DE1668837C - - Google Patents
Info
- Publication number
- DE1668837C DE1668837C DE19671668837 DE1668837A DE1668837C DE 1668837 C DE1668837 C DE 1668837C DE 19671668837 DE19671668837 DE 19671668837 DE 1668837 A DE1668837 A DE 1668837A DE 1668837 C DE1668837 C DE 1668837C
- Authority
- DE
- Germany
- Prior art keywords
- dinitrile
- oxygen
- adipic
- temperature
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BTGRAWJCKBQKAO-UHFFFAOYSA-N Adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 claims description 13
- 239000003054 catalyst Substances 0.000 claims description 12
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 238000009835 boiling Methods 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N Adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- DVARTQFDIMZBAA-UHFFFAOYSA-O Ammonium nitrate Chemical compound [NH4+].[O-][N+]([O-])=O DVARTQFDIMZBAA-UHFFFAOYSA-O 0.000 claims description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N Copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 3
- BGTOWKSIORTVQH-UHFFFAOYSA-N Cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 claims description 3
- 230000002378 acidificating Effects 0.000 claims description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 3
- 150000002466 imines Chemical class 0.000 claims description 3
- 230000001264 neutralization Effects 0.000 claims description 3
- -1 nitrate anion Chemical class 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- UXJVWJGDHIZPLD-UHFFFAOYSA-O Ammonium vanadate Chemical compound [NH4+].O=[V-](=O)=O UXJVWJGDHIZPLD-UHFFFAOYSA-O 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 239000006227 byproduct Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000004821 distillation Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 5
- 238000000034 method Methods 0.000 claims 5
- 150000003839 salts Chemical class 0.000 claims 5
- 239000011780 sodium chloride Substances 0.000 claims 5
- VZJVWSHVAAUDKD-UHFFFAOYSA-N Potassium permanganate Chemical compound [K+].[O-][Mn](=O)(=O)=O VZJVWSHVAAUDKD-UHFFFAOYSA-N 0.000 claims 4
- 239000000126 substance Substances 0.000 claims 3
- 239000003153 chemical reaction reagent Substances 0.000 claims 2
- 230000000694 effects Effects 0.000 claims 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 2
- 229910001385 heavy metal Inorganic materials 0.000 claims 2
- 230000002452 interceptive Effects 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 150000002823 nitrates Chemical class 0.000 claims 2
- 150000002825 nitriles Chemical class 0.000 claims 2
- 238000007363 ring formation reaction Methods 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M bisulfite Chemical class OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000011109 contamination Methods 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 230000000875 corresponding Effects 0.000 claims 1
- 239000012043 crude product Substances 0.000 claims 1
- 150000003997 cyclic ketones Chemical class 0.000 claims 1
- 230000009089 cytolysis Effects 0.000 claims 1
- 230000002349 favourable Effects 0.000 claims 1
- 238000005755 formation reaction Methods 0.000 claims 1
- 238000005194 fractionation Methods 0.000 claims 1
- 238000003958 fumigation Methods 0.000 claims 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 claims 1
- 230000002934 lysing Effects 0.000 claims 1
- LBSANEJBGMCTBH-UHFFFAOYSA-N manganate Chemical compound [O-][Mn]([O-])(=O)=O LBSANEJBGMCTBH-UHFFFAOYSA-N 0.000 claims 1
- BDRTVPCFKSUHCJ-UHFFFAOYSA-N molecular hydrogen;potassium Chemical compound [K].[H][H] BDRTVPCFKSUHCJ-UHFFFAOYSA-N 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- 230000001590 oxidative Effects 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- AFVLVVWMAFSXCK-VMPITWQZSA-N α-cyano-4-hydroxycinnamic acid Chemical group OC(=O)C(\C#N)=C\C1=CC=C(O)C=C1 AFVLVVWMAFSXCK-VMPITWQZSA-N 0.000 claims 1
- NPDODHDPVPPRDJ-UHFFFAOYSA-N permanganate Chemical compound [O-][Mn](=O)(=O)=O NPDODHDPVPPRDJ-UHFFFAOYSA-N 0.000 description 4
- JFCQEDHGNNZCLN-UHFFFAOYSA-N Glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- IPMQSLPLJDKUPI-UHFFFAOYSA-N 2-oxocyclopentane-1-carbonitrile Chemical compound O=C1CCCC1C#N IPMQSLPLJDKUPI-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
von weniger als 250 ppm an Ringverbind';ngen zu reinigen.to clean of less than 250 ppm of ring connections.
Eine weitere Verkürzung der Reaktionszeit kann durch Zusatz von organischen Mono- und/oder Dicarbonsäuren erzielt werden. In der Praxis hat sich das bei der Oxydation von Cyclohexan mit Salpetersäure zu Adipinsäure verwendeteSystem Kupfernitrat— Ammoniumvanadat—Eisen, das zusammen mit Oxal-, Bernstein- und Glutarsäure als Rückstand anfällt, sehr bewährt.The reaction time can be shortened further by adding organic mono- and / or dicarboxylic acids be achieved. In practice, this has been the case with the oxidation of cyclohexane with nitric acid system used for adipic acid copper nitrate - ammonium vanadate - iron, which together with oxalic, Succinic and glutaric acid accumulates as residue, very reliable.
Die Dauer der Oxydation wird dadurch auf ungefähr 1 y2 Stunden verkürzt.The duration of the oxidation is thereby shortened to about 1 and 2 hours.
Schließlich kann eine noch weitergehende Reduktion der Zeitdauer und Temperatur dadurch erreicht werden, daß man die oben beschriebenen Oxydationen unter Druck ausführt, zweckmäßigerweise bei 100 bis 1700C und einem Druck von 2 bis 25 atü. In dieser Form verläuft die Oxydation der Nebenprodukte so rapid, daß auf zusätzliche Erwärmung verzichtet werden kann und außerdem eine kontinuierliche Arbeitsweise auch bei großen Durchsätzen möglich ist.Finally, an even further reduction in time and temperature can be achieved by carrying out the above-described oxidations under pressure, expediently at 100 to 170 ° C. and a pressure of 2 to 25 atmospheres. In this form, the oxidation of the by-products proceeds so rapidly that additional heating can be dispensed with and, moreover, continuous operation is possible even with large throughputs.
Als Sauerstoff enthaltendes Gas wird zweckmäßigerweise Luft verwendet. Reiner Sauerstoff kann ebenfalls eingesetzt werden, sollte aber zur besseren Ausnutzung im Kreislauf zurückgeführt werden, wobei eine Reaktionstemperatur von 180° aus Sicherheitsgründen nicht Überschritten werden soll.Air is expediently used as the oxygen-containing gas. Pure oxygen can also are used, but should be recycled for better utilization, with a reaction temperature 180 ° should not be exceeded for safety reasons.
Alle oben beschriebenen Oxydationen mit Sauerstoff enthaltenden Gasen werden zweckmäßigerweise apparativ so ausgeführt, daß der am Gasaustritt liegende Wärmeaustauscher bei einer Temperatur gehalten wird, der das hochsiedende (3OO°/76O mm Hg) Adipinsäuredinitril kondensiert, jedoch andere leichter siedende Verunreinigungen, wie beispielsweise das ebenfalls ständig vorhandene Cyclopentanon, durch den Gasstrom entfernt.All of the above-described oxidations with oxygen-containing gases are expediently apparatus-based designed so that the heat exchanger located at the gas outlet is kept at one temperature which is the high-boiling (3OO ° / 76O mm Hg) adipic acid dinitrile condensed, but other lower-boiling impurities such as that as well always present cyclopentanone, removed by the gas stream.
Die auf die oben beschriebenen Weisen erhaltenen Produkte besitzen einen geringen Permanganatverbrauch, daß sie zur Erzielung höchster Reinheit — unter 10 ppm «-Cyancyclopentanylimin- bzw. «-Cyancyclopentanongehalt — entweder als solche, besser aber nach Abtrennung der schwersiedenden teerartigen Verunreinigungen auf ökonomische Weise beispielsweise einer Nachreinigung durch Permanganat-Oxydation unterworfen werden können. Eine derartige Endreinigung durch Permanganat ist übrigens dadurch erleichtert, daß das ursprünglich vorhandene «-Cyancyclopentanylimin nicht nur weitgehend zerstört ist, sondern auch der verbleibende Restgehalt an Imin zu 70 bis 75% durch Hydrolyse in a-Cyancyclopentanon übergegangen ist, das schon durch neutrales Permanganat oxydiert wird, während o-Cyancylopentanylimin sauer ίο oxydiert werden muß.The products obtained in the ways described above have a low consumption of permanganate, that they to achieve the highest purity - below 10 ppm "-Cyancyclopentanylimin- or" -Cyancyclopentanonealtehalt - Either as such, but better after the high-boiling tar-like impurities have been separated off in an economical way, for example post-cleaning by means of permanganate oxidation can be subjected. This kind of final cleaning with permanganate is made easier by that the originally present "-Cyancyclopentanylimin is not only largely destroyed, but 70 to 75% of the remaining imine content was also converted into α-cyanocyclopentanone by hydrolysis is that is already oxidized by neutral permanganate, while o-Cyancylopentanylimin acidic ίο must be oxidized.
1. 1 kg rohes Adipinsäuredinitril mit einem Gehalt an 1,8% Cyancyciopentanylimin, 2,2% Cyclopentanon, 0,2% Wasser und 5,1 % höhersiedender Verunreinigungen werden bei 170° mittels eines Intensivrührers mit einem auf 150° vorgewärmten Luftstrom von 5001 pro Stunde in einer Höhe von 68 cm begast. Der Gehalt an Cyancyclopentanyl-1. 1 kg of crude adipic dinitrile with a content of 1.8% cyancyciopentanylimine, 2.2% cyclopentanone, 0.2% water and 5.1% higher-boiling impurities are at 170 ° by means of a Intensive stirrer with an air stream preheated to 150 ° of 5001 per hour at a height of 68 cm fumigated. The content of cyancyclopentanyl
ao imin beträgt nach 1 Stunde 1,65%, nach 3 Stunden 1,24%, nach 6 Stunden 0,49% und nach 8 Stunden 0,058%. Das braunschwarze Material ergibt nach Destillation über Kopf 872 g reines Dinitril. Der Rückstand wiegt 143 g.ao imine is 1.65% after 1 hour, 1.24% after 3 hours, 0.49% after 6 hours and after 8 hours 0.058%. The brown-black material yields 872 g of pure overhead after distillation Dinitrile. The residue weighs 143 g.
2. 1 kg Adipinsäuredinitril derselben Zusammensetzung wie im Beispiel I wird mit 0,1 g Kupfernitrat,
0,03 g Ammoniumvanadat und 2 g Ammoniumnitrat bei 120° mit 100 1 Luft wie im Beispiel
1 begast. Nach 4 Stunden wird das schwarze Reaktionsprodukt destilliert. Man erhält 881 g
Dinitril mit einem Cyancylopentanon-Gc-halt von
weniger als 100 ppm (0,01 %) neben 140 g Rückstand.
3. 1 kg Adipinsäuredinitril der Zusammensetzung wie im Beispiel 1 und 2 wird mit 35 g eines Katalysatorgemisches
versetzt, das als Mutterlaugen-Rückstand bei der Fabrikation der Adipinsäure anfällt. Das Katalysatorsystem enthält neben den
Dicarbonsäuren mindestens 0,6% Kupfernitrat.2. 1 kg of adipic dinitrile of the same composition as in Example I is gassed with 0.1 g of copper nitrate, 0.03 g of ammonium vanadate and 2 g of ammonium nitrate at 120 ° with 100 liters of air as in Example 1. After 4 hours the black reaction product is distilled. 881 g of dinitrile are obtained with a cyanocyclopentanone Gc content of less than 100 ppm (0.01%) in addition to 140 g of residue.
3. 1 kg of adipic dinitrile of the composition as in Examples 1 and 2 is mixed with 35 g of a catalyst mixture which is obtained as a mother liquor residue in the manufacture of the adipic acid. In addition to the dicarboxylic acids, the catalyst system contains at least 0.6% copper nitrate.
Die Begasung mit Luft erfolgt wie im Beispiel 2. Nach 1 Yz Stunden wird das Gemisch destilliert. Man erhält 876 g Dinitril mit einem «-Cyancyclopentanon-Gehalt von 70 ppm.The gassing with air is carried out as in Example 2. After 1 1/2 hours, the mixture is distilled. 876 g of dinitrile are obtained with a «-cyanocyclopentanone content of 70 ppm.
Claims (4)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEV0035098 | 1967-12-23 | ||
DEV0035098 | 1967-12-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE1668837A1 DE1668837A1 (en) | 1971-12-23 |
DE1668837C true DE1668837C (en) | 1973-04-19 |
Family
ID=7589433
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19671668837 Granted DE1668837A1 (en) | 1967-12-23 | 1967-12-23 | Process for the purification of Adipinsaeuredinitril |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE1668837A1 (en) |
-
1967
- 1967-12-23 DE DE19671668837 patent/DE1668837A1/en active Granted
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