CN86102003A - Metal-sticking technology - Google Patents
Metal-sticking technology Download PDFInfo
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- CN86102003A CN86102003A CN 86102003 CN86102003A CN86102003A CN 86102003 A CN86102003 A CN 86102003A CN 86102003 CN86102003 CN 86102003 CN 86102003 A CN86102003 A CN 86102003A CN 86102003 A CN86102003 A CN 86102003A
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- sticking
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- glue
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Abstract
The invention relates to metal film is transferred to a kind of method on the printed material.Its major technique feature is: will glue gold copper-base alloy by the adhesive that is fit to and paste mutually with printed material, will glue the gold copper-base alloy substrate behind the adhesive solidification and remove, and stay ornamental very strong metallic film on printed material, and improve product appearance.Sticking gold process is simple and easy to do, not limited by the material of place and printed material, and it is applicable to the sticking seal of multiple materials such as plastics, metal, fabric, building materials, timber, glass, pottery, rubber, fiberglass, bamboo, turf leather.
Description
The invention relates to metal film is sticked with glue the sticking method that prints on the objects such as metal, fabric, building materials, plastics, timber, glass, pottery, rubber, fiberglass, paper, bamboo, grass, leather of agent.
The present invention abbreviates metal-sticking technology as, sticking is imprinted on metal film on the object sticking golden film, glues golden material therefor sticking gold copper-base alloy.
The invention belongs to the printing class.
The prior art approaching with the present invention is gilding technology.
Gilding technology is a kind of printing method for processing.The equipment that thermoprint need have the heating apparatus that pressurizes during thermoprint heats metallic plate, and discharge bronzing material on printed material, and pressurization can be at printed material such as book cover then, or impresses literal or pattern on other printed matter.Thermoprint in recent years also can be used for decoration on dial plate, panel and the recorder shell of plastic instrument instrument etc.
Gilding technology has boiling hot metal forming (gold, silver, copper, aluminium foil), scald the toner paper tinsel, scald embossing seal etc. several.
There are following three aspect deficiencies in gilding technology:
1, can not realize the three-dimensional thermoprint of object.
2, can not thermoprint under the condition that breaks away from hot stamping equipment and metal printing forme.
3, be only limited to thermoprint on minority materials such as paper, plastics, timber, leather, varnished cloth, silk.
Owing to above-mentioned deficiency, limited the scope of application of gilding technology.
The prior art approaching with the present invention also has the straight aluminium plating terylene film that pastes.The straight subsides is: with aluminium plating terylene film on request size cut out, stick with glue agent and directly be attached on the object.The common edge on the plastic products that has mounts decorations, and the subsides on the bicycle are decorated with and paste certainly the aluminium plating terylene film trade mark.Because whole straight the subsides together with substrate.Lack the coordination sense of one, sticker intensity is also owing to the existence of substrate is affected.
The objective of the invention is to remedy gilding technology and straight deficiency of pasting aluminium plating terylene film, at wider realization metallic film decoration.
The present invention is on printed material, or the suitable adhesive of coated on the sticking gold copper-base alloy, will glue the gold copper-base alloy substrate then and paste mutually with printed material outwardly, flattens, treat that adhesive solidifies fully after, substrate is removed, metal film is just sticking securely to be imprinted on the printed material.
After solidifying fully, adhesive removes the sticking golden film of substrate, smooth and bright surface, and the gloss and the texture of metal are strong.If throw off substrate when adhesive does not solidify fully, then sticking golden film lustrous surface is soft.In order to improve the wearability and the service life on sticking golden film surface, can be coated with one deck protection glue-line on the surface.The protection glue-line can be that unsaturated polyester (UP) adhesive or polyacrylate powder coating resin etc. are transparent, ageing resistace good, the adhesive of strong adhesion or coating.
Sticking gold copper-base alloy is a substrate with polypropylene film or polyester film etc., and substrate thickness can be decided according to instructions for use, generally should be about 10～30 microns.On substrate, be coated with after the remover, be coated with the coloured transparent adhesive tape of one deck again, can print decorative pattern and pattern on the glue-line.Method with vacuum evaporation plates metal film at last, and thicknesses of layers is about the 500 Izod right sides, and metal membrane material is an aluminium.
The substratum transparent of coating before the metal-coated membrane can shield to sticking golden film.
Do general ornament materials or can be when not high with common bronzing material or the bronzing material that is not coated with PUR for making sticking gold copper-base alloy to sticking requirement of strength.
In sticking gold process, it is very important selecting suitable adhesive, and it directly affects sticking seal intensity, service life and the sticking seal quality of metal film.Should select adhesive for use according to physics, chemical property, purposes, the environment for use of printed material.Also note that performance, characteristics and the price etc. of adhesive itself when selecting for use.
Can select for use fabric, leather:
Maleate-vinyl acetate adhesive;
Phenolic aldehyde-neoprene adhesive;
Two component neoprene sticks;
The resin modified neoprene adhesive;
Phenolic aldehyde nitrile rubber adhesive.
Can select for use timber, bamboo, grass:
The polyvinyl acetate adhesive;
Polyurethane adhesive;
Polyurethane paint.
Can use neoprene-modified phenolic adhesive to rubber.
Can select for use metal, plastics, glass, pottery:
Epoxy resin-Versamid adhesive;
Epoxy resin gathers the sulphur adhesive;
Give the aggressiveness polyurethane adhesive;
The unsaturated polyester resin adhesive;
The acrylic acid polyester resin adhesive.
Can select the unsaturated polyester (UP) adhesive for use to cement, building stones.
Should select for use non-polar material polystyrene, polyethylene, polypropylene:
Neoprene adhesive;
Polyurethane resin adhesive.
Should select for use low pole materials A BS plastics, lucite, fiberglass etc.:
The epoxy polysulfide rubber adhesive;
The unsaturated polyester (UP) adhesive.
Above-mentioned adhesive majority is normal temperature cure, in 24 hours hardening times.
Except selecting above-mentioned hot-setting adhesive or thermoplastic for use, under to the less demanding situation of sticking seal fastness, can also adopt pressure-sensitive adhesive, as acrylate pressure-sensitive adhesive etc.
In order to guarantee sticking seal quality, the reply metal printed material processing of rust removing of deoiling before gluing; The decontamination of deoiling is handled to nonmetallic materials; Also should remove surperficial plasticizer, remover etc. to plastics.
Gluing can be taked roller coating, spraying according to material, shape, the state of printed material, method such as brush, bite.For the bigger adhesive of viscosity, can take to scrape coating method.
Contain the adhesive of inertia dissolubility such as phenolic resin glue etc., should hang behind the gluing 20～30 minutes, treat to paste again after solvent is given full play to.
In order to guarantee sticking golden amount, make it even, complete, available roll extrusion, brush equality method make sticking gold copper-base alloy closely paste mutually with printed material, do not interspace.
Three-dimensional gluing when printing can will be glued gold copper-base alloy according to the printed material body and be cut off sticking seal, will note at corner angle and lap-joint blank place being arranged during sticking printing.Find that but blank coating adhesive benefit is sticking.For complex-shaped printed material, can make softening back of substrate and the sticking clothes of printed material by blowing hot-air.But note the adhesive of selecting solidification temperature high slightly, guarantee sticking seal quality.
Metal-sticking technology is convenient and easy, is not subjected to the restriction of place and printed material material.Therefore be of wide application.Utilize metal-sticking technology can make the sticking golden fabric that can wash, sticking golden fabric not only can be made clothes, and can make parasols, awning, sunbonnet and handbag, wallet, curtain, sheet, quilt cover or the like.
Sticking gold not only can be decorated, and rust-proof effect is arranged on metal.Sticking golden film can become the ornament on bicycle, motorcycle, automobile, sewing machine and household electrical appliance, the instrument and meter.
Sticking golden film will be widely used in the decoration of various plastic products, and it can make product more exquisite.
Metal-sticking technology can also be used for the decoration of construction material, straw-made articles, leather, wooden furniture, pottery, rubber and glass.Metal-sticking technology has wide application future in a word.
Applicating example
Following example is used for illustrating the present invention, and does not limit the present invention.
1, sticking seal metal film on fabric
The sticking gold of fabric is selected for use along the vinegar copolymer emulsion adhesive, and its composition and weight ratio are vinyl acetate 262.5, dibutyl maleate 112.5, ammonium persulfate 2.5, polyvinyl alcohol 32.4, water 437.5.Have along vinegar emulsion copolymer stick that bonding force is better, water-fast, ageing-resistant, creep-resistant property is good; Advantage such as nontoxic, easy to use, cheap.
The sticking gold of large tracts of land adopts the roll coating process gluing, will note not starved during gluing, can be coated with in case of necessity 2 times.Behind the gluing, fabric and sticking gold copper-base alloy press together by adjacent two squeegees together up and down.Through the ventilation path of pressing composite bed by 20 ℃～40 ℃ of temperature, placed then 24 hours, to treat to throw off substrate after adhesive solidifies fully, the sticking gold of large tracts of land fabric has just been finished.
The sticking golden fabric of large tracts of land can be done parasols, awning, curtain etc.Also can make a hat, gloves bag, wallet etc., can also do ornament materials.Umbrella, paulin that sticking golden fabric is made can reflect the solar radiant energy about 80%, and shaded effects are good.
Sticking bronze printing belongs to film figure and decorative pattern on fabric, gluing can adopt silk screen process to stamp adhesive pattern on fabric, take then and the sticking metallographic of fabric large tracts of land method together, gold copper-base alloy will be glued and fabric pressing lumps together, after treating adhesive solidification, throw off substrate, the sticking golden pattern on the fabric forms at this point.
The fabric that has sticking golden pattern is magnificent, and certain shaded effects are arranged, and is mainly used in clothes, can do also that umbrella is fluffy, curtain, cap etc.
Sticking golden patterned fabric is done summer clothes certain cooling-down effect.
Do printed material with canvas, select for use phenolic aldehyde nitrile rubber adhesive to make sticking golden canvas, have the advantage of reflective thermal radiation energy, can make the high temperature insulating clothes.For ventilative, lines can leave some space when sticking seal.
Phenolic aldehyde-nitrile rubber stick composition and weight proportion are: the first component: resorcinol formaldehyde resin 75; Component B: fourth is fine
40100, paraformaldehyde 12.5, reinforced white carbon black 10, zinc oxide 5 TM monex TD4.
First: second=1: 6
Sticking seal technology is identical with fabric.
2, be imprinted on the metallic article metal film is sticking
The sticking seal of planar metal is selected epoxy-Versamid adhesive for use, and its composition and weight proportion are: 618
#3 parts of epoxy resin, 400
#1 part of polyamide.Epoxy one Versamid is toxic little, adhesive strength height, advantages such as acid and alkali-resistance.
The sticking gold of curved surface is selected the acrylic acid polyester resin adhesive for use, and its composition and weight proportion are: 313
#Mylar 45.2; Methacrylate 9.6; Acrylamide 26.2.
The acrylic acid polyester resin adhesive has that strong, the bonding scope of bonding force is wide, ageing-resistant performance good, to by advantage such as printed material material surface treatment requirement is not strict.
Use the sand paper deburring before the sticking seal, deoil with gasoline, derust with hydrochloric acid, water is rinsed well.
Epoxy resin one Versamid adhesive coats glue sticking gold copper-base alloy is pasted mutually with printed material with knife coating gluing on printed material, and with the squeegee pushing, drives gas out of, makes it to paste closely, places 24 hours, treats to throw off substrate behind the adhesive solidification.
Acrylic size adopts brushes.Because sticking seal on three-dimensional object or curved surface.Note not starved when therefore brushing.Coat glue and be the sticking gold copper-base alloy of Pasting, can cut off to paste and notice that lap-joint is not blank gluing gold copper-base alloy in case of necessity.It is flat with stickup face brush to paste available scrub-brush, and drives gas out of.Post the back and placed 12 hours, treat to throw off substrate behind the adhesive solidification.If having the sticking place of leakage can be coated with cyanacrylate adhesive mends sticking.
The all available said method of sticking golden clothes decorations such as bicycle, sewing machine, motorcycle, automobile, household electrical appliance, electronic instrument is realized.The available heat curing-type polyacrylate powder coating resin in sticking golden film surface is made protection glue, and this coating resin has the light of guarantor colour retention can be good, strong adhesion, characteristics such as shock-resistant.
3, the sticking gold of straw-made articles
The sticking gold of straw-made articles is selected solvent-borne type vinyl acetate adhesive for use, 100 ℃ of solidification temperatures.Its composition and weight proportion are: poly-vinegar ethene 20～40, acetone 60～80, zinc chloride 3.Zinc chloride adds before use.It is strong that solvent-borne type polyvinyl acetate adhesive has a bonding force, characteristics such as glue-line softness.Gluing adopts brushes, and presses layout coating adhesive on straw-made articles, sticks sticking gold copper-base alloy, and blowing hot-air makes substrate softening then, and takes advantage of the occasion will glue gold copper-base alloy and be pasted clothes by the seal straw-made articles with hairbrush, treats behind the adhesive solidification substrate to be thrown off.
The main decoration function that rises of sticking gold on the straw-made articles.
4, the sticking gold of cement, building stones
The sticking gold of cement, building stones is selected the unsaturated polyester (UP) adhesive for use, and its composition and weight proportion are 306
#Unsaturated polyester (UP) 50; 3193
#Unsaturated polyester (UP) 50, cycloethanone peroxide (50%DBP solution) 3～4; Cobalt naphthenate (2% solution) advantages such as 2. the unsaturated polyester resin adhesive has the adhesive strength height, viscosity is low, and is easy to use, cheap.
Cement, the sticking gold spread coating gluing of building stones will glue gold copper-base alloy with scrub-brush after pasting and develop, and treat behind the adhesive solidification substrate to be thrown off.
If when being used for exterior decoration, also can select the sticking gold of acrylic acid polyester resin adhesive for use, sticking golden film can be done diaphragm with the polyacrylic acid powder coating resin.
Claims (6)
1, a kind ofly prints to method on the printed material metal film is sticking.Major technique feature of the present invention is: on printed materials such as metal, fabric, building materials, plastics, timber, glass, pottery, rubber, fiberglass, paper, bamboo, grass, leather or be coated with one deck adhesive on the sticking gold copper-base alloy, to glue golden material substrate then pastes mutually, flattens with printed material outwardly, treat that the substrate that will glue gold copper-base alloy behind the adhesive solidification removes, on the just sticking securely printed material of metal film.If when adhesive does not solidify fully, throw off substrate, the soft surface of lustrous surface will be obtained.In order to improve the wearability and the service life on sticking golden film surface, can be again coating protection glue-line from the teeth outwards.
2, by the said method of claim 1, adhesive can be hot-setting adhesive, thermoplastic or pressure sensitive adhesive.
3, by the said method of claim 1, sticking gold copper-base alloy can replace with common bronzing material or the bronzing material that is not coated with PUR.
4, by the said method of claim 1, the protection glue-line on sticking golden film surface can with thermosetting polyacrylate powder coating resin or other be transparent, ageing resistace good, the adhesive of strong adhesion or coating.
5, product such as sticking golden fabric of making by the said method of claim 1 and clothes, paulin umbrella, quilt cover.
6, the high temperature insulating clothes of making by the said method of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86102003 CN86102003A (en) | 1986-03-23 | 1986-03-23 | Metal-sticking technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86102003 CN86102003A (en) | 1986-03-23 | 1986-03-23 | Metal-sticking technology |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN86102003A true CN86102003A (en) | 1987-10-14 |
Family
ID=4801586
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 86102003 Pending CN86102003A (en) | 1986-03-23 | 1986-03-23 | Metal-sticking technology |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN86102003A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101318436B (en) * | 2007-06-06 | 2010-05-26 | 曾正华 | Heat transferring tackiness positioning method for hot paper |
| CN101457492B (en) * | 2008-11-18 | 2011-06-15 | 吴江市凌通纺织整理有限公司 | Fabric gold stamping technological method |
| CN105667109A (en) * | 2016-01-13 | 2016-06-15 | 宁波创源文化发展股份有限公司 | Gold blocking method for printing paper |
| CN108908667A (en) * | 2018-06-28 | 2018-11-30 | 南京中高知识产权股份有限公司 | A kind of ceramics gilding technology |
-
1986
- 1986-03-23 CN CN 86102003 patent/CN86102003A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101318436B (en) * | 2007-06-06 | 2010-05-26 | 曾正华 | Heat transferring tackiness positioning method for hot paper |
| CN101457492B (en) * | 2008-11-18 | 2011-06-15 | 吴江市凌通纺织整理有限公司 | Fabric gold stamping technological method |
| CN105667109A (en) * | 2016-01-13 | 2016-06-15 | 宁波创源文化发展股份有限公司 | Gold blocking method for printing paper |
| CN108908667A (en) * | 2018-06-28 | 2018-11-30 | 南京中高知识产权股份有限公司 | A kind of ceramics gilding technology |
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