DD229157A5 - Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium - Google Patents

Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium Download PDF

Info

Publication number: DD229157A5
Authority: DD; German Democratic Republic
Prior art keywords: magnesium; decomposition; anthracene; bar; pressure
Prior art date: 1983-11-09

Application number

DD84269170A

Other languages

German (de)

English (en)

Inventor

Borislav Bogdanovic

Original Assignee

Studiengesellschaft Kohle Mbh

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-11-09

Filing date

1984-11-06

Publication date

1985-10-30

1984-11-06 Application filed by Studiengesellschaft Kohle Mbh filed Critical Studiengesellschaft Kohle Mbh

1985-10-30 Publication of DD229157A5 publication Critical patent/DD229157A5/de

Links

FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 120
239000011777 magnesium Substances 0.000 title claims abstract description 99
229910052749 magnesium Inorganic materials 0.000 title claims abstract description 87
238000004519 manufacturing process Methods 0.000 title abstract description 4
238000000034 method Methods 0.000 claims abstract description 26
GRJWDJVTZAUGDZ-UHFFFAOYSA-N anthracene;magnesium Chemical compound [Mg].C1=CC=CC2=CC3=CC=CC=C3C=C21 GRJWDJVTZAUGDZ-UHFFFAOYSA-N 0.000 claims abstract description 21
229910012375 magnesium hydride Inorganic materials 0.000 claims abstract description 18
238000006243 chemical reaction Methods 0.000 claims abstract description 17
230000008569 process Effects 0.000 claims abstract description 17
238000000354 decomposition reaction Methods 0.000 claims abstract description 15
125000000217 alkyl group Chemical group 0.000 claims abstract description 10
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 9
238000002360 preparation method Methods 0.000 claims abstract description 9
JUOXOUBQXJJXAO-UHFFFAOYSA-N [Mg].C=CC=C Chemical compound [Mg].C=CC=C JUOXOUBQXJJXAO-UHFFFAOYSA-N 0.000 claims abstract description 7
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 7
150000001875 compounds Chemical class 0.000 claims abstract description 6
150000002901 organomagnesium compounds Chemical class 0.000 claims abstract description 6
229910052736 halogen Inorganic materials 0.000 claims abstract description 3
239000000843 powder Substances 0.000 claims abstract description 3
239000000376 reactant Substances 0.000 claims abstract 5
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 24
229910052739 hydrogen Inorganic materials 0.000 claims description 11
150000001993 dienes Chemical class 0.000 claims description 9
-1 magnesium compounds ethyl bromide Chemical class 0.000 claims description 9
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
239000002904 solvent Substances 0.000 claims description 8
230000008021 deposition Effects 0.000 claims description 6
125000001931 aliphatic group Chemical group 0.000 claims description 5
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 4
239000003054 catalyst Substances 0.000 claims description 4
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 3
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
239000002815 homogeneous catalyst Substances 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 2
PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 claims description 2
150000004820 halides Chemical class 0.000 claims description 2
239000000010 aprotic solvent Substances 0.000 claims 1
150000002367 halogens Chemical class 0.000 claims 1
230000000737 periodic effect Effects 0.000 claims 1
150000003512 tertiary amines Chemical class 0.000 claims 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 4
229910052760 oxygen Inorganic materials 0.000 abstract description 3
230000002441 reversible effect Effects 0.000 abstract description 3
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
125000005843 halogen group Chemical group 0.000 abstract description 2
125000005842 heteroatom Chemical group 0.000 abstract description 2
229910052757 nitrogen Inorganic materials 0.000 abstract description 2
239000001301 oxygen Chemical group 0.000 abstract description 2
229910052698 phosphorus Inorganic materials 0.000 abstract description 2
239000011574 phosphorus Chemical group 0.000 abstract description 2
239000011593 sulfur Chemical group 0.000 abstract description 2
229910052717 sulfur Inorganic materials 0.000 abstract description 2
238000001556 precipitation Methods 0.000 abstract 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 70
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 51
239000000725 suspension Substances 0.000 description 15
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 14
238000002474 experimental method Methods 0.000 description 11
238000003756 stirring Methods 0.000 description 9
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 8
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 8
QTBFPMKWQKYFLR-UHFFFAOYSA-N isobutyl chloride Chemical compound CC(C)CCl QTBFPMKWQKYFLR-UHFFFAOYSA-N 0.000 description 8
239000000203 mixture Substances 0.000 description 8
OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 6
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 6
230000009257 reactivity Effects 0.000 description 6
239000000126 substance Substances 0.000 description 6
238000001149 thermolysis Methods 0.000 description 6
239000007789 gas Substances 0.000 description 5
230000007062 hydrolysis Effects 0.000 description 5
238000006460 hydrolysis reaction Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
238000009835 boiling Methods 0.000 description 4
238000004817 gas chromatography Methods 0.000 description 4
238000005984 hydrogenation reaction Methods 0.000 description 4
150000002680 magnesium Chemical class 0.000 description 4
CYSFUFRXDOAOMP-UHFFFAOYSA-M magnesium;prop-1-ene;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C=C CYSFUFRXDOAOMP-UHFFFAOYSA-M 0.000 description 4
239000000047 product Substances 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
JXGNHEUFHNJWDY-UHFFFAOYSA-N 2,5-dihydro-1h-phosphole Chemical class C1PCC=C1 JXGNHEUFHNJWDY-UHFFFAOYSA-N 0.000 description 3
238000003747 Grignard reaction Methods 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
229910052786 argon Inorganic materials 0.000 description 3
RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 3
238000003776 cleavage reaction Methods 0.000 description 3
238000004821 distillation Methods 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
239000001282 iso-butane Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
230000008018 melting Effects 0.000 description 3
238000002844 melting Methods 0.000 description 3
150000002896 organic halogen compounds Chemical class 0.000 description 3
239000002245 particle Substances 0.000 description 3
230000002829 reductive effect Effects 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
238000005979 thermal decomposition reaction Methods 0.000 description 3
GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 2
101150065749 Churc1 gene Proteins 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
102100038239 Protein Churchill Human genes 0.000 description 2
150000001500 aryl chlorides Chemical class 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
239000012039 electrophile Substances 0.000 description 2
238000000921 elemental analysis Methods 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
239000012065 filter cake Substances 0.000 description 2
239000005556 hormone Substances 0.000 description 2
229940088597 hormone Drugs 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
125000000896 monocarboxylic acid group Chemical group 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
150000003018 phosphorus compounds Chemical class 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
230000009467 reduction Effects 0.000 description 2
230000007017 scission Effects 0.000 description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
JFLKFZNIIQFQBS-FNCQTZNRSA-N trans,trans-1,4-Diphenyl-1,3-butadiene Chemical compound C=1C=CC=CC=1\C=C\C=C\C1=CC=CC=C1 JFLKFZNIIQFQBS-FNCQTZNRSA-N 0.000 description 2
238000010626 work up procedure Methods 0.000 description 2
NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
WZGMIOQDQJETRK-UHFFFAOYSA-N (5-oxo-5-phenylpentyl) benzoate Chemical compound C=1C=CC=CC=1C(=O)CCCCOC(=O)C1=CC=CC=C1 WZGMIOQDQJETRK-UHFFFAOYSA-N 0.000 description 1
238000005160 1H NMR spectroscopy Methods 0.000 description 1
WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 1
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical group CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
238000004438 BET method Methods 0.000 description 1
RTAQCQOZRWKSTQ-UHFFFAOYSA-N CC(C)C[Mg]CC(C)C Chemical compound CC(C)C[Mg]CC(C)C RTAQCQOZRWKSTQ-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
238000005727 Friedel-Crafts reaction Methods 0.000 description 1
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
230000004913 activation Effects 0.000 description 1
239000012190 activator Substances 0.000 description 1
229910001508 alkali metal halide Inorganic materials 0.000 description 1
150000008045 alkali metal halides Chemical class 0.000 description 1
150000001454 anthracenes Chemical class 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
238000006480 benzoylation reaction Methods 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
238000005695 dehalogenation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000006471 dimerization reaction Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000012992 electron transfer agent Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
239000012259 ether extract Substances 0.000 description 1
239000000284 extract Substances 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
239000005457 ice water Substances 0.000 description 1
238000002329 infrared spectrum Methods 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
YSMZEMQBSONIMJ-UHFFFAOYSA-M magnesium;2-methanidylpropane;chloride Chemical compound [Mg+2].[Cl-].CC(C)[CH2-] YSMZEMQBSONIMJ-UHFFFAOYSA-M 0.000 description 1
FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 description 1
KFIGICHILYTCJF-UHFFFAOYSA-N n'-methylethane-1,2-diamine Chemical compound CNCCN KFIGICHILYTCJF-UHFFFAOYSA-N 0.000 description 1
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000006884 silylation reaction Methods 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
238000000859 sublimation Methods 0.000 description 1
230000008022 sublimation Effects 0.000 description 1
QKMNLIDNGUCJIK-UHFFFAOYSA-N trimethyl(4-trimethylsilylbutoxy)silane Chemical compound C[Si](C)(C)CCCCO[Si](C)(C)C QKMNLIDNGUCJIK-UHFFFAOYSA-N 0.000 description 1
238000002604 ultrasonography Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/023—Hydrogen absorption
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/04—Hydrides of alkali metals, alkaline earth metals, beryllium or magnesium; Addition complexes thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/20—Obtaining alkaline earth metals or magnesium
- C22B26/22—Obtaining magnesium

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Nanotechnology (AREA)
Geology (AREA)
General Life Sciences & Earth Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Materials Engineering (AREA)
Manufacturing & Machinery (AREA)
General Chemical & Material Sciences (AREA)
General Physics & Mathematics (AREA)
Environmental & Geological Engineering (AREA)
Condensed Matter Physics & Semiconductors (AREA)
Composite Materials (AREA)
Physics & Mathematics (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Inorganic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Crystallography & Structural Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Manufacture And Refinement Of Metals (AREA)
Catalysts (AREA)
Glass Compositions (AREA)
Crystals, And After-Treatments Of Crystals (AREA)
Analysing Materials By The Use Of Radiation (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

DD84269170A 1983-11-09 1984-11-06 Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium DD229157A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19833340492 DE3340492A1 (de)	1983-11-09	1983-11-09	Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium und dessen verwendung

Publications (1)

Publication Number	Publication Date
DD229157A5 true DD229157A5 (de)	1985-10-30

Family

ID=6213852

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD84269170A DD229157A5 (de)	1983-11-09	1984-11-06	Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium

Country Status (11)

Country	Link
US (1)	US4659373A (es)
EP (1)	EP0147581B1 (es)
JP (1)	JPS60116732A (es)
AT (1)	ATE40573T1 (es)
AU (1)	AU575354B2 (es)
CA (1)	CA1232764A (es)
DD (1)	DD229157A5 (es)
DE (2)	DE3340492A1 (es)
DK (1)	DK164368C (es)
ES (1)	ES537364A0 (es)
IE (1)	IE57704B1 (es)

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3639545C1 (de) *	1986-11-20	1988-06-01	Studiengesellschaft Kohle Mbh	Verfahren zur Waermespeicherung und -transformation sowie Kaelteerzeugung
DE3722993A1 (de) *	1987-07-11	1989-01-19	Studiengesellschaft Kohle Mbh	Loesliche magnesiumdihydride, verfahren zu ihrer herstellung und ihre verwendung
JPH01136910A (ja) *	1987-11-20	1989-05-30	Nisshin Steel Co Ltd	粒状微細金属粉末の製造方法
US4933003A (en) *	1989-07-18	1990-06-12	The United States Of America As Represented By The Secretary Of The Army	Metal alloy formation by reduction of polyheterometallic complexes
US5061313A (en) *	1990-09-07	1991-10-29	Northeastern University	Direct alloy synthesis from heteropolymetallic precursors
AU2682492A (en) *	1991-09-25	1993-04-27	Research Corporation Technologies, Inc.	The sonochemical synthesis of amorphous metals
DE4419456A1 (de) *	1994-06-03	1995-12-07	Goldschmidt Ag Th	Verfahren zur Herstellung von Magnesiumhydrid
US6074447A (en) *	1997-02-21	2000-06-13	University Of Hawaii	Hydrogen storage
CN100427249C (zh) *	2003-12-10	2008-10-22	辽宁师范大学	一种通过真空热解由卤代烃引发合成的蒽镧系金属有机化合物来制备纳米镧系金属粉末的方法
DE102008063895B3 (de) *	2008-12-19	2010-06-10	Gkss-Forschungszentrum Geesthacht Gmbh	Verfahren zur Aktivierung oder Regeneration eines Wasserstoffspeichermaterials

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Publication number	Priority date	Publication date	Assignee	Title
FR1292322A (fr) *	1961-03-03	1962-05-04	Commissariat Energie Atomique	Procédé de préparation de masses à base de poudre de magnésium fluorée et comprimée
BE622459A (es) *	1961-09-14
US3351646A (en) *	1965-01-04	1967-11-07	Exxon Research Engineering Co	Magnesium and tin derivatives of styrenes and the preparation thereof
US3354190A (en) *	1965-01-04	1967-11-21	Exxon Research Engineering Co	Magnesium and tin derivatives of fusedring hydrocarbons and the preparation thereof
US3388179A (en) *	1965-01-04	1968-06-11	Exxon Research Engineering Co	Organomagnesium addition compounds, process therefor, and derivatives thereof
US3969104A (en) *	1974-02-19	1976-07-13	Ivan Andreevich Barannik	Granules of magnesium and its alloys
DE2804445A1 (de) *	1978-02-02	1979-08-09	Studiengesellschaft Kohle Mbh	Verfahren zur herstellung von magnesiumhydriden
DE3247361A1 (de) *	1982-12-22	1984-06-28	Studiengesellschaft Kohle mbH, 4330 Mülheim	Verfahren zur abtrennung und reinigung von wasserstoff
DE3247362A1 (de) *	1982-12-22	1984-06-28	Studiengesellschaft Kohle mbH, 4330 Mülheim	Verfahren zur herstellung von silicium-wasserstoff-verbindungen, insbesondere des silans
US4543122A (en) *	1983-10-19	1985-09-24	Johannesburg Consolidated Investment Company Limited	Magnesium production
US4541867A (en) *	1984-03-20	1985-09-17	Amax Inc.	Varnish-bonded carbon-coated magnesium and aluminum granules

1983
- 1983-11-09 DE DE19833340492 patent/DE3340492A1/de not_active Withdrawn
1984
- 1984-11-02 DK DK523284A patent/DK164368C/da not_active IP Right Cessation
- 1984-11-05 ES ES537364A patent/ES537364A0/es active Granted
- 1984-11-06 DD DD84269170A patent/DD229157A5/de not_active IP Right Cessation
- 1984-11-07 AT AT84113406T patent/ATE40573T1/de active
- 1984-11-07 US US06/669,209 patent/US4659373A/en not_active Expired - Fee Related
- 1984-11-07 EP EP84113406A patent/EP0147581B1/de not_active Expired
- 1984-11-07 DE DE8484113406T patent/DE3476561D1/de not_active Expired
- 1984-11-07 CA CA000467265A patent/CA1232764A/en not_active Expired
- 1984-11-08 IE IE2867/84A patent/IE57704B1/en not_active IP Right Cessation
- 1984-11-08 AU AU35230/84A patent/AU575354B2/en not_active Ceased
- 1984-11-08 JP JP59236558A patent/JPS60116732A/ja active Granted

Also Published As

Publication number	Publication date
ATE40573T1 (de)	1989-02-15
ES8600418A1 (es)	1985-09-16
DE3340492A1 (de)	1985-05-15
IE57704B1 (en)	1993-03-10
AU3523084A (en)	1985-05-30
IE842867L (en)	1985-05-09
DK523284D0 (da)	1984-11-02
DK523284A (da)	1985-05-10
EP0147581B1 (de)	1989-02-01
ES537364A0 (es)	1985-09-16
AU575354B2 (en)	1988-07-28
EP0147581A1 (de)	1985-07-10
US4659373A (en)	1987-04-21
DE3476561D1 (en)	1989-03-09
DK164368B (da)	1992-06-15
JPS60116732A (ja)	1985-06-24
DK164368C (da)	1992-11-02
JPH0331773B2 (es)	1991-05-08
CA1232764A (en)	1988-02-16

Legal Events

Date	Code	Title	Description
1997-09-11	ENJ	Ceased due to non-payment of renewal fee

Publication	Publication Date	Title
DD141297A5 (de)	1980-04-23	Verfahren zur herstellung von hydriden des magnesiums
DE3934351A1 (de)	1991-04-18	Verfahren zur herstellung von mikrokristallinen bis amorphen metall- bzw. legierungspulvern und ohne schutzkolloid in organischen solventien geloesten metallen bzw. legierungen
DD229157A5 (de)	1985-10-30	Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium
EP0582692A1 (de)	1994-02-16	Diphosphinliganden
EP0583433A1 (de)	1994-02-23	Diphosphinliganden
DE69131264T2 (de)	1999-10-14	Verfahren zur Herstellung von Silazykloalkanen
DD200226A5 (de)	1983-03-30	Organomagnesiumloesungen geringer viskoesitaet
DE1159949B (de)	1963-12-27	Verfahren zur Herstellung Cyclopentadienyl-Metallverbindungen
US4731203A (en)	1988-03-15	Process for using finely divided highly reactive magnesium
WO2016156195A2 (de)	2016-10-06	Hochreaktive metallhydride, verfahren zu deren herstellung und anwendung
DE4024205A1 (de)	1992-02-06	Metall-magnesium-verbindungen, verfahren zu ihrer herstellung und ihre verwendung zur herstellung feinverteilter metall- und legierungspulver sowie intermetallischer verbindungen
DE2303271B2 (de)	1974-11-07	Verfahren zur Herstellung von Essigsäure oder deren Gemisch mit Methylacetat
US5069894A (en)	1991-12-03	Process for preparing finely divided highly reactive magnesium and use thereof
DE2052144C3 (de)	1974-03-07	Verfahren zur Herstellung von Alkalialuminiumdialkyldihydriden sowie stabile Lösungen von Alkalialuminiumdialkyldihydriden
DE3013240A1 (de)	1980-10-09	Verfahren zur herstellung von erdalkalialkoxyalanaten
DE1768223B1 (de)	1971-12-02	Verfahren zur Herstellung mehrkerniger Komplexe von UEbergangsmetallen der VI.bis VIII.Gruppe des Periodensystems
EP1919925A1 (de)	2008-05-14	Hochreaktive zinkform, verfahren zu deren herstellung und verwendung der hochreaktiven zinkform
EP0915889A1 (de)	1999-05-19	Verfahren zur synthese von grignard-verbindungen unter einsatz von katalysatoren
DE3722993A1 (de)	1989-01-19	Loesliche magnesiumdihydride, verfahren zu ihrer herstellung und ihre verwendung
DE1216304B (de)	1966-05-12	Verfahren zur Herstellung von Alkylaluminiumverbindungen
DE2928313A1 (de)	1981-02-05	Verfahren zur herstellung von 3-(4)- formyltricyclo- eckige klammer auf 5,2,1, 0 hoch 2,6 eckige klammer zu -decen-8
DE1768223C (de)	1972-07-13	Verfahren zur Herstellung mehrkerniger Komplexe von Übergangsmetallen der VI. bis VIII. Gruppe des Periodensystems
DE2061491A1 (de)	1971-07-22	Verfahren zur katalytischen Isomerisierung von olefinisch ungesättigten Verbindungen
DE2134328A1 (de)	1973-01-18	Verfahren zur herstellung von dicyanen
CA1240156A (en)	1988-08-09	Process for preparing finely divided highly reactive magnesium and use thereof