CO4900002A1 - Compuestos de n-(triazoloazinil) arilsulfonamida . - Google Patents
Compuestos de n-(triazoloazinil) arilsulfonamida .Info
- Publication number
- CO4900002A1 CO4900002A1 CO97055758A CO97055758A CO4900002A1 CO 4900002 A1 CO4900002 A1 CO 4900002A1 CO 97055758 A CO97055758 A CO 97055758A CO 97055758 A CO97055758 A CO 97055758A CO 4900002 A1 CO4900002 A1 CO 4900002A1
- Authority
- CO
- Colombia
- Prior art keywords
- alkyl
- alkynyl
- alkenyl
- optionally substituted
- fluorine atoms
- Prior art date
Links
- -1 SULFONAMIDE COMPOUNDS Chemical class 0.000 title abstract 4
- 229940124530 sulfonamide Drugs 0.000 title 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 abstract 14
- 229910052794 bromium Inorganic materials 0.000 abstract 9
- 229910052801 chlorine Inorganic materials 0.000 abstract 9
- 239000000460 chlorine Substances 0.000 abstract 9
- 125000003342 alkenyl group Chemical group 0.000 abstract 7
- 125000000304 alkynyl group Chemical group 0.000 abstract 7
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 6
- 229910052731 fluorine Inorganic materials 0.000 abstract 6
- 125000001153 fluoro group Chemical group F* 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 229910052740 iodine Inorganic materials 0.000 abstract 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 3
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 2
- JNCMHMUGTWEVOZ-UHFFFAOYSA-N F[CH]F Chemical compound F[CH]F JNCMHMUGTWEVOZ-UHFFFAOYSA-N 0.000 abstract 1
- 108010081348 HRT1 protein Hairy Proteins 0.000 abstract 1
- 102100021881 Hairy/enhancer-of-split related with YRPW motif protein 1 Human genes 0.000 abstract 1
- 239000012634 fragment Substances 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
- C07D487/04—Ortho-condensed systems
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
- C07D333/62—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
- C07D333/66—Nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Abstract
Un compuesto de N-(triazolazinil)arilsulfonamida de la fórmula: en donde X representa N o C-Y; W representa O(alquilo C1 -C3 ), Cl, Br, F ó H; Y representa H, OCH3, F, Cl, Br, I, o CH3 opcionalmente substituido con hasta tres átomos de flúor, Z representa O(alquilo C1 -C3 ), H, F, Cl, Br, I, S(C1 -C3 alquilo), o CH3 opcionalmente substituido con hasta tres átomos de flúor; con la condición de que al menos uno de W y Z representa O(alquilo C1 -C3 ); Q representa C-H o N; A representa F, Cl, Br, o I, o CO2 (alquilo C1 -C4 ) o representa alquilo C1 -C3 , O(alquilo C3 -C4 ), O(alquenilo C3 -C4 ), O(alquinilo C3 -C4 ), o S(alquilo C1 -C3 ) substituido opcionalmente con uno de O(alquilo C1 -C3 ), S(alquilo C1 -C3 ), cloro, bromo, o substituyente ciano o con hasta el número máximo posible de átomos de flúor, o representa una porción 2-metil-1,3-dioxolan-2-il, y, cuando Q representa N, H; B representa H, F, Cl, Br, I, NO2 , CN, CO2 (C1 - C4 alquilo), NH(alquilo C1 -C3 ), N(alquilo C1 - C3 )2 o representa O(alquilo C1 -C4 ), O(alquenilo C3 -C4 ), O(alquinilo C3 -C4 ), alquilo C3 -C4 , S(alquilo C3 - C4 ), SO(alquilo C1 -C3 ), SO2 (alquilo C1 -C3 ), S(alquenilo C3 -C4 ), SO(C3 -C4 alquenilo), SO2 (alquenilo C3 -C4 ), S(alquinilo C3 -C4 ), SO(alquinilo C3 -C4 ), o SO2 (alquinilo C3 -C4 ) substituido opcionalmente con uno de O(alquilo C1 - C3 ), S(alquilo C1 -C3 ), cloro, bromo, o sustituyente ciano o con hasta un número máximo posible de átomos de flúor, con la condición de que A y B no representen simultáneamente H:D representa H, F, Cl, Br, I, alquilo C1 -C3 , o CH3 OC2 H5 , CH2 F, CHF2 , o CF3 ; o B y D representan en conjunto un fragmento de la fórmula O-CH2 -O, opcionalmente sustituido con uno o dos F o CH3; T representa H, SO2 R, C(O)R, C(O)OR, C(O)NR´2 , o CH2 CH2 C(O)OR;R representa alquilo C1 -C4 , alquenilo C3 -C4 , o alquinilo C3 -C4 cada uno poseyendo opcionalmente hasta dos cloro, bromo, O(C1 -C4 )alquilo, o fenilo sustituyentes y hasta un número máximo posible de sustituyentes fluoro; y R´ representa H, alquilo C1 -C4 alquenilo C3 -C4 , o alquinilo C3 -C4 ; y cuanto T representa H, la sal aceptable para la agricultura de la misma.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2655696P | 1996-09-24 | 1996-09-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
CO4900002A1 true CO4900002A1 (es) | 2000-03-27 |
Family
ID=21832490
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CO97055758A CO4900002A1 (es) | 1996-09-24 | 1997-09-24 | Compuestos de n-(triazoloazinil) arilsulfonamida . |
Country Status (23)
Country | Link |
---|---|
US (5) | US5858924A (es) |
EP (1) | EP0877745B1 (es) |
JP (2) | JP4215824B2 (es) |
KR (1) | KR100488277B1 (es) |
CN (2) | CN1092195C (es) |
AR (1) | AR012020A1 (es) |
AU (1) | AU723666B2 (es) |
BG (1) | BG63123B1 (es) |
BR (1) | BR9706774B1 (es) |
CA (1) | CA2238316C (es) |
CO (1) | CO4900002A1 (es) |
CZ (1) | CZ297521B6 (es) |
DE (2) | DE122009000052I2 (es) |
DK (1) | DK0877745T3 (es) |
EA (1) | EA001064B1 (es) |
ES (1) | ES2158513T3 (es) |
FR (1) | FR08C0037I2 (es) |
GR (1) | GR3036961T3 (es) |
HU (2) | HU229886B1 (es) |
PL (1) | PL190282B1 (es) |
TR (1) | TR199800906T1 (es) |
UA (1) | UA59350C2 (es) |
WO (1) | WO1998013367A1 (es) |
Families Citing this family (71)
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DE19525162A1 (de) | 1995-07-11 | 1997-01-16 | Bayer Ag | Sulfonylamino(thio)carbonylverbindungen |
JP2001233718A (ja) * | 2000-02-22 | 2001-08-28 | Dow Chem Japan Ltd | 除草剤組成物 |
TWI287547B (en) * | 2000-06-14 | 2007-10-01 | Dow Agrosciences Llc | Process for the selective deprotonation and functionalization of 3-substituted benzotrifluorides |
BR0111993A (pt) | 2000-06-16 | 2003-04-01 | Dow Agrosciences Llc | Processo para preparação de 2-amino-5,8dimetóxi [1,2,4] triazolo [1,5-c] pirimidina |
DE60103416T2 (de) * | 2000-09-26 | 2004-10-14 | Dow Agrosciences Llc, Indianapolis | VErfahren zur Herstellung von 2-Alkoxy-6-Trifluoromethyl-N-([1,2,4]Triazolo[1,5-C]Pyrimidin-2-YL)Benzolsulfonamiden |
JP3911236B2 (ja) | 2000-11-03 | 2007-05-09 | ダウ・アグロサイエンス・エル・エル・シー | N−(5,7−ジメトキシ[1,2,4]トリアゾロ[1,5−a]ピリミジン−2−イル)アリールスルホンアミド化合物及び除草剤としてのそれらの使用 |
KR20040004427A (ko) | 2000-11-03 | 2004-01-13 | 다우 아그로사이언시즈 엘엘씨 | 제초제로서의 ν-([1,2,4]트리아졸로아지닐)티오펜설폰아미드 화합물 |
DE10063116A1 (de) * | 2000-12-18 | 2002-06-20 | Bayer Ag | Azinylsulfonylimidazole |
AU2002309825A1 (en) * | 2001-05-14 | 2002-11-25 | Prismedical Corporation | Powered sterile solution device |
AU2002358028A1 (en) * | 2001-11-23 | 2003-06-10 | Basf Aktiengesellschaft | Pyridine-3-sulfonyl compounds as pesticidal agents |
US20030166469A1 (en) * | 2001-12-21 | 2003-09-04 | Bahr James T. | Crop harvesting method using a 1,2,4-triazol-1-ylpropanoic acid and derivatives |
CN1787742A (zh) | 2003-03-13 | 2006-06-14 | 巴斯福股份公司 | 除草混合物 |
ZA200605472B (en) * | 2003-12-23 | 2007-11-28 | Dow Agrosciences Llc | Process for the preparation of triazolopyrimidines |
ZA200605471B (en) * | 2003-12-23 | 2007-11-28 | Dow Agrosciences Llc | Process for the preparation of pyridine derivatives |
ATE451370T1 (de) * | 2004-03-26 | 2009-12-15 | Dow Agrosciences Llc | Verbesserte verfahren zur herstellung von n-(ä1,2,4ütriazolopyrimidin-2-yl)arylsulfonamid n |
WO2006012320A1 (en) * | 2004-06-25 | 2006-02-02 | Dow Agrosciences Llc | Process for the preparation of 4-trifluoromethyl-2(1h)-pyridinone |
CN102578084B (zh) * | 2004-08-11 | 2014-06-11 | 组合化学工业株式会社 | 农药组合物 |
TR201905658T4 (tr) * | 2005-02-11 | 2019-05-21 | Dow Agrosciences Llc | Bir çim otu, üzüm bağı ve meyve bahçesi zemin herbisidi olarak penokssulam. |
WO2008089307A2 (en) * | 2007-01-18 | 2008-07-24 | Lexicon Pharmaceuticals, Inc. | Delta 5 desaturase inhibitors for the treatment of pain, inflammation and cancer |
WO2008089310A2 (en) * | 2007-01-18 | 2008-07-24 | Lexicon Pharmaceuticals, Inc. | Delta 5 desaturase inhibitors for the treatment of obesity |
WO2009006211A1 (en) * | 2007-06-29 | 2009-01-08 | Dow Agrosciences Llc | An improved process for the preparation of 4-trifluoromethyl-2(1h)-pyridinone |
US8288320B2 (en) | 2007-10-04 | 2012-10-16 | Oms Investments, Inc. | Methods for preparing granular weed control products having improved distribution of agriculturally active ingredients coated thereon |
GB0719803D0 (en) | 2007-10-10 | 2007-11-21 | Cancer Rec Tech Ltd | Therapeutic compounds and their use |
EP2110019A1 (de) * | 2008-04-19 | 2009-10-21 | Bayer CropScience AG | Herbizide Verbindungen auf Basis von N-Azinyl-N'-phenylsulfonylharnstoffen |
KR20110132441A (ko) * | 2009-03-11 | 2011-12-07 | 스미또모 가가꾸 가부시끼가이샤 | 제초 조성물 및 잡초의 방제 방법 |
BRPI1009637A2 (pt) | 2009-06-05 | 2019-04-30 | Cephalon, Inc | composto, composição e uso de um composto |
CN104756990B (zh) * | 2009-10-28 | 2017-07-07 | 陶氏益农公司 | 包含氟草烟和五氟磺草胺、氯吡嘧磺隆、甲氧咪草烟或咪唑乙烟酸的协同除草剂组合物 |
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BR112012019311B8 (pt) * | 2010-02-03 | 2022-10-11 | Dow Agrosciences Llc | Mistura herbicida sinérgica compreendendo penoxsulam e flazassulfurona, composição herbicida, e método para controle de vegetação indesejável |
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GB2555635B (en) * | 2016-11-07 | 2022-04-13 | Rotam Agrochem Int Co Ltd | A novel form of penoxsulam, a process for its preparation and use of the same |
CN107668053A (zh) * | 2017-11-27 | 2018-02-09 | 浙江永太科技股份有限公司 | 一种含哒草特和五氟磺草胺的除草剂组合物 |
CN108395435B (zh) * | 2018-05-10 | 2021-02-05 | 深圳大学 | ***并嘧啶磺酰胺类化合物及其制备方法和应用 |
CN108558744A (zh) * | 2018-07-04 | 2018-09-21 | 常州大学 | 一种2-甲氧基-4-三氟甲基-3-吡啶磺酰氯的制备方法 |
CN108707109A (zh) * | 2018-08-29 | 2018-10-26 | 常州沃腾化工科技有限公司 | 一种2-甲氧基-4-三氟甲基吡啶-3-磺酰氯的制备方法 |
CN113272277A (zh) * | 2018-12-27 | 2021-08-17 | 科迪华农业科技有限责任公司 | 磺酰胺除草剂方法中间体的制备 |
EP3902786B1 (en) | 2018-12-27 | 2022-12-14 | Corteva Agriscience LLC | Preparation of sulfonamide herbicide process intermediates |
CN111217817B (zh) * | 2020-02-26 | 2022-06-10 | 山东潍坊润丰化工股份有限公司 | 一种***并嘧啶类除草剂的制备方法 |
CN112730689B (zh) * | 2020-12-29 | 2023-04-07 | 营口昌成新材料科技有限公司 | 2-氨基-5,8-二甲氧基[1,2,4]***并[1,5-c]嘧啶液相色谱分析方法 |
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BE758749A (fr) * | 1969-11-12 | 1971-05-10 | Ciba Geigy | Procede de preparation de nouveaux acides pyridine-sulfoniques |
US3787573A (en) * | 1970-03-18 | 1974-01-22 | R Mizzoni | Pyridine sulfonic acids as diuretics |
US3674794A (en) * | 1970-03-18 | 1972-07-04 | Ciba Geigy Corp | Certain-3-pyridine-sulfonamide derivatives |
US3671512A (en) * | 1970-04-01 | 1972-06-20 | Aba Gelgy Corp | 6-amino-3-pyridinesulfonamides |
US3824241A (en) * | 1970-08-26 | 1974-07-16 | Ciba Geigy Corp | Pyridinesulfonic acids |
US4204870A (en) * | 1978-07-25 | 1980-05-27 | Eastman Kodak Company | Photographic products and processes employing novel nondiffusible heterocyclyazonaphthol dye-releasing compounds |
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US4528288A (en) * | 1983-05-02 | 1985-07-09 | Riker Laboratories, Inc. | Substituted triazolo[1,5-c]pyrimidines |
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US4666501A (en) * | 1984-12-11 | 1987-05-19 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
US4638075A (en) * | 1985-01-14 | 1987-01-20 | The Dow Chemical Company | Herbicidal sulfonamides |
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US4605433A (en) * | 1985-05-30 | 1986-08-12 | The Dow Chemical Company | 1,2,4-triazolo[1,5-a]-1,3,5-triazine-2-sulfonamides and compositions and methods of controlling undesired vegetation |
DE3539386A1 (de) * | 1985-11-04 | 1987-05-14 | Schering Ag | N-(s-triazolo(1,5-a)pyrimidin-2-yl)-2-alkoxy-benzolsulfonamide, verfahren zur herstellung dieser verbindungen sowie diese enthaltende mittel mit herbizider und pflanzenwachstumsregulierender wirkung |
EP0244948A3 (en) * | 1986-04-30 | 1989-03-15 | Schering Agrochemicals Limited | Triazolopyrimidine herbicides |
US4685958A (en) * | 1986-05-06 | 1987-08-11 | The Dow Chemical Company | Sulfonamides derived from substituted 2-amino-1,2,4-triazolo[1,5-a]-1,3,5-triazines and compositions and methods of controlling undesired vegetation |
US4910306A (en) * | 1987-11-09 | 1990-03-20 | The Dow Chemical Company | Preparation of substituted 1,2,4-triazolo[1,5-a]pyrimidine-2-sulfonanilides |
US5272128A (en) * | 1992-04-01 | 1993-12-21 | Rohm And Haas Company | Phosphosulfonate herbicides |
FR2703051B1 (fr) * | 1993-03-26 | 1995-04-28 | Adir | Nouvelles pyridothiadiazines, leurs procédés de préparation, et les compositions pharmaceutiques qui les contiennent. |
US5571775A (en) * | 1994-07-11 | 1996-11-05 | Dowelanco | N-aryl[1,2,4]triazolo[1,5-a]pyridine-2-sulfonamide herbicides |
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1997
- 1997-09-23 US US08/936,046 patent/US5858924A/en not_active Expired - Lifetime
- 1997-09-23 AU AU47363/97A patent/AU723666B2/en not_active Expired
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- 1997-09-23 HU HU1200420A patent/HU229886B1/hu unknown
- 1997-09-23 DK DK97909857T patent/DK0877745T3/da active
- 1997-09-23 TR TR1998/00906T patent/TR199800906T1/xx unknown
- 1997-09-23 KR KR10-1998-0703833A patent/KR100488277B1/ko not_active IP Right Cessation
- 1997-09-23 DE DE122009000052C patent/DE122009000052I2/de active Active
- 1997-09-23 CN CN97191491A patent/CN1092195C/zh not_active Expired - Lifetime
- 1997-09-23 JP JP51578798A patent/JP4215824B2/ja not_active Expired - Lifetime
- 1997-09-23 AR ARP970104360A patent/AR012020A1/es active IP Right Grant
- 1997-09-23 DE DE69705821T patent/DE69705821T2/de not_active Expired - Lifetime
- 1997-09-23 CZ CZ0156398A patent/CZ297521B6/cs not_active IP Right Cessation
- 1997-09-23 HU HU0002072A patent/HU228039B1/hu unknown
- 1997-09-23 CA CA002238316A patent/CA2238316C/en not_active Expired - Lifetime
- 1997-09-23 ES ES97909857T patent/ES2158513T3/es not_active Expired - Lifetime
- 1997-09-23 CN CNB02118609XA patent/CN1159297C/zh not_active Expired - Lifetime
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- 1997-09-23 WO PCT/US1997/016867 patent/WO1998013367A1/en active IP Right Grant
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1998
- 1998-05-22 BG BG102478A patent/BG63123B1/bg unknown
- 1998-07-31 US US09/127,328 patent/US6005108A/en not_active Expired - Lifetime
- 1998-07-31 US US09/127,378 patent/US6130335A/en not_active Expired - Lifetime
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2000
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