DE1919185A1 - Laminates and processes for their manufacture - Google Patents

Laminates and processes for their manufacture

Info

Publication number
DE1919185A1
DE1919185A1 DE19691919185 DE1919185A DE1919185A1 DE 1919185 A1 DE1919185 A1 DE 1919185A1 DE 19691919185 DE19691919185 DE 19691919185 DE 1919185 A DE1919185 A DE 1919185A DE 1919185 A1 DE1919185 A1 DE 1919185A1
Authority
DE
Germany
Prior art keywords
polyvinyl chloride
foam
polyurethane
laminates
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19691919185
Other languages
German (de)
Inventor
Boehm Dr Friedrich
Schwab Dr Johann
Kromp Dr Kurt
Hascic Dipl-Ing Wladimir
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Semperit Gummiwerke Deuts GmbH
Original Assignee
Semperit Gummiwerke Deuts GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AT518468A external-priority patent/AT284057B/en
Application filed by Semperit Gummiwerke Deuts GmbH filed Critical Semperit Gummiwerke Deuts GmbH
Priority to DE19691919185 priority Critical patent/DE1919185A1/en
Priority to NL6906665A priority patent/NL6906665A/xx
Priority to SE07594/69*A priority patent/SE368238B/xx
Priority to GB2713569A priority patent/GB1208544A/en
Publication of DE1919185A1 publication Critical patent/DE1919185A1/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/33—Agglomerating foam fragments, e.g. waste foam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/144—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethane and polymerisation products, e.g. acrylics, PVC
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • C08J2401/08—Cellulose derivatives
    • C08J2401/26—Cellulose ethers
    • C08J2401/28—Alkyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2475/04—Polyurethanes
    • C08J2475/06—Polyurethanes from polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Description

Case 6190Case 6190

DEUTSCHE SEMPERIT GUMMIWERK GES.M.B.H., MÜNCHENGERMAN SEMPERIT GUMMIWERK GES.M.B.H., MUNICH

" Schichtstoffο und Verfahren zu deren Herstellung"Laminate o and process for their manufacture

Schichtstoffe aus Gewebeunterlagen, Kunststoffschaumzwischen-Bchicht und homogener Kunststoffdeckschicht, bei welchen die Schaumzwischenschicht und die homogene Beckschicht aus Polyvinylchlorid bestehen, welche Schichtstoffe von lederartiger Beschaffenheit sind, werden ss.B. so erhalten, daß auf eine homogene Polyvinylchloridsohicht eine blähmittelhalt ige PoIyvinylchloriddispersion aufgebracht und nach Auflegen eines Gewebes diese Mittelschicht durch Erhitzen gebläht wird. Ausserdem sind auch Polyvinylchloridfilme schon als Deckenschichten auf eine Polyurethanschaumschicht aufgeklebt worden, um einen elastischen Schichtstoff zu bilden.Laminates made from fabric underlays, plastic foam interlayer and homogeneous plastic cover layer, in which the Foam intermediate layer and the homogeneous basin layer are made of polyvinyl chloride, which laminates of leather-like Condition are, ss.B. so get that on one homogeneous polyvinyl chloride layers a polyvinyl chloride dispersion containing blowing agent applied and after laying on a fabric this middle layer is expanded by heating. In addition, polyvinyl chloride films are also already used as top layers has been glued to a polyurethane foam layer to form an elastic laminate.

Sohichtstoffa von Kunstledercharakter, die auf Polyvlnylchloridbasis hergestellt wurden, besitzen aber einen speckigen Griff und weJsen' trotz ihres Forengehaltes nur eine unbefriedigende Atmungsaktiv! tat auf, während Schichtstoffe auf Polyurethanbasis einen trockenen rauhen Griff besitzen und ausserdem der günstigen präge- und Schw«ia eigenschaft en des Polyvinylchloride entbehren.Synthetic leather-like sealants based on polyvinyl chloride were produced, but have a greasy handle and, despite their forum content, only have an unsatisfactory one Breathable! did on while polyurethane-based laminates have a dry, rough handle and also the cheap The embossing and black properties of the polyvinyl chloride are lacking.

Durch die vorliegende Erfindung werden nun die vorteilhaften Eigenschaften des Polyurethans in Schichtstoffen beibehalten und mit denjenigen des Polyvinylchlorids kombiniert, wobei in überraschender Weise die unangenehmen Eigenschaften beider Schichten weitgehend unterdrückt werden. Nach der vorliegendenThe present invention now maintains the advantageous properties of polyurethane in laminates and combined with those of polyvinyl chloride, surprisingly the unpleasant properties of both Layers are largely suppressed. According to the present

BAD 009843/1804 BATH 009843/1804

Anmeldung wird ein Schichtstoff dadurch erhalten, daß ein weitgehend durch Pressen verdichtetes Agglomerat aus Schaumßtoffteiichen, insbesondere aus Polyurethanschaumstoff abfall en, mit Haftklebstoff auf einer Gewebeunterlage befestigt und dann mit einer Deckschicht versehen wird, die anmeldungsgemäß aus ' einer Polyurethan-Polyvinylchloridmischung besteht.Application, a laminate is obtained in that a agglomerate of foam particles, largely compressed by pressing, especially waste from polyurethane foam, attached to a fabric backing with adhesive and then provided with a cover layer which, according to the application, consists of ' a polyurethane-polyvinyl chloride mixture.

Solche Mischungen können beispielsweise auf 1 Gewichtsteil Polyurethanharz 0,1 bis 1,0 Gewichtsteil gegebenenfalls weichgemachtes und stabilisiertes Polyvinylchlorid enthalten·Such mixtures can, for example, contain 0.1 to 1.0 part by weight of optionally plasticized per part by weight of polyurethane resin and contain stabilized polyvinyl chloride

Das die Mittelschicht bildende Agglomerat aus Schaumstoff-* . teilchen, kann beispielsweise wie folgt hergestellt werdent 80 Gewichtsteile Polyurethanschaumabfälle werden auf einer Messermühle bis zu einer Teilchengrösse von etwa 8-10 mm zerkleinert. Gegebenenfalls kann ein Teil der Polyurethansohaumabfälle durch Schaumgummi oder Polyvinylchloridschaum ersetzt werden. Dann werden 18 Gewichte teile eines Klebemittels aus 7 Gewichtsteilen Adipinsäureglykolester, 7 dewichtateilen Methylenchlorid und 4 Gewichtsteilen Soluylendiisocyanat vorbereitet und dieses Klebemittel auf einer Mischmaschine mit den Schaumstoff teilchen innig vermischt und die Mischung in Formen vergossen. Kach etwa 3-5 Minuten setzt unter leichter Temperaturerhöhung das Verschäumen des Polyurethanbindemittels ein. Nach Abklingen der Reaktion wird abkühlen gelassen und der platten- ) förmige Verbundstoff aus der Form entnommen. In der vorstehend beschriebenen Zusammensetzung des Klebemittels kann aber auch •in foil des Polyesters durch eine wässrig® Methyleellulose-Itisung ersetzt werden. Ein günstiges Verhältnis sind 40 Teile Polyester su 2 !«ilen einer 4 £-igea MethyleelluXosaldeung« Pie Hethyleellulose verbessert die Verteilung des klebemittel® und wirkt eich auch auf die mechanischen Eigenschaften, des hergestellten FonokörperB aus, da sie dem fertigen Gegenstand eine erhöhte Geschmeidigkeit verleiht.The agglomerate of foam * that forms the middle layer. particles, can be produced, for example, as follows: 80 parts by weight of polyurethane foam waste are comminuted on a knife mill to a particle size of about 8-10 mm. If necessary, some of the polyurethane foam waste can be replaced by foam rubber or polyvinyl chloride foam. Then 18 parts by weight of an adhesive made of 7 parts by weight of adipic acid glycol ester, 7 parts by weight of methylene chloride and 4 parts by weight of solvent diisocyanate are prepared and this adhesive is intimately mixed with the foam particles on a mixer and the mixture is poured into molds. After about 3-5 minutes, the foaming of the polyurethane binder starts with a slight increase in temperature. After the reaction is allowed to cool and taken out of the plate-like) shaped composite from the mold. In the above-described composition of the adhesive, however, the polyester can also be replaced by an aqueous® methylcellulose solution in foil. A favorable ratio is 40 parts of polyester su 2! «Ilen of a 4-pound methyleelluXosaldeung« Pie Hethyleellulose improves the distribution of the adhesive® and also has an effect on the mechanical properties of the manufactured FonobodyB, since it gives the finished object an increased suppleness .

Die so erhaltenen Schaumstoff platten «erden dann durch Pressen so weitgehend verdichtet, daß z.B.. deren Stärke von 1,5 cm auf 1 mm vermindert wird. Die Weiterverarbeitung kann nun so erfolgen, daß auf die eine Seite der Schäumstoffschicht einThe foam sheets obtained in this way are then grounded by pressing compacted to such an extent that, for example, their thickness is reduced from 1.5 cm to 1 mm. Further processing can now be done that on one side of the foam layer

009843/1804 BADORiGfNAL009843/1804 BADORiGfNAL

Gewebe, ζ· B. aus Jute oder Mollino, aufkaschiert und auf die andere Seite eine Siechung aus Polyurethan und Polyvinylchlorid aufgebracht wird« Vorteilhafterweiso wird jedoch eueret die Polyurethanpolyvinylchloriddeckschicht auf die gepreßte Platte aufgetragen und thermisch behandelt und erst dann die Gowebekaschierung vorgenommen.Fabric, e.g. made of jute or mollino, laminated on and on the other side is a seal made of polyurethane and polyvinyl chloride is applied «Advantageously, however, the polyurethane polyvinyl chloride top layer is used applied to the pressed plate and thermally treated and only then carried out the Gowebekaschierung.

Die Deckschicht wird anmeldungsgemHß dadurch hergestellt, daß eine Polyoletrcichmasoe gegebenenfalls unter Zusatz von Ltteungemitteln wie z. B* Äthylacetat mit einer in an sich bekannter Weise hergestellten PVC-Streichpasts vereetst und ßur Homogenisierung in einer Mischvorrichtung verarbeitet wird, worauf dann die für die Polyurethanbildung erforderlichen Polyisocyanate und BoBchleunigermengen eingebracht werden, worauf anechliecsend die erhaltene Mischung unter gleichzeitiger Verdampfung des Löeungaaiittelß zur Anvernetzung der Polyurethankomponente auf 50 - 120° C vorsugtweiee auf 60 - 80° 0, enechliaasend jedoch zur CeIi«rung dor PVC-Komponento auf Über 130° C erhitzt wird,According to the application, the cover layer is produced by that a Polyoletrcichmasoe optionally with the addition of Soldering agents such as B * ethyl acetate with an in itself PVC spreading paste produced in a known manner and admired ßur homogenization is processed in a mixing device, whereupon the necessary for the polyurethane formation Polyisocyanates and BoB accelerator quantities are introduced, whereupon anechliecsend the mixture obtained with simultaneous Evaporation of the solvent to cross-link the polyurethane component to 50 - 120 ° C, preventive to 60 - 80 ° 0, enechliaasend however, for the purpose of cutting the PVC component to over 130 ° C is heated,

Dieae Gelierung erfolgt vorzugsweise w'ährend 1-2 Minuten bei 140 - 150° C, dieselbe kann aber auch kursfrietig bei höheren Temperaturen erfolgen, sofern dadurch das Polyurethemharz nicht geschädigt wird· Der Bohmiechung werden Eolche Athylacetataengen zugesetzt, daß die gewünschte Viskosität eingestellt wird. Da eine gute Verteilung der PVC-Paste in der Polyurethanstreichisasse zu erreichen, wird die Mischung beispielsweise im einmaligen Durchgang in einem Einwalzenstuhl abgerieben·The gelling takes place preferably for 1-2 minutes at 140 - 150 ° C, but the same can also be used at higher temperatures take place, provided that this causes the polyurethane resin is not harmed · The bohemian smell are Eolche Athylacetataengen added that the desired viscosity is set. Since a good distribution of the PVC paste in To achieve the polyurethane paintsasse, the mixture will for example rubbed off in a single pass in a single roller mill

Die Aufbringung der Miechung auf die gepreöte Schaumplatte kann im Streichprozeß naturgen&Q nur in d»innen Schichten erfolgen, welohe aber s.B· bei 60 - Go° getrocknet bzw· anvernetzt werden mlissen, bevor die nächste Schicht aufgebracht wird, wobei dao PVO noch unvernetzt bleibt· Ea hat eich dabei gezeigt, daß die Polyurethan-PVC-Bößchichtung auch bei niehtausgeliorten PVC schon nach der ersten Temperaturbehandlung soweit getrocknet ist, daß die beschichtete Bahn nicht mehr klebt. FUr die Gelierung der PVC-Fbmponcnte ist a-n Ende der gesamten Beschichtung eine einmalige ffcrtpcraturbehandlung beispielsweiseThe application of the Miechung to the pre-squeezed foam sheet can in the coating process naturally & Q only take place in the inner layers, which, however, are dried or crosslinked at 60 - Go ° mlissen before the next layer is applied, whereby dao PVO still remains unlinked · Ea has shown that the Polyurethane-PVC lining even with non-exposed PVC Already dried after the first temperature treatment is that the coated web is no longer sticky. For the Gelation of the PVC component is at the end of the entire coating a one-off temperature treatment, for example

009843/1804 BAD 0BielNAu009843/1804 BAD 0BielNA u

in einem einzigen Kanaldurchgang ausreichend.sufficient in a single canal pass.

Zur besseren Haftung der Deckschicht wird vorteilhafterweise zuerst ein Grundstrich und dann der eigentliche Deckstrich aufgebracht, welche Schichten z. B. nachstehende Zusammensetzung besitzen können: PVC-Paste: For better adhesion of the top layer, it is advantageous to first apply a base coat and then the actual top coat. B. may have the following composition: PVC paste:

Emulsions/PVC, K-Wert 40Emulsions / PVC, K value 40 Polyester, isooyanatverlängertPolyester, isocyanate-extended ,000,—, 000, - 100,—100.00 DioctylphthalatDioctyl phthalate 35 ?i-ige Lösung in Äthylaeetat . 1,35% solution in ethyl acetate. 1, 287,25287.25 90,—90.00 PVC-Paet·PVC package 250,—250.00 1,51.5 ÄthylaoetatEthyl acetate —- 191,5191.5 Ba-Cd-Laurat (Stabilisator)Ba-Cd-Laurate (stabilizer) Pigmentpigment PolyisocyanatPolyisocyanate 58,-58.00 75 #-ige lösung in Äthylacetat75 # solution in ethyl acetate GrundstrichtBasic line Amin-BesohleunigerAmine accelerator (10 $S-ige Lösung in Äthylaoetat +(10 $ S solution in ethyl acetate + 58,-58.00 DeckstrichtCover stroke + Äthylenchlorid »+ Ethylene chloride » 1.000,—1,000.00 287,25287.25 400,—400.00 50,—50.00 58,—58.00 58,—58.00

1.653,25 1.853,251,653.25 1,853.25

Sowohl beim Gnmdstrich ale auch beim Deckstrich werden erst knapp vor Gebrauch zuerst der Beschleuniger und dann das Isooyanat gut in die Streichmasse eingerührt. Durch den Zusatz von Stabilisatoren, wie Bariura-Kadmiumlaurat in Mengen von 0,3 - 3 i»t vorssugew·!·· von 1 - 1,5 ^ zur PVC-Paste, wird 'die letehaffenheit der Deckschicht weitgehend verbessert. Anmeldungsgemäß ist ·ε auch möglich, bis zu 100 Teile Weichmacher auf 100 !eile Polyvinylchlorid in das Polyurethanharsi einzubringen. Der Vorteil gegenüber einem nichtweichgemachten PVC-Zusatz liegt daher dabei darin, daß abgesehen von der Billigkeit das Polyvinylchlorid besser verteilt wird und völlig ausgelieren kann.Both in the case of the top coat and the top coat, first the accelerator and then the isocyanate are thoroughly stirred into the coating material just before use. The addition of stabilizers such as Bariura-Kadmiumlaurat in amounts of 0.3 - for PVC paste, is' the letehaffenheit the top layer largely improved 1.5 ^ - 3 i "t vorssugew · · · of the first According to the application, it is also possible to incorporate up to 100 parts of plasticizer per 100 parts of polyvinyl chloride into the polyurethane resin. The advantage over a non-plasticized PVC additive is that, apart from being inexpensive, the polyvinyl chloride is better distributed and can completely melt out.

BAD QRIG/NAL· 009843/1804BAD QRIG / NAL 009843/1804

Statt flor Polyvinylchloridpaste kann aber auch pulverförmiges oder tveichgenachtes, vorzugsweise niedrig gelierendes PVC (damit das Polyurethan nicht au lange Zelt !Temperaturen über 160° C ausgesetzt werden muß, in eine thermoplastische Polyurethaninasse eingearbeitet und .auf Kalandern au entsprechenden Bahnen gesogen v/erden, welche dann auf den gepreßten Schaumkern aufgeklebt werden, Schichtstoffe mit I3VC-fcältigen Polyurethandeckschichten sind gegenüber Schichtstoffen mit PVG-f reieia Deckschichten weicher und angenehmer im Griff, während der PVC-Zußatß bei der Finishgebung die Lackierung erleichtert, da verschiedene lacktypen wie 2.B* Acryllacke, die auf reinem Polyurethan nicht haften, durch den PVC-Zucatz in der !Deckschicht hinreichend verankert werden. PVC-hältigo Polyurethandeckschichten lassen sich aiisaerdem besser mit einer Oberflächenprügung durch .Vorheizen der Oberfläche und Durchgang durch eine Prägewalze versehen, als diea mit Deckschichten aus reinem Polyurethanharss möglichInstead of polyvinyl chloride paste, however, powdery or plasticized, preferably low-gelling PVC (so that the polyurethane does not have to be exposed to temperatures above 160 ° C for long periods of time) can be incorporated into a thermoplastic polyurethane paste and then sucked onto appropriate webs on calenders, which then glued onto the pressed foam core, laminates with I 3 VC-colored polyurethane top layers are softer and more pleasant to the touch compared to laminates with PVG-free top layers, while the addition of PVC makes painting easier during the finishing process, as different types of paint such as 2.B * Acrylic lacquers that do not adhere to pure polyurethane are adequately anchored in the top layer by the PVC-Zucatz. PVC-resistant polyurethane top layers can also be better with a surface test by preheating the surface and passing through an embossing roller than the top layers made of pure polyurethane harss possible

- Patentansprüche -- patent claims -

BAD ORIGINAL 009843/1804 BATH ORIGINAL 009843/1804

Claims (1)

SchichtStoffe aus einer Gewebeunterlage, einer Kunntstoffschaumswiechenschicht und einer homogenen Kirnststoff deckschicht, dadurch gekennzeichnet, daß die Zwischen« schicht aus einem durch Pressen verdichtetem Agglomerat aus zerkleinerten Schaumstoffen, insbesondere aus Poly» urethaaschaumstoffabfällen allein oder mit anderen Schaum· stoff en gemischt besteht, «führend Als Deckschicht eine Polyurethatt-FolyvinylchloridmlBohung dient·Laminates made of a fabric backing, a plastic foam layer and a homogeneous plastic cover layer, characterized in that the intermediate layer made of an agglomerate of crushed foams, especially made of poly » uretha foam waste alone or with other foam mixed materials, "leading The top layer is a polyurethane-polyvinyl chloride perforation. 2«. Schichtstoffe nach Anspruch 1, dadurch gekennzeichnet, daß die Deckschicht aus einer Mischung von vernetz tem Poly« urethanharz mit gelierten Polyvinylchlorid besteht, welche auf 1 Oewiohtstoil Polyurethanhars 0,1 bis 1,0 Gewichts teile gegebenenfalls weichgemachtea Polyvinylchlorid enthält«2 «. Laminates according to claim 1, characterized in that the top layer made of a mixture of cross-linked poly « urethane resin with gelled polyvinyl chloride, which on 1 Oewiohtstoil Polyurethanhars 0.1 to 1.0 parts by weight possibly plasticizeda contains polyvinyl chloride " 3» Verfahren zur Herstellung eines Schichtstoffea nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß in eine thermoplastische Polyurethanmasse pulverförmiges oder weichgemachtes Polyvinylchlorid eingearbeitet, daß die Kasse beispielsweise aa Kalander zu Secksohichtbahnen ausgezogen auf über 130° C erhitzt und dann mit der Zwischenschicht verbunden wird.3 »A method for producing a laminate according to claim 1 or 2, characterized in that powdered or plasticized polyvinyl chloride is incorporated into a thermoplastic polyurethane mass that the cash register, for example, aa Calender stretched into secko sheets to over 130 ° C heated and then bonded to the intermediate layer. DEUTSCHE ^EMPERLt GUMMIVSRK GES.M.jp.HGERMAN ^ EMPERLt GUMMIVSRK GES.M.jp.H BAD·BATH· 009843/1804009843/1804
DE19691919185 1968-05-30 1969-04-16 Laminates and processes for their manufacture Pending DE1919185A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE19691919185 DE1919185A1 (en) 1968-05-30 1969-04-16 Laminates and processes for their manufacture
NL6906665A NL6906665A (en) 1968-05-30 1969-05-01
SE07594/69*A SE368238B (en) 1968-05-30 1969-05-29
GB2713569A GB1208544A (en) 1968-05-30 1969-05-29 Improvements in or relating to laminated materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT518468A AT284057B (en) 1968-05-30 1968-05-30 Laminate and method of making the same
DE19691919185 DE1919185A1 (en) 1968-05-30 1969-04-16 Laminates and processes for their manufacture

Publications (1)

Publication Number Publication Date
DE1919185A1 true DE1919185A1 (en) 1970-10-22

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DE19691919185 Pending DE1919185A1 (en) 1968-05-30 1969-04-16 Laminates and processes for their manufacture

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DE (1) DE1919185A1 (en)
GB (1) GB1208544A (en)
NL (1) NL6906665A (en)
SE (1) SE368238B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT401908B (en) * 1993-11-29 1996-12-27 Greiner & Soehne C A MULTI-LAYERED COMPONENT AND METHOD AND DEVICE FOR ITS PRODUCTION
AT401932B (en) * 1993-11-29 1996-12-27 Greiner & Soehne C A Moulding made from plastic foam, in particular flexible plastic foam, and process and apparatus for producing this moulding

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2116572B (en) * 1982-03-05 1985-10-30 Kun Huang Chang High density flexible polyurethane foam
ITPG20100038A1 (en) * 2010-06-14 2011-12-15 Noonk S R L MULTIPLE LAYER PRODUCT DERIVED FROM THE RECOVERY AND COMPACTION OF LEATHER SCROLLS OR FABRIC ROLLS
CN109383104A (en) * 2018-09-03 2019-02-26 李永平 A kind of super film processing method of lamination coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT401908B (en) * 1993-11-29 1996-12-27 Greiner & Soehne C A MULTI-LAYERED COMPONENT AND METHOD AND DEVICE FOR ITS PRODUCTION
AT401932B (en) * 1993-11-29 1996-12-27 Greiner & Soehne C A Moulding made from plastic foam, in particular flexible plastic foam, and process and apparatus for producing this moulding

Also Published As

Publication number Publication date
GB1208544A (en) 1970-10-14
NL6906665A (en) 1969-12-02
SE368238B (en) 1974-06-24

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