DE109496C - - Google Patents
Info
- Publication number
- DE109496C DE109496C DENDAT109496D DE109496DA DE109496C DE 109496 C DE109496 C DE 109496C DE NDAT109496 D DENDAT109496 D DE NDAT109496D DE 109496D A DE109496D A DE 109496DA DE 109496 C DE109496 C DE 109496C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- gold
- glaze
- goods
- melted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052737 gold Inorganic materials 0.000 claims description 16
- 239000010931 gold Substances 0.000 claims description 16
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 5
- 230000004907 flux Effects 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 2
- 238000005498 polishing Methods 0.000 claims description 2
- 239000005308 flint glass Substances 0.000 claims 2
- 239000004328 sodium tetraborate Substances 0.000 claims 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N Calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims 1
- 235000010333 potassium nitrate Nutrition 0.000 claims 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 235000012431 wafers Nutrition 0.000 claims 1
- 238000010304 firing Methods 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- FDWREHZXQUYJFJ-UHFFFAOYSA-M Gold(I) chloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- WMWLMWRWZQELOS-UHFFFAOYSA-N Bismuth(III) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 210000001138 Tears Anatomy 0.000 description 1
- 229940036248 Turpentine Drugs 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002343 gold Chemical class 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000001184 potassium carbonate Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3605—Coatings of the type glass/metal/inorganic compound
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3684—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used for decoration purposes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Adornments (AREA)
Description
PATENTAMT.PATENT OFFICE.
Man hat bereits versucht, Gold unter Glasur anzubringen (vgl. Jae.n nicke, Porcellanmalerei, 1891, S, 239), doch sind bestimmte Angaben über die Art der Ausführung nicht bekannt geworden, so dafs die Technik der Porcellanmalerei aus den sporadisch erschienenen Andeutungen allein eine Vervollkommnung in dieser Richtung nicht hat erfahren können.Attempts have already been made to apply gold under glaze (see Jae.n nicke, Porcellanmalerei, 1891, p, 239), but certain details about the type of execution are not known so that the technique of porcelain painting has emerged from the sporadic hints but could not experience a perfection in this direction.
Die vorliegende Erfindung betrifft ein Verfahren zum Vergolden keramischer Erzeugnisse, bei welchem ein bestimmtes Goldpräparat auf die fertige Waafe aufgetragen, gebrannt und mit einer Glasur bei einer etwas niedrigeren Temperatur als der Aufbrenntemperatur überfangen wird. Dafs die Vergoldung auf der fertigen Waare stattfinden kann, ist von ebenso erheblicher gewerblicher Bedeutung, wie die Eigenschaft der fertigen vergoldeten Waare gegen Abnutzung der Vergoldung gesichert zu sein, was man von den bislang erzeugten, goldig verzierten Porcellanwaaren nicht behaupten kann.The present invention relates to a method for gilding ceramic products, in which a certain gold preparation is applied to the finished waafe, fired and with a glaze at a slightly lower temperature than the firing temperature is overextended. That the gilding can take place on the finished goods is of just as significant commercial importance as the quality of the finished gold-plated goods to be secured against wear and tear of the gold plating, which is what can be seen from the previously produced, gold decorated porcelain ware cannot claim.
Zur Ausführung des Verfahrens benutzt man eine GoldflUssigkeit, welche in bekannter Weise dadurch erzeugt ist, dafs man einen Theil von mit Quecksilber gefälltem Golde und einen Theil von mit Kaliumcarbonat und Oxalsäure gefälltem Golde innig vermengt und zu je 16 Gewichtstheilen davon einen Gewichtstheil Wismuthoxyd als Flufsmittel zusetzt und dieses Gemenge mit Terpentinöl in geeignetem Verhältnifs versetzt, um eine für das Malen von Hand geeignete Flüssigkeit zu erzielen. Diese Goldflüssigkeit wird vorzugsweise auf dem Wege der Handmalerei auf die fertige (d. h. glasirte und gebrannte) Waare aufgetragen und einer Temperatur von etwa 800 ° C. ausgesetzt.To carry out the process one uses a gold liquid, which is known in Is produced by using a portion of gold precipitated with mercury and a portion of gold precipitated with potassium carbonate and oxalic acid intimately mixed and one part by weight of bismuth oxide is added to each 16 parts by weight as a flux and this mixture is mixed with oil of turpentine in a suitable proportion to make one for painting by hand to achieve suitable fluid. This gold liquid is preferred by hand painting on the finished (i.e. glazed and fired) goods applied and exposed to a temperature of about 800 ° C.
Nach dem Brennen wird die vergoldete Oberfläche der Waare polirt, glatt und gleichmäfsig gemacht. Sodann werden die Vergoldungen mit Grundiröl überpinselt, und auf dieses wird gepulverte Glasur gestreut. Die Waare wird sodann abermals gebrannt, und zwar bei einer Temperatur, welche etwas niedriger ist,' als die beim vorangegangenen Einbrennen des Goldes benutzte. Das Verfahren ist dann beendigt, und die Goldoberfläche ist glatt und vor Abnutzung durch Reibung geschützt.After firing, the gold-plated surface of the goods is polished, smooth and even made. The gilding is then brushed over with primer oil, and powdered glaze is sprinkled on top of it. the The goods are then fired again, at a temperature that is somewhat is lower than that used in the previous burn-in of the gold. The procedure is then terminated, and the gold surface is smooth and from frictional wear protected.
Soll die Verzierung durch Drucken oder durch ein andersartiges Uebertragen auf der Waare erzeugt werden, so mischt man das wie vorstehend angegeben vorbereitete Gold mit Druckeröl, statt mit Terpentinöl; im Uebrigen wird wie vorstehend beschrieben verfahren. Das Poliren der vergoldeten Flächen nach dem ersten Brennen geschieht am besten mittelst Blutsteins.Should the decoration be printed or otherwise transferred on the Goods are produced, the gold prepared as indicated above is mixed in with it Printer oil, instead of turpentine oil; Otherwise, proceed as described above. The polishing of the gold-plated surfaces after the first firing is best done using a medium Blood stone.
Das nach vorliegender Erfindung zu verwendende Gold, metallisches gefälltes Gold im Gegensatz zu dem allgemein benutzten Goldchlorid, ist für den Zweck besonders geeignet und gestattet, Wirkungen zu erzielen, weiche bisher nicht erreicht wurden und auch mit dem bisher benutzten Goldchlorid nicht erreicht werden können. .The gold to be used according to the present invention, metallic precipitated gold im In contrast to the commonly used gold chloride, is particularly suitable for the purpose and allows to achieve effects that have not yet been achieved and also with the gold chloride previously used cannot be achieved. .
Die zu verwendende letzte Glasur bereitet man zweckmäfsig aus 4 Theilen einer im amerikanischen Handel unter dem Namen Nr. 8The last glaze to be used is expediently prepared from 4 parts of an im American trade under the name No. 8
Claims (1)
Publications (1)
Publication Number | Publication Date |
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DE109496C true DE109496C (en) |
Family
ID=379385
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT109496D Active DE109496C (en) |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE109496C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2529194A1 (en) * | 1982-06-25 | 1983-12-30 | Briare Emaux | PROCESS FOR COATING GOLD OR PLATINUM ON CERAMIC OR GLASS OBJECTS |
EP0844218A1 (en) * | 1996-11-25 | 1998-05-27 | SICIS INTERNATIONAL S.r.l. | Method for manufacturing glass and gold slabs for mosaics |
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0
- DE DENDAT109496D patent/DE109496C/de active Active
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2529194A1 (en) * | 1982-06-25 | 1983-12-30 | Briare Emaux | PROCESS FOR COATING GOLD OR PLATINUM ON CERAMIC OR GLASS OBJECTS |
EP0098220A1 (en) * | 1982-06-25 | 1984-01-11 | Emaux De Briare | Method of gold or platinum coating articles, particularly ceramic and glass articles, and articles so obtained |
EP0844218A1 (en) * | 1996-11-25 | 1998-05-27 | SICIS INTERNATIONAL S.r.l. | Method for manufacturing glass and gold slabs for mosaics |
US5974832A (en) * | 1996-11-25 | 1999-11-02 | Sicis International S.R.L. | Method for manufacturing glass and gold slabs for mosaics |
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