DE19941085A1 - Liberation of hydrogen from reserve for use as fuel in hydrogen-driven engine uses chemical and/or physical reaction of saline and/or alloy-type hydride - Google Patents

Liberation of hydrogen from reserve for use as fuel in hydrogen-driven engine uses chemical and/or physical reaction of saline and/or alloy-type hydride

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Publication number
DE19941085A1
DE19941085A1 DE19941085A DE19941085A DE19941085A1 DE 19941085 A1 DE19941085 A1 DE 19941085A1 DE 19941085 A DE19941085 A DE 19941085A DE 19941085 A DE19941085 A DE 19941085A DE 19941085 A1 DE19941085 A1 DE 19941085A1
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Germany
Prior art keywords
hydrides
hydrogen
hydride
alloy
fuel
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
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DE19941085A
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German (de)
Inventor
Rainer Haas
Franz Dietrich Oeste
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Individual
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Individual
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Priority to DE19941085A priority Critical patent/DE19941085A1/en
Publication of DE19941085A1 publication Critical patent/DE19941085A1/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/065Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B43/00Engines characterised by operating on gaseous fuels; Plants including such engines
    • F02B43/08Plants characterised by the engines using gaseous fuel generated in the plant from solid fuel, e.g. wood
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/30Use of alternative fuels, e.g. biofuels

Abstract

Liberation of hydrogen (H2) from hydrides as reserve for H2-driven engines comprises liberating H2 from a saline and/or alloy-type hydride by (a) a chemical reaction when required and/or (b) physical action and using the H2 generated as fuel. An Independent claim is also included for the use of specified hydrides in this process.

Description

Das erfindungsgemäße Verfahren beschreibt ein wirtschaftliches Verfahren, Wasserstoff als Hydrid gefahrlos zu speichern und in wasserstoffbetriebenen Kraftmaschinen als Reserve mitzuführen. Die Anwendung von Hydriden für diesen Zweck ist ebenfalls Bestandteil des erfindungsgemäßen Verfahrens.The process according to the invention describes an economical process, hydrogen as Store hydride safely and as a reserve in hydrogen-powered engines to carry along. The use of hydrides for this purpose is also part of the inventive method.

Nach dem Stand der Technik wird Wasserstoff derzeit unter hohem Druck in Tanks, die Platinmetalle als Wasserstoffspeichermedien enthalten, gefahrlos gespeichert. Im Gegensatz zu Maschinen, die mit Otto- oder Dieselkraftstoff betrieben werden, ist das Mitführen einer Kraftstoffreserve an ein Speichermedium für Wasserstoff gebunden. Ein Reservetank wäre im Falle einer wasserstoffbetriebenen Krafimaschine als zusätzlicher Platintank denkbar. Dies wäre jedoch nur unter erheblichen Nachteilen wie hohe Kosten, zusätzliches Gewicht, zusätzlicher Raumbedarf, realisierbar.According to the prior art, hydrogen is currently under high pressure in tanks that Contain platinum metals as hydrogen storage media, stored safely. In contrast to machines that run on petrol or diesel fuel is one Fuel reserve tied to a storage medium for hydrogen. A reserve tank would be conceivable as an additional platinum tank in the case of a hydrogen-powered motor vehicle. However, this would only be with considerable disadvantages such as high costs, additional weight, additional space required, realizable.

Das Mitführen von Wasserstoff in einer Druckgasflasche als Krafistoffreserve birgt hohe Risiken (Explosion) und ist deshalb nicht realisierbar. Auch ist die Zahl der Wasserstofftankstellen noch gering, was den Aktionsradius von wasserstoffbetriebenen Fahrzeugen einschränkt. Die erfindungsgemäße Lösung, den Wasserstoff als Hydride mitzuführen, bietet den Vorteil, daß die Hydride in geeigneten Gefäßen relativ gefahrlos zu händeln sind und deshalb an vielen Stellen, z. B. an normalen Kraftstoff-Tankstellen, zum Verkauf angeboten werden können. Die Anwendung von Hydriden als Wasserstoffspeichermedium für wasserstoffgetriebene Kraftmaschinen ist ebenfalls Bestandteil des erfindungsgemäßen Verfahrens.Carrying hydrogen in a pressurized gas bottle as a fuel reserve harbors a high level Risks (explosion) and is therefore not feasible. Is also the number of Hydrogen filling stations are still small, which is the range of action of hydrogen-powered Vehicles. The solution according to the invention, the hydrogen as hydrides has the advantage that the hydrides are relatively safe in suitable vessels are trading and therefore in many places, e.g. B. at normal fuel filling stations, for Can be offered for sale. The application of hydrides as Hydrogen storage medium for hydrogen powered engines is also Part of the method according to the invention.

Mit dem erfindungsgemäßen Verfahren gemäß Ansprüchen 1 bis 8 kann dieser Bedarf gedeckt werden.With the inventive method according to claims 1 to 8, this need to be covered.

Das erfindungsgemäße Verfahren beruht auf dem Prinzip eines drucklosen chemischen Wasserstoffspeichers, aus dem jederzeit bei Bedarf Wasserstoff durch chemische bzw. physikalische Reaktionen freigesetzt werden kann und damit als sicherer Brennstoff zur Verfügung steht. The method according to the invention is based on the principle of an unpressurized chemical Hydrogen storage, from which hydrogen is available at any time through chemical or physical reactions can be released and thus as a safe fuel for Available.  

Als drucklose Wasserstoff-Speichermedien für das erfindungsgemäße Verfahren kommen vorzugsweise salzartige Hydride aus den Gruppen der Alkalihydride (z. B. Natriumhydrid, Kaliumhydrid), Erdalkalihydride (z. B. Calciumhydrid), Mischhydride (z. B. Natriumborhydrid, Natriumaluminiumhydrid) und legierungsartige Hydride (z. B. Titanhydrid) zum Einsatz.Coming as pressureless hydrogen storage media for the method according to the invention preferably salt-like hydrides from the groups of the alkali metal hydrides (e.g. sodium hydride, Potassium hydride), alkaline earth hydrides (e.g. calcium hydride), mixed hydrides (e.g. Sodium borohydride, sodium aluminum hydride) and alloy-like hydrides (e.g. Titanium hydride).

Die genannten Hydride sind stabile Verbindungen, aus denen durch geeignete chemische oder physikalische Reaktionen Wasserstoff freigesetzt werden kann.The hydrides mentioned are stable compounds from which suitable chemical or physical reactions hydrogen can be released.

Der Reservetank besteht bevorzugt aus einem Behältnis, das eines oder mehrere der o. g. Hydride enthält.The reserve tank preferably consists of a container that holds one or more of the above. Contains hydrides.

Die Wasserstofffreisetzung geschieht im Falte der salzartigen Hydride bevorzugt durch chemische Reaktion mit einem geeigneten, vorzugsweise flüssigen, Reaktionspartner. Dieser Reaktionspartner wird bevorzugt in einem zweiten Behältnis gelagert und kann durch gezielte Dosierung, z. B. automatisch durch Druckregelung, zum Hydrid dosiert werden und dadurch die Wasserstofffreisetzung auslösen. Der entstandene Wasserstoff kann über eine Verbindungsleitung in den Wasserstofftank überfährt und von dem dort befindlichen Speichermedium aufgenommen werden. Er kann auch in einen kleineren Platin enthaltenden Tank überführt und dort als Brennstoff gespeichert werden. Bevorzugt wird Wasser als Reaktionspartner eingesetzt.The release of hydrogen occurs preferentially in the fold of the salt-like hydrides chemical reaction with a suitable, preferably liquid, reaction partner. This Reaction partner is preferably stored in a second container and can be targeted Dosage, e.g. B. automatically dosed by pressure control to hydride and thereby trigger the hydrogen release. The hydrogen generated can Connecting line runs over into the hydrogen tank and from there Storage medium can be recorded. It can also be contained in a smaller platinum Tank transferred and stored there as fuel. Water is preferred as Reaction partner used.

Im Falle der legierungsartigen Hydride wird der enthaltene Wasserstoff vorzugsweise durch physikalische Methoden, bevorzugt durch Temperaturerhöhung auf größer 100°C, freigesetzt. Bevorzugte Energiequelle für die Temperaturerhöhung ist die Batterie.In the case of alloy-like hydrides, the hydrogen contained is preferably through physical methods, preferably by increasing the temperature to greater than 100 ° C, released. The preferred energy source for the temperature increase is the battery.

Bei erfolgtem Druckabfall im Haupttank wird die chemische oder physikalische Wasserstoff- Entwicklung in Gang gesetzt und der entstandene Wasserstoff in den Wasserstofftank überführt. Die Überführung in den Wasserstofftank wird vorzugsweise automatisch durch das entstandene Druckgefälle ausgelöst.If there is a pressure drop in the main tank, the chemical or physical hydrogen Development started and the resulting hydrogen in the hydrogen tank transferred. The transfer into the hydrogen tank is preferably carried out automatically by the created pressure drop triggered.

Claims (9)

1. Verfahren zur Freisetzung von Wasserstoff aus Hydriden als Reserve für wasserstoffgetriebene Kraftmaschinen, dadurch gekennzeichnet, daß
  • a) salzartige und/oder legierungsartige Hydride eingesetzt werden, aus denen im Bedarfsfall durch chemische Reaktionen Wasserstoff freigesetzt wird und/oder
  • b) salzartige und/oder legierungsartige Hydride eingesetzt werden, aus denen durch physikalische Einwirkung Wasserstoff freigesetzt wird,
und daß der generierte Wasserstoff als Kraftstoff genutzt wird.
1. A process for the release of hydrogen from hydrides as a reserve for hydrogen-powered engines, characterized in that
  • a) salt-like and / or alloy-like hydrides are used, from which hydrogen is released if necessary by chemical reactions and / or
  • b) salt-like and / or alloy-like hydrides are used, from which hydrogen is released by physical action,
and that the generated hydrogen is used as fuel.
2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß der Wasserstoff aus den salzartigen und/oder legierungsartigen Hydriden durch Wasser und/oder andere Hydroxylgruppen-haltige Flüssigkeiten freigesetzt wird.2. The method according to claim 1, characterized in that the hydrogen from the salt-like and / or alloy-like hydrides by water and / or others Liquids containing hydroxyl groups is released. 3. Verfahren nach Anspruch 1 und 2, dadurch gekennzeichnet, daß der Wasserstoff aus den salzartigen und/oder legierungsartigen Hydriden durch Temperaturerhöhung auf mehr als 100°C freigesetzt wird.3. The method according to claim 1 and 2, characterized in that the hydrogen from the salt-like and / or alloy-like hydrides by increasing the temperature to more than 100 ° C is released. 4. Verfahren nach Anspruch 1 bis 3, dadurch gekennzeichnet, daß Hydride als Reinstoffe eingesetzt werden.4. The method according to claim 1 to 3, characterized in that hydrides as pure substances be used. 5. Verfahren nach Anspruch 1 bis 4, dadurch gekennzeichnet, daß Hydride als Gemische eingesetzt werden.5. The method according to claim 1 to 4, characterized in that hydrides as mixtures be used. 6. Verfahren nach Anspruch 1 bis 5, dadurch gekennzeichnet, daß die Wasserstofffreisetzung aus dem Reservetank durch Druckabfall im Haupttank ausgelöst und nach erfolgtem Druckanstieg im Haupttank gestoppt wird.6. The method according to claim 1 to 5, characterized in that the hydrogen release triggered from the reserve tank by pressure drop in the main tank and after the Pressure rise in the main tank is stopped. 7. Verfahren nach Anspruch 1 bis 6, dadurch gekennzeichnet, daß der aus einem Reservetank freigesetzte Wasserstoff in den Haupttank überführt wird. 7. The method according to claim 1 to 6, characterized in that the from a reserve tank released hydrogen is transferred to the main tank.   8. Verfahren nach Anspruch 1 bis 7, dadurch gekennzeichnet, daß als Hydride eines oder mehrere der salzartigen Hydride aus den Gruppen der Alkalihydride und Erdalkalihydride, insbesondere Natriumhydrid, Kaliumhydrid, Calciumhydrid und/oder Mischhydride aus den Gruppen der Alkaliborhydride und der Alkalierdalkalihydride, insbesondere Natriumborhydrid, Natriumaluminiumhydrid und/oder legierungsartigen Hydride wie Titanhydrid einzeln oder in Mischungen zum Zwecke der Speicherung und Freisetzung von Wasserstoff als Hydrid als Brennstoff für wasserstoffbetriebene Kraftmaschinen eingesetzt werden.8. The method according to claim 1 to 7, characterized in that one or as hydrides several of the salt-like hydrides from the groups of the alkali hydrides and alkaline earth hydrides, in particular sodium hydride, potassium hydride, calcium hydride and / or mixed hydrides from the Groups of alkali borohydrides and Alkalierdalkalihydride, in particular Sodium borohydride, sodium aluminum hydride and / or alloy-like hydrides such as Titanium hydride individually or in mixtures for the purpose of storing and releasing Hydrogen is used as a hydride as a fuel for hydrogen-powered engines become. 9. Anwendung von Hydriden nach Anspruch 1 bis 8 dadurch gekennzeichnet, daß eines oder mehrere der salzartigen Hydride aus den Gruppen der Alkalihydride und Erdalkalihydride, insbesondere Natriumhydrid, Kaliumhydrid, Calciumhydrid und/oder Mischhydride aus den Gruppen der Alkaliborhydride und der Alkalierdalkalihydride, insbesondere Natriumborhydrid, Natriumaluminiumhydrid und/oder legierungsartigen Hydride wie Titanhydrid einzeln oder in Mischungen in geeigneten Gebinden zum Zwecke der Speicherung von Wasserstoff als Hydrid als Brennstoff für wasserstoffbetriebene Kraftmaschinen eingesetzt werden.9. Use of hydrides according to claim 1 to 8, characterized in that one or several of the salt-like hydrides from the groups of the alkali hydrides and alkaline earth hydrides, in particular sodium hydride, potassium hydride, calcium hydride and / or mixed hydrides from the Groups of alkali borohydrides and Alkalierdalkalihydride, in particular Sodium borohydride, sodium aluminum hydride and / or alloy-like hydrides such as Titanium hydride individually or in mixtures in suitable containers for the purpose of Storage of hydrogen as a hydride as a fuel for hydrogen-powered Engines are used.
DE19941085A 1999-08-30 1999-08-30 Liberation of hydrogen from reserve for use as fuel in hydrogen-driven engine uses chemical and/or physical reaction of saline and/or alloy-type hydride Withdrawn DE19941085A1 (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1531301A1 (en) * 2003-11-13 2005-05-18 Air Products And Chemicals, Inc. System and method for generating and storing pressurized hydrogen
DE10241688B4 (en) * 2001-10-25 2006-06-14 Honda Giken Kogyo K.K. A hydrogen fueling station charging control unit, on-board terminal unit, hydrogen refueling station, method for charging a hydrogen refueling station and a storage device with a computer program product for the on-board terminal unit
EP2055669A2 (en) 2007-11-01 2009-05-06 Honeywell International Inc. Hydrogen producing fuel for power generator
US8187348B2 (en) 2008-04-07 2012-05-29 Honeywell International Inc. Hydrogen generator
US8551663B2 (en) 2007-04-25 2013-10-08 Honeywell International Inc. Power generator with additional hydrogen storage
US9029038B2 (en) 2007-11-01 2015-05-12 Honeywell International Inc. Method of forming a fuel cell stack

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10241688B4 (en) * 2001-10-25 2006-06-14 Honda Giken Kogyo K.K. A hydrogen fueling station charging control unit, on-board terminal unit, hydrogen refueling station, method for charging a hydrogen refueling station and a storage device with a computer program product for the on-board terminal unit
EP1531301A1 (en) * 2003-11-13 2005-05-18 Air Products And Chemicals, Inc. System and method for generating and storing pressurized hydrogen
US8551663B2 (en) 2007-04-25 2013-10-08 Honeywell International Inc. Power generator with additional hydrogen storage
US9799899B2 (en) 2007-04-25 2017-10-24 Honeywell International Inc. Power generator with additional hydrogen storage
EP2055669A2 (en) 2007-11-01 2009-05-06 Honeywell International Inc. Hydrogen producing fuel for power generator
EP2055669A3 (en) * 2007-11-01 2010-01-06 Honeywell International Inc. Hydrogen producing fuel for power generator
US7807131B2 (en) 2007-11-01 2010-10-05 Honeywell International Inc. Hydrogen producing fuel for power generator
US8337806B2 (en) 2007-11-01 2012-12-25 Honeywell International Inc. Hydrogen producing fuel for power generator
US9029038B2 (en) 2007-11-01 2015-05-12 Honeywell International Inc. Method of forming a fuel cell stack
US9225027B2 (en) 2007-11-01 2015-12-29 Honeywell International Inc. Method of forming a fuel cell stack
US8187348B2 (en) 2008-04-07 2012-05-29 Honeywell International Inc. Hydrogen generator

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