CN86108161A - Fly attracting composition - Google Patents
Fly attracting composition Download PDFInfo
- Publication number
- CN86108161A CN86108161A CN86108161.7A CN86108161A CN86108161A CN 86108161 A CN86108161 A CN 86108161A CN 86108161 A CN86108161 A CN 86108161A CN 86108161 A CN86108161 A CN 86108161A
- Authority
- CN
- China
- Prior art keywords
- cis
- fly
- red
- composition
- carbene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 95
- 150000001875 compounds Chemical class 0.000 claims abstract description 28
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 32
- -1 3-phenoxy benzyl Chemical group 0.000 claims description 19
- 239000002728 pyrethroid Substances 0.000 claims description 15
- 239000003016 pheromone Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
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- 238000009472 formulation Methods 0.000 claims description 2
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- 238000002360 preparation method Methods 0.000 abstract description 38
- 239000002245 particle Substances 0.000 abstract description 16
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
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- 241000238631 Hexapoda Species 0.000 description 4
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- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- ZFRKQXVRDFCRJG-UHFFFAOYSA-N skatole Natural products C1=CC=C2C(C)=CNC2=C1 ZFRKQXVRDFCRJG-UHFFFAOYSA-N 0.000 description 1
- LGZQSRCLLIPAEE-UHFFFAOYSA-M sodium 1-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C(S([O-])(=O)=O)C2=C1 LGZQSRCLLIPAEE-UHFFFAOYSA-M 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- TXHPORRYUKITDP-UHFFFAOYSA-N sulfamoylsulfamic acid Chemical compound NS(=O)(=O)NS(O)(=O)=O TXHPORRYUKITDP-UHFFFAOYSA-N 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 235000012751 sunset yellow FCF Nutrition 0.000 description 1
- 239000004173 sunset yellow FCF Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a fly attracting composition, which is characterized in that: a) as a fly-attracting compound, at least one sex pheromone selected from the group consisting of 9-tricosene, cis-9-tricosene, 10-methyl-9-tricosene, cis-2-methyl-8-tricosene, cis-9-tricosene, cis-8-tricosene and cis-10-tricosene is contained, b) it has a yellowish red color with a hue in the range of 2.5R to 2.5YR, c) it is a granular preparation with an average particle size in the range of 0.5 to 5 mm.
Description
The invention relates to attraction, the composition of fly is killed in trapping.The present invention also is about attracting, trap to kill attraction insecticides and the attraction of fly and luring that fly picked-up said composition reaches the malicious erbium composition of luring of poisoning fly into.
The open fly of uncensored Japanese patent publication SH056-115706 can be attracted by yellow substance, and this color is according to being 5YR to 7.5GY in the standard described in the JIS Z 8721.Yet the yellow substance of this color is not enough to the attraction effect of fly, and is unsafty.
On the other hand, well known, the 9-tricosene, cis-9-tricosene waits the information of the property that all can be used as fly to reach the effect that attracts fly.Yet the attraction effect of the pheromones of these property also is not enough, when therefore these pheromones as attractant being combined with the fly controlling agent, is still very low in the control effect.
The invention provides a kind of fly and attract composition, said composition has high attraction effect to fly, and than described prior art effect height.
The present invention further provides a kind of attraction-insecticides, said composition can attract and control fly effectively.
Having the present invention further provides a kind of luring-malicious erbium composition is used for attracting fly effectively and causes that they produce attraction to the malicious erbium with high viscosity, so that its insecticide ingredient enters in the body, reach and control fly fully under the situation that increases dosage.
Fly of the present invention attracts its feature of composition to be listed below:
A) attract compound as a kind of fly, at least the pheromones that contains a kind of property, this pheromones is selected from this group, promptly contain the 9-tricosene, cis-9-tricosene, 10-methyl-9-tricosene, cis-2-methyl-8-22 carbene, cis-9-22 carbene, cis-8-22 carbene and cis-10-23 carbene
B) a kind of color of yellowish red color is arranged in the amplitude of 2.5R to 2.5YR color,
C) form of preparation of granules is pressed the average grain specification, is about 0.5 to about 5mm.
It is the pheromones of the property of a kind of fly of all knowing that the applied fly of the present invention attracts compound, has the effect that attracts fly, but effect is low, yet, we have been found that through research working as the preparation that contains compound presents the red color of a kind of Huang, and color is between 2.5R to 2.5YR amplitude, and the one-tenth graininess, the average grain specification is in about specific amplitude of 0.5 to about 5mm, and preparation just presents the attraction effect that fly is had height unexpectedly.The height of fly is attracted effect, have only, as mentioned above, be together with each other and just can gather effect when the form structure that attracts compound, color and preparation.If use the compound of other attraction, perhaps the color of preparation is outside the specific amplitude of 2.5R to 2.5YR, and perhaps preparation is not a graininess, though perhaps be graininess, but not that so this distinguished attraction effect just can't obtain in the amplitude of above-mentioned specification.
The pheromones that to be used for attraction compound of the present invention be a kind of property is selected from the 9-tricosene, cis-9-tricosene, 10-methyl-9-tricosene, cis-2-methyl-8-22 carbene, cis-9-22 carbene, cis-8-22 carbene and cis-10-23 carbene.In the middle of them, cis-9-23 carbon are rare to be particularly best.According to the present invention, use a kind of in these compounds at least.Though use concentration a great difference is arranged, in preparation, attracting the compound concentrations spouse often is about 0.01 to about 15 percentage by weights, more preferably is about 0.02 to 4 percentage by weight.
The particularly important is fly of the present invention and attract composition to be rendered as yellowish red color, the color amplitude is pressed in JIS Z 8721 described standards between 2.5R to 2.5YR.If color has like red but less than 2.5R or like yellow but less than 2.5YR, so, the desired high effect that fly is attracted just can not obtain.Especially more preferably, color is between the amplitude of 7.5R to 2.5YR.Preparation of the present invention according to JIS Z 8721, need have above-mentioned specific color, and brightness is 4 at least, especially more preferably is 5, and degree of saturation is 6 at least, is 7 especially more preferably, and this also is sought after.
Pigment is used for not only comprising general pigment (coloring material) to composition of the present invention is painted, and comprises material fluorescent or luminous.It is as follows now to list suitable pigment example:
No. 2 red (amaranth, acid is red 27, sodium 1-(4-sulfo--1-naphthyl azo)-beta naphthals-3, the 6-disulfonate)
No. 3 red (erythrosine, acid is red 51,9-ortho position-carboxy phenyl-6-hydroxyl-2,4,5, the different yellow disodium of the 7-tetraiodo-3-)
No. 102 red (new kermes, acid is red 18, trisodium 1-(4-sulfone-1-naphthyl azo)-beta naphthals-6, the 8-disulfonate)
104-(1) number red (phloxin b, acid is red 92,9-(3,4,5,6-tetrachloro-neighbour-carboxy phenyl)-6-hydroxyl-2,4,5, the different yellow disodium of 7-tetrabromo-3-)
105-(1) number red (rose agar, acid red 94,9-(3,4,5,6-tetrachloro-neighbour-carboxy phenyl)-6-hydroxyl-2,4,5,7, the different yellow disodium of-tetraiodo-3-)
No. 106 red (acid is red, and acid is red 52,9-(4 '-sulfo--2 '-sulfonium phenyl)-6-diethylamino-3-(N, N-diethyl imino group)-the different yellow disodium of 3-)
No. 4 Huangs (tartrazines, acid is yellow 23, and 3-carboxyl-5-hydroxyl 1-is right-and thio-phenyl-4-is right-sulfo group azo pyrazoles-3 sodium)
No. 5 Huangs (sunset yellow FCF, acid is yellow 3, and disodium 1-is right-sulphur benzeneazo-beta naphthal-6-sulfonation)
No. 201 red (lithol rubin B, paratonere 57-1, single sodium 4-(neighbour-sulfo group-right-tolyl azo)-3-hydroxyl-2-naphthoates)
No. 202 red (lithol rubin B CA, paratonere 57-1, calcium 4-(neighbour-sulfo group-P-tolylazo)-3-hydroxyl-2-naphthoates
No. 203 red (the red C in lake, paratonere 533(sodium), 1-(4-chloro-neighbour-sulfo group-5-tolylazo)-beta naphthal list sodium
No. 204 red (the red CBA in lake, paratonere 53(barium), 1-(4-chloro-neighbour-sulfo group-5-tolylazo)-beta naphthal barium
No. 205 red (lithol rubin, pigment red 4 9(sodium), single sodium 2-(2-hydroxyl-1-naphthyl azo)-1-naphthalene sulfonic aicd salt
No. 206 red (lithol rubin CA, pigment red 49, calcium 2-(2-hydroxyl-1-naphthyl azo)-1-naphthalene sulfonic aicd salt)
No. 207 red (lithol rubin B A, pigment red 4 9(barium), barium 2-(2 hydroxyl-1-naphthyl azo)-1-naphthalene sulfonic aicd salt)
No. 208 red (lithol rubin SR, pigment red 4 9(strontium), strontium 2-(2-hydroxyl-1-naphthyl azo)-1-naphthalene sulfonic aicd salt)
No. 213 red (rhodamine B, alkaline purple 10, the 9-neighbour-carboxylic phenolic group-different xanthene of 6-diethylamino-3-ethyl imido-3--3-ethyl chloride)
No. 214 red (rhodamine B acetate, alkaline purple 10, the 9-neighbour-carboxy phenyl-different xanthene of 6-diethylamino-3-ethyl imido-3--3-ethyl acetate)
No. 215 red (rhodamine B stearate, solvent red 49, the 9-neighbour-carboxy phenyl-different xanthene of 6-diethylamino-3-ethyl imido-3--3-ethyl acetate)
No. 218 red (tetrachloro tetrabromofluorescein, solvent red 92,2,4,5,7-4 bromo-12,13,14,15-tetrachloro-3,6-fluorane glycol)
No. 219 red (the red R in gorgeous lake, paratonere 64, calcium 3-hydroxy-4-phenyl azo-2-naphthoate)
No. 220 red (dark maroon, paratonere 63(calcium), calcium 4-(1-sulfo group-2-phenylazo)-3-hydroxyl-2-naphthoate)
No. 221 red (toluidine red, pigment red 3,1-(neighbour-nitro-right-tolylazo)-beta naphthals)
No. 223 red (tetrabromofluorescein, solvent red 43,2,4,5,7-tetrabromo-3,6-fluorane glycol)
No. 225 red (1-is to one phenylazo-phenylazo-beta naphthal for oil red, solvent red 23)
No. 226 red (the pink CN of helindone, urn is red 1,5,5 '-dichloro 3,3 '-the diformazan thioindigo)
No. 227 red (acidproof magenta, acid red 33, disodium 8-amino-2-phenylazo-1-naphthols-3,6-disulfonate)
No. 228 red (the laminated plastic colour is red, pigment red 4,1-(neighbour-chloro-is right-nitrophenylazo)-beta naphthal)
230-(1) number red (eosin W or W S S, acid is red 87,9-neighbour-carboxy phenyl-6-hydroxyl-2,4,5, the different xanthene ketone-disodium of 7-tetrabromo-3-)
No. 231 red (Japan Red 231, acid is red 92,9-(3,4,5,6-tetrachloro-neighbour-carboxy phenyl)-6-hydroxyls-2,4,5, the different xanthene ketone of 7-tetrabromo-3-dipotassium)
No. 232 red (rose-red K, acid is red 94,9-(3,4,5,6-tetrachloro-neighbour-carboxy phenyl)-6-hydroxyls-2,4,5, the different xanthene ketone of the 7-tetraiodo-3-dipotassium)
No. 201 oranges (Dibromofluorescein, solvent red 72,4,5-two bromo-3,6-fluorane glycol)
No. 203 oranges (permanent orange, pigment orange 5,1-(2,4-phenodiazine phenylazo)-beta naphthal)
No. 204 oranges (Benzidine orange G, pigment orange 13,3,3 '-dichloro diphenyl-4,4 '-bisazo-(1-phenyl-3-methyl-5-pyrazolones ketone)
No. 205 oranges (1-is right for orange II, acid orange 7-sulfo group-benzeneazo-beta naphthal list sodium)
No. 401 red (violamine R, acid violet, the 9-neighbour-carboxy phenyl-different xanthene disodium of 6-4(4-sulfo group-toluene imido-3-)
No. 404 red (sun-proof is scarlet, paratonere 24,1-(4-nitrogen-2-tolylazo)-2-hydroxyl-3-naphthoic acid N-anilides)
No. 405 Huangs (permanent red F5R, pigment red 48, calcium 1-(3-chloro-6-sulfo group-4-tolylazo)-2-hydroxyl-3-naphthoate)
No. 501 red (medicinal scarlet red, solvent red 24, neighbour-tolylazo-neighbour-tolylazo-2-naphthol)
No. 502 red (Ponceau 3R, edible red 6, disodium 1-2,3,5-trimethylphenyl azo-beta naphthal-3,6-disulfonate)
No. 503 red (ponceau R, acid red 26, disodium 1-xylyl azo-beta naphthal-3,6-disulfonate)
No. 504 red (FD C Red No. 4, edible red 1, disodium 2-(5-sulfo group-2,4-xylyl azo)-1-naphthols-45-sulfonate)
No. 505 red (oil red XO, solvent orange 7,1-xylyl azo-beta naphthal)
No. 506 red (the red S of sun-proof, acid red 88, single sodium 4-(2-hydroxyl-1-naphthyl azo)-1-naphthalene sulfonic aicd salt)
No. 401 oranges (Chinese spreads orange, pigment orange 1, α-(neighbour-nitrogen-right-anisyl azo)-o-acetyl-acetyltoluene ammonia)
No. 402 oranges (4-is right for orange I, acid orange 20-sulfo group-phenylazo-1-naphthols list sodium)
Luciferin
No. 403 oranges (orange SS, solvent orange 2,1-neighbour-tolylazo-2-naphthol)
No. 401 Huangs (hansa yellow a, man of virtue and ability expects Huang 1, α-(neighbour-nitrogen-right-tolylazo) N-AAA)
These pigment can be used separately, or their two kinds middle mixtures share at least.Pigment quantities is that the preparation of determining like this that is obtained that makes has a kind of color in above-mentioned specific scope.Usually the quantity of using pigment be according to this composition about 0.05 to 4, by weight percentage, more preferably by weight percentage about 0.08 to 2.
Fly of the present invention attracts composition need become a kind of graininess, have a kind of average grain specification of about 0.5 to about 5mm, and this is very crucial.If the average grain specification is lower than 0.5mm, i.e. powdering, perhaps greater than 5mm, so, composition just can't meet the requirements of the high effect that attracts.In fact to imitate shadow be never to report so far to the attraction that can have influence on fly of the particle specification of preparation; This is that we study first and open this fact.More preferably, the present invention on the particle specification, preferably about 1 to about 3mm scope.Possessed above-mentioned specific particle specification as fruit granule, composition does not just have any particular determination at aspects such as configuration, weight.For example, composition can become particle, ball/sheet shape or garden shape, and perhaps the particle of dish type is amorphous, perhaps any required shape.
Insecticide can attract composition to combine with fly of the present invention, so that kill the fly of preferendum fruitfully.When the application of various insecticides, during the insecticidal effect of agreeing on killing fly, pyrethroid, organic phosphor and carbamate kill agent and all are sought after.Now down the example of these insecticides row:
3-pi-allyl-2-methyl cyclopentadiene also-2-alkene-4-ketone-1-base cis/trans-chrysanthemate (popular name: allethrin)
3-pi-allyl-2-methyl cyclopentadiene also-2-alkene-4-ketone-1-base trans-chrysanthemate salt (popular name: biological allethrin)
5-benzyl-3-furfuryl d-cis/trans-allethrin (popular name: Reamethrin)
The 5-(2-propargyl)-3-furfuryl allethrin (popular name: Furamethrin)
3-benzyloxy phenoxy base cis/trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid salt (popular name: Permethrin)
3-benzyloxy phenoxy base cis/trans-allethrin (popular name: Phenothrin)
The neighbour, neighbour-dimethyl neighbour-(2, the 2-dichloro) ethephon hydrochlorate (DDVP)
Neighbour-o-phenyl-isopropyl methyl carbamate (popular name: Propoxur)
The neighbour, the even phosphorus sulfo-salt (popular name: Fenitrothion) of neighbour-dimethyl neighbour-(3-methyl-4-pyridyl)
The neighbour, neighbour-diethyl neighbour-2-isopropyl-4-methyl-pyrimidine radicals (6)-thiophosphate (popular name: Diazinon)
N-(3,4,5,6-tetrahydrochysene benzene two (first) acylimino)-methyl .d1-cis/trans-allethrin (popular name: Phthalthrin)
The neighbour, neighbour-dimethyl s-(1,2-two carbon ethoxy ethyl esters)-dithiophosphates (popular name: Malathion)
Alpha-cyano-3 '-phenoxy benzyl α-isopropyl-4-chlorphenyl-acetate (popular name: Fenvalerate)
Neighbour-(4-bromo-2,5-dichlorophenyl) neighbour, neighbour-dimethyl idol phosphorus sulfo-salt (popular name: Bromophos)
S-methyl-N(methylamino formoxyl oxygen base) thioacetyl imido (base) salt (popular name: Methomyl)
The neighbour, neighbour-dimethyl neighbour-4-methyl mercapto--toluoyl idol phosphorus sulfo-salt (board name: Baycid) (popular name: Fenthion)
Dimethyl-(2,2,2-three chloro-1-ethylene glycol) phosphonic acids (popular name: Trichlorfon)
Neighbour-2,4 dichloro benzene base neighbour-ethyl-s-propyl group-even phosphorus dithio salt (popular name: Prothiophos)
In these pesticide compounds, pyrethroid is particularly preferable.In the compound in these specifications, 5-benzyl-3-furyl methyl d-cis/trans-allethrin, phenothrin and permethrin are particularly best.These insecticides are to use separately, and perhaps two kinds in them share together.Though the ratio of used insecticide is not particularly limited, generally be gross weight by existing composition, scope about 0.1 to about 15 weight percent meters.
Now Fa Ming fly absorbing composition is mixed mutually and prepares with some compounds by a kind of appropriate carriers, and mixture is formed a kind of suitable granular form, and this is granular to have a kind of uniform granular specification in above-mentioned scope.The kind of used carrier can be subdivided into non-organic substance as: talcum, kaolin, silicic acid, activated carbon, bentonite, silica, alumina, alumina-silica, carbonic acid fine particle calcium carbonate, powder pottery or pottery and diatomite and organic substance as paper pulp, fiber, pigment, Icing Sugar, analysis for soybean powder, flour, starch, resin and rubber.
More preferably, now the fly of invention attract composition be by, for example, pigment mixes mutually with attraction compound as a kind of active component and prepares, if needed, also can become a kind of specific particle specification to mixture, remove solvent and dry up grain products a kind of suitable insecticide as a kind of solvent and/or a kind of binder solution.Be used for this law solvent types and be alcohol type as methyl alcohol and ethanol, ketone such as acetone and methyl ethyl ketone, the ester class as: oxolane He diox and other material as (just) hexane, kerosene, paraffin wax, benzinum, toluene, ethyl acetate and dichloroethane.The kind of adhesive therefor is cellulosic derivative as nitrocellulose, hydroxy propyl cellulose, acetylcellulose, acetobutyryl cellulose and methylcellulose, polyvinyl alcohol, gum Arabic, sodium carboxy methyl cellulose, casein, gelatin, alginic acid.This adhesive usually with about 1 to about 20% aqueous solution for the most useful.When the required various additives of all knowing as: synergist, age resistor, antidecomposition agent, bactericide, kill note of the ancient Chinese microbial inoculum, accidental absorbent prophylactic etc., in case and present fly absorbent combine, then they also can be of great use.It also is useful that other attractant of all knowing combines.
Effectively the example of synergist is N-(2-ethyl-hexyl) two ring [2,2,1]-5-heptene-2,2-dicarboximide, 6-(propyl group piperonyl) butyl Ka Biji ether, or the like.Effectively the example of age resistor is butylated hydroxy anisole, dibutyl hydroxy toluene, vitamin e, Υ-vinegar amine alcohol (oryzanol), etc.Effectively the example of antidecomposition agent is a benzene glycidol ether etc.Well known, these preparations can be employed in method commonly used, and can be used in combination.
Effectively the example of bactericide is between salicylic acid, benzoic acid, right-chloro--xylenols, 2-(4 '-thiazolyl) benzimidazole, or the like.The example that effectively kills agent is α-bromocinnamaldehyde, N-dimethyl-N-benzene-N '-(fluoro dichloromethyl) sulfo-sulphamide etc.The tincture that the effectively accidental example that absorbs prophylactic is Capsicum year, the quassia of Japan, chloramphenicol or the like.Using the ratio of this this preparation can suitably determine.For example, the accidental prophylactic that absorbs, by the weight percent meter of its gained preparation, consumption is about 0.1 to being about 3.
The example of the vapor that can combine with existing fly attraction composition is to absorb the temptation material, comprises the material such as milk powder, egg powder, pupa powder, krill powder, meat broth, albumin, globulin, amino acid (dried meat acid acid), malt extract, caramel, vanillin, whey, flour, yeast, glucose, sucrose, maltose, monose and the disaccharides that contain protein and/or carbohydrate.The example of other effective attractant is terpineol, farnesol, geraniol, ammonium carbonate, scatol, formaldehyde, hexamethylene-tetramine, aminoquinoxaline, pumpkin proteinase, butyric acid, isopentyl aldehyde, ethamine, the monoesters class of chlorated alkene polyalcohol, pancreatin.The quantity of applied these attractants can suitably be determined, needn't place restrictions on especially.
Optimum implementation of the present invention comprises a kind of malicious erbium composition, wherein combine with a kind of pyrethroid insectide at least, this insecticide is selected from a kind of base group, this base group contains (5-benzyl-3-furyl) methyl d-cis/trans-allethrin worm ester (popular name: allethrin), the 3-phenoxy benzyl, cis/trans-allethrin (popular name: phen-othrin) with 3-phenoxy benzyl, cis/trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl-cyclopropane carboxylic acid hydrochlorate (popular name: permethrin).Usually, malicious erbium composition comprises a kind of food that supplies fly to sting food, and this food is through a kind of impregnated with insecticides or directly combines with a kind of insecticide.In order to obtain a kind of gratifying effect, malicious erbium composition must meet following needs.At first, selected insecticide ingredient repels each other to fly at least.The second, must possess physics and/or chemical method, make malicious erbium attracted by fly.The 3rd, malicious erbium must be attractive on flavour, removes to absorb malicious erbium so that lure the fly that is attracted into.The 4th, before fly is pressed vicious erbium or toxigenicity note of the ancient Chinese shape in some aspects, should make fly take in enough fatal dosage.These requirements are not what isolate, but combine closely each other.In case malicious erbium loses these a kind of in requiring, malicious erbium composition a kind of very big inefficacy will occur and produce unsafty effect.
At present know that all the insecticide ingredient of malicious erbium only limits to some organic phosphors or carbamate pesticide, and pyrethroid is used seldom.Know all that generally pyrethroid insectide can produce a kind of distinguished down effect to the fly effect of growing up very fast (hereinafter all claiming " fly "), because insecticide can enter in the body of fly and generation effect on nervous system soon by skin or mouth.Correspondingly, the application of such insecticide is to only limit to the mouth breathing road contact with skin.Utilize above-mentioned characteristic, pyrethroid insectide not only can the preparation form be used for fly, and can be used for mosquito, cockroach etc., the agent (stomatodeum) that repels each other of said preparation such as mosquito, the mosquito electricity cover (the same) that repels each other, aerosol (stomatodeum and skin road), fumigant or gasification component (the same) etc.Yet they are not used for stomatodeum with insecticide poison erbium composition form so far as yet.
For example, 1978, the one piece literary composition of J.Keiding on Denmark's insect infection experiment yearbook report is in the laboratory test of " malicious erbium paint ", once report pyrethroid insectide on probation and reached the control insect, follow pyrethroid insectide to combine and to reach gratifying effect but report illustrates malicious erbium by stomatodeum.The result who is reported is quite reasonable, and in view of present scientific information, promptly intending removing the ant pyrethrin pesticide is can not absorbed by insect.Moreover, recently report 2,2-dimethyl-3-(B, β-dihydro vinyl)-cyclopropane-carboxylic acid a-cyano group-3-phenoxy group-4-fluorine (generation) benzene, a kind of pyrethroid insectide is to the effective a kind of malicious erbium of fly (can consult uncensored Japanese patent publication SHO 59-78111).Yet report explanation above-mentioned compound separately just can be gathered effects, and other pyrethroid insectide just discomfort be used as malicious erbium.Therefore, common people are to intend insecticide to have the vigor that insect is repelled each other to the understanding of this technology at present, but in case after oral, its effectiveness is very low.
Yet, our research shows, in case fly of the present invention attracts in composition and the above-mentioned three kinds of pyrethroid compounds after at least a the combining, even by oral, pyrethroid compound still can present a kind of strong insecticidal effect, moreover, said composition can attract fly effectively and can not cause any detest, and can lure that the fly that attracted on one's own initiative, removes to absorb the lethal dose of malicious erbium very doggedly into, the result just reaches the control effect.
Be used to lure into that attractant and composition that fly absorbs malicious erbium composition combine.The attractant of having demonstrated is to can be used as attractant.Taking in the temptation attractant is a kind of material, and it is ingestible to fly.The material that useful carrier preferably can eat is as: Icing Sugar, a yellow powder, flour, starch etc.Take in temptation attractant and/or edible material from soybeans, as carrier, by the percentage by weight of its component, its quantity is at least 70%.
Above-mentioned pyrethroid insectide compound can use separately, or two kinds of uses that combine in them at least, and its quantity is 0.1 to 15 percentage by weight, is preferably 0.3 to 10, presses the weight percent meter of composition.Particularly best is to use allethrin.
The pheromones of used property, quantity are about 0.01 to being about 15, by weight percentage, preferably are about 0.02 to being about 4, press the weight percent meter of composition.Though pyrethroid insectide compound and property pheromones use in proportion, though this ratio is not placed restrictions on especially, but also be selectively in broad terms, the former generally is 1 with the latter's ratio (by weight): 0.001-1 more preferably is about 1: 0.005-0.5.
Once the same additive of narrating can be used as the malicious erbium composition of preparation.Its composition can be made a kind of granular preparation by aforesaid Same Way.
Attractant composition of the present invention can use by its former particle, or also can be adhered to a kind of suitable material as paper, fiber and film, plate, plate, ball, gengon or synthetic resin, wood or metal.As fly control or eliminate agent, now the fly of invention attracts composition, in case combine, just can be used to place, spray or adhere to place that fly haunts as the field of crops, growth crop, orchard, greenhouse, vinyl factory building, livestock canopy, poultry room, granary, kitchen, dwelling house chamber or the like with agrochemical.After not containing insecticide and combine as existing component, also can be used for these places.Place that the quantity of composition therefor can be used according to need and method are come suitably in to determine.For example, when being used for spraying, it is to add 1mg on relevant every square metre at least that existing fly attracts the quantity that composition was employed, and more preferably is about 3 to about 10mg activated complex.
The example that is subjected to the attractant composition of the present invention that fly attracts is tame Nuscidae as housefly, false stable fly, matting chela fly and Ophyra Leucos-toma; Fanninae; Beautiful grey section is as green grey, the mercerising cupreous fly of: calliphorid, Aldrichina qrahami, mercerising, lucilia cuoser ,-lucilia illustris, Chrysomyia megacephala and Phormia regina; Flesh fly section as: sarcophaga peregrina and Parasarcophaga are as Sarcophaga peregrina and Parasarcophaga Similis; Drosophilidae is as Prosophila melanog aster and Prosophila virilia; Piophilidae is as Piophila casei; The coprophagy Nuscidae is as the loose stool fly; The bamily Promyzidae is as Stenodngomyza formosa; Phoridae is as Megaselic scalaris etc.
Example
The present invention will further translate with following example and chat:
Example one
1. Icing Sugar 60g
2. pigment 0.8g
3. cis-9-23 carbene 15mg
(1.5cm is as 1 percentage by weight acetone)
4. methyl alcohol and acetone are pressed equal number mixing 100ml
5. adhesive 7ml
(gum Arabic aqueous solution, 20 percentage by weights)
Said components 1 to 5 usefulness stirs and is mixed together, and solvent can be evaporated it under 50 ℃ of situations by a rotary evaporator, and mixture can screen with the sieve of 2mm one mesh.The part of excessive specification can be pressed pure one-tenth particle again.Spray the aqueous solution of adhesive again, last mixture integrates into particle fully under pressure, and average specification is about 2mm.Granulate mixture was required to keep at least at room temperature 12 hours, became a kind of granular preparation after to be dried.In this respect, fly attracts composition 1a to 1m just can obtain.
The concentration of the cis of these preparation products-9-23 carbene is 0.025 percentage by weight.The formulation samples of gained can check color by JIS Z 8721.Table 1 shows the result.
Table 1
Preparation pigment preparation color
1a tartrazines No4 6YR
1b Uranine K（202-1） 2Y
1c naphthol yellow S 3Y
1d luciferin 1YR
1e Kui Linhuang $$ 10YR
1f Fast Yellow G 7YR
1g luciferin (ranine) is 2Y (202-2)
The yellow G 5YR of 1h biphenyl
1i tropeolin G 5Y
1j hansa yellow 3Y
No. 5 yellow 9R of 1k
The pale yellow F 1YR of 1l
No. 4 yellow 1.5R of 1m
Example two
Fly attracts particulate composition 2a to 2m, has a kind of insecticide concentration, percentage by weight is 1, but the same procedure of use-case one prepares, Methomyl(S-methyl N-(methyl-carbamyl oxygen) the thioacetyl imidazole salts, the carbamate pesticide that just add another kind of insecticide component 600mg in addition are by the Nemours ﹠amp of E.I. Du Pont; Co. produce.
Each sample in the gained preparation can both be found out the corresponding color that conforms to sample 1a to 1m in example one table.
Can test it with following method at example 2 gained preparations and attract effect.
The test I
Preparation, every umber amount is 60 grams, places glass plate (diameter is 15.5cm) respectively, on the floor in laboratory glass plate is put into a garden shape then, and each spacing distance is about 30cm, and housefly is put into laboratory.After past, check the fly number of in each dish, killing at preset time.
Every kind of preparation can recently be assessed according to the percentage of killing the fly number in the dish the attraction effect of fly, and promptly in laboratory, preparation contained in the plate is with the ratio (just killing the sum of fly in all plates) of killing the fly sum.
The test II
Preparation can be assessed with the same method of test I the attraction effect of fly, just the preparation of every kind 10 gram is placed some plastic cups respectively, then these plastic cups place outdoors glass chamber (on the floor of 1.45m * 1.4m), they to each other be spaced apart 20cm.
Test result is as table 2(test I) and table 3(test II)
Table 2
Preparation number attracts effect (%) to fly
2a 1
2b 3
2c 2
2d 28
2e 3
2f 4
2g 4
2h 4
2i 3
2j 3
2k 30
2l 11
2m 3
Control 1
Table 2
Preparation number attracts effect % to fly
2a 3
2b 2
2c 1
2d 16
2e 4
2f 5
2g 5
2h 3
2i 3
2j 5
2k 28
2l 21
2m 3
Control 1
Example three
Except using is 0.08 to 1.3 the pale yellow F by weight percentage, is equipped with fly agent for killing composition by example two identical methods.The gained preparation is tested the attraction effect that the identical method of I is tested fly by example two.Table 4 has been listed the result of test.
Table 4
The preparation paint color attracts effect to fly
Title concentration (wt.%)
Pale yellow F 0.08 1YR 12 of 3a
Pale yellow F 1.3 1YR 16 of 3b
Example four
Pigment (fluorescein) 1 gram
Insecticide (Permethrin) 1 gram
25 milligrams of cis-9-23 carbene
Replenishers (Icing Sugar) 100 grams
The concrete quantity of pigment, cis-9-23 carbene (as 1 ml n-hexane solution) and Icing Sugar is mixed with stirring mutually, the solid mixture of gained can be through crushing, the aqueous solution of spraying content and be 20% acacia gum is blended together it, makes particle and put dried at room temperature under pressure.
The insecticide that is dissolved in the acetone is sprayed on the mixture of gained, and quantity is 15 milliliters in per 50 gram mixtures.Mixture is fully stirred, use a rotary evaporator subsequently, temperature is fallen removal of solvents at 50 ℃, attracts composition so that obtain a kind of fly of the present invention.Said composition is called as " invention 4a ".
Comparative example one
A kind of relatively fly attracts composition, and it has the specification of identical color of example 4 compositions and same single-size, except not using cis-9-23 carbon, other all press the identical method of example four in to prepare.This composition is called as " relatively 4b ".
Comparative example two
The composition that is used for example four is mixed by stirring mutually, then their pulverizes in dried to put, a kind of relatively fly that just becomes a kind of powdery attracts composition.This composition is " relatively 4c ".
The test of attraction insecticide
The attractant sample of above-mentioned preparation is carried out fly is attracted to kill the activity test, some samples, every kind 20 gram places some serving dish, the interior diameter of plate is 15cm, place these plates a test cabinet (on 4 * 3 * 2.6m) the floor, to emit about 140 to 150 flies respectively indoor.After on-test 1 to 2 hour, the fly number that causes death in each dish is calculated.Every kind of sample is undertaken four times by above-mentioned test repeatedly, and the mean value of gained just can be used to estimate required activity.
Under tabulate 5 the explanation results
The tested number sample attracts agent for killing activity (fly number)
1 invention 4a 6.91
2 compare 4b 9.1
3 compare 4c 2.9
About table 5, the invention 4c with same combination and relatively 4b compare and just present the superiority of invention 4a on activity because the characteristic of preparation all is specific particle specification on used particle.Effect in this respect, the preparation of invention also are to be better than not being subjected to the comparison 4b that cis-9-23 carbene influences.Therefore, result of the test shows that distinguished attraction effect is the application that belongs to cis-23 carbene, and belongs to specific particle specification.
Example five
Insecticide (Methomyl, S-methyl N-2 gram
(methylamino methanoyl) thioacetyl inferior amine salt
Cis-9-23 carbene 50 grams
Icing Sugar 100 grams
Age resistor (BHT, 2,6-pair-the tertiary butyl methylbenzene) 2 grams
Luciferin 1 gram
Icing Sugar and cis-9-23 carbene (as 1 milliliter hexane solution) just becomes a kind of solid-state mixture through stirring mutual mixing, then they crushing, spray content again and be the gum Arabic of 20% aqueous solution and they are fully integrated, under pressure, make the single-size specification of a kind of 2mm and at room temperature they are put dried.
The above-mentioned insecticide that is dissolved in acetone one after the other is sprayed on granulate mixture; the mixture of per 50 grams is sprayed 15 milliliters quantity; mixture is fully stirred; use a rotary evaporator (under 50 ℃ situation) that removal of solvents is fallen again, attract composition so just obtained a kind of fly of the present invention.This component is called as " invention 5a "
This component has 1YR color and average grain specification at 1.5mm.
Comparative example three
A kind of have above-mentioned comparison fly with above-mentioned same hue and single-size to attract composition be by the identical methods preparation of example 5, just do not use cis-9-23 carbene.Component can be consulted " relatively 5b ".
The composition sample that is obtained in these examples is to be carried out test by example 4 identical methods, i.e. every kind of each 20 gram of sample.Under tabulate 6 the explanation results.Activity is that every kind of sample is assessed through the mean that is obtained behind five methods of testing repeatedly.
Table 6
The tested number sample attracts insecticide activity (fly number)
1 invention 5a 43.3
2 compare 6b 10.4
Example six-11
Press the identical method of example 4, composition listed in the table 7 is used to prepare the invention composition of various variable grain specifications.
The symbolic representation of some compositions that is used for table 7 is as follows:
Pigment
A-1: pale yellow
The A-2:2 Huang
A-3: luciferin
Insecticide
B-1：Permethrin
B-2:Chrysron-Forte(compound title: 5-benzyl-3-furyl-methyl d-cis/trans-chrysanthemate)
B-3：Phenothrin
Table 7
Example cis-9-title insecticide pigment Icing Sugar particle color
23 carbene quantity title quantity quantity specifications
Number quantity part part part part (mm)
6 0.025 B-1 1.0 A-1 1.0 97.975 1.5 1YR
7 0.025 B-2 1.0 A-2 1.0 97.975 1.5 9R
8 0.025 B-3 1.0 A-3 1.0 97.975 1.5 1YR
9 0.025 B-1 3.0 A-1 3.0 93.975 3.0 1YR
10 0.025 B-2 3.0 A-1 3.0 93.975 3.0 1YR
11 0.025 B-3 3.0 A-3 3.0 93.975 3.0 1YR
The invention composition sample that in these examples, prepares, press method identical in the example 4 and on fly, test the activity that attracts insecticide.Again every kind of obtained result of sample is gone to compare with the invention composition results that has obtained.
Example 12-17
Granular attraction insecticide composition, component by the example of inventing 4 has the single-size specification and identical color of 2mm, and prepare by the same procedure of example 4, the information of just having used property listed in the table 8 usually substitutes following cis-9-23 carbene.
Table 8
The information table of example
12 9-23 carbenes
13 10-methyl-9-23 carbene
14 cis-2-methyl-8-22 carbene
15 cis-9-22 carbene
16 cis-8-22 carbene
17 cis-10-22 carbene
The component that obtains by the identical method test of example 4, its result finds that every kind of component all occurs with the identical effect of invention composition in the example 4.
Example 18
(after this claim " compd A ", No. 5 Huangs of 1.04 grams, 0.1 gram cis-9-tricosane, 60 gram Icing Sugar and 20 gram nymphosis powder to mix by stirring mutually 0.6 gram (5-benzyl-3-furyl) methyl d-cis/trans-chrysanthemate.With a rotary evaporator (under 50 ℃ situation) solvent is removed from mixture.Sieve with a 2mm screens mixture and the part of big specification is ground into particle again.The combining powder of Huo Deing is blended together with 1.2 milliliters the aqueous binder solution of spraying (AmycolH) more like this, makes a kind of homogeneous granules specification of 2mm under pressure.Granulate mixture just can obtain a kind of according to malicious erbium composition of the present invention after 40 ℃ situation underlying is done 4 hours.
Example 19
A kind of malicious erbium composition of the present invention is to prepare by example 18 identical methods, only has been to use 40 gram nymphosis powder.
Example 20
The malicious erbium composition of a kind of table of the present invention is by the identical method preparation of example 18 gram, only be to use 10 gram flours and 30 gram glucose come for 1 generation Icing Sugar and 5 gram gravy substitute the pupa powder.
Example 21
A kind of malicious erbium composition of invention is to prepare by example 18 identical methods, has just used Permethrin and has come alternative compounds A.
Example 22
A kind of malicious erbium composition of the present invention is to prepare by example 18 identical methods, has just used Phenothrin and has come alternative compounds A.
The test example
Each 2 gram of the malicious erbium composition that is obtained in example 18,21 and 22 are placed a plastic cup (KP-430), contain 100 male adult flies in this cup.Along with the migration of time, check the fly numeral of knocking down.This result of table 9 explanation.
Table 9
Example is knocked down
After 5 minutes after 24 hours
18 100 100
21 100 100
22 100 100
Claims (9)
1, a kind of fly attracts its feature of composition as follows:
A) compound that attracts as a kind of fly, at least the pheromones that contains a kind of property, this pheromones is selected from the base group, this base group contains 9-23 carbene, cis-9-23 carbene, 10-methyl-9-23 carbene, cis-2-methyl-8-22 carbene, cis-9-22 carbene, cis-8-22 carbene and cis-10-23 carbene
B) have a kind of yellowish red color, Color Range is at 2.5R to 2.5YR,
C) be granular formulations, the single-size specification is between 0.5 to 5mm.
2, by the described composition of claim 1, the pheromones of wherein said property is cis-9-23 carbene.
3, by the described composition of claim 1, the range format of wherein said color is at 7.5R to 2.5YR.
4, by the described composition of claim 1, wherein said homogeneous granules specification amplitude is to about 3mm 1.
5, by the described composition of claim 1, wherein also contain a kind of pesticide compound.
6, by the described composition of claim 5, wherein said pesticide compound is a kind of pyrethroid compound at least.
7, by the described composition of claim 6, wherein said pesticide compound is a kind of compound that is selected from the base group at least, this base group contains 5-benzyl-3-furyl-methyl-d-cis/trans-chrysanthemate, 3-phenoxy benzyl cis/trans-chrysanthemate and 3-benzyloxy phenoxy base cis/trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid salt.
8, by the described composition of claim 7, wherein said pesticide compound is-5 benzyls-3-furyl methyl d-cis/trans-chrysanthemate.
9,, wherein contain a kind of picked-up temptation material and can be used as a kind of fly poison bait by claim 7 or 8 described compositions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86108161 CN1030680C (en) | 1985-07-18 | 1986-11-29 | Composition for attracting flies |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60158835A JPS6219504A (en) | 1985-07-18 | 1985-07-18 | Attractant for fly |
| CN 86108161 CN1030680C (en) | 1985-07-18 | 1986-11-29 | Composition for attracting flies |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86108161A true CN86108161A (en) | 1988-06-08 |
| CN1030680C CN1030680C (en) | 1996-01-17 |
Family
ID=25742266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 86108161 Expired - Fee Related CN1030680C (en) | 1985-07-18 | 1986-11-29 | Composition for attracting flies |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1030680C (en) |
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| CN102106356A (en) * | 2009-12-28 | 2011-06-29 | 住友化学株式会社 | Fly attractant composition and fly attracting method, as well as fly expellant composition and fly expelling method |
| CN102388913A (en) * | 2011-09-23 | 2012-03-28 | 湖北省农业科学院果树茶叶研究所 | Chip for trapping and killing citrus fruit fly, and preparation method thereof |
| CN102499242A (en) * | 2011-11-02 | 2012-06-20 | 云南农业大学 | Piophila casei attractant |
| CN103155917A (en) * | 2013-03-26 | 2013-06-19 | 德清科中杰生物科技有限公司 | Housefly attractant |
| CN104982433A (en) * | 2015-06-23 | 2015-10-21 | 潍坊友容实业有限公司 | Injurious insect attractant and application thereof in cape gooseberry saline-alkali soil planting |
| CN106614576A (en) * | 2016-10-28 | 2017-05-10 | 广州翼鲲植物保护有限公司 | Fly attractant |
| CN109640654A (en) * | 2016-05-30 | 2019-04-16 | 环球化学股份有限公司 | 9- tricosene is used to control the purposes of spotted wing drosophila |
| CN110250122A (en) * | 2013-07-22 | 2019-09-20 | 埃梅卡泰克有限责任公司 | For effectively inhibiting the system of fly population |
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1986
- 1986-11-29 CN CN 86108161 patent/CN1030680C/en not_active Expired - Fee Related
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| US9867374B2 (en) | 2009-12-28 | 2018-01-16 | Sumitomo Chemical Company, Limited | Fly attractant composition and fly attracting method, as well as fly expellant composition and fly expelling method |
| CN102106356A (en) * | 2009-12-28 | 2011-06-29 | 住友化学株式会社 | Fly attractant composition and fly attracting method, as well as fly expellant composition and fly expelling method |
| CN102388913B (en) * | 2011-09-23 | 2014-08-13 | 湖北省农业科学院果树茶叶研究所 | Chip for trapping and killing citrus fruit fly, and preparation method thereof |
| CN102388913A (en) * | 2011-09-23 | 2012-03-28 | 湖北省农业科学院果树茶叶研究所 | Chip for trapping and killing citrus fruit fly, and preparation method thereof |
| CN102499242B (en) * | 2011-11-02 | 2013-05-08 | 云南农业大学 | Piophila casei attractant |
| CN102499242A (en) * | 2011-11-02 | 2012-06-20 | 云南农业大学 | Piophila casei attractant |
| CN103155917A (en) * | 2013-03-26 | 2013-06-19 | 德清科中杰生物科技有限公司 | Housefly attractant |
| CN103155917B (en) * | 2013-03-26 | 2014-08-20 | 德清科中杰生物科技有限公司 | Housefly attractant |
| CN110250122A (en) * | 2013-07-22 | 2019-09-20 | 埃梅卡泰克有限责任公司 | For effectively inhibiting the system of fly population |
| CN104982433A (en) * | 2015-06-23 | 2015-10-21 | 潍坊友容实业有限公司 | Injurious insect attractant and application thereof in cape gooseberry saline-alkali soil planting |
| CN109640654A (en) * | 2016-05-30 | 2019-04-16 | 环球化学股份有限公司 | 9- tricosene is used to control the purposes of spotted wing drosophila |
| CN109640654B (en) * | 2016-05-30 | 2021-04-13 | 环球化学股份有限公司 | Use of 9-eicosatriene for controlling Onyctada punctata |
| CN106614576A (en) * | 2016-10-28 | 2017-05-10 | 广州翼鲲植物保护有限公司 | Fly attractant |
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|---|---|
| CN1030680C (en) | 1996-01-17 |
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