CS215106B2 - Method of making the methan and ev.ethan and other hydrocarbons - Google Patents

Method of making the methan and ev.ethan and other hydrocarbons Download PDF

Info

Publication number: CS215106B2
Authority: CS; Czechoslovakia
Prior art keywords: catalyst; hydrogen; titanium; iron; methane
Prior art date: 1977-02-14

Application number

CS78924A

Other languages

Czech (cs)

English (en)

Inventor

Mehmet N Ozyagcilar

Original Assignee

Oezyagcilar Mehmet N

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-02-14

Filing date

1978-02-13

Publication date

1982-07-30

1978-02-13 Application filed by Oezyagcilar Mehmet N filed Critical Oezyagcilar Mehmet N

1982-07-30 Publication of CS215106B2 publication Critical patent/CS215106B2/cs

Links

VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 85
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 title claims abstract description 36
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 19
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 19
238000004519 manufacturing process Methods 0.000 title description 31
239000003054 catalyst Substances 0.000 claims abstract description 87
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 48
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 48
239000001257 hydrogen Substances 0.000 claims abstract description 48
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 31
239000010936 titanium Substances 0.000 claims abstract description 31
239000000203 mixture Substances 0.000 claims abstract description 28
229910045601 alloy Inorganic materials 0.000 claims abstract description 24
239000000956 alloy Substances 0.000 claims abstract description 24
150000001298 alcohols Chemical class 0.000 claims abstract description 16
229910001069 Ti alloy Inorganic materials 0.000 claims abstract description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 57
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 54
229910052719 titanium Inorganic materials 0.000 claims description 30
229910052742 iron Inorganic materials 0.000 claims description 28
239000001569 carbon dioxide Substances 0.000 claims description 27
229910002092 carbon dioxide Inorganic materials 0.000 claims description 27
238000000034 method Methods 0.000 claims description 25
230000008569 process Effects 0.000 claims description 20
230000015572 biosynthetic process Effects 0.000 claims description 10
IXQWNVPHFNLUGD-UHFFFAOYSA-N iron titanium Chemical compound [Ti].[Fe] IXQWNVPHFNLUGD-UHFFFAOYSA-N 0.000 claims description 6
230000018044 dehydration Effects 0.000 claims description 4
238000006297 dehydration reaction Methods 0.000 claims description 4
238000003786 synthesis reaction Methods 0.000 claims description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 8
229910052799 carbon Inorganic materials 0.000 abstract description 8
239000002245 particle Substances 0.000 abstract description 8
229910000640 Fe alloy Inorganic materials 0.000 abstract description 4
238000004845 hydriding Methods 0.000 abstract description 2
230000002829 reductive effect Effects 0.000 abstract description 2
238000006243 chemical reaction Methods 0.000 description 37
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 34
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 29
239000007789 gas Substances 0.000 description 22
229910002091 carbon monoxide Inorganic materials 0.000 description 19
229910052759 nickel Inorganic materials 0.000 description 17
230000004913 activation Effects 0.000 description 13
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
239000000047 product Substances 0.000 description 11
229910002090 carbon oxide Inorganic materials 0.000 description 10
-1 Carbonyl metals Chemical class 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
230000003197 catalytic effect Effects 0.000 description 5
239000000446 fuel Substances 0.000 description 5
239000003245 coal Substances 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
238000005336 cracking Methods 0.000 description 4
238000002309 gasification Methods 0.000 description 4
239000001307 helium Substances 0.000 description 4
229910052734 helium Inorganic materials 0.000 description 4
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
239000012535 impurity Substances 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
239000002994 raw material Substances 0.000 description 4
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
238000010494 dissociation reaction Methods 0.000 description 3
230000005593 dissociations Effects 0.000 description 3
150000004678 hydrides Chemical class 0.000 description 3
229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
239000007858 starting material Substances 0.000 description 3
229910002593 Fe-Ti Inorganic materials 0.000 description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
229910002056 binary alloy Inorganic materials 0.000 description 2
150000001722 carbon compounds Chemical class 0.000 description 2
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
238000007872 degassing Methods 0.000 description 2
230000008021 deposition Effects 0.000 description 2
238000009826 distribution Methods 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
229910000765 intermetallic Inorganic materials 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000036961 partial effect Effects 0.000 description 2
231100000614 poison Toxicity 0.000 description 2
239000002574 poison Substances 0.000 description 2
231100000572 poisoning Toxicity 0.000 description 2
230000000607 poisoning effect Effects 0.000 description 2
239000000376 reactant Substances 0.000 description 2
229910052707 ruthenium Inorganic materials 0.000 description 2
238000000926 separation method Methods 0.000 description 2
238000005245 sintering Methods 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
229910000048 titanium hydride Inorganic materials 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
FOQQJHCZDOPOPX-UHFFFAOYSA-N [Ti].[C]=O Chemical compound [Ti].[C]=O FOQQJHCZDOPOPX-UHFFFAOYSA-N 0.000 description 1
230000032683 aging Effects 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910000905 alloy phase Inorganic materials 0.000 description 1
238000007664 blowing Methods 0.000 description 1
238000009835 boiling Methods 0.000 description 1
IHXMFRISYNVURW-UHFFFAOYSA-N butane ethane ethanol methane methanol propane Chemical compound CCCC.CCC.C(C)O.CC.CO.C IHXMFRISYNVURW-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000001728 carbonyl compounds Chemical class 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
238000007036 catalytic synthesis reaction Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000004939 coking Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000013056 hazardous product Substances 0.000 description 1
230000036541 health Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
238000005184 irreversible process Methods 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
239000002754 natural gas substitute Substances 0.000 description 1
229910017464 nitrogen compound Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
238000004064 recycling Methods 0.000 description 1
238000012552 review Methods 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000000758 substrate Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
231100000925 very toxic Toxicity 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/08—Production of synthetic natural gas
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CS78924A 1977-02-14 1978-02-13 Method of making the methan and ev.ethan and other hydrocarbons CS215106B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US77236077A	1977-02-14	1977-02-14

Publications (1)

Publication Number	Publication Date
CS215106B2 true CS215106B2 (en)	1982-07-30

Family

ID=25094810

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS78924A CS215106B2 (en)	1977-02-14	1978-02-13	Method of making the methan and ev.ethan and other hydrocarbons

Country Status (5)

Country	Link
US (1)	US4139551A (nl)
BE (1)	BE863888A (nl)
CS (1)	CS215106B2 (nl)
TR (1)	TR19844A (nl)
ZA (1)	ZA78854B (nl)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4182926A (en) *	1978-09-21	1980-01-08	Merck & Co., Inc.	Catalytic process for obtaining methane from methanol
EP0035328A1 (en) *	1980-02-14	1981-09-09	The University of South Carolina	Method of synthesizing hydrocarbons and alcohols
ZA814007B (en) *	1980-06-18	1982-10-27	Oezyagcilar Mehmet N	Method for the coproduction of hydrocarbons and alcohols
US4287095A (en) *	1980-06-24	1981-09-01	The United States Of America As Represented By The Secretary Of The Interior	High surface area transition metal catalysts and method of preparing same
US4560816A (en) *	1982-06-01	1985-12-24	University Of South Carolina	Catalyzed hydrogenation and dehydrogenation processes
US7709541B2 (en) *	2006-07-14	2010-05-04	Headwaters Technology Innovation, Llc	Fischer-Tropsch catalysts incorporating promoter for increasing yields of C5+ hydrocarbons and methods for making and using same
CN105561739B (zh) *	2014-10-11	2018-10-09	中国科学院大连化学物理研究所	一种密闭空间内co2富集与转化设备及方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB473932A (en) *	1935-11-30	1937-10-22	Ig Farbenindustrie Ag	Improvements in the manufacture and production of valuable hydrocarbons and their derivatives containing oxygen from carbon monoxide and hydrogen
US2683726A (en) *	1947-03-18	1954-07-13	Kellogg M W Co	Hydrocarbon synthesis with reduced magnetite catalyst
US2543327A (en) *	1947-03-18	1951-02-27	Kellogg M W Co	Preparation of reduced magnetite synthesis catalyst
US2593250A (en) *	1947-07-30	1952-04-15	Standard Oil Dev Co	Hydrocarbon synthesis
BE508220A (nl) *	1951-01-08
DE1156768B (de) *	1960-12-17	1963-11-07	Varta Ag	Verfahren zur Aktivierung metallischer Katalysatoren
US3776855A (en) *	1965-09-14	1973-12-04	Atomic Energy Commission	Hydriding process
US3967936A (en) *	1975-01-02	1976-07-06	The United States Of America As Represented By The United States Energy Research And Development Administration	Methanation process utilizing split cold gas recycle

1977
- 1977-05-16 US US05/797,294 patent/US4139551A/en not_active Expired - Lifetime
1978
- 1978-02-06 TR TR19844A patent/TR19844A/xx unknown
- 1978-02-13 BE BE2056680A patent/BE863888A/nl not_active IP Right Cessation
- 1978-02-13 CS CS78924A patent/CS215106B2/cs unknown
- 1978-02-14 ZA ZA00780854A patent/ZA78854B/xx unknown

Also Published As

Publication number	Publication date
TR19844A (tr)	1980-01-28
US4139551A (en)	1979-02-13
BE863888A (nl)	1978-05-29
ZA78854B (en)	1979-02-28

Publication	Publication Date	Title
Kikuchi et al.	1974	Steam reforming of hydrocarbons on noble metal catalysts (part 1) the catalytic activity in methane-steam reaction
EP0002575B1 (en)	1981-10-28	Method for preparing a high-activity supported nickel catalyst, and a catalyst thereby prepared
Onda et al.	2001	Preparation and catalytic properties of single-phase Ni–Sn intermetallic compound particles by CVD of Sn (CH3) 4 onto Ni/Silica
WO2014003817A1 (en)	2014-01-03	Method of forming a syngas mixture
Xu et al.	2001	Ultrafine NiO–La2O3–Al2O3 aerogel: a promising catalyst for CH4/CO2 reforming
CN109569704A (zh)	2019-04-05	一种用于合成气直接制备烯烃和芳烃的催化剂及其应用
Phillipson et al.	1969	The hydrogenation of alkadienes. Part III. The hydrogenation of buta-1, 3-diene catalysed by iron, cobalt, nickel, and copper
US4560816A (en)	1985-12-24	Catalyzed hydrogenation and dehydrogenation processes
Ishihara et al.	1992	Effect of alloying on CO hydrogenation activity over SiO2-supported Co Ni alloy catalysts
CS215106B2 (en)	1982-07-30	Method of making the methan and ev.ethan and other hydrocarbons
EP0692451A1 (en)	1996-01-17	A stable and active nickel catalyst for carbon dioxide reforming of methane to synthesis gas
Bridgewater et al.	1986	A comparison of Raney copper-zinc and coprecipitated copper-zinc-aluminium oxide methanol syntheses catalysts
EP0034403A1 (en)	1981-08-26	Method of making ammonia
CN109833910B (zh)	2022-05-31	一种用于合成氨反应的催化剂
SU1028244A3 (ru)	1983-07-07	Способ получени метана
JPS6012905B2 (ja)	1985-04-04	メタン化法
Nishimoto et al.	2002	Partial Oxidation of Methane to Synthesis Gas Over Ru-Loaded Y 2 O 3 Catalyst
Liu et al.	2002	Partial oxidation of methane over Ni/Ce-ZrO 2/θ-Al 2 O 3
GB1604924A (en)	1981-12-16	Synthesis of hydrocarbons and alcohols using an alloy catalyst
US4623532A (en)	1986-11-18	Catalysts for synthesis of ammonia
JPH04331704A (ja)	1992-11-19	一酸化炭素および水素を含有する合成ガスの製造方法
Psaro et al.	1991	The story of silica-supported Os 3 (CO) 12 a molecular approach to heterogeneous catalysis
Zadeh et al.	1999	Two-step homologation of methane on supported Co catalysts
Ferretti et al.	1998	Improvements in selectivity and stability of Rh catalysts modified by SnBu 4. dehydrogenation of isobutane to isobutene
EP0042309A1 (en)	1981-12-23	Method for the coproduction of hydrocarbons and alcohols