DE112011102534A5 - Polymers comprising substituted benzodithiophene units, blends containing these polymers and devices containing these polymers or blends - Google Patents

Polymers comprising substituted benzodithiophene units, blends containing these polymers and devices containing these polymers or blends Download PDF

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Publication number
DE112011102534A5
DE112011102534A5 DE112011102534T DE112011102534T DE112011102534A5 DE 112011102534 A5 DE112011102534 A5 DE 112011102534A5 DE 112011102534 T DE112011102534 T DE 112011102534T DE 112011102534 T DE112011102534 T DE 112011102534T DE 112011102534 A5 DE112011102534 A5 DE 112011102534A5
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Prior art keywords
polymers
blends
benzodithiophene units
substituted
devices
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DE112011102534T
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German (de)
Inventor
Rémi Manouk Anémian
Aurélie Ludemann
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Raynergy Tek Inc
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Merck Patent GmbH
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Publication of DE112011102534A5 publication Critical patent/DE112011102534A5/en
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    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C—CHEMISTRY; METALLURGY
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    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/06—Polythioethers from cyclic thioethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/12—Light sources with substantially two-dimensional radiating surfaces
    • H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
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    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
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    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
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    • C08G2261/124—Copolymers alternating
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    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/148—Side-chains having aromatic units
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    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
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    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/31—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
    • C08G2261/314—Condensed aromatic systems, e.g. perylene, anthracene or pyrene
    • C08G2261/3142—Condensed aromatic systems, e.g. perylene, anthracene or pyrene fluorene-based, e.g. fluorene, indenofluorene, or spirobifluorene
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    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/31—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
    • C08G2261/316—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain bridged by heteroatoms, e.g. N, P, Si or B
    • C08G2261/3162—Arylamines
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    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
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    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3241—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more nitrogen atoms as the only heteroatom, e.g. carbazole
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    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3243—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more sulfur atoms as the only heteroatom, e.g. benzothiophene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/34—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain
    • C08G2261/342—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3422—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms conjugated, e.g. PPV-type
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    • C08G2261/50—Physical properties
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    • H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
    • H10K10/462—Insulated gate field-effect transistors [IGFETs]
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DE112011102534T 2010-07-29 2011-07-19 Polymers comprising substituted benzodithiophene units, blends containing these polymers and devices containing these polymers or blends Pending DE112011102534A5 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102010032737A DE102010032737A1 (en) 2010-07-29 2010-07-29 Polymers containing substituted benzodithiophene units, blends containing these polymers and devices containing these polymers or blends
DE102010032737.9 2010-07-29
PCT/EP2011/003594 WO2012013310A1 (en) 2010-07-29 2011-07-19 Polymers containing substituted benzodithiophene units, blends containing said polymers, and devices containing said polymers or blends

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DE112011102534A5 true DE112011102534A5 (en) 2013-05-02

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DE112011102534T Pending DE112011102534A5 (en) 2010-07-29 2011-07-19 Polymers comprising substituted benzodithiophene units, blends containing these polymers and devices containing these polymers or blends

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US (1) US9394406B2 (en)
JP (1) JP5866355B2 (en)
DE (2) DE102010032737A1 (en)
WO (1) WO2012013310A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20140129080A (en) * 2012-02-03 2014-11-06 더 유니버시티 오브 시카고 Semiconducting polymers
JP2013159724A (en) * 2012-02-07 2013-08-19 Sumitomo Chemical Co Ltd Polymer compound and electronic element using the polymer compound
DE102013206586A1 (en) * 2013-04-12 2014-10-16 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Semiconducting copolymer and process for its preparation, mixture, electrical or electronic component and process for its preparation
CN104672434B (en) * 2015-01-27 2017-11-07 华南理工大学 A kind of organic semiconducting materials and preparation method and application
CN104945602B (en) * 2015-05-14 2017-06-20 华南理工大学 The crosslinkable composition of conjugated polymer material, click chemistry containing alkenyl/alkynyl functionality
US11690283B2 (en) 2021-11-19 2023-06-27 Phillips 66 Company Fused dithieno benzothiadiazole polymers for organic photovoltaics
US11332579B1 (en) 2021-11-19 2022-05-17 Phillips 66 Company Fused dithieno benzothiadiazole polymers for organic photovoltaics
US11849629B2 (en) 2021-11-19 2023-12-19 Phillips 66 Company Fused dithieno benzothiadiazole polymers for organic photovolatics
US11326019B1 (en) 2021-11-19 2022-05-10 Phillips 66 Company Fused dithieno benzothiadiazole polymers for organic photovoltaics

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8909011D0 (en) 1989-04-20 1989-06-07 Friend Richard H Electroluminescent devices
DE10109027A1 (en) 2001-02-24 2002-09-05 Covion Organic Semiconductors Rhodium and iridium complexes
JP4438042B2 (en) 2001-03-08 2010-03-24 キヤノン株式会社 Metal coordination compound, electroluminescent element and display device
KR100939468B1 (en) 2001-03-10 2010-01-29 메르크 파텐트 게엠베하 Solutions and dispersions of organic semiconductors
WO2002077060A1 (en) 2001-03-24 2002-10-03 Covion Organic Semiconductors Gmbh Conjugated polymers containing spirobifluorene units and fluorene units, and the use thereof
DE10116962A1 (en) 2001-04-05 2002-10-10 Covion Organic Semiconductors Rhodium and iridium complexes
DE10141624A1 (en) 2001-08-24 2003-03-06 Covion Organic Semiconductors Solutions of polymeric semiconductors
DE10159946A1 (en) 2001-12-06 2003-06-18 Covion Organic Semiconductors Process for the production of aryl-aryl coupled compounds
DE10238903A1 (en) 2002-08-24 2004-03-04 Covion Organic Semiconductors Gmbh New heteroaromatic rhodium and iridium complexes, useful in electroluminescent and/or phosphorescent devices as the emission layer and for use in solar cells, photovoltaic devices and organic photodetectors
DE10249723A1 (en) 2002-10-25 2004-05-06 Covion Organic Semiconductors Gmbh Conjugated polymers containing arylamine units, their preparation and use
DE10304819A1 (en) 2003-02-06 2004-08-19 Covion Organic Semiconductors Gmbh Carbazole-containing conjugated polymers and blends, their preparation and use
DE10328627A1 (en) 2003-06-26 2005-02-17 Covion Organic Semiconductors Gmbh New materials for electroluminescence
DE10333232A1 (en) 2003-07-21 2007-10-11 Merck Patent Gmbh Organic electroluminescent element
DE10337346A1 (en) 2003-08-12 2005-03-31 Covion Organic Semiconductors Gmbh Conjugated polymers containing dihydrophenanthrene units and their use
DE602004024629D1 (en) * 2003-10-15 2010-01-28 Merck Patent Gmbh Polybenzodithiophene
EP1675930B1 (en) 2003-10-22 2018-05-30 Merck Patent GmbH New materials for electroluminescence and the utilization thereof
DE10350606A1 (en) 2003-10-30 2005-06-09 Covion Organic Semiconductors Gmbh Process for the preparation of heteroleptic, ortho-metallated organometallic compounds
CN101490862B (en) * 2006-07-25 2013-03-13 默克专利有限公司 Polymer blends and their use in organic light emitting devices
US7834132B2 (en) * 2006-10-25 2010-11-16 Xerox Corporation Electronic devices
US7820782B2 (en) * 2006-10-25 2010-10-26 Xerox Corporation Poly(dithienylbenzo[1,2-b:4,5-b′]dithiophene) polymers
CA2606985C (en) * 2006-10-25 2011-02-01 Xerox Corporation Electronic devices
US8115200B2 (en) * 2007-12-13 2012-02-14 E.I. Du Pont De Nemours And Company Electroactive materials
US20090242878A1 (en) * 2008-03-27 2009-10-01 Xerox Corporation Optimization of new polymer semiconductors for better mobility and processibality
BRPI0915969B1 (en) * 2008-07-18 2019-08-13 Univ Chicago semiconductor polymers, conjugates, their uses and photovoltaic layers comprising the same
DE102008049037A1 (en) * 2008-09-25 2010-04-22 Merck Patent Gmbh New polymers with low polydispersity
US8367798B2 (en) 2008-09-29 2013-02-05 The Regents Of The University Of California Active materials for photoelectric devices and devices that use the materials
US20100121004A1 (en) * 2008-11-13 2010-05-13 Xerox Corporation Purification process for semiconducting monomers
US7956199B2 (en) * 2009-10-08 2011-06-07 Xerox Corporation Methods for preparing benzodithiophenes
CN102844312B (en) * 2010-04-19 2015-04-15 默克专利股份有限公司 Polymers of benzodithiophene and their use as organic semiconductors

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