CO6341529A2 - Composicion fungicida y metodo para el control de las enfermedades de las plantas - Google Patents
Composicion fungicida y metodo para el control de las enfermedades de las plantasInfo
- Publication number
- CO6341529A2 CO6341529A2 CO10163909A CO10163909A CO6341529A2 CO 6341529 A2 CO6341529 A2 CO 6341529A2 CO 10163909 A CO10163909 A CO 10163909A CO 10163909 A CO10163909 A CO 10163909A CO 6341529 A2 CO6341529 A2 CO 6341529A2
- Authority
- CO
- Colombia
- Prior art keywords
- group
- plant diseases
- alkoxy group
- halogen atom
- alkoxy
- Prior art date
Links
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/48—Nitro-carboxylic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Proporcionar una composición fungicida que tenga efectos altamente fungicidas y estables frente a cosechas cultivadas infectadas con enfermedades de plantas que resultan de las enfermedades de las plantas.Una composición fungicida que contiene, como ingredientes activos, (a) un derivado de benzoilpiridina representado por la fórmula (I) o su sal: donde cuando A es -N=, B es -CX4=; cuando A es -CH=, B es -N=; cada uno de X1 y X2 los cuales son independientes entre sí, es un átomo de halógeno, un grupo alcoxi, un grupo hidroxilo, un grupo alquilo, un grupo CF3 o un grupo alquiltio; X3 es un átomo de hidrógeno, un átomo de halógeno, un grupo alcoxi, un grupo alquilo, un grupo CF3 o un grupo alquiltio; X4 es un átomo de hidrógeno, un átomo de halógeno, un grupo alcoxi, un grupo alquilo, un grupo CF3 o un grupo alquiltio; R1 es un grupo alquilo; R2' es un grupo alcoxi; p es 0, 1 o 2; y cada uno de R2" y R2'" es un grupo alcoxi, y (b) al menos un fungicida adicional.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008174963 | 2008-07-03 | ||
JP2008292511 | 2008-11-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
CO6341529A2 true CO6341529A2 (es) | 2011-11-21 |
Family
ID=41466400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CO10163909A CO6341529A2 (es) | 2008-07-03 | 2010-12-29 | Composicion fungicida y metodo para el control de las enfermedades de las plantas |
Country Status (27)
Country | Link |
---|---|
US (3) | US8962661B2 (es) |
EP (2) | EP2323487B1 (es) |
JP (1) | JP5449887B2 (es) |
KR (1) | KR20110025676A (es) |
CN (3) | CN105994322B (es) |
AR (1) | AR072464A1 (es) |
AU (1) | AU2009266746B2 (es) |
BR (2) | BR122017002275B1 (es) |
CA (5) | CA2923126C (es) |
CL (3) | CL2010001565A1 (es) |
CO (1) | CO6341529A2 (es) |
CY (1) | CY1115930T1 (es) |
DK (1) | DK2323487T3 (es) |
EC (1) | ECSP10010726A (es) |
ES (1) | ES2526555T3 (es) |
HR (1) | HRP20150052T1 (es) |
MA (1) | MA32428B1 (es) |
MX (4) | MX344105B (es) |
NZ (2) | NZ603490A (es) |
PH (2) | PH12014502690B1 (es) |
PL (1) | PL2323487T3 (es) |
PT (1) | PT2323487E (es) |
RS (1) | RS53759B1 (es) |
RU (1) | RU2507746C2 (es) |
SI (1) | SI2323487T1 (es) |
TW (2) | TWI547239B (es) |
WO (1) | WO2010002026A2 (es) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012077077A1 (en) * | 2010-12-08 | 2012-06-14 | Basf Se | Fungicidal mixtures |
JP5940368B2 (ja) | 2011-05-24 | 2016-06-29 | 石原産業株式会社 | 殺菌剤組成物及び植物病害の防除方法 |
JP5940369B2 (ja) | 2011-05-27 | 2016-06-29 | 石原産業株式会社 | 植物病害の防除方法 |
JP6013032B2 (ja) | 2011-07-08 | 2016-10-25 | 石原産業株式会社 | 殺菌剤組成物及び植物病害の防除方法 |
US10660335B2 (en) * | 2011-12-22 | 2020-05-26 | Sds Biotech K.K. | Plant disease control agent |
JP2014015449A (ja) | 2012-06-13 | 2014-01-30 | Ishihara Sangyo Kaisha Ltd | 殺菌剤組成物及び植物病害の防除方法 |
TWI511667B (zh) * | 2013-01-30 | 2015-12-11 | Meiji Seika Pharma Co Ltd | Waterborne Suspension Pesticide Composition |
CN105076137A (zh) * | 2014-05-21 | 2015-11-25 | 深圳诺普信农化股份有限公司 | 一种杀菌组合物 |
CN105076143A (zh) * | 2014-05-21 | 2015-11-25 | 深圳诺普信农化股份有限公司 | 杀菌组合物 |
CN104025954A (zh) * | 2014-06-20 | 2014-09-10 | 广西壮族自治区农业科学院蔬菜研究所 | 一种预防和治疗厚皮甜瓜蔓枯病的生物方法 |
US10172357B2 (en) | 2015-05-29 | 2019-01-08 | Ishihara Sangyo Kaisha, Ltd. | Fungicidal composition and method for controlling plant diseases |
CN105165828B (zh) * | 2015-10-28 | 2017-05-10 | 陕西上格之路生物科学有限公司 | 一种含苯菌酮和硝苯菌酯的杀菌组合物 |
RU2680309C1 (ru) * | 2018-02-13 | 2019-02-19 | Андрей Васильевич Кудряшов | Средство для защиты растений "Агройод" |
CN108174856A (zh) * | 2018-02-28 | 2018-06-19 | 佛山市海力盈生物科技有限公司 | 一种含Pyriofenone和苯醚甲环唑的农药组合物 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69618370T2 (de) * | 1995-04-11 | 2002-09-26 | Mitsui Chemicals Inc | Substituierte Thiophenderivate und diese als aktiver Bestandteil enthaltenden Fungizide für Land- und Gartenbauwirtschaft |
TWI252231B (en) * | 1997-04-14 | 2006-04-01 | American Cyanamid Co | Fungicidal trifluorophenyl-triazolopyrimidines |
TW521072B (en) | 1997-06-02 | 2003-02-21 | Meiji Seika Kaisha | 4-quinolinol derivatives and fungicides containing the same as an active ingredient used for agriculture and horticulture |
AR029289A1 (es) * | 2000-07-05 | 2003-06-18 | Ishihara Sangyo Kaisha | Derivado de benzoilpiridina o su sal, fungicida que lo contiene como un ingrediente activo, su proceso de produccion e intermediario para producirlo |
RU2255088C2 (ru) * | 2001-02-09 | 2005-06-27 | Исихара Сангио Кайся, Лтд. | Производное бензоилпиридина или его соль, содержащий его в качестве активного ингредиента фунгицид, способы его получения и промежуточные соединения для его получения |
JP4373054B2 (ja) * | 2002-07-02 | 2009-11-25 | 三井化学アグロ株式会社 | 水性懸濁農薬組成物 |
US20060089390A1 (en) * | 2002-10-31 | 2006-04-27 | Ishihara Sangyo Kaisha, Ltd. | 3-benzoyl-2,4,5-substituted pyridine derivatives or salts thereof and bactericides containing the same |
CN100581362C (zh) * | 2003-10-31 | 2010-01-20 | 石原产业株式会社 | 杀菌剂组合物和植物病害的防除方法 |
DK1679003T3 (en) | 2003-10-31 | 2015-05-11 | Ishihara Sangyo Kaisha | BACTERICID COMPOSITION AND PROCEDURE FOR COMBATING PLANT DISEASE |
JP4918215B2 (ja) * | 2003-10-31 | 2012-04-18 | 石原産業株式会社 | 殺菌剤組成物及び植物病害の防除方法 |
WO2005112642A1 (de) | 2004-05-07 | 2005-12-01 | Basf Aktiengesellschaft | Fungizide mischungen zur bekämpfung von reispathogenen |
GB0422400D0 (en) * | 2004-10-08 | 2004-11-10 | Syngenta Participations Ag | Fungicidal compositions |
NZ573695A (en) * | 2006-07-05 | 2011-12-22 | Ishihara Sangyo Kaisha | Fungicidal composition and method for controlling plant disease |
DE102006055477A1 (de) * | 2006-11-24 | 2008-05-29 | Bayer Cropscience Ag | Pflanzenschutzgranulate zur Applikation auf die Blattoberfläche |
CL2008000512A1 (es) * | 2007-02-22 | 2008-08-29 | Bayer Cropscience Sa | Compuestos derivados de n-(3-fenilpropil)carboxamida; procedimiento de preparacion de dichos compuestos; composicion fungicida; y metodo para combatir de forma preventiva o curativa los hongos fitopatogenos de cultivos. |
JP6013032B2 (ja) | 2011-07-08 | 2016-10-25 | 石原産業株式会社 | 殺菌剤組成物及び植物病害の防除方法 |
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2009
- 2009-06-30 ES ES09773604.5T patent/ES2526555T3/es active Active
- 2009-06-30 NZ NZ603490A patent/NZ603490A/en unknown
- 2009-06-30 RU RU2011103772/13A patent/RU2507746C2/ru active
- 2009-06-30 BR BR122017002275-0A patent/BR122017002275B1/pt active IP Right Grant
- 2009-06-30 BR BRPI0915594-5A patent/BRPI0915594B1/pt active IP Right Grant
- 2009-06-30 MX MX2013008267A patent/MX344105B/es unknown
- 2009-06-30 CA CA2923126A patent/CA2923126C/en active Active
- 2009-06-30 DK DK09773604.5T patent/DK2323487T3/en active
- 2009-06-30 EP EP09773604.5A patent/EP2323487B1/en active Active
- 2009-06-30 RS RS20150036A patent/RS53759B1/en unknown
- 2009-06-30 CA CA3171691A patent/CA3171691A1/en active Pending
- 2009-06-30 AU AU2009266746A patent/AU2009266746B2/en active Active
- 2009-06-30 NZ NZ590218A patent/NZ590218A/xx unknown
- 2009-06-30 MX MX2010014502A patent/MX2010014502A/es active IP Right Grant
- 2009-06-30 PT PT97736045T patent/PT2323487E/pt unknown
- 2009-06-30 SI SI200931134T patent/SI2323487T1/sl unknown
- 2009-06-30 WO PCT/JP2009/062259 patent/WO2010002026A2/en active Application Filing
- 2009-06-30 MX MX2016015994A patent/MX368023B/es unknown
- 2009-06-30 PL PL09773604T patent/PL2323487T3/pl unknown
- 2009-06-30 CA CA2995175A patent/CA2995175C/en active Active
- 2009-06-30 CA CA2729618A patent/CA2729618C/en active Active
- 2009-06-30 CN CN201610356467.9A patent/CN105994322B/zh active Active
- 2009-06-30 EP EP12005174A patent/EP2529627A1/en not_active Withdrawn
- 2009-06-30 JP JP2009155522A patent/JP5449887B2/ja active Active
- 2009-06-30 KR KR1020107029867A patent/KR20110025676A/ko not_active Application Discontinuation
- 2009-06-30 CN CN200980125689.8A patent/CN102083317B/zh active Active
- 2009-06-30 CA CA3105364A patent/CA3105364C/en active Active
- 2009-06-30 US US13/002,361 patent/US8962661B2/en active Active
- 2009-06-30 CN CN201310632181.5A patent/CN103636636B/zh active Active
- 2009-07-01 TW TW104116041A patent/TWI547239B/zh active
- 2009-07-01 TW TW098122281A patent/TWI495432B/zh active
- 2009-07-02 AR ARP090102472A patent/AR072464A1/es active IP Right Grant
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2010
- 2010-12-21 MX MX2019010860A patent/MX2019010860A/es unknown
- 2010-12-23 CL CL2010001565A patent/CL2010001565A1/es unknown
- 2010-12-29 EC EC2010010726A patent/ECSP10010726A/es unknown
- 2010-12-29 CO CO10163909A patent/CO6341529A2/es not_active Application Discontinuation
- 2010-12-31 MA MA33476A patent/MA32428B1/fr unknown
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2014
- 2014-12-02 PH PH12014502690A patent/PH12014502690B1/en unknown
- 2014-12-16 US US14/572,237 patent/US9474281B2/en active Active
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2015
- 2015-01-05 CY CY20151100005T patent/CY1115930T1/el unknown
- 2015-01-15 HR HRP20150052AT patent/HRP20150052T1/hr unknown
- 2015-02-25 CL CL2015000462A patent/CL2015000462A1/es unknown
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2016
- 2016-08-15 US US15/237,194 patent/US10136643B2/en active Active
- 2016-11-08 CL CL2016002833A patent/CL2016002833A1/es unknown
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2019
- 2019-09-09 PH PH12019502042A patent/PH12019502042A1/en unknown
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