CO6710898A2 - Phosphine ligands for catalytic rations - Google Patents
Phosphine ligands for catalytic rationsInfo
- Publication number
- CO6710898A2 CO6710898A2 CO13029369A CO13029369A CO6710898A2 CO 6710898 A2 CO6710898 A2 CO 6710898A2 CO 13029369 A CO13029369 A CO 13029369A CO 13029369 A CO13029369 A CO 13029369A CO 6710898 A2 CO6710898 A2 CO 6710898A2
- Authority
- CO
- Colombia
- Prior art keywords
- formula
- disclosure
- ligand
- reaction
- directed
- Prior art date
Links
- 239000003446 ligand Substances 0.000 title abstract 7
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
Classifications
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
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- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
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- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
- B01J31/2423—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member comprising aliphatic or saturated rings
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- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
- B01J31/2466—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring comprising aliphatic or saturated rings
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- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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- B01J31/248—Bridged ring systems, e.g. 9-phosphabicyclononane
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- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
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Abstract
La divulgación está dirigida a ligandos fosfaciclos para sistemas catalizadores con metales de transición que incluyen aquellos representados por la fórmula general I,o sales de estos.La divulgación se refiere a composiciones catalizadoras que comprenden un ligando de fórmula (I) y uno o más compuestos de metales de transición.La divulgación se refiere a composiciones catalizadoras que comprenden un ligando de fórmula (I) unidos de manera covalente a un soporte catalizador sólido.La divulgación está dirigida a métodos para producir una reacción formadora de unión que comprende catalizar la reacción con un ligando de formula (I).La divulgación está dirigida a métodos para formar una unión en una reacción química que comprende catalizar la reacción con un ligando de formula (I).La divulgación se refiere a métodos para preparar ligandos fosfaciclos de formula (I).The disclosure is directed to phosphacyl ligands for transition metal catalyst systems that include those represented by the general formula I, or salts thereof.The disclosure refers to catalyst compositions comprising a ligand of formula (I) and one or more compounds of transition metals. The disclosure refers to catalyst compositions comprising a ligand of formula (I) covalently bound to a solid catalyst support. The disclosure is directed to methods for producing a binding-forming reaction comprising catalyzing the reaction with a ligand of formula (I). The disclosure is directed to methods for forming a linkage in a chemical reaction comprising catalyzing the reaction with a ligand of formula (I). The disclosure relates to methods for preparing phosphacyl ligands of formula (I ).
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US36529310P | 2010-07-16 | 2010-07-16 |
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AU2014280934B2 (en) * | 2010-07-16 | 2017-03-16 | Abbvie Ireland Unlimited Company | Phosphine ligands for catalytic reactions |
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EP3461556A1 (en) * | 2010-07-16 | 2019-04-03 | AbbVie Ireland Unlimited Company | Phosphine ligands for catalytic reactions |
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KR102582223B1 (en) * | 2021-07-23 | 2023-09-25 | 한국화학연구원 | Ag catalyst for carboxylation of aromatic compounds and method for producing aromatic carboxylic acid using same |
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