DE10018103A1 - Multi-layer film with a radiation hardenable paint useful for substrate coating, includes a decorative paint coating and an adhesive and reduces costs in production of painted products and avoids expensive maintenance costs - Google Patents
Multi-layer film with a radiation hardenable paint useful for substrate coating, includes a decorative paint coating and an adhesive and reduces costs in production of painted products and avoids expensive maintenance costsInfo
- Publication number
- DE10018103A1 DE10018103A1 DE10018103A DE10018103A DE10018103A1 DE 10018103 A1 DE10018103 A1 DE 10018103A1 DE 10018103 A DE10018103 A DE 10018103A DE 10018103 A DE10018103 A DE 10018103A DE 10018103 A1 DE10018103 A1 DE 10018103A1
- Authority
- DE
- Germany
- Prior art keywords
- film
- paint
- adhesive
- carrier
- radiation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1733—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
- B44C1/1745—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive using an intermediate support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/172—Decalcomanias provided with a layer being specially adapted to facilitate their release from a temporary carrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/1725—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive using an intermediate support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1733—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
- B44C1/1741—Decalcomanias provided with a layer being specially adapted to facilitate their release from a temporary carrier
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2429/00—Presence of polyvinyl alcohol
- C09J2429/006—Presence of polyvinyl alcohol in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
- C09J2433/006—Presence of (meth)acrylic polymer in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Die Erfindung betrifft eine mehrlagige Folie mit härtbarem Lack, ein Verfahren zum Herstellen einer solchen Folie und die Verwendung derselben zum Beschichten eines Substrates.The invention relates to a multilayer film with curable Varnish, a process for making such a film and the Use of the same for coating a substrate.
Im Stand der Technik werden farbig dekorierte Produkte (Sub strate) in aller Regel lackiert, wobei der Lack bei anspruchs volleren Produkten einer Strahlungshärtung, insbesondere mit UV-Strahlung, unterzogen wird. Dies erfordert beim Hersteller des Produktes einigen Aufwand hinsichtlich der Anlagen und des Verfahrens.In the prior art, colored decorated products (sub strate) usually painted, whereby the paint at demanding fuller products of radiation curing, especially with UV radiation. This requires the manufacturer the product some effort with regard to the plants and the Procedure.
Der Erfindung liegt die Aufgabe zugrunde, den Aufwand beim Herstellen lackierter Produkte zu verringern.The invention has for its object the effort Manufacture to reduce painted products.
Erfindungsgemäß wird hierfür eine mehrlagige Folie bereitge
stellt mit zumindest folgenden Lagen:
According to the invention, a multilayer film is provided for this with at least the following layers:
- - einem Träger mit "Release"-Eigenschaft,- a carrier with "release" property,
- - darauf einem thermoplastisch verformbaren, härtbaren Lack, und- a thermoplastic, hardenable lacquer, and
- - einem Kleber.- an adhesive.
Mit einer solchen Folie kann der Hersteller eines Produkts beliefert werden. Er kann die Folie auf das zu lackierende und gegebenenfalls zu dekorierende Produkt (Substrat) auflegen und die Folie insgesamt an die Form des Substrates anpassen, wobei die thermoplastische Verformbarkeit des Lackes diese Anpassung fördert. Nachdem die Folie mit dem Lack und dem Kleber formge nau an das Substrat angelegt ist, kann der Lack mit Strahlung ausgehärtet werden. Vor oder bevorzugt nach dem Härten kann der Träger mit "Release"-Eigenschaft vom Lack abgezogen werden.With such a film, the manufacturer of a product be supplied. He can apply the film to the paint and if applicable, place the product (substrate) to be decorated and overall adapt the film to the shape of the substrate, wherein the thermoplastic deformability of the paint this adjustment promotes. After the film with the varnish and adhesive formge If the paint is applied precisely to the substrate, it can be exposed to radiation be cured. Before or preferably after curing, the Carriers with a "release" property are peeled off the paint.
Die sogenannte "Release"-Technik ist als solche bekannt (z. B. EP 0 573 676 A1). Als flächige Träger mit "Release"- Eigenschaften kommen insbesondere in Betracht Papiere und auch Kunststoffolien, die an ihre Oberfläche so präpariert sind, daß aufgetragene Farbschichten oder Lackschichten in der Art eines "Abpellens" (wie ein Abziehbild) auf ein Substrat übertragbar sind. Dies ist als solches dem Fachmann bekannt.The so-called "release" technique is known as such (e.g. EP 0 573 676 A1). As a flat beam with "release" - Properties come into consideration in particular papers and also Plastic films that are prepared on their surface so that applied layers of paint or varnish in the manner of a "Peeling off" (like a decal) transferable to a substrate are. As such, this is known to the person skilled in the art.
Die vorstehend beschriebene Technik ermöglicht eine hochwertige Lackierung eines Produktes, wobei der Hersteller des Produktes keine aufwendigen Lackieranlagen und auch keine aufwendige Vorratshaltung hinsichtlich des Lackes betreiben muß. Vielmehr wird ihm die beschriebene Folie geliefert. Die Folie ermöglicht eine homogene Auftragung des Lackes mit relativ wenig aufwendi gen Mitteln.The technique described above enables high quality Painting a product, being the manufacturer of the product no complex painting systems and also no complex Must keep stocks of paint. Much more the film described is delivered to him. The film allows a homogeneous application of the paint with relatively little effort resources.
Gemäß einer bevorzugten Ausgestaltung der Erfindung weist die mehrlagige Folie zwischen dem Lack und dem Kleber eine Farbde kor-Lage auf. Somit kann das letztlich herzustellenden Produkt mit der Folie nicht nur lackiert sondern auch in einfacher Weise in einem einzigen Arbeitsgang farbig dekoriert werden, wobei unter einer "farbigen Dekoration" hier auch ein einfarbi ges Dekor oder auch eine Holzdarstellung oder dergleichen gemeint ist.According to a preferred embodiment of the invention, the multilayer film between the paint and the adhesive a color de kor location on. Thus, the product ultimately to be manufactured not only painted with the film but also easier Be decorated in color in a single operation, under a "colored decoration" here also a monochrome ges decor or a wood representation or the like is meant.
Es können die als UV-härtbar bekannten Pulverlacke mit den üblichen Zusatzstoffen verwendet werden, bevorzugt ungesättigte Polyester oder acrylierte Polyacrylate.The powder coatings known as UV-curable can be mixed with the usual additives are used, preferably unsaturated Polyester or acrylated polyacrylates.
Als Kleber werden bevorzugt Polyurethankleber, Polyacrylatkle ber oder Polyolefinkleber eingesetzt.Polyurethane glue, polyacrylate glue are preferred as glue over or polyolefin glue used.
Gemäß einer weiteren bevorzugten Ausgestaltung der Folie ist der Träger so ausgewählt, daß er für diejenige Strahlung, mit der der Lack härtbar ist, durchlässig ist. Dies hat den Vor teil, daß die Folie solange auf dem Substrat verbleiben kann, bis die Härtung abgeschlossen ist. Hierzu wird als Träger bevorzugt PVA (Polyvinylalkohol) verwendet.According to a further preferred embodiment of the film the carrier is selected so that it for that radiation with that the paint is curable, is permeable. This has the intent partly that the film can remain on the substrate as long as until curing is complete. This is done as a carrier preferably PVA (polyvinyl alcohol) used.
Die Erfindung lehrt auch ein Verfahren zum Herstellen einer mehrlagigen Folie, bei dem auf einen Träger mit "Release"- Eigenschaft ein thermoplastisch verformbarer, strahlungshärtba rer Lack aufextrudiert wird und auf den Lack ein Kleber aufge tragen wird.The invention also teaches a method of making a multilayer film in which on a carrier with "release" - Property a thermoplastic deformable, radiation curable rer lacquer is extruded and an adhesive is applied to the lacquer will wear.
Dieses Verfahren kann mit einem herkömmlichen Extruder mit Schlitzdüse ausgeführt werden. Dabei wird der Lack bevorzugt noch in Granulatform (also nicht als Pulver) in den Extruder eingegeben und geschmolzen. Die Verwendung des Lackes als Granulat vereinfacht und verbilligt das Verfahren.This method can be used with a conventional extruder Slot nozzle are executed. The paint is preferred still in granulate form (not as a powder) into the extruder entered and melted. The use of the paint as Granules simplify and make the process cheaper.
Die Erfindung beinhaltet auch ein Verfahren zum Beschichten eines Produktes bzw. Substrates, bei dem eine Folie gemäß einem der Ansprüche 1 bis 6 unter Druck- und/oder Wärmeeinwirkung auf das Substrat aufgebracht wird und der Lack nach thermoplasti scher Verformung mit Strahlung, insbesondere UV-Strahlung, gehärtet wird. Dabei wird, wie oben bereits angedeutet, der Träger bevorzugt erst nach der Härtung des Lackes abgezogen, so daß er bis dahin als Schutzschicht zur Verfügung steht.The invention also includes a method of coating a product or substrate in which a film according to a of claims 1 to 6 under pressure and / or heat the substrate is applied and the varnish after thermoplastic shear deformation with radiation, especially UV radiation, is hardened. As already indicated above, the Carrier preferably only peeled off after the paint has hardened, see above that until then it will be available as a protective layer.
Nachfolgend wird ein Ausführungsbeispiel der Erfindung mit Blick auf die Zeichnung näher erläutert. Es zeigt:An exemplary embodiment of the invention is described below View of the drawing explained in more detail. It shows:
Fig. 1 schematisch einen Schnitt durch eine Folie; Figure 1 shows schematically a section through a film.
Fig. 2 schematisch die Aufbringung einer Folie gemäß Fig. 1 auf ein Substrat. Fig. 2 shows schematically the application of a film according to Fig. 1 on a substrate.
Ein Träger 10 mit "Release"-Eigenschaft (Abpell-Fähigkeit) wird in als solches bekannter Weise bereitgestellt, z. B. ein "Relea se"-Träger aus PVA.A carrier 10 with a "release" property (peeling ability) is provided in a manner known per se, e.g. B. a "Relea se" carrier made of PVA.
Auf den Träger 10 wird ein Lack 12 aufgetragen, hier ein schmelzbarer, mit UV-Strahlung härtbarer Lack, bevorzugt vom obengenannten Typ.A varnish 12 is applied to the carrier 10 , here a fusible, UV-curable varnish, preferably of the type mentioned above.
Die Stärke des Trägers 10 und die Stärke der aufgebrachten Lackschicht hängen vom letztlich zu lackierenden Produkt ab. The thickness of the carrier 10 and the thickness of the lacquer layer applied depend on the product ultimately to be lacquered.
Der Lack kann z. B. als Pulver auf die Folie aufgetragen werden und geschmolzen werden. Er kann auch in einem Extruder mit Schlitzdüse direkt auf eine fertige Folie aufextrudiert werden. Bevorzugt wird der Lack in Granulatform in den Extruder einge geben.The paint can e.g. B. applied as a powder to the film and be melted. It can also be used in an extruder Slot die can be extruded directly onto a finished film. The lacquer in granular form is preferably introduced into the extruder give.
Auf den Lack wird ein Farbdekor 14 aufgetragen (nicht unbedingt erforderlich, wenn das Produkt nur lackiert werden soll).A color decor 14 is applied to the lacquer (not absolutely necessary if the product is only to be lacquered).
Bei Verwendung eines Farbdekors wird der Lack 12 bevorzugt transparent gewählt.When using a color decor, the paint 12 is preferably chosen to be transparent.
Alle hier beschriebenen Lagen, insbesondere also die Farbdekor- Lage 14 können mit der "Release"-Technik aufgebracht werden. Zum Beispiel kann das Farbdekor von einem Film aus Polypropylen auf die Lackschicht "Released" werden. Dabei wird bevorzugt mit etwas erhöhter Temperatur gearbeitet, was die Haftung des Farbdekors an der Lackschicht verbessert.All the layers described here, in particular the colored decor layer 14, can be applied using the "release" technique. For example, the color decor can be "released" from a film of polypropylene on the lacquer layer. It is preferred to work at a somewhat elevated temperature, which improves the adhesion of the color decor to the lacquer layer.
Falls kein Farbdekor vorgesehen ist, kann der Lack bevorzugt eingefärbt sein.If no color decor is provided, the lacquer can be preferred be colored.
Der Trägerfilm 10 kann bevorzugt geprägt sein, d. h. auf seiner dem Lack 12 zugekehrten Seite weist die Oberfläche des Träger films 10 eine Struktur auf, ist also nicht glatt. Diese Struk tur überträgt sich dann in den Lack 12. So kann z. B. eine Holzstruktur im Lack 12 erzeugt werden.The carrier film 10 can preferably be embossed, ie on its side facing the lacquer 12 the surface of the carrier film 10 has a structure, that is to say is not smooth. This structure is then transferred to the lacquer 12 . So z. B. a wood structure in the paint 12 are generated.
Es ist auch möglich, die Oberfläche des Trägerfilms 10 aufzu rauhen oder mit einer sehr feinen Struktur zu versehen, und zwar auf der dem Lack zugekehrten Seite. Daraus folgt letztlich im Endprodukt eine Mattierung des Lackes, ohne daß besondere Mattierungsmittel erforderlich sind.It is also possible to roughen the surface of the carrier film 10 or to provide it with a very fine structure, specifically on the side facing the paint. This ultimately results in a matting of the lacquer in the end product without the need for special matting agents.
Auf das Farbdekor 14 wird eine Kleberschicht 16 aufgetragen, bevorzugt vom oben angegebenen Typ. An adhesive layer 16 is applied to the color decor 14 , preferably of the type specified above.
Die so hergestellte Folie gemäß Fig. 1 ist als solche handhab bar und transportierbar. Sie kann dazu dienen, Produkte (Sub strate) zu lackieren und gegebenenfalls zu dekorieren. Dies ist schematisch in Fig. 2 dargestellt.The film thus produced according to FIG. 1 can be handled and transported as such. It can be used to paint products (sub strate) and to decorate them if necessary. This is shown schematically in FIG. 2.
Das Substrat 18 kann eine relativ komplizierte 3-dimensionale Form haben. Die Folie gemäß Fig. 1 wird mit dem Kleber 16 zuunterst auf das Substrat aufgelegt. Dabei wird bevorzugt eine Druckdifferenz p erzeugt, um die Folie insgesamt pass- und formgenau auf das Substrat 18 aufzubringen. Zum Beispiel kann in einer Membranpresse eine Membran (nicht gezeigt) über die Folie gelegt werden (was als solches bekannt ist) und durch Ausbildung eines Druckes durch die Membran und/oder durch Erzeugung eines Vakuums auf der Unterseite der Membran mit Hilfe der Membran die Folie an das Substrat 18 angelegt werden. Dabei wird die Temperatur der Folie so erhöht, daß der Kleber seine Haftung entfaltet. Die Temperaturerhöhung wird so einge stellt, daß auch der Lack 12 sich thermoplastisch genau an die Konturen homogen anpaßt. Zu diesem Zeitpunkt ist der Lack 12 noch nicht ausgehärtet.The substrate 18 can have a relatively complicated 3-dimensional shape. The film of FIG. 1 with the adhesive 16 at the bottom placed on the substrate. In this case, a pressure difference p is preferably generated in order to apply the film overall to the substrate 18 with a precise fit and shape. For example, in a membrane press, a membrane (not shown) can be placed over the film (which is known as such) and by applying pressure through the membrane and / or by creating a vacuum on the underside of the membrane using the membrane be applied to the substrate 18 . The temperature of the film is increased so that the adhesive develops its adhesion. The temperature increase is set so that the paint 12 conforms thermoplastic precisely to the contours homogeneously. At this time, the paint 12 has not yet hardened.
Nachdem die Folie gemäß Fig. 2 exakt an das Substrat 18 ange legt und zumindest teilweise bereits verklebt ist, kann der Lack 12 mit Strahlung S ausgehärtet werden, z. B. UV-Strahlung oder Elektronenstrahl.After the film according to FIG. 2 is placed exactly on the substrate 18 and is at least partially already glued, the lacquer 12 can be cured with radiation S, for. B. UV radiation or electron beam.
Claims (11)
- - einem Träger (10) mit "Release"-Eigenschaft,
- - darauf einem thermoplastisch verformbaren, härtbaren Lack (12), und
- - einem Kleber (16).
- - a carrier ( 10 ) with "release" property,
- - Thereon a thermoplastic deformable, curable lacquer ( 12 ), and
- - an adhesive ( 16 ).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10018103A DE10018103A1 (en) | 2000-04-12 | 2000-04-12 | Multi-layer film with a radiation hardenable paint useful for substrate coating, includes a decorative paint coating and an adhesive and reduces costs in production of painted products and avoids expensive maintenance costs |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10018103A DE10018103A1 (en) | 2000-04-12 | 2000-04-12 | Multi-layer film with a radiation hardenable paint useful for substrate coating, includes a decorative paint coating and an adhesive and reduces costs in production of painted products and avoids expensive maintenance costs |
Publications (1)
Publication Number | Publication Date |
---|---|
DE10018103A1 true DE10018103A1 (en) | 2001-10-25 |
Family
ID=7638453
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE10018103A Withdrawn DE10018103A1 (en) | 2000-04-12 | 2000-04-12 | Multi-layer film with a radiation hardenable paint useful for substrate coating, includes a decorative paint coating and an adhesive and reduces costs in production of painted products and avoids expensive maintenance costs |
Country Status (1)
Country | Link |
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DE (1) | DE10018103A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1876035A1 (en) * | 2005-03-31 | 2008-01-09 | Yoshino Kogyosho Co., Ltd. | Transfer film |
US7332046B2 (en) | 2003-09-26 | 2008-02-19 | Eastman Chemical Company | Methods of blocking stains on a substrate to be painted, and composites suitable for use in such methods |
WO2012072794A1 (en) * | 2010-12-02 | 2012-06-07 | Corso Magenta | Process for manufacturing an article enabling a decorative film to be fixed to a final support |
WO2022074386A1 (en) * | 2020-10-06 | 2022-04-14 | Essentra Packaging And Security Limited | Sheet material |
-
2000
- 2000-04-12 DE DE10018103A patent/DE10018103A1/en not_active Withdrawn
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7332046B2 (en) | 2003-09-26 | 2008-02-19 | Eastman Chemical Company | Methods of blocking stains on a substrate to be painted, and composites suitable for use in such methods |
EP1876035A1 (en) * | 2005-03-31 | 2008-01-09 | Yoshino Kogyosho Co., Ltd. | Transfer film |
EP1876035A4 (en) * | 2005-03-31 | 2012-08-15 | Yoshino Kogyosho Co Ltd | Transfer film |
WO2012072794A1 (en) * | 2010-12-02 | 2012-06-07 | Corso Magenta | Process for manufacturing an article enabling a decorative film to be fixed to a final support |
FR2968241A1 (en) * | 2010-12-02 | 2012-06-08 | Corso Magenta | METHOD FOR MANUFACTURING AN ARTICLE FOR APPLYING A DECORATIVE FILM TO A DEFINITIVE SUPPORT |
CN103380009A (en) * | 2010-12-02 | 2013-10-30 | 科尔索-马真塔公司 | Process for manufacturing an article enabling a decorative film to be fixed to a final support |
US9457614B2 (en) | 2010-12-02 | 2016-10-04 | Corso Magenta | Process for manufacturing an article enabling a decorative film to be fixed to a final support |
WO2022074386A1 (en) * | 2020-10-06 | 2022-04-14 | Essentra Packaging And Security Limited | Sheet material |
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