CS195708B2 - Oxidative catalyst for oxidation,ammoxidation and oxidehydrogenation - Google Patents
Oxidative catalyst for oxidation,ammoxidation and oxidehydrogenation Download PDFInfo
- Publication number
- CS195708B2 CS195708B2 CS755174A CS517475A CS195708B2 CS 195708 B2 CS195708 B2 CS 195708B2 CS 755174 A CS755174 A CS 755174A CS 517475 A CS517475 A CS 517475A CS 195708 B2 CS195708 B2 CS 195708B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- catalyst
- mixture
- tungsten
- oxidation
- catalysts
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 118
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 17
- 230000003647 oxidation Effects 0.000 title claims abstract description 15
- 230000001590 oxidative effect Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 27
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 20
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 13
- 239000010937 tungsten Substances 0.000 claims abstract description 13
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 11
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011651 chromium Chemical group 0.000 claims abstract description 10
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 8
- 239000010955 niobium Chemical group 0.000 claims abstract description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 8
- 239000011574 phosphorus Substances 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 7
- 239000010941 cobalt Substances 0.000 claims abstract description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 7
- 239000010949 copper Substances 0.000 claims abstract description 7
- 239000011777 magnesium Substances 0.000 claims abstract description 7
- 239000011135 tin Chemical group 0.000 claims abstract description 7
- 229910052718 tin Inorganic materials 0.000 claims abstract description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 6
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 6
- 239000011575 calcium Substances 0.000 claims abstract description 6
- 229910052738 indium Inorganic materials 0.000 claims abstract description 6
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical group [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 6
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052714 tellurium Inorganic materials 0.000 claims abstract description 6
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 239000011701 zinc Substances 0.000 claims abstract description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical group [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 5
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 5
- 229910052709 silver Inorganic materials 0.000 claims abstract description 5
- 239000004332 silver Chemical group 0.000 claims abstract description 5
- 229910052716 thallium Inorganic materials 0.000 claims abstract description 5
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims abstract description 5
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical group [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims abstract description 4
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical group [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052776 Thorium Inorganic materials 0.000 claims abstract description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 4
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical group [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 4
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 4
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims abstract description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 3
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 3
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical group [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052796 boron Inorganic materials 0.000 claims abstract description 3
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical group [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical group [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 40
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011593 sulfur Chemical group 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 abstract description 13
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 abstract description 5
- 150000001491 aromatic compounds Chemical class 0.000 abstract description 2
- 239000005864 Sulphur Chemical group 0.000 abstract 2
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 238000009738 saturating Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 26
- 239000000243 solution Substances 0.000 description 25
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 24
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 20
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 18
- 239000000725 suspension Substances 0.000 description 17
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 12
- 229910002651 NO3 Inorganic materials 0.000 description 11
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 11
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 10
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 10
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 10
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 10
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 9
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 8
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 8
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 7
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 7
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229940117975 chromium trioxide Drugs 0.000 description 5
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 5
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 235000010333 potassium nitrate Nutrition 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 125000000174 L-prolyl group Chemical group [H]N1C([H])([H])C([H])([H])C([H])([H])[C@@]1([H])C(*)=O 0.000 description 3
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 229910001960 metal nitrate Inorganic materials 0.000 description 3
- 239000004323 potassium nitrate Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Chemical compound [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 description 2
- -1 praseodyne Chemical compound 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 1
- 229910006111 GeCl2 Chemical group 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 101150004094 PRO2 gene Proteins 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910020169 SiOa Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910006213 ZrOCl2 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- IAQRGUVFOMOMEM-ARJAWSKDSA-N cis-but-2-ene Chemical compound C\C=C/C IAQRGUVFOMOMEM-ARJAWSKDSA-N 0.000 description 1
- PPNKDDZCLDMRHS-UHFFFAOYSA-N dinitrooxybismuthanyl nitrate Chemical compound [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 description 1
- 229940044658 gallium nitrate Drugs 0.000 description 1
- QHGIKMVOLGCZIP-UHFFFAOYSA-N germanium dichloride Chemical group Cl[Ge]Cl QHGIKMVOLGCZIP-UHFFFAOYSA-N 0.000 description 1
- PSCMQHVBLHHWTO-UHFFFAOYSA-K indium(iii) chloride Chemical compound Cl[In](Cl)Cl PSCMQHVBLHHWTO-UHFFFAOYSA-K 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000003112 potassium compounds Chemical group 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- SWLJJEFSPJCUBD-UHFFFAOYSA-N tellurium tetrachloride Chemical compound Cl[Te](Cl)(Cl)Cl SWLJJEFSPJCUBD-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- IPCAPQRVQMIMAN-UHFFFAOYSA-L zirconyl chloride Chemical compound Cl[Zr](Cl)=O IPCAPQRVQMIMAN-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US49053274A | 1974-07-22 | 1974-07-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
CS195708B2 true CS195708B2 (en) | 1980-02-29 |
Family
ID=23948462
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CS755174A CS195708B2 (en) | 1974-07-22 | 1975-07-22 | Oxidative catalyst for oxidation,ammoxidation and oxidehydrogenation |
Country Status (19)
Country | Link |
---|---|
JP (2) | JPS6036812B2 (fr) |
AT (1) | AT354408B (fr) |
BE (1) | BE831530A (fr) |
BR (1) | BR7504680A (fr) |
CA (1) | CA1075672A (fr) |
CH (1) | CH616861A5 (fr) |
CS (1) | CS195708B2 (fr) |
DD (1) | DD122065A5 (fr) |
DE (1) | DE2530959C2 (fr) |
EG (1) | EG12556A (fr) |
ES (1) | ES439592A1 (fr) |
FR (1) | FR2279465A1 (fr) |
GB (1) | GB1523772A (fr) |
IN (1) | IN144016B (fr) |
IT (1) | IT1039883B (fr) |
NL (1) | NL188016B (fr) |
NO (1) | NO145184C (fr) |
RO (1) | RO70128A (fr) |
YU (1) | YU37273B (fr) |
Families Citing this family (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL175175C (nl) * | 1970-10-30 | 1984-10-01 | Standard Oil Co Ohio | Werkwijze voor de omzetting van propeen en/of isobuteen met een moleculaire zuurstof bevattend gas en ammoniak in aanwezigheid van een katalysator. |
GB1523772A (en) * | 1974-07-22 | 1978-09-06 | Standard Oil Co | Oxidation catalysts |
JPS51113807A (en) * | 1975-03-31 | 1976-10-07 | Mitsubishi Rayon Co Ltd | Process for preparation of methacrolein and methacrylic acid and or 1, 3-butadiene |
JPS527904A (en) * | 1975-07-04 | 1977-01-21 | Mitsubishi Rayon Co Ltd | Process for preparation of methacrolein, methacrylic acid or 1,3-butad iene |
US4118419A (en) * | 1975-12-03 | 1978-10-03 | Mitsubishi Rayon Company, Ltd. | Catalytic process for the preparation of an unsaturated carboxylic acid |
JPS5353613A (en) * | 1976-10-26 | 1978-05-16 | Nippon Zeon Co Ltd | Preparation of methacrylic acid |
CA1133505A (fr) * | 1977-07-28 | 1982-10-12 | Andrew T. Guttmann | Methode d'oxydation de olefines |
IL55073A (en) * | 1977-07-28 | 1982-01-31 | Standard Oil Co | Catalysts for the oxidation and ammoxidation of olefins |
CA1127137A (fr) * | 1977-12-20 | 1982-07-06 | Dev D. Suresh | Ammoxydation d'olefines sur de nouveaux catalyseurs a l'antimonate |
JPS5416410A (en) * | 1978-06-26 | 1979-02-07 | Mitsubishi Rayon Co Ltd | Preparation of methacrolein, methacrylic acid and 1,3-butadiene |
JPS5416409A (en) * | 1978-06-26 | 1979-02-07 | Mitsubishi Rayon Co Ltd | Preparation of 1,3-futadiene |
JPS5517306A (en) * | 1978-07-20 | 1980-02-06 | Standard Oil Co | Olefin oxidation using catalyst containing various promoter elements |
JPS5538330A (en) * | 1978-09-13 | 1980-03-17 | Ube Ind Ltd | Preparation of acrylonitrile |
DE2841712A1 (de) * | 1978-09-25 | 1980-04-10 | Basf Ag | Verfahren zur herstellung von p- substituierten benzaldehyden |
JPS6122040A (ja) * | 1984-07-10 | 1986-01-30 | Mitsubishi Rayon Co Ltd | メタクロレイン及びメタクリル酸の製造法 |
JPS6338417A (ja) * | 1986-08-01 | 1988-02-19 | 松下電器産業株式会社 | 炊飯器 |
JPH04136537A (ja) * | 1990-09-26 | 1992-05-11 | Kobe Steel Ltd | 構造物の振動抑制装置 |
JPH04140530A (ja) * | 1990-09-28 | 1992-05-14 | Kobe Steel Ltd | 構造物の振動抑制装置 |
JPH04133043U (ja) * | 1991-06-03 | 1992-12-10 | 富士ポリマテツク株式会社 | バネ定数可変式動制振器 |
DE4200248A1 (de) * | 1992-01-08 | 1993-07-15 | Basf Ag | Verfahren zur regenerierung von metalloxid-katalysatoren |
JPH05302643A (ja) * | 1992-04-15 | 1993-11-16 | Kobe Steel Ltd | 住宅用床パネル |
CN1046499C (zh) * | 1994-06-22 | 1999-11-17 | 旭化成工业株式会社 | 制备异丁烯醛的方法 |
US6136998A (en) * | 1996-10-15 | 2000-10-24 | Mitsubishi Rayon Co., Ltd. | Retention of activity of molybdenum-containing metallic oxide catalyst |
FR2756499B1 (fr) * | 1996-12-03 | 1999-01-22 | Atochem Elf Sa | Systeme catalytique notamment pour l'oxydation menagee et selective des alcanes en alcenes et aldehydes insatures |
DE19957416A1 (de) * | 1999-11-29 | 2001-06-13 | Aventis Res & Tech Gmbh & Co | Verfahren zur katalytischen Herstellung von Halogenbenzaldehyden und Katalysatoren zur Durchführung des Verfahrens |
DE10137534A1 (de) | 2001-08-01 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung von Maleinsäureanhydrid |
JP4030740B2 (ja) | 2001-10-11 | 2008-01-09 | ダイヤニトリックス株式会社 | アンモ酸化用触媒の製造方法 |
JP4503444B2 (ja) * | 2004-02-05 | 2010-07-14 | ダイヤニトリックス株式会社 | アクリロニトリル製造用触媒、及びアクリロニトリルの製造方法 |
DE102007003076A1 (de) * | 2007-01-16 | 2008-07-17 | Basf Se | Verfahren zur Herstellung einer das Element Eisen in oxidischer Form enthaltenden Multielementoxidmasse |
JP2008267759A (ja) * | 2007-04-25 | 2008-11-06 | Dainichi Co Ltd | 加湿装置 |
KR20100017489A (ko) * | 2007-05-03 | 2010-02-16 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 촉매, 이의 제조 및 용도 |
WO2008137572A2 (fr) * | 2007-05-03 | 2008-11-13 | Shell Oil Company | Catalyseur, sa préparation et son utilisation |
JP2016502549A (ja) | 2012-12-06 | 2016-01-28 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | n−ブテン類からブタジエンへの酸化的脱水素化法 |
US9399606B2 (en) | 2012-12-06 | 2016-07-26 | Basf Se | Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene |
US10144681B2 (en) | 2013-01-15 | 2018-12-04 | Basf Se | Process for the oxidative dehydrogenation of N-butenes to butadiene |
KR20150105456A (ko) | 2013-01-15 | 2015-09-16 | 바스프 에스이 | 산화성 탈수소화를 통해 n-부텐으로부터 1,3-부타디엔을 제조하는 방법 |
EP2945921B1 (fr) | 2013-01-16 | 2017-03-22 | Basf Se | Procédé de préparation de butadiène par déshydrogénation oxydative de n-butènes, avec surveillance de la teneur en peroxyde lors de l'élaboration du produit |
EP3019458B1 (fr) | 2013-07-10 | 2017-04-05 | Basf Se | Procédé de déshydrogénation oxydative de n-butènes pour donner du butadiène |
JP6478996B2 (ja) | 2013-10-30 | 2019-03-06 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 酸化的脱水素反応によりn−ブテンから1,3−ブタジエンを製造するための方法 |
CN106103390A (zh) | 2014-01-13 | 2016-11-09 | 巴斯夫欧洲公司 | 启动用于正丁烯的氧化脱氢的反应器的方法 |
DE102014203725A1 (de) | 2014-02-28 | 2015-09-03 | Basf Se | Oxidationskatalysator mit sattelförmigem Trägerformkörper |
WO2016023892A1 (fr) | 2014-08-12 | 2016-02-18 | Basf Se | Procédé de production de 1,3-butadiène à partir de n-butène par déshydrogénation oxydative |
CN106795066A (zh) | 2014-09-26 | 2017-05-31 | 巴斯夫欧洲公司 | 由正丁烯通过氧化脱氢制备1,3‑丁二烯的方法 |
WO2016071268A1 (fr) | 2014-11-03 | 2016-05-12 | Basf Se | Procédé de préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation oxydative |
EA034435B1 (ru) | 2014-11-14 | 2020-02-07 | Басф Се | Способ получения 1,3-бутадиенов путем дегидрирования н-бутенов с получением потока вещества, содержащего бутаны и 2-бутены |
WO2016151008A1 (fr) | 2015-03-26 | 2016-09-29 | Basf Se | Procédé de préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation oxydative |
WO2016150940A1 (fr) | 2015-03-26 | 2016-09-29 | Basf Se | Procédé de préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation oxydative |
EP3274319A1 (fr) | 2015-03-26 | 2018-01-31 | Basf Se | Procédé de préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation oxydative |
WO2016151074A1 (fr) | 2015-03-26 | 2016-09-29 | Basf Se | Procédé de préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation oxydative |
KR20180101361A (ko) | 2015-12-03 | 2018-09-12 | 바스프 에스이 | n-부텐의 산화성 탈수소화에 의해 부타디엔을 제조하는 방법 |
EP3402769B1 (fr) | 2016-01-13 | 2020-03-25 | Basf Se | Procede de fabrication de 1,3-butadiene a partir de n-butenes par deshydratation oxydante |
JP2019508401A (ja) | 2016-02-04 | 2019-03-28 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 酸化的脱水素化によるn−ブテンからの1,3−ブタジエンの製造方法 |
CN109843836A (zh) | 2016-08-09 | 2019-06-04 | 巴斯夫欧洲公司 | 启动用于正丁烯的氧化脱氢的反应器的方法 |
WO2018095776A1 (fr) | 2016-11-22 | 2018-05-31 | Basf Se | Procédé pour la préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation par oxydation comprenant un lavage aqueux du flux gazeux produit en c4 |
WO2018095856A1 (fr) | 2016-11-22 | 2018-05-31 | Basf Se | Procédé pour la préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation oxydante comprenant une séparation de méthacroléine lors du traitement |
WO2018095840A1 (fr) | 2016-11-22 | 2018-05-31 | Basf Se | Procédé pour la préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation oxydante comprenant une séparation de furanne lors du traitement |
EP3323797A1 (fr) | 2016-11-22 | 2018-05-23 | Basf Se | Procédé de fabrication de 1,3-butadiène à partir de n-butènes par déshydrogénation oxydante comprenant un lavage acide de flux de produit gazeux c4 |
WO2018219996A1 (fr) | 2017-06-02 | 2018-12-06 | Basf Se | Procédé pour la préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation oxydative par recyclage de gaz avec un gaz de recyclage enrichi en co2 |
WO2018234158A1 (fr) | 2017-06-19 | 2018-12-27 | Basf Se | Procédé pour la préparation de 1,3-butadiène à partir de n-butènes par déshydrogénation par oxydation comprenant un lavage du flux gazeux produit en c4 |
Family Cites Families (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS481645Y1 (fr) | 1968-07-25 | 1973-01-17 | ||
US3761424A (en) * | 1968-08-31 | 1973-09-25 | Degussa | Catalysts for the oxidation of alkenes |
US3642930A (en) * | 1968-12-30 | 1972-02-15 | Standard Oil Co Ohio | Process for the manufacture of isoprene from isoamylenes and methyl butanols and catalyst therefor |
DE2000425A1 (de) * | 1969-01-11 | 1970-07-16 | Toa Gosei Chem Ind | Verfahren zur Oxydation von Olefinen |
DE2125032C3 (de) | 1970-05-26 | 1979-11-22 | Nippon Catalytic Chem Ind | Verfahren zur Herstellung von (Meth) Acrolein neben geringen Mengen (Meth) Acrylsäure |
NL158483B (nl) * | 1970-05-29 | 1978-11-15 | Sumitomo Chemical Co | Werkwijze voor het bereiden van acrylonitrile uit propeen. |
US3928462A (en) * | 1970-07-08 | 1975-12-23 | Sumitomo Chemical Co | Catalytic process for the preparation of methacrolein |
NL175175C (nl) * | 1970-10-30 | 1984-10-01 | Standard Oil Co Ohio | Werkwijze voor de omzetting van propeen en/of isobuteen met een moleculaire zuurstof bevattend gas en ammoniak in aanwezigheid van een katalysator. |
US3801670A (en) * | 1970-12-25 | 1974-04-02 | Sumitomo Chemical Co | Catalytic process for the production of diolefins |
DE2161471C3 (de) * | 1970-12-26 | 1982-05-13 | Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka | Verfahren zur Herstellung von Acrolein und Acrylsäure |
SU441701A3 (ru) * | 1970-12-29 | 1974-08-30 | Мицубиси Петрокемикал Компани Лимитед (Фирма) | Способ получения акролеина |
JPS5112603B1 (fr) * | 1971-05-26 | 1976-04-21 | ||
US3839227A (en) * | 1971-06-02 | 1974-10-01 | Rohm & Haas | Novel catalyst for methacrolein production |
JPS5111603B1 (fr) * | 1971-06-14 | 1976-04-13 | ||
US3786000A (en) * | 1972-01-06 | 1974-01-15 | Rohm & Haas | Catalyst for the production of acrolein and acrylic acid |
JPS5310573B2 (fr) | 1972-02-15 | 1978-04-14 | ||
DE2308782C2 (de) * | 1972-02-22 | 1982-11-11 | Asahi Glass Co. Ltd., Tokyo | Verfahren zur Herstellung von Acrolein oder Methacrolein |
GB1426303A (en) * | 1972-08-25 | 1976-02-25 | Ube Industries | Catalyst and process for oxidation of ammoxidation of olefin mixtures |
DE2249922C2 (de) | 1972-10-12 | 1982-05-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur katalytischen Oxidation von Propylen oder Isobutylen zu Acrolein oder Methacrolein in der Gasphase mit molekularem Sauerstoff |
FR2208399A5 (fr) * | 1972-11-27 | 1974-06-21 | Ugine Kuhlmann | |
CA1049553A (fr) * | 1973-04-30 | 1979-02-27 | The Standard Oil Company | Synthese d'acide acrylique ou methacrylique a partir de propylene ou d'isobutylene |
NL171440C (nl) * | 1973-05-10 | 1983-04-05 | Japan Synthetic Rubber Co Ltd | Werkwijze voor het bereiden van methacroleien door katalytische oxydatie van isobuteen. |
DE2424934A1 (de) * | 1973-06-04 | 1975-01-02 | Standard Oil Co Ohio | Verfahren zur katalytischen herstellung ungesaettigter nitrile |
US3972920A (en) * | 1973-06-11 | 1976-08-03 | Mitsubishi Rayon Co., Ltd. | Process for producing unsaturated aldehydes, unsaturated fatty acids or conjugated dienes |
US3883573A (en) * | 1973-06-15 | 1975-05-13 | Standard Oil Co | Commercial fixed-bed acrylonitrile or methacrylonitrile |
CH569926A5 (fr) * | 1973-06-15 | 1975-11-28 | Bartolomeis Spa Forni Ed Impia | |
GB1467865A (en) * | 1973-07-27 | 1977-03-23 | Basf Ag | Catalytic oxidation or ammoxidation of a-olefins to alpha,beta- olefinically unsaturated aldehydes acids or nitriles |
GB1483097A (en) * | 1973-08-29 | 1977-08-17 | Mitsubishi Rayon Co | Method for vapour-phase catalytic oxidation of tert-butyl alcohol |
US3932551A (en) * | 1973-10-12 | 1976-01-13 | The Standard Oil Company | Process for the preparation of diolefins from olefins |
JPS5245692B2 (fr) * | 1973-10-16 | 1977-11-17 | ||
DE2516966A1 (de) * | 1974-04-19 | 1975-10-30 | Mitsubishi Chem Ind | Katalysator und verfahren zur herstellung von maleinsaeureanhydrid |
JPS5432766B2 (fr) * | 1974-06-04 | 1979-10-16 | ||
GB1523772A (en) * | 1974-07-22 | 1978-09-06 | Standard Oil Co | Oxidation catalysts |
US4001317A (en) * | 1974-07-22 | 1977-01-04 | Standard Oil Company | Process for the oxidation of olefins using catalysts containing various promoter elements |
GB1489559A (en) * | 1975-03-03 | 1977-10-19 | Mitsubishi Rayon Co | Catalytic process for the preparation of acrylic acid or methacrylic acid |
US4075232A (en) * | 1975-03-06 | 1978-02-21 | The Standard Oil Company | Preparation of maleic anhydride from n-butene in a one-reactor, fluid-bed system using two different catalysts |
GB1490683A (en) * | 1975-03-12 | 1977-11-02 | Mitsubishi Rayon Co | Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene |
GB1513335A (en) * | 1975-03-17 | 1978-06-07 | Mitsubishi Rayon Co | Process and a catalyst for the preparation of unsaturated carboxylic acid |
IN142430B (fr) * | 1975-04-21 | 1977-07-09 | Standard Oil Co | |
DE3315745C2 (de) * | 1983-04-30 | 1986-11-27 | Schott Glaswerke, 6500 Mainz | Kochfeld mit gasbeheizten Brennern und einer durchgehenden Kochfläche aus Glaskeramik oder vergleichbarem Material |
-
1975
- 1975-07-08 GB GB28688/75A patent/GB1523772A/en not_active Expired
- 1975-07-11 DE DE2530959A patent/DE2530959C2/de not_active Expired
- 1975-07-11 IN IN1358/CAL/75A patent/IN144016B/en unknown
- 1975-07-15 AT AT544975A patent/AT354408B/de not_active IP Right Cessation
- 1975-07-15 DD DD187311A patent/DD122065A5/xx unknown
- 1975-07-16 CA CA231,620A patent/CA1075672A/fr not_active Expired
- 1975-07-17 IT IT25502/75A patent/IT1039883B/it active
- 1975-07-18 NL NLAANVRAGE7508637,A patent/NL188016B/xx active IP Right Review Request
- 1975-07-18 BE BE158437A patent/BE831530A/fr not_active IP Right Cessation
- 1975-07-18 NO NO752572A patent/NO145184C/no unknown
- 1975-07-21 CH CH952175A patent/CH616861A5/de not_active IP Right Cessation
- 1975-07-21 EG EG432/75A patent/EG12556A/xx active
- 1975-07-21 RO RO7582908A patent/RO70128A/fr unknown
- 1975-07-21 ES ES439592A patent/ES439592A1/es not_active Expired
- 1975-07-21 FR FR7522659A patent/FR2279465A1/fr active Granted
- 1975-07-22 BR BR7504680*A patent/BR7504680A/pt unknown
- 1975-07-22 YU YU1863/75A patent/YU37273B/xx unknown
- 1975-07-22 JP JP50089599A patent/JPS6036812B2/ja not_active Expired
- 1975-07-22 CS CS755174A patent/CS195708B2/cs unknown
-
1985
- 1985-04-25 JP JP60089889A patent/JPS6118435A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
DD122065A5 (fr) | 1976-09-12 |
NL188016B (nl) | 1991-10-16 |
JPS6036812B2 (ja) | 1985-08-22 |
ATA544975A (de) | 1979-06-15 |
RO70128A (fr) | 1982-10-11 |
AT354408B (de) | 1979-01-10 |
NO145184C (no) | 1982-02-03 |
NL7508637A (nl) | 1976-01-26 |
BR7504680A (pt) | 1976-07-06 |
ES439592A1 (es) | 1977-06-01 |
CH616861A5 (en) | 1980-04-30 |
YU186375A (en) | 1983-04-27 |
JPS6118435A (ja) | 1986-01-27 |
IN144016B (fr) | 1978-03-11 |
YU37273B (en) | 1984-08-31 |
DE2530959A1 (de) | 1976-02-05 |
FR2279465B1 (fr) | 1981-08-28 |
DE2530959C2 (de) | 1986-03-20 |
FR2279465A1 (fr) | 1976-02-20 |
IT1039883B (it) | 1979-12-10 |
NO752572L (fr) | 1976-01-23 |
CA1075672A (fr) | 1980-04-15 |
NO145184B (no) | 1981-10-26 |
JPS5140391A (fr) | 1976-04-05 |
EG12556A (en) | 1979-09-30 |
JPS6242654B2 (fr) | 1987-09-09 |
BE831530A (fr) | 1975-11-17 |
GB1523772A (en) | 1978-09-06 |
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