CN86103809A - General electrode cleaning device - Google Patents

General electrode cleaning device Download PDF

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Publication number
CN86103809A
CN86103809A CN 86103809 CN86103809A CN86103809A CN 86103809 A CN86103809 A CN 86103809A CN 86103809 CN86103809 CN 86103809 CN 86103809 A CN86103809 A CN 86103809A CN 86103809 A CN86103809 A CN 86103809A
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CN
China
Prior art keywords
electrode
fluid
cleaning device
spherical spinner
friction part
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CN 86103809
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Chinese (zh)
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CN1003216B (en
Inventor
赵秉烈
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NEW TECHNIQUE APPLIED INST GUANGZHOU
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NEW TECHNIQUE APPLIED INST GUANGZHOU
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Priority to CN86103809A priority Critical patent/CN1003216B/en
Publication of CN86103809A publication Critical patent/CN86103809A/en
Publication of CN1003216B publication Critical patent/CN1003216B/en
Expired legal-status Critical Current

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Abstract

A kind of electrode cleaning device general in fluid is made up of infundibulate shell, spherical spinner, friction member etc., and the fluid that need only rely on electrode to work therein drives.Friction member is easy to change, and mixes the friction member that coincide with the electrode sensitive face, can clean the electrode of Any shape.Have simple in structurely, volume is small and exquisite, can be general, can long-term continuous operation, and advantage such as not fragile.

Description

General electrode cleaning device
The present invention is a kind of electrode cleaning device general in fluid.Electrode is widely used in electrochemistry, and the occasion that has requires electrode to clean automatically down in working order.Existing electrode cleaning device except that uncommon ultrasonic cleaner, mainly is made up of motor, eccentric wheel, connecting rod, slide block etc., also has the fluid dynamic utilized to drive screw or impeller.Their shortcoming is: complex structure, can not miniaturization, eccentric wheel, linkage have the alternation radial component, make the electrode fatigue break easily, and load when becoming big the torque of motor also become greatly, that is to say meets with obstruction can not stop, this factor also makes electrode damage easily, in addition, they all can only be special-purpose, can not be general.
Task of the present invention provides the electrode cleaning device that a kind of simple structure, little, not fragile, the difform electrode of volume all are suitable for (promptly so-called " general ").
The electrode cleaning device that the present invention is general is made up of infundibulate shell (1), spherical spinner (2), friction part critical pieces such as (3), sees accompanying drawing 1, Fig. 2 (reference electrode does not draw).With its vertical orientation be connected in the fluid line of electrode work, just can utilize fluid to drive, carry out cleaning.
Embodiment one, the electrode that can freely process for sensitive area, and metal one metal oxide electrode for example, its cleaning device is fairly simple.Now take widely antimony one antimony oxide electrode (hereinafter to be referred as antimony electrode) (4) details are as follows for example:
With the vertical placement of infundibulate shell (1), glass marble is that spherical spinner (2) is placed in one, and the concave spherical surface that the end face of antimony electrode (4) is made and glass marble coincide is as the sensitive area that is cleaned.Antimony electrode is packed among the infundibulate shell coaxially, and sensitive area is above glass marble, at a distance of a small distance (about 1 millimeter).Be provided with O shape elastic washer (6) below the fastening nut of electrode (5), play holding electrode and sealing, and can allow electrode do the adjustment of axial location.Utilize the potential energy of fluid after having assembled or with pump fluid is imported from bottom to up, glass marble is followed the reciprocal axial displacement of generating period simultaneously just by the fluid driven rotary, and the sensitive area of antimony electrode is subjected to the periodic shock of glass marble and grinding and cleans up.Flow out from infundibulate shell upper opening after the fluid work done, collect or discard.
When fluid flows through diffusion admittance and walks around spheroid with radiation mode, can drive the spheroid rotation.This is existing expression in Soviet Union description of the invention SU-941665, and the present invention has done further simplification and improvement and has been applied in the cleaning of the electrode of working in the fluid.The remarkable improvement of the more above-mentioned Soviet Union of the present invention invention is to start voluntarily.Turning to during starting is at random, but once rotating turning to of just relatively keeping determining.For cleaning, turning to does not have decisive action, can select arbitrarily.Under the same conditions, rotating speed just becomes to become with flow, regulate flow can make rotating speed per minute several forward to 200 change between.
The axial displacement of above-mentioned glass marble (hereinafter to be referred as ball) is to produce like this: when the active force of fluid was not enough to raise ball, ball fell by gravity, and is tangent with hopper walls, and a circle is formed at the point of contact, and path is closed extremely.When the active force of fluid is enough to raise ball and opens passage, except that ball produced rotation effect, also because of the principle of continuity and the Bernoulli's theorem of fluid, ball is more than half of fluid dorsad, passage is very big, flow velocity is very slow, and pressure approaches atmospheric pressure, and meets the smaller part face to fluid, passage is relatively little a lot, flow velocity is very fast, and pressure is lower, for being defeated by atmospheric pressure.This pressure differential up and down forces ball to move down and closing passage.Pressure differential disappears thereupon this moment, so be returned to initial state again, fluid is raised ball once more, moves up and down endlessly so again and again.Under the same conditions, frequency becomes contravariant with electrode sensitive face to the distance between ball.Regulating this distance, can to make frequency remain on per second several conspicuous between tens hertz.
When moving the contact electrode sensitive area on the ball, because of time of contact very short, the momentum of ball is changed out bigger impulse force, can prevent and remove the fouling on the electrode sensitive face effectively, keeps constant surface state.In addition, this pulsation cleaning way is more energy-conservation, in water, is 10 millimeters to 25 millimeters solid glass ball for diameter, only 20 centimetres to 40 centimetres the height of water need be arranged, can reliably working.Ball is made hollow, then under the littler height of water, also can be worked.
Embodiment two, for sensitive area moulding, and the electrode that can not reprocess, its cleaning device is an example with ball bubble shape glass electrode (7), is described as follows:
The electrode that this type of sensitive area of all genus does not coincide with spherical spinner need only be changed the ball among Fig. 1 a spherical spinner (see figure 2) with the friction part (3) that coincide with the electrode sensitive face, just can solve.This rotor is to extend a hollow cylinder (8) on the main body of ball, will rub the part socket on it, and hollow institute capture power remains upwards facing to electrode the friction part.Also can not establish hollow and adopt other equivalent structure, for example the proportion of order friction part is light than spherical spinner, make whole centre of buoyancy that both are combined near friction part one end and center of gravity near the other end, can rely on buoyancy that the friction part is kept up equally.Difform electrode need only be used instead and its friction part that coincide, so can be general.When electrode limits when a kind of, then rub part and rotor can be made a hollow integral body.Ball bubble shape glass electrode sensitive area as thin as a wafer, damaged easily, should do the friction part with rubber, the strong material of plastics one class flexible resilient, its contact-making surface is made half concave spherical surface that coincide with the ball bubble, and can open some groove line or breach as required thereon, upgrade to strengthen friction and to be beneficial to fluid.On the friction part cap straight coupling and spherical spinner socket (stationary fit) are arranged.The installation of kind electrode cleaning device, starting and work are identical with embodiment one.Obviously, embodiment two also is applicable to the electrode of embodiment one, and embodiment one is the special case of embodiment two only, can simplify.
More than two embodiment be fluid and pass through from bottom to top, in fact whole device is inverted and is installed, and fluid is passed through from top to bottom, can also receive identical effect.When introducing fluid with siphon pipe; It is more convenient to be inverted installation.Embodiment one as the change on any structure, can directly not be inverted use.Embodiment two is inverted when using, and the combination of friction part and spherical spinner must be made the structure of centre of buoyancy near spheroid, and spheroid is remained upwards.
More than two embodiment all make, and in this institute laboratory, use, respond well.
Good effect of the present invention is: (one) is simple in structure, and element is few, and itself is not fragile, can adapt to the requirement in the medium-term and long-term continuous operation of fluid; (2) since the power resources of cleaning electrode in the friction of fluid, and frictional force mainly occurs in the very thin boundary-layer of rotor surface, and when load increased to the motionless rotor of fluid band, fluid just slipped over outside boundary-layer, it is excessive to be that driving force can not increase, thereby not fragile electrode; (3) need only prepare the friction part that some and difform electrode coincide one by one, just can accomplish general; (4) volume can be done very littlely, can also make one with electrode, can install in narrow space, thereby applicability is strong; (5) easily sealing is particularly suitable for using in the fluid that does not allow to leak with outside contamination; (6) make easily, production cost is low; (7) energy savings.
The specification errata
Page or leaf OK Before the revisal After the revisal
1 13 With it The circular cone of infundibulate shell, its drift angle are that 50 degree are to 90 degree.With it
1 21 (about 1 millimeter) (0.5 millimeter to 3 millimeters)
2 17 Several conspicuous to tens hertz Several times to tens times
3 1 Ball bubble shape If it is darker that the friction part is inserted in electrode, both are difficult for slippage, then can save hollow, promptly do not utilize the buoyancy orientation, but not brisk if any the work of buoyancy orientation.Ball bubble shape

Claims (3)

1. general electrode cleaning device is a kind of fluid dynamic wash machine that can match corresponding friction part according to electrode shape, be connected among the pipeline of working fluid its vertical orientation, drive by fluid, it has infundibulate shell (1), spherical spinner (2), friction part main building blocks such as (3), feature of the present invention is, pack into the small end of infundibulate shell of spherical spinner, contact with hopper walls circle inscribe, be installed on to the electrode dead in line the big end of infundibulate shell, between electrode sensitive face and spherical spinner or attached thereon the shape and the friction part that coincide of electrode sensitive face, keep 0.5 millimeter to 3 mm distance.
2. electrode cleaning device according to claim 1 is characterized in that the circular cone of infundibulate shell, its drift angle are that 50 degree are to 90 degree.
3. electrode cleaning device according to claim 1, the combination of it is characterized in that rubbing part and spherical spinner is the structure that centre of buoyancy and center of gravity do not coincide.
CN86103809A 1986-05-30 1986-05-30 Washing device of universal electrode Expired CN1003216B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN86103809A CN1003216B (en) 1986-05-30 1986-05-30 Washing device of universal electrode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN86103809A CN1003216B (en) 1986-05-30 1986-05-30 Washing device of universal electrode

Publications (2)

Publication Number Publication Date
CN86103809A true CN86103809A (en) 1987-04-15
CN1003216B CN1003216B (en) 1989-02-08

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Application Number Title Priority Date Filing Date
CN86103809A Expired CN1003216B (en) 1986-05-30 1986-05-30 Washing device of universal electrode

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CN (1) CN1003216B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102053111A (en) * 2010-11-18 2011-05-11 上海衡伟信息技术有限公司 On-line pH electrode cleaning device
CN103675069A (en) * 2012-09-13 2014-03-26 阿尔斯通技术有限公司 Cleaning and grinding of sulfite sensor head
CN104259149A (en) * 2014-07-23 2015-01-07 宁波钰烯阴极保护材料有限责任公司 Surface coating treatment equipment for tubular ferrosilicon positive electrode
CN109026276A (en) * 2018-06-29 2018-12-18 江苏理工学院 A kind of engine pressure balance-conditioning system
CN109057914A (en) * 2018-06-29 2018-12-21 江苏理工学院 A kind of engine pressure balance system

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102053111A (en) * 2010-11-18 2011-05-11 上海衡伟信息技术有限公司 On-line pH electrode cleaning device
CN102053111B (en) * 2010-11-18 2013-03-27 上海衡伟信息技术有限公司 On-line pH electrode cleaning device
CN103675069A (en) * 2012-09-13 2014-03-26 阿尔斯通技术有限公司 Cleaning and grinding of sulfite sensor head
US9579765B2 (en) 2012-09-13 2017-02-28 General Electric Technology Gmbh Cleaning and grinding of sulfite sensor head
CN103675069B (en) * 2012-09-13 2017-04-12 通用电器技术有限公司 Cleaning and grinding of sulfite sensor head
CN104259149A (en) * 2014-07-23 2015-01-07 宁波钰烯阴极保护材料有限责任公司 Surface coating treatment equipment for tubular ferrosilicon positive electrode
CN109026276A (en) * 2018-06-29 2018-12-18 江苏理工学院 A kind of engine pressure balance-conditioning system
CN109057914A (en) * 2018-06-29 2018-12-21 江苏理工学院 A kind of engine pressure balance system
CN109026276B (en) * 2018-06-29 2020-09-15 江苏理工学院 Engine pressure balance adjustment system

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CN1003216B (en) 1989-02-08

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