihydro-thiazol-2-yl)-4-(2-methyl-propyl)-6-trifluor methyl-pyridin-3-carbonsäure-methylester (Thiazopyr), 6-(6,7-Dihydro-6,6- dimethyl-3H,5H-pyrrolo[2,1-c]-1,2,4-thiadiazol-3-ylidenamino)-7-fluor-4-(2- propinyl)-2H-1,4-benzoxazin-3(4H)-on (Thidiazimin), N-(4-Methoxy-6- methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-thien-3-yl-sulfonyl)-harn stoff (Thifensulfuron-methyl), 2-(Ethoximino-propyl)-3-hydroxy-5-(2,4,6-tri methyl-phenyl)-2-cyclohexen-1-on (Tralkoxydim), S-(2,3,3-Trichlor-2- propenyl)-diisopropylcarbamothioat (Triallate), N-(4-Methoxy-6-methyl- 1,3,5-triazin-2-yl)-N'-[2-(2-chlor-ethoxy)-phenylsulfonyl]-harnstoff (Triasulf uron), N-Methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxy carbonyl-phenylsulfonyl)-harnstoff (Tribenuron-methyl), (3,5,6-Trichlor)- pyridin-2-yl-oxy-essigsäure (Triclopyr), 2-(3,5-Dichlor-phenyl)-2-(2,2,2-tri chlor-ethyl)-oxiran (Tridiphane), N-[[(4,6-Dimethoxy-2-pyrimidinyl)-amino] - carbonyl]-3-(2,2,2-trifluor-ethoxy)-2-pyridinsulfonamid-Natriumsalz (Tri floxysulfuron), 1-Amino-2,6-dinitro-N,N-dipropyl-4-trifluormethyl-benzol (Trifluralin), N-[4-Dimethylamino-6-(2,2,2-trifluor-ethoxy)-1,3,5-triazin-2- yl]-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Triflusulfuron methyl), N-[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3-(N-methyl- N-methylsulfonyl-amino])-2-pyridinsulfonamid, (vgl. WO-A-92/10 660), 2- [[[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]-4- [[(methylsulfonyl)-amino]methyl]-benzoesäure-methylester (vgl. DE-A- 43 35 297), 4-[4,5-Dihydro-4-methyl-5-oxo-(3-trifluormethyl)-1H-1,2,4-tri azol-1-yl]-2-[(ethylsulfonyl)amino]-5-fluor-benzencarbothioamid (vgl. WO- A-95/30 661)
(" Wirkstoffe der Gruppe 2"),

und/oder gegebenenfalls

a) eine die Kulturpflanzenverträglichkeit verbessernde Verbindung aus der folgenden Gruppe von Verbindungen:
4-Dichloracetyl-1-oxa-4-aza-spiro[4.5]-decan (AD-67), 1-Dichloracetyl-hexa hydro-3,3,8a-trimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-on (BAS-145138), 4- Dichloracetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazin (Benoxacor), 5- Chlor-chinoxalin-8-oxy-essigsäure-(1-methyl-hexylester) (Cloquintocet mexyl), α-(Cyanomethoximino)-phenylacetonitril (Cyometrinil), 2,4-Dichlor phenoxy-essigsäure (2,4-D), 2,2-Dichlor-N-(2-oxo-2-(2-propenylamino)- ethyl)-N-(2-propenyl)-acetamid (DKA-24), 2,2-Dichlor-N,N-di-2-propenyl acetamid (Dichlormid), N-(4-Methyl-phenyl)-N'-(1-methyl-1-phenyl-ethyl)- harnstoff (Dymron), 4,6-Dichlor-2-phenyl-pyrimidin (Fenclorim), 1-(2,4-Di chlor-phenyl)-5-trichlormethyl-1H-1,2,4-triazol-3-carbonsäure-ethylester (Fenchlorazol-ethyl), 2-Chlor-4-trifluormethyl-thiazol-5-carbonsäure-phenyl methylester (Flurazole), 4-Chlor-N-(1,3-dioxolan-2-yl-methoxy)-α-trifluor acetophenonoxim (Fluxofenim), 3-Dichloracetyl-5-(2-furanyl)-2,2-dimethyl oxazolidin (Furilazole, MON-13900), Ethyl-4,5-dihydro-5,5-diphenyl-3- isoxazolcarboxylat (Isoxadifen-ethyl), (4-Chlor-2-methyl-phenoxy)-essig säure (MCPA), (+-)-2-(4-Chlor-2-methylphenoxy)propansäure (Mecoprop), Diethyl-1-(2,4-dichlorphenyl)-4,5-dihydro-5-methyl-1H-pyrazol-3,5-di carboxylat (Mefenpyr-diethyl) 2-Dichlormethyl-2-methyl-1,3-dioxolan (MG- 191), 1,8-Naphthalsäureanhydrid, α-(1,3-Dioxolan-2-yl-methoximino)- phenylacetonitril (Oxabetrinil), 2,2-Dichlor-N-(1,3-dioxolan-2-yl-methyl)-N- (2-propenyl)-acetamid (PPG-1292) und 3-Dichloracetyl-2,2,5-trimethyl oxazolidin (R-29148)
("Wirkstoffe der Gruppe 3").

and

a) one or more compounds from a second group of herbicides which contains the active compounds mentioned below:
(5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) acetic acid-N-isopropyl-N- (4-fluorophenyl) -amide (flufenacet), 2- (2-methoxycarbonyl-phenylsulfonylamino carbonyl) - 4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one or the sodium salt of this compound (propoxycarbazone (sodium), 2- (2-trifluoromethoxy-phenylsulfonylaminocarbonyl) -4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazol-3-one or the sodium salt of this compound (flucarbazone (sodium), N- (3,4-dichlorophenyl) propanamide (Propanil), N-2-benzothiazolyl-N, N'-dimethylurea (methabenzthiazuron), 4-amino-6- (1,1-dimethylethyl) -3- (methylthio) -1,2,4-triazine-5 ( 4H) -one (metribuzin), 4- (2-chlorophenyl) -N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1 H-tetrazole-1-carboxamide (fentrazamide), 4-amino -3-methyl-6-phenyl-1,2,4-triazin-5 (4H) -one (metamitron), 2- (2-benzothiazolyloxy) -N-methyl-N-phenylacetamide (Mefenacet), 4-amino- 6- (1,1-dimethylethyl) -3- (ethylthio) -1,2,4-triazine-5 (4H) -one (ethiozine), 1-methylethyl 5- [4-bromo-1-methyl-5- (trifluoromethyl) - 1H-pyrazol-3-yl] -2-chloro-4-fluorobenzoate (fluazolates)

and if necessary

a) one or more compounds from a second group of herbicides which contains the active compounds mentioned below:
2-chloro-N- (ethoxymethyl) -N- (2-ethyl-6-methyl-phenyl) -acetamide (aceto chlorine), 5- (2-chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoic acid- Sodium salt (Acifluorfen-sodium), 2-chloro-6-nitro-3-phenoxy-benzenamine (Aclonifen), 2-chloro-N- (methoxymethyl) -N- (2,6-diethyl-phenyl) -acetamide (alachlor ), N-ethyl-N'-i-propyl-6-methylthio-1,3,5-triazine-2,4-diamine (ametryn), 4-amino-N- (1,1-dimethyl-ethyl) - 4,5-dihydro-3- (1-methyl-ethyl) - 5-oxo-1H-1,2,4-triazole-1-carboxamide (amicarbazone), N- (4,6-dimethoxy pyrimidin-2-yl ) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), 1H-1,2,4-triazol-3-amine (amitrole), 6-chloro-4-ethyl amino-2- isopropylamino-1,3,5-triazine (atrazine), 2- [2,4-dichloro-5- (2-propynyloxy) phenyl] -5,6,7,8-tetrahydro-1,2,4- triazolo- [4,3-a] pyridin-3 (2H) -one (azafenidin), N- (4,6-dimethoxypyrimidin-2-yl) -N '- [1-methyl-4- (2nd -methyl- 2H-tetrazol-5-yl) -1H-pyrazol-5-ylsulfonyl] urea (azimsulfonate), N-benzyl-2- (4-fluoro-3-trifluoromethyl-phenoxy) -butanamide (beflubutamide), 4 - chlorine -2-oxo-3 (2H) -benzthiazole acetic acid (benazoline), N-butyl-N-ethyl-2,6-dinitro-4-trifluoromethyl-benzenamine (benfluralin), N- (4,6-dimethoxy pyrimidine-2- yl) -N '- (2-methoxycarbonylphenylmethylsulfonyl) urea (bensulfuron), 2- [2- [4- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 ( 2H) -pyrimidinylphenoxymethyl] -5-ethyl-phenoxy-propanoic acid methyl ester (benzfendizone), 3- (2-chloro-4-methylsulfonyl-benzoyl) -4-phenylthio-bi cyclo- [3.2.1] -oct-3- en-2-one (benzobicyclone), ethyl N-benzoyl-N- (3,4-di chlorophenyl) -DL-alaninate (benzoylprop-ethyl), 3-i-propyl-1H-2,1,3- benzothiadiazin-4 (3H) -one (bentazone), methyl 5- (2,4-dichlorophenoxy) -2-nitro benzoate (bifenox), 2,6-bis- (4,6-dimethoxy-pyrimidine- 2-yl-oxy) -benzoic acid sodium salt (bispyribac-sodium), 2-bromo-3,3-dimethyl-N- (1-methyl-1-phenyl-ethyl) -butanamide (bromobutide), 3,5-dibromo -4-hydroxy-benzaldehyde-O- (2,4-dinitro-phenyl) -oxime (bromofenoxime), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), N-butoxymethyl-2-chloro-N - (2,6-diethyl phenyl) acetam id (butachlor), 2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) -benzoic acid- [1,1-dimethyl-2 -oxo-2- (2-propenyloxy)] ethyl ester (butafenacil-allyl), 2- (1-ethoximino-propyl) -3-hydroxy-5- [2,4,6-trimethyl-3- (1-oxo -butyl) -phenyl] -2-cyclohexen-1-one (butoxydim), S-ethyl-bis- (2-methyl-propyl) -thiocarbamate (butylate), N, N-diethyl-3- (2.4 , 6-trimethyl-phenylsulfonyl) -1H-1,2,4-triazole-1-carboxamide (cafenstrole), 2- [1 - [(3-chloro-2-propenyl) -oxy-imino] -propyl] -3 -hydroxy-5- (tetrahydro-2H-pyran-4-yl) -2-cyclohexen-1-one (caloxydim, tepraloxydim), 2- (4-chloro-2-fluoro-5- (2-chloro-2- ethoxycarbonyl-ethyl) -phenyl) -4-difluoro methyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (Carfentrazone-ethyl), 2,4-dichloro-1- (3-methoxy-4-nitro-phenoxy) benzene (chloromethoxyfen), 3-amino-2,5-dichloro-benzoic acid (chlorambene), N- (4-chloro-6-methoxy-pyrimidin-2-yl) -N '- (2-ethoxycarbonyl-phenylsulfonyl) urea (chlorimuron ethyl), 1,3,5-trichloro-2- (4-nitro-phenoxy) benzene (chloronitrofen), N- (4- Methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-chlorophenylsulfonyl) urea (chlorosulfuron), N' - (3-chloro-4-methylphenyl) - N, N-dimethyl-urea (chlorotoluron), 2-chloro-3- [2-chloro-5- (1, 3, 4,5,6,7-hexahydro-1,3-dioxo-2H-isoindole-2 -yl) -phenyl] -2-propanoic acid ethyl ester (cinidon-ethyl), N- (4,6-dimethoxy-1,3,5-triazin-2-yl) -N '- (2- (2-methoxy -ethoxy) phenylsulfonyl) urea (cinosulfuron), 2- [1- [2- (4-chlorophenoxy) propoxyaminobutyl] -5- (tetrahydro-2H-thiopyran-3-yl) -1,3-cyclohexanedione (Clefoxydim), (E, E) - (+) - 2- [1 - [[(3-chloro-2-propenyl) -oxy] -imino] -propyl] -3-hydroxy-2-cyclohexene-1- on (Clethodim), (R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yl-oxy) phenoxy propanoate (Clodinafop propargyl), 3.6 -Dichloropyridine-2-carboxylic acid (clopyralide), methyl-3-chloro-2 - [(5-ethoxy-7-fluoro [1,2,4] triazolo [1,5-c] pyrimidin-2-yl -sulfonyl) -amino] -benzoate (chlorosulam-methyl), 2-chloro-4-ethylamino-6- (1-cyano-1-methyl-ethylamino) -1,3,5-triazine (cyanazine), N- ( 4,6-Dimethoxypyrimidin-2-yl) -N '- (2-c yclopropylcarbonylphenylsulfonyl) urea (cyclosulfamuron), 2- (1-ethoximinobutyl) -3-hydroxy-5- (tetra hydro-2H-thiopyran-3-yl) -2-cyclohexen-1-one (cycloxydim), (R. ) -2- [4- (4- Cyano-2-fluorophenoxy) phenoxy] propanoic acid butyl ester (cyhalofop butyl), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6- Dichloro-2-methoxy-benzoic acid (Dicamba), (R) -2- (2,4-dichlorophenoxy) propanoic acid (dichloroprop-P), methyl 2- [4- (2,4-dichlorophenoxy) -phenoxy] propanoate (diclofop-methyl), N- (2,6-dichlorophenyl) -5-ethoxy-7-fluoro [1,2,4] triazolo [1,5-c] pyrimidine -2-sulfonamide (diclosulam), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methyl sulfate (difenzoquat), N- (2,4-difluorophenyl) -2- (3-trifluoromethylphenoxy ) - pyridine-3-carboxamide (diflufenican), 2- [1 - [(3,5-difluorophenyl) amino carbonyl hydrazono] ethyl] pyridine-3-carboxylic acid (diflufenzopyr), S- (1- Methyl 1-phenyl-ethyl) -1-piperidine carbothioate (dimepiperate), (S-) 2-chloro-N- (2,4-dimethyl-3-thienyl) -N- (2-methoxy-1-methyl -ethyl) -acetamide (S-) (di methenamid), 2- Amino-4- (1-fluoro-1-methyl-ethyl) -6- (1-methyl-2- (3,5-dimethyl-phenoxy) -ethylamino) -1,3,5-triazine (dimexyflam), N3, N3-diethyl-2,4-dinitro-6-trifluoromethyl-1,3-diamino-benzene (dinitramine), 6,7-dihydro dipyrido [1,2-a: 2 ', 1'-c] pyrazine diium ( Diquat), S, S-dimethyl-2-difluoromethyl-4-i-butyl-6-trifluoromethyl-pyridine-3,5-dicarbothioate (dithiopyr), N '- (3,4-di chlorophenyl) -N, N-dimethyl-urea (diuron), 2- [2- (3-chlorophenyl) oxiranylmethyl] -2-ethyl-111-indene-1,3 (2H) -dione (epropodane), S-ethyl-dipro pylthiocarbamate (EPTC), S- (phenylmethyl) -N-ethyl-N- (1,2-dimethylpropyl) thiocarbamate (Esprocarb), N-ethyl-N- (2-methyl-2-propenyl) -2, 6- dinitro-4-tri fluoromethylbenzamine (ethalfluralin), (S) - (2-ethoxy-1-methyl-2-oxoethyl) - 2-chloro-5- (2-chloro-4-trifluoromethylphenoxy) benzoate ( Ethoxyfen), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (2-ethoxyphenoxysulfonyl) urea (ethoxysulfuron), (R) -ethyl-2- [4- (6-chloro -benzoxazol-2-yl-oxy) phenoxy] propanoate (fenoxaprop- (P) -ethyl), 4- (2-chlorophenyl) -N-cyclohe xyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamide), isopropyl-N-benzoyl-N- (3-chloro-4-fluro-phenyl) -DL-alaninate (Flamprop-isopropyl), isopropyl-N-benzoyl-N- (3-chloro-4-fluro-phenyl) -L-alaninate (flamprop-isopropyl-L), methyl-N-benzoyl-N- (3- chloro-4-fluorophenoxy) -DL-alaninate (Flamprop-methyl), N- (2,6-difluorophenyl) -8-fluoro-5-methoxy- [1,2,4] - triazolo- [1 , 5-c] -pyrimidine-2-sulfonamide (florasulam), (R) -2- [4- (5-trifluoromethyl-pyridin-2-yl-oxy) phenoxy] propanoic acid butyl ester (fluazifop, butyl , -P-butyl), 5- (4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl) -2-chloro-4-fluoro-benzoic acid i-propyl ester (fluazolates), 4, 5-Dihydro-3-methoxy-4-methyl-5-oxo-N - [(2-trifluoromethoxyphenyl) sulfonyl] -1-H-1,2,4-triazole-1-carboxamide sodium salt (flucarbazone- sodium), N- (4-fluorophenyl) -nipropyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (Flufenacet), N- (2,6 -Difluorophenyl) -5-methyl-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfone amide (flumetsulam), pentyl- [2-chloro-4-fluoro -5- (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenoxy] acetate (flumiclorac-pentyl), 2- [7-fluoro- 3,4-dihydro-3-oxo-4- (2-propynyl) -2H-1,4-benzoxazin-6-yl] -4,5,6,7-tetra hydro-1H-isoindole-1,3- dione (flumioxazin), 2- [4-chloro-2-fluoro-5 - [(1-methyl-2-propynyl) -oxy] phenyl] -4,5,6,7-tetrahydro-1H-isoindole-1 , 3 (2H) -dione (flumipropyn), 3-chloro-4-chloromethyl-1- (3-trifluoromethyl-phenyl) -2-pyrrolidinone (fluorochloridone), 5- (2-chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoic acid ethoxycarbonylmethyl ester (fluoroglycofen-ethyl), 1- (4-chloro-3- (2, 2,3,3,3-pentafluoropropoxy methyl) phenyl) -5-phenyl-1H-1, 2,4-triazole-3-carboxamide (flupoxam), 1-isopropyl-2-chloro-5- (3,6-dihydro-3-methyl-2,6-di oxo-4-trifluoromethyl-1 (2H) - pyrimidyl) benzoate (flupropacil), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl) urea sodium salt ( Flupyrsulfuron-methyl-sodium), 9-hydroxy-9H-fluoren-9-carboxylic acid (flurenol), (4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy ) -acetic acid (-2-butoxy-1-methyl-ethyl ester, -1-methyl heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 5-methylamino-2-phenyl-4- (3-trifluoromethyl-phenyl) -3 (2H) -furanone (Flurtamone), methyl - [(2-chloro-4-fluoro-5- (tetrahydro-3-oxo-1H, 3H- [1,3,4] thiadiazolo- [3,4-a ] -pyridazin-1-ylidene) -amino-phenyl] -thio-acetate (Fluthiacet-methyl), 5- (2-chloro-4-trifluoromethyl-phenoxy) -N-methylsulfonyl-2-nitro-benzamide (Fomesafen) , 2- [[[[(4,6-Dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -4- formylamino-N, N-dimethyl-benzamide (foramsulfuron), 2-amino- 4- (hydroxymethylphosphinyl) butanoic acid (ammonium salt) (glufosinate (ammonium)), N-phosphonomethylglycine (isopropylammonium salt), (glyphosate, isopropylammonium), (R) -2- [4- (3rd -Chlor-5-trifluoromethyl-pyridin-2-yl-oxy) -phenoxy] -propanoic acid (-methyl ester, -2-ethoxy-ethyl ester, -butyl ester) (haloxyfop, -methyl, -P-methyl, -ethoxyethyl, - butyl), 3-cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4 (1H, 3H) -dione (hexazinones), methyl-2- (4th , 5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -4-methyl-benzoate (imazamethabenz-methyl), 2- (4,5-dihydro-4-methyl- 4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methyl-pyridine-3-carboxylic acid (Imaza methapyr), 2- (4,5-dihydro-4-methyl-4-isopropyl-5 -oxo-1H-imidazol-2-yl) -5- methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol- 2-yl) -quinolin-3-carboxylic acid (imaza quin), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -5-ethyl pyridin-3-carboxylic acid (imazethapyr), N- (4,6-dimethoxypyrimidin-2-yl) -N'- (2-chloro-imidazo [1,2-a] pyridin-3-yl-sulfonyl) urea (imazosulfuron), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (5-iodo-2-methoxycarbonyl phenylsulfonyl) urea sodium salt (iodosulfuron) methyl-sodium), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), N, N-dimethyl-N '- (4-isopropylphenyl) -urea (isoproturon), N- (3- (1-ethyl -1-methyl-propyl) -isoxazol-5- yl) -2,6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methylsulfonyl-phenyl) - ( 5-cyclopropyl-isoxazol-4-yl) -methanone (isoxachlorotole), (5-cyclopropyl-isoxazol-4-yl) - (2-methylsulfonyl-4-trifluoromethyl-phenyl) -methanone (isoxa flutole), 2- [2- [4- [3,5-dichloro-2-pyridinyl) -oxy] -phenoxy] -1-oxo-propyl] -is oxazolidine (isoxapyrifop), (2-ethoxy-1-methyl-2-oxo-ethyl) - 5- (2-chloro-4-tri fluoromethyl-phenoxy) -2-nitro-benzoate (lactofen), N '- (3,4-dichlorophenyl) -N-methoxy-N-methyl-urea (Linuron), (4-chloro-2-methylphenoxy) acetic acid (MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (mecoprop), 2- (2-benzothiazolyloxy) -N-methyl-N -phenyl-acetamide (Mefenacet), 2- (4-methylsulfonyl-2-nitro-benzoyl) -1,3-cyclohexanedione (mesotrione), 4-amino-3-methyl-6-phenyl-1,2,4-triazine -5 (4H) -one (metamitron), 2-chloro-N- (2,6-dimethylphenyl) -N- (1H-pyrazol-1-ylmethyl) acetamide (metazachlor), N'- (4- (3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy) phenyl) -N-methoxy-N-methyl-urea (metobenzuron) , N '- (4-bromophenyl) -N-methoxy-N-methylurea (metobromuron), (S) -2-chloro-N- ( 2-ethyl-6-methyl-phenyl) -N- (2-methoxy-1-methyl-ethyl) -acet-amide (Metola chlor, S-Metolachlor), N- (2,6-dichloro-3-methyl- phenyl) -5,7-dimethoxy-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (metosulam), N '- (3-chloro-4-methoxy-phenyl) -N, N-dimethyl-urea (metoxuron), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin), N- (4-methoxy-6- methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (metsulfuron-methyl), S-ethyl-hexahydro-1H-azepine-1-carbothioate (Moli nate) , 2- (2-Naphthyloxy) -N-phenyl-propanamide (naproanilide), N-butyl-N'- (3,4-dichlorophenyl) -N-methyl-urea (neburon), N- (4,6 -Dimethoxy-pyrimidin-2-yl) -N '- (3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl) urea (Nico sulfuron), S- (2-chloro-benzyl) -N, N-diethyl- thiocarbamate (Orbencarb), 4-di propylamino-3,5-dinitro-benzenesulfonamide (Oryzalin), 3- [2,4-dichloro-5- (2-propynyloxy) phenyl] -5- (t-butyl) -1 , 3,4-oxadiazol-2 (3H) -one (oxadiargyl), 3- [2,4-dichloro-5- (1-methylethoxy) phenyl] -5- (t-butyl) -1.3 , 4-oxadiazol-2 (3H) - one (oxadiazon), N- (4,6-dimethyl-pyrimidin-2-yl) -N '- (2-oxetan-3-yl-oxycarbonylphenylsulfonyl) urea (Oxasulfuron), 3- [1- (3,5-dichlorophenyl) -1-i-propyl] -2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4- on (oxaziclo mefone), 2-chloro-1- (3-ethoxy-4-nitro-phenoxy) -4-trifluoromethyl-benzene (oxyfluorfen), 1,1'-dimethyl-4,4'-bipyridinium (paraquat), 1-Amino-N- (1-ethyl-propyl) -3,4-dimethyl-2,6-dinitro-benzene (pendimethalin), 4- (t-butyl) -N- (1-ethyl-propyl) -2 , 6-dinitro-benzenamine (pendralin), 4-amino-3,5,6-trichloropyridine-2-carboxylic acid (picloram), 2-chloro-N- (2,6-diethyl-phenyl) -N- (2nd -prop oxy-ethyl) -acetamide (pretilachlor), N- (4,6-bis-difluoromethoxy-pyrimidin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) -urea (Primisulfuron methyl), 1-chlorine -N- [2-chloro-4-fluoro-5 - [(6S, 7aR) -6-fluoro-tetrahydro-1,3-di oxo-1H-pyrrolo [1,2-c] imidazole-2 (3H) -yl] -phenyl] -methanesulfonamide (proflu azole), 2-chloro-N-isopropyl-N-phenyl-acetamide (propachlor), N- (3,4-dichlorophenyl) -propanamide (propane il), (R) - [2 - [[(1-methylethylidene) amino] oxy] ethyl] -2- [4- (6-chloro-2-quinoxalinyloxy) phenoxy] propanoate (propaquizafop ), 2-chloro-N- (2-ethyl-6-methyl-phenyl) -N - [(1-methyl-ethoxy) -methyl] -acetamide (propisochlor), 2 - [[[(4,5- Dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino] sulfonyl] benzoic acid methyl ester sodium salt (propoxycarbazone sodium), S-phenylmethyl-N, N-dipropyl-thiocarb amate (prosulfocarb), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2- (3.3 , 3-trifluoropropyl) phenylsulfonyl) urea (prosulfuron), ethyl [2-chloro-5- (4-chloro-5-difluoromethoxy-1-methyl-1 H-pyrazol-3-yl) -4- fluorophenoxy] acetate (pyraflufen-ethyl), 1- (3-chloro-4,5,6,7-tetrahydro-pyrazolo [1,5-a] pyridin-2-yl) -5- (methyl-2 -propinylamino) -1H-pyrazole-4-carbonitrile (pyrazogyl), 4- (2,4-dichlorobenzoyl) -1,3-dimethyl-5- (4-methylphenylsulfonyloxy) -pyrazole (pyrazolate), 4 - (2,4-dichlorobenzoyl) -1,3-dimethyl-S- (phenylcarbonylmethoxy) pyrazole (pyrazoxyfen), N- (4,6-dimethoxypyrimidin-2-yl) -N ' - (4-ethoxycarbonyl-1-methyl-pyrazol-5-yl-sulfonyl) urea (pyrazosulfuron-ethyl), diphenylmethanone-O- [2,6-bis- (4,6-dimethoxy-pyrimidin-2-yl -oxy) -benzoyl] - oxime (pyribenzoxime), 6-chloro-3-phenyl-4-pyridazinol (pyridafol), O- (6-chloro-3-phenyl-pyridazin-4-yl) -S-octylthiocarbonate (Pyridate), 6-chloro-3-phenyl-pyridazin-4-ol (pyridatol), 7 - [(4,6-dimethoxy-2-pyrimidinyl) thio] -3-methyl-1 (3H) -isobenzofuranone ( Pyriftalid), 2- (4,6-dimethoxypyrimidin-2-yl-oxy) -benzoic acid methyl ester (pyriminobac-methyl), 2-chloro-6- (4,6-di methoxypyrimidin-2-ylthio) -benzoic acid sodium salt (Pyrithiobac-sodium), 3,7-dichloro-quinoline-8-carboxylic acid (Quinchlorac), 7-chloro-3-methyl quinoline-8-carboxylic acid (Quinmerac), 2- [4- (6-chlorine -2-quinoxalinyloxy) -phen oxy] -propanoic acid (-ethyl ester, -tetrahydro-2-furanyl-methyl ester) (Quizalo fop, -ethyl, -P-ethyl, -P-tefuryl), N- (4,6-dimethoxy -pyrimidin-2-yl) -N '- (3-ethylsulfonyl-pyridin-2-yl-sulfonyl) urea (rimsulfuron), 2- (1-ethoximinobutyl) -5- (2-ethylthiopro pyl) -3-hydroxy-2-cyclohexen-1-one (sethoxy dim), 6-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazine), 2- (2-chloro-4 - methylsulfonyl-benzoyl) -cyclohexane-1,3-dione (sulcotrione), 2- (2,4-dichloro-5-methylsulfonylamino-phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro-3H-1 , 2,4-triazol-3-one (sulfentrazone), N-phosphonomethyl-glycine-trimethyl sulfonium (sulfosate), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (2-ethyl sulfonyl -imidazo [1,2-a] pyridine-3-sulfonamide (sulfosulfuron), 6-chloro-4-ethylamino-2-tert-butylamino-1,3,5-triazine (terbuthylazine), 2-tert-butyl amino- 4-ethylamino-6-methylthio-1,3,5-triazine (terbutryn), 2-chloro-N- (2,6-dimethyl-phenyl) -N- (3-methoxy-2-thienyl-methyl) -acetamide (Thenylchlor), 2-difluoromethyl-S- (4,5-dihydro-thiazol-2-yl) -4- (2-methyl-propyl) -6-trifluoromethyl-pyridine-3-carboxylic acid, methyl ester (thiazopyr), 6- (6,7-dihydro-6,6-dimethyl-3H, 5H-pyrrolo [2,1-c] -1,2,4-thiadiazol-3-ylidenamino) -7-fluoro-4- (2- propynyl) -2H-1,4-benzoxazin-3 (4H) -one (thidiazimin), N- (4-methoxy-6-methyl-1,3,5- triazin-2-yl) -N '- (2-methoxycarbonyl-thien-3-yl-sulfonyl) urea (thifensulfuron-methyl), 2- (ethoximino-propyl) -3-hydroxy-5- (2,4 , 6-tri methyl-phenyl) -2-cyclohexen-1-one (tralkoxydim), S- (2,3,3-trichloro-2-propenyl) -diisopropylcarbamothioate (triallate), N- (4-methoxy-6- methyl-1,3,5-triazin-2-yl) -N '- [2- (2-chloroethoxy) phenylsulfonyl] urea (triasulfuron), N-methyl-N- (4-methoxy-6 -methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonylphenylsulfonyl) urea (tribenuron-methyl), (3,5,6-trichloro) pyridin-2-yl -oxyacetic acid (triclopyr), 2- (3,5-dichlorophenyl) -2- (2,2,2-tri chloroethyl) oxirane (tridiphane), N - [[(4,6-dimethoxy -2-pyrimidinyl) amino] - carbonyl] -3- (2,2,2-trifluoro-ethoxy) -2-pyridinesulfonamide sodium salt (tri-floxysulfuron), 1-amino-2,6-dinitro-N, N- dipropyl-4-trifluoromethyl-benzene (trifluralin), N- [4-dimethylamino-6- (2,2,2-trifluoro-ethoxy) -1,3,5-triazin-2-yl] -N '- (2nd -methoxycarbonyl-phenylsulfonyl) urea (triflusulfuron methyl), N - [[(4,6-dimethoxy-2-pyrimidinyl) amino] -c arbonyl] -3- (N-methyl-N-methylsulfonylamino]) - 2-pyridinesulfonamide, (cf. WO-A-92/10 660), 2- [[[[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -4- [[(methylsulfonyl) amino] methyl] -benzoic acid methyl ester (cf. DE-A-43 35 297), 4- [4,5-dihydro-4-methyl-5-oxo (3-trifluoromethyl) -1H-1,2,4-tri azol-1-yl] -2 - [(ethylsulfonyl) amino] -5-fluorobenzenecarbothioamide (cf. WO-A-95/30 661)
("Active substances of group 2"),

and / or if necessary

a) a compound which improves crop plant tolerance from the following group of compounds:
4-dichloroacetyl-1-oxa-4-aza-spiro [4.5] -decane (AD-67), 1-dichloroacetyl-hexa hydro-3,3,8a-trimethylpyrrolo [1,2-a] pyrimidine-6 ( 2H) -one (BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (Benoxacor), 5-chloro-quinoxaline-8-oxyacetic acid- (1- methyl hexyl ester) (Cloquintocet mexyl), α- (cyanomethoximino) phenylacetonitrile (Cyometrinil), 2,4-dichlorophenoxyacetic acid (2,4-D), 2,2-dichloro-N- (2-oxo-2 - (2-propenylamino) - ethyl) -N- (2-propenyl) -acetamide (DKA-24), 2,2-dichloro-N, N-di-2-propenyl acetamide (dichlormid), N- (4- Methyl-phenyl) -N '- (1-methyl-1-phenyl-ethyl) urea (Dymron), 4,6-dichloro-2-phenyl-pyrimidine (Fenclorim), 1- (2,4-di chloro) phenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid ethyl ester (fenchlorazole-ethyl), 2-chloro-4-trifluoromethyl-thiazole-5-carboxylic acid-phenyl methyl ester (flurazole), 4- Chloro-N- (1,3-dioxolan-2-yl-methoxy) -α-trifluoroacetophenone oxime (fluxofenim), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyl oxazolidine (furilazole, MON-13900 ), Ethyl-4,5-dih ydro-5,5-diphenyl-3-isoxazole carboxylate (isoxadifen-ethyl), (4-chloro-2-methylphenoxy) acetic acid (MCPA), (+ -) - 2- (4-chloro-2-methylphenoxy ) propanoic acid (mecoprop), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole-3,5-di carboxylate (mefenpyr-diethyl) 2-dichloromethyl-2-methyl -1,3-dioxolane (MG-191), 1,8-naphthalic anhydride, α- (1,3-dioxolan-2-yl-methoximino) - phenylacetonitrile (oxabetrinil), 2,2-dichloro-N- (1, 3-dioxolan-2-yl-methyl) -N- (2-propenyl) acetamide (PPG-1292) and 3-dichloroacetyl-2,2,5-trimethyl oxazolidine (R-29148)
("Active substances of group 3").

2. Herbizide Mittel gemäß Anspruch 1, dadurch gekennzeichnet, dass sie als Wirkstoff der Gruppe 3 zumindest eine die Kulturpflanzenverträglichkeit ver bessernde Verbindung aus der folgenden Gruppe von Verbindungen ent halten:
5-Chlor-chinoxalin-8-oxy-essigsäure-(1-methylhexylester) (Cloquintocet), 1- (2,4-Dichlor-phenyl)-5-trichlormethyl-1H-1,2,4-triazol-3-carbonsäure-ethyl ester (Fenchlorazol-ethyl), Ethyl-4,5-dihydro-5,5-diphenyl-3-isoxazolcarb oxylat (Isoxadifen-ethyl), Diethyl-1-(2,4-dichlorophenyl)-4,5-dihydro-5-me thyl-1H-pyrazol-3,5-dicarboxylat (Mefenpyr-diethyl) und 2,4-Dichlor phenoxyessigsäure (2,4-D) sowie dessen Derivate.2. Herbicidal compositions according to claim 1, characterized in that they contain, as an active ingredient in group 3, at least one compound from the following group of compounds which improves crop compatibility.
5-chloro-quinoxaline-8-oxyacetic acid (1-methylhexyl ester) (cloquintocet), 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid -ethyl ester (fenchlorazole-ethyl), ethyl-4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifen-ethyl), diethyl-1- (2,4-dichlorophenyl) -4,5-dihydro -5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl) and 2,4-dichlorophenoxyacetic acid (2,4-D) and its derivatives.

3. Verwendung eines Mittels gemäß Anspruch 1 oder 2 zur Bekämpfung von un erwünschten Pflanzen.3. Use of an agent according to claim 1 or 2 for combating un desired plants.

4. Verfahren zur Bekämpfung von unerwünschten Pflanzen, dadurch gekenn zeichnet, dass man Mittel gemäß Anspruch 1 oder 2 auf die unerwünschten Pflanzen und/oder ihren Lebensraum einwirken lässt.4. A method of combating undesirable plants, characterized records that means according to claim 1 or 2 to the undesirable Plants and / or their habitat.

5. Verfahren zur Herstellung eines herbiziden Mittels, dadurch gekennzeichnet, dass man ein Mittel gemäß Anspruch 1 oder 2 mit oberflächenaktiven Mitteln und/oder Streckmitteln vermischt.5. A process for the preparation of a herbicidal composition, characterized in that that one has a composition according to claim 1 or 2 with surfactants and / or extenders mixed.