CN85103491A - The coating that can form the class ceramic coating is formed and the preparing such coating method for compositions - Google Patents
The coating that can form the class ceramic coating is formed and the preparing such coating method for compositions Download PDFInfo
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- CN85103491A CN85103491A CN198585103491A CN85103491A CN85103491A CN 85103491 A CN85103491 A CN 85103491A CN 198585103491 A CN198585103491 A CN 198585103491A CN 85103491 A CN85103491 A CN 85103491A CN 85103491 A CN85103491 A CN 85103491A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
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Abstract
Having disclosed a kind of special coating forms, comprises a kind of cement, a kind of batching (A), and a kind of composition (B) that contains latex.Batching (A) contains several components, and (1) a kind of shaping gather materials powder, (2) a kind of derivatived cellulose and (3) a kind of metal-salt than high fatty acid that can be water-soluble are wherein arranged.When the aforementioned coating composition coated to a kind of substrate, just can provide a kind of and improve water repelling property, improve the stability surface of the wearing and tearing of anti-surface tear and the performance of fading.Also disclosed the method for preparation aforementioned coating composition.Coating composition of the present invention can be coated on a kind of substrate, for example forms a kind of coating with spraying method, when this coating curing or sclerosis, just can provide a kind of class ceramic surface of growing timeliness.
Description
Theme of the present invention is, just can form the coating component of a kind pottery and preparing such coating method for compositions at substrate surface without sintering.The present invention will be formation waterproof or decorative surface in civil engineering and construction work, and will obtain to use in making civil engineering material or material of construction.
In the past, " ceramic coating " speech is meant such class refractory coating, and this type coating is that sintering forms on some metallic substance the glaze of enamel frit and refractory mix composition, today, this speech has been used for summarizing whole coatings of being produced by various new coating technologies.
Be used in ceramic furring brick on the building concrete wall with the requirement that improves its U.S. or water-proof surface is provided, this has been the common practice.The pottery furring brick also is used for providing water-proof surface for washroom, kitchen, trough washer and bathing pool.But all stupaliths all are to become by sintering glaze body.The production of pottery furring brick is no exception, also relates to a complicated procedures of forming of burning till this furring brick simultaneously.Like this, for the surface of ornamental or waterproof is provided, and ceramic furring brick is attached on the outer wall or inwall or ground of buildings, just need pays huge work and very high cost.
The practice of another kind of band ubiquity is to paste the lining metal surface with glass, or one deck enamel coating is provided on the metallic surface.So,, relate to again mixture of raw material be melted to strong physical work on the metallic surface and expensive operation in order to form this kind glass lining or enamel coating.
In order to produce class pottery waterproof paster face brick, and do not involve in the cellar for storing things sintered body or melt raw-material complex steps, the inventor once was engaged in research miscellaneous, to develop a kind of easy method.At last, the inventor finds the following fact: after the coating composition prepares, for example, with behind a kind of cement and the powdered mixture mixing that is shaped with gather materials powder and methylcellulose gum and calcium stearate, add a kind of SBR latex and water again, then it is coated on the substrate of slabstone, concrete blocks, concrete slab and so on or on the metal sheet, can forms outward appearance and character with coating like the ceramic-like.A kind of like this coating is formed and can be used in other substrates.For example on the different substrates and plank of porous plastics or other plastic mould pressing goods and so on, can both form same coating.The present invention succeeds according to these clues.
The present invention be directed to a kind of like this coating and form, it can form the coating or the surface of class pottery on the substrate of institute's coated.
The special coating of this kind is formed and is comprised a kind of tackiness agent, a kind of batching (A) and a kind of batching (B) that contains latex.Batching (A) contains several compositions, comprising, (1) a kind of shaping with the powder that gathers materials, (2) a kind of water-soluble derivatived cellulose, and the metal-salt of (3) a kind of more senior lipid acid.When this coating is formed compress to substrate, just can provide improved water-resisting property, improved scratch resistance, the surface with permanent stability of the anti-surface abrasion and the character of fading.
Also comprise the above-mentioned coat composed method of preparation in the scope of the present invention, for example, will prepare burden (A) and a kind of cement mixing, then the mixture that obtains has like this been added the batching (B) that contains latex.This kind coating composition can be formed coating with spraying one class methods coated to substrate then, after its solidifies or hardens, just provide a kind of class ceramic surface of growing timeliness.
In one embodiment of the invention, the coat composed rete of this kind that is formed on the substrate surface at first hardens, then with a kind of can form transparent glossy coating again coated on the above-mentioned coating of hardened, so just made a kind of outward appearance and character with the extremely similar coating of pottery, the examples of paints that can form a kind of transparent gloss coating is vinylformic acid or urethane resin latex.
For this reason, first purpose of the present invention is to provide a kind of like this coating composition, and it can not need firing process just can form a kind ceramic coating on the surface of any substrate with a kind of easy technology.
Second purpose of the present invention is to provide the method for a kind of like this coating composition of preparation, and it can not need firing process just can form a kind ceramic coating on the surface of any substrate with a kind of easy technology.
The 3rd purpose of the present invention is to provide a kind of method, do not need firing process, just can form a kind of coating with class pottery outward appearance and character by easy technology.
According to the present invention, a kind of cement and cement admixture are mixed, the latter is contained the metal-salt of powder, derivatived cellulose and a kind of more senior lipid acid of gathering materials that is shaped.Add latex and water to form a kind of coating composition in this mixture, coated forms coating to substrate then, if the moisture content that exists in the latex is very high, so, just need not add water more usually.Then, this kind coating is promptly solidified, or sclerosis, becomes the class ceramic coating on substrate surface.
Can on the class ceramic coating of making in a manner described, answer the coating that the cloth last layer can form transparent gloss coating again, the final like this coating that obtains, its outward appearance and character and ceramic-like are seemingly.
The regular step of preparation the present invention used coating composition is: 10 kilograms cement are mixed with the shaping of about 5 to 20 kilograms (preferably 12 to the 17 kilograms) powder that gathers materials, the derivatived cellulose of about 5 to 500 grams (preferably 7 to 50 grams), and the metal-salt of the more senior lipid acid of about 10 to 1000 grams (preferably 100 to 500 grams); Then the mixture of gained is added the latex of about 2 to 10 kilograms (preferably 4 to 6 kilograms), and (where necessary) water of 4 to 8 kilograms, even mix by stirring closely with each relevant component.Painted if desired class ceramic coating then can add pigment or dyestuff again to such coatings formulated composition.Can also in this kind coating composition, add a kind of fibrous material 10 to 1000 grams again, be well 100 to 600 grams again, the advantage that contains the coating composition of this fibrous material is can form a kind of flexible on substrate surface, the class ceramic coating of tear strength.
In the coating composition of foundation the present invention preparation, used cement forms a kind ceramic coating with the shaping powder that gathers materials.The cement of any routine all can adopt, as an illustration, the example of this respect has ordinary Portland cement, cement that initial strength is high, borrow just energy hardened cement of suitable heat, white portland cement, fly ash cement, portland-pozzolan cement, and the blast-furnace cinder silicate cement, wherein suitable with ordinary Portland cement.
The shaping powder that gathers materials is selected from the powder of a following class common rocks, comprises grouan, marble, serpentinite, peridotites, zircon sand stone and Wingdale or the like, and quartz sand and ceramic powder.Because most purposes of class ceramic coating require water-repellancy, the powdery rock then has a spot of water-absorbent, so preferably adopt ceramic powder, the powder that gathers materials of being shaped can be had any granularity, but size range with 30 to 400 orders for well, and better during especially with 42 to 325 orders.In order to produce the composition that outward appearance and character are similar to pottery, normal compact structure and the water resisting property that requires to have height, for reaching this purpose, the shaping powder that gathers materials is preferably wanted the such size-grade distribution of tool, make and to have 20%(weight at least) its granularity of this kind powder less than 100 orders, and have 40%(weight at least) greater than 100 orders, thick preferably is ground into by ceramic material.
Interpolation is not only in order to improve adhesivity and the water resisting property to substrate than the metal-salt of high fatty acid, also is in order to be injected into coating more smoothly with spray gun simultaneously.Be fit to the metal-salt than high fatty acid of this purpose, comprise calcium stearate, Magnesium Stearate, Zinic stearas, lead stearate, Palmiticacid calcium, Palmiticacid magnesium, zinc palmitate, lead palmitate, Magnesium monolaurate, zinc laurate, lead laurate, calcium oleate, magnesium oleate, zinc oleate and lead oleate.Wherein, comparatively desirable with calcium stearate, Zinic stearas, Palmiticacid calcium and zinc palmitate.
The purpose that adds fiber derivative not only is to improve the binding property of cement, simultaneously also in order to increase the viscosity of coating composition, help continue after the coating operation.Remove this, also can make this coating coated not cause the loss of coating to approaching on the axial substrate.The derivatived cellulose that is fit to this respect purposes comprises carboxymethyl cellulose, methylcellulose gum, ethyl cellulose and cellulose acetate, and is best with methylcellulose gum and carboxymethyl cellulose.
The result who increases latex can improve the elasticity of cement and improve its adhesivity.This will help to provide a kind of outward appearance and character with coating like the ceramic-like.Various natural and synthetic latex all can be used, comprising natural rubber latex, vinylbenzene polyvinyl butadiene rubber (SBR) breast, polyvinyl butadiene rubber (BR) breast, isoprene glue (IR) breast, neoprene latex (CR) breast, acrylonitrile polyvinyl butadiene rubber (NBR) breast, vinylformic acid (ACR, ANM) latex and urethane latex.Best example is natural rubber latex, SBR latex and NBR latex.
According to the present invention, can in forming, coating composition add fibrous material, whereby, can on substrate surface, form the class ceramic coating of shock resistance and anti tear.Conform with this respect application purpose fibrous material comprise vinylon, nylon, trevira, polypropylene fibre, polyacrylonitrile, alkali resistant glass fibre, asbestos, mineral fibre, wollastonite, metal titanium silicate fiber with and a little pottery fine.For cost and otherwise reason, preferably select vinylon and alkali resistant glass fiber for use.
According to the present invention, such coating is formed the method that the multiple method to substrate of cloth comprises following any routine, for example spray, brushing, dip-coating, flow coat, carry out manual coating so that paint cutter.Preferably adopt simple spraying method, this is because this coating of the present invention is formed, though very high aggregate content is arranged, is fit to spraying coating process, and can obtains the class ceramic coating of good artistic appeal in this way.
Coating composition of the present invention can be used on the substrate of any kind, for example the trade(brand)name of the light weight concrete crossed of concrete product, mortar product, porous plastics, timber-work, Silica-licito(hot-pressing processing), wall, ground or the top ceiling of metal, glass, buildings; More particularly concrete slab, concrete blocks, mortar plate, slabstone, concrete brick, mortar brick, porous plastics molding, metal products, the asbestos material that flexibility is arranged, calcium-silicate plate and cover tile, and the concrete wall of buildings, mortar wall, concrete floor, mortar ground and bituminous pavement.Coating composition of the present invention can form the coating of class pottery on above-mentioned any substrate.
Coating composition of the present invention can coated to no matter be level, on the axial or substrate that tilts.This coating is formed the both sides of the axial substrate of coated to easily.
When being coated to a kind of coating composition that adds pigment or dye coloring on the substrate, a kind of chromatic with regard to forming, thereby the coating that is similar to pottery more true to nature.Such pigmented coating, both can coated on whole substrate surface, also can execute cloth position through selecting and so as to forming pattern on substrate.If need the polychrome coating, that just can be coated with all surfaces that covers substrate with the different coating of multiple color, or their compress part through selecting and desirable pattern is provided to the substrate.Utilize spraying method, can at first spray first kind of colored coating, then before this one deck is still unhardened, spray second kind of colored coating again, so just can obtain a kind of two-tone image with diffusion term line.According to the class ceramic coating that above-mentioned operation forms, can obtain the outward appearance of class pottery by a kind of external coating (EC), this external coating (EC) then forms by forming transparent glossy coating or a kind of lustre colour material.
When the substrate that scribbles coating of the present invention being remained in room temperature condition following time, then the coating on the coated will could form the coating of class pottery several days time to an about week.The coating of a kind pottery like this has good water resisting property, and its surface then presents graceful artistic charm.So, the single outside for buildings of this kind coating provides decorative surface with the road surface of paving, the place that it can also need water to clean in buildings is the wall and the ground of washroom, kitchen, bathroom and other parts, as the surrogate of furring brick.
At severe cold area, the water in concrete or the mortar slit can freeze in sub-zero temperature, and melts under higher temperature; If such thermal cycling repeats repeatedly, then in these concrete or mortar as pavement course or basis, the observation mark part on expression border, ground perhaps in the protective wall part of embankment, often damages in the reinforcement wall part of embankment probably.If on suitable substrate, form the complete fluid-tight coating of one deck of preparation, just can avoid above-mentioned fault according to the present invention.
Example given below is to be used for further setting forth the present invention, and should not see a kind of restriction as.
Example 1
The preparation of cement Additive (A):
With size-grade distribution is the powder of 59.58 kilograms Mirabilitum crystallina (crystallization Wingdale) shown below, and methylcellulose gum and the 360 calcium stearate thorough mixing that restrain with 60 grams are mixed with a kind of cement Additive (60 kilograms).
The size-grade distribution of Mirabilitum crystallina is:
+ 42 orders 3.00% (weight)
+ 60 orders 17.20% (weight)
+ 80 orders 20.80% (weight)
+ 100 orders 10.75% (weight)
+ 200 orders 32.60% (weight)
+ 325 orders 14.50% (weight)
+ 325 orders 1.15% (weight)
Example 2
The preparation of cement Additive (B):
With used identical 59.28 kilograms of methylcellulose gum of Mirabilitum crystallina powder, the calcium stearates and the 300 useless vinylon fiber thorough mixing that restrain of 360 grams in size-grade distribution and the example 1, be mixed with a kind of cement Additive (60 kilograms) with 60 grams.
Example 3
The preparation of coating composition (1):
Ordinary Portland cement (40 kilograms) is closely mixed with the 60 kilograms of cement Additives (A) that prepare in the example 1.Add 20 kilograms vinylbenzene polyvinyl butadiene rubber breast (SBR) and 17 kilograms water to this mixture, above various components are mixed fully, form 137 kilograms coating composition (1).
Example 4
The preparation of coating composition (2):
With the same cement admixture (B) according to example 2 preparations of ordinary Portland cement (40 kilograms), and size-grade distribution is 30 gram ceramic powder thorough mixing shown below.In this mixture, add 20 kilograms vinylbenzene polyvinyl butadiene rubber breast (SBR) and 17 kilograms water, make the above thorough mixing of respectively organizing then, form 167 kilograms coating composition (2).
The size-grade distribution of ceramic powder is:
+ 42 order 11.00%(weight)
+ 70 order 73.70%(weight)
70 to 100 order 15.30%(weight)
Example 5
The preparation of coating composition (3):
With (1) 60 kilogram of blue pigment thorough mixing of coatings formulated composition in the example 3, produce 60.5 kilograms blue look coating composition thus with 500 grams.
Example 6
The preparation of coating composition (4):
(1) 60 kilogram of red thorough mixing with 500 grams of coating composition with preparing in the example 3 produces 60.5 kilograms encrimson composition thus.
Example 7
The preparation of coating composition (5):
With 60 kilograms of the coating compositions that prepare in the example 4 blue pigment thorough mixing, produce 60.5 kilograms blue look coating composition thus with 500 grams.
Example 8
The preparation of coating composition (6):
With 60 kilograms of the coating compositions that prepare in the example 4 yellow pigment thorough mixing, produce 61 kilograms yellow paint composition thus with 1 kilogram.
Example 9
Cement blends the preparation of material (C):
With size-grade distribution is methylcellulose gum and the 360 calcium stearate thorough mixing that restrain that 59.58 kilograms ceramic powder same 60 shown below restrains, and is mixed with a kind of cement and blends material (60 kilograms).
The size-grade distribution of ceramic powder:
+ 42 order 3.00%(weight)
+ 60 order 17.20%(weight)
+ 80 order 20.80%(weight)
+ 100 order 10.75%(weight)
+ 200 order 32.60%(weight)
+ 325 order 14.50%(weight)
-325 order 1.15%(weight)
Example 10
Cement blends the preparation of material (D):
With used 59.28 kilograms identical ceramic powder in size-grade distribution and the example 9,, be mixed with a kind of cement and blend material (60 kilograms) with the methylcellulose gum of 60 grams, the calcium stearates and the 300 useless vinylon fiber thorough mixing that restrain of 360 grams.
Example 11
The preparation of coating composition (7):
Ordinary Portland cement (40 kilograms) is blended material (C) thorough mixing with the cement for preparing in the example 9.In the mixture that obtains like this, add 20 kilograms vinylbenzene polyvinyl butadiene rubber (SBR) breast and 17 kilograms water, and make above each relevant component thorough mixing, form 137 kilograms coating composition (7) thus.
Example 12
The preparation of coating composition (8):
Ordinary Portland cement (40 kilograms) is blended 60 kilograms in material (D) with the cement for preparing in the example 10, and size-grade distribution is the specific lime masonry thorough mixing shown in down.To the mixture of such acquisition, add 20 kilograms vinylbenzene polyvinyl butadiene rubber (SBR) breast and 17 kilograms water, make above-mentioned each component thorough mixing, form 167 kilograms coating composition (8) thus.
The size-grade distribution of Wingdale:
+ 42 order 11.00%(weight)
+ 70 order 73.70%(weight)
70 to 100 order 15.30%(weight)
Example 13
The preparation of coating composition (9):
(7) the 60 kilograms of blue pigment with 500 grams of coating composition that prepare in the example 11 are mixed, form 60.5 kilograms blue look coating composition thus.
Example 14
The preparation of coating composition (10):
(7) the 60 kilograms of reds with 500 grams of coating composition that prepare in the example 11 are mixed, form 60.5 kilograms encrimson composition thus.
Example 15
The preparation of coating composition (11):
With 60 kilograms of the coating compositions that prepare in the example 12 blue pigment thorough mixing, form 60.5 kilograms blue look coating composition thus with 500 grams.
Example 16
The preparation of coating composition (12):
With 60 kilograms of the coating compositions that prepare in the example 12 yellow pigment thorough mixing with 1 kilogram, the limit forms 61 kilograms yellow paint composition.
Example 17
On axial concrete slab, form the class ceramic coating with spraying method
One block concrete plate (200 * 50 * 15 centimetres) is placed on the position of a nearly erect.With coatings formulated (1) in the example 3, spray to a side of this sheet material with a kind of vacuum spray gun, form the coating of 0.5 millimeter thickness thus by 5.17 kilograms/square metre speed.Spraying was through two days, and this coating i.e. sclerosis fully.And then the external coating (EC) of acrylic resins of painting latex in the above, be similar to ceramic coating in order to form outward appearance with character.This coating that scribbles above-mentioned class pottery just can be used as the veneer sheet material of buildings.
Example 18
On axial styrofoam plate, form the method (1) of class ceramic coating with spraying coating process
A styrofoam plate (100 * 50 * 2 centimetres) is put into one is close to axial position.Use the vacuum spray gun,,, spray to a side of above-mentioned sheet material, form thickness thus and be 1 millimeter coating by 2.34 kilograms/square metre speed with the coating composition (1) for preparing in the example 3.Spraying is after three days, and this coating i.e. sclerosis fully, and provides outward appearance and character to be similar to ceramic coating.The styrofoam plate that such class ceramic coating has been arranged has promptly possessed good water resisting property matter, is especially suitable for use as the veneer sheet material on the buildings.
On axial styrofoam plate, form the method (2) of class ceramic coating with spraying coating process
A styrofoam plate (100 * 50 * 2 centimetres) is put into one is close to axial position.Use the vacuum spray gun,, spray to a side of this plate by 1.4 kilograms/square metre speed the coating composition (2) for preparing in the example 4.And then coatings formulated composition (3) in the example 5 is sprayed to strip form on the surface of existing coating of this polystyrene board.Through after above twice spraying, face is again with the coating (2) for preparing in the example 4, by the vacuum spray gun, according to 0.94 kilogram/square metre ratio, above spraying to.After three days that spraying finishes the last time, coating i.e. sclerosis fully.Then, the external coating (EC) of acrylic resin latex on the coated forms the coating that outward appearance and character are similar to pottery thus again.At this moment styrofoam plate has blue vitta band pattern, has good water repelling property simultaneously, is particularly suitable for doing the veneer sheet material on building walls or the floor.
Example 20
On concrete member, form the method (1) of ornamental class ceramic coating:
On concrete member, form one deck under coat glaze and make its drying.By the vacuum spray gun, with the coating composition (1) for preparing in the example 3,, spray on this dried under coat glaze by 2.34 kilograms/square metre speed, forming thick therefrom is 1 millimeter coating.After three days of this spraying, this coating i.e. sclerosis fully, has provided outward appearance and character with coating like the ceramic-like.The class ceramic coating of Xing Chenging has enough good water repelling property like this, is available as the decorative cover of buildings.
Example 21
On concrete member, form the method (2) of ornamental class ceramic coating
On concrete member, form a kind of under coat glaze and make its drying.With being coated with roller, with 1.97 kilograms/square metre speed, with coatings formulated composition (2) coated in the example 4 to this exsiccant under coat glaze.And then use the vacuum spray gun, the encrimson composition (4) for preparing in the example 6 is sprayed into vertical strips.After this secondary coating, by the vacuum spray gun, by 0.84 kilogram/square metre speed, the coating for preparing in the example 3 on the coated (1) is formed with the patterned thick 12 millimeters coating of red bar thus more thereupon.After three days of spraying, be coated with acrylic resin latex the last time, form outward appearance and character thus with coating like the ceramic-like with redness.The class ceramic coating of Xing Chenging has pleasing patterned surfaces like this, and abundant good water repelling property, can be used as the decorative cover of buildings outside.
Example 22
On cylindrical foam polystyrene container, form the class ceramic coating with dip coating:
With a columniform styrofoam container (millimeter (height) * 10,100 millimeters (diameter) * 300 millimeter (thick)), impregnated in the jar that fills the coating composition (2) that configures in the example 4, thus the outside surface of this container form one thick be 1.5 millimeters coating.Behind this kind Dipping four days, this coating i.e. sclerosis fully.Overcoating forms the coating that a kind of outward appearance and character are similar to pottery therefrom with the acrylic resin latex then.Cylindrical foam polystyrene container with this kind ceramic coating has sufficient stopping property to glassware for drinking water, can directly be used as flowerpot.
Example 23
On the concrete slab of horizontal positioned, form the coating of pottery with spraying method:
One block concrete plate (200 * 50 * 3 centimetres) placed be put in a position near level.Use a kind of air gun,,,, form thick 1 millimeter coating thus its side that sprays to this concrete slab with 2,3 kilograms/square metre speed with the coating composition (1) for preparing in the example 3.After three days, this coating is a complete drying, and has provided the coating of a kind of outward appearance and the similar pottery of character in spraying.Concrete slab with this kind ceramic coating has obtained to be suitable as the good water repelling property of sufficient Enough of buildings veneer sheet material.
Example 24
On axial concrete blocks spare, form the method (1) of class ceramic coating with spraying technology
One block concrete member (500 * 250 * 150 millimeters) is put into one near axial position.Adopt air gun, with the coating composition (2) for preparing in the example 4, the speed by 2,20 kilograms/square metre sprays on all surface of this block, forms thick 1,2 millimeter coating.Spraying is after three days, and this kind coating i.e. sclerosis fully.Be coated with the external coating (EC) with the acrylic resin latex then, concrete blocks spare has at this moment just had outward appearance and character with coating like the ceramic-like.Concrete blocks spare with this kind ceramic coating all has pleasing outward appearance on its all surface, can be used as the unit member of fence, door pillar or the wall of buildings.
Example 25
On axial concrete blocks spare, form the method (2) of class ceramic coating with spraying technology
One block concrete member (500 * 250 * 150 millimeters) is put into one near axial position.Adopt air gun, with the coating composition in the example 4 (2), the speed by 1,40 kilogram/square metre sprays on all surface of this block.Use the vacuum spray gun immediately, spray the yellow paint composition (6) for preparing in the example 8 with 0,94 kilogram/square metre speed.Be right after after this secondary spraying, again by the vacuum spray gun, by 0,7 kilogram/square metre speed, the coating composition for preparing by example 3 is gone up in spraying again.After two days, this layer coating i.e. sclerosis fully, provides the yellow coating that a kind of outward appearance and character are similar to pottery therefrom through last spraying.The concrete blocks spare that all has such class ceramic coating on all surface can be used as the unit member of fence, door pillar or the wall of buildings quite equally with surface treated part in the example 24.
When the present invention contrasts after relevant embodiment did to describe in detail, obviously need not break away from thought of the present invention and scope for the people who is familiar with this respect technology, just can make the change or the improvement of each style.
Claims (19)
1, can form a kind of coating composition of class ceramic coating, it is characterized in that, this composition comprises a kind of cement, a kind of batching (A) and a kind of batching (B); Batching (A) comprising:
(1) a kind of shaping powder that gathers materials;
(2) a kind of derivatived cellulose that can be water-soluble;
(3) a kind of metal-salt than high fatty acid;
Prepare burden (B) then comprise a kind of latex.
2, according to claim 1 described a kind of composition, the gather materials size-grade distribution of powder institute tool of shaping wherein is: have 40%(weight at least) the granularity of this kind powder greater than 100 orders; Have 20%(weight at least) the granularity of this kind powder less than 100 orders.
3, according to claim 1 described a kind of composition, the powder that gathers materials of shaping wherein is selected from following one group of raw material: grouan, marble, serpentinite, peridotites, zircon sand, Wingdale, quartz sand and pottery.
4, according to claim 1 described a kind of composition, cement wherein is selected from following one group of cement: ordinary Portland cement, cement that initial strength is high, for suitable heat just can hardened cement, white portland cement, fly ash cement, portland-pozzolan cement and air blast blast-furnace slag silicate cement.
5, according to claim 1 described a kind of composition, wherein can be water-soluble derivatived cellulose, be selected from the following raw material group: methylcellulose gum, ethyl cellulose, methylcellulose gum, cellulose acetate and the mixture between them.
6, according to claim 1 described a kind of composition, the metal-salt than high fatty acid wherein is selected from the following raw material group: hard fat acid Calcium, soft fat acid Calcium, month osmanthus acid Calcium, Zinic stearas, zinc palmitate, zinc laurate, lead stearate, lead palmitate, lead laurate and the mixture between them.
7, according to claim 1 described a kind of composition, latex wherein is selected from one group of following latex: natural rubber latex, vinylbenzene polyvinyl butadiene rubber breast, polyvinyl butadiene rubber breast, isoprene latex, polychloroprene latex, ABS resin latex, acrylic latex, urethane latex, and the composition between them.
8, a kind of method that can form the coating composition of based ceramic film layer of preparation, its operation is: a kind of cement is mixed with a kind of batching (A), add a kind of batching (B) batching (A) and comprise in this kind mixture:
(1) a kind of shaping powder that gathers materials;
(2) a kind of derivatived cellulose that can be water-soluble;
(3) a kind of metal-salt than high fatty acid;
And admixtion (B) comprises a kind of latex.
9, according to claim 8 described a kind of methods, the gather materials size-grade distribution of powder institute tool of shaping wherein is: have 40%(weight at least) the granularity of this kind powder greater than 100 orders; Have 20%(weight at least) the granularity of this kind powder less than 100 orders.
10, according to claim 8 described a kind of methods, the powder that gathers materials of shaping wherein is selected from the following material group: granite, marble, serpentinite, peridotites, zircon sand, Wingdale, quartz sand and pottery.
11, according to claim 8 described a kind of methods, cement wherein is selected from a kind of in the following thing group: ordinary Portland cement, cement that initial strength is high, for suitable heat just can hardened cement, white portland cement, fly ash cement, portland-pozzolan cement and air blast blast-furnace slag silicate cement.
12, according to claim 8 described a kind of methods, derivatived cellulose wherein is selected from the following thing group: methylcellulose gum, ethyl cellulose, methylcellulose gum, cellulose acetate, and the mixture between them.
13, according to claim 8 described a kind of methods, the metal-salt than high fatty acid wherein is selected from the following raw material group: hard fat acid Calcium, soft fat acid Calcium, month osmanthus acid Calcium, Zinic stearas, zinc palmitate, zinc laurate, lead stearate, lead palmitate and the mixture between them.
14, according to claim 8 described a kind of methods, latex wherein is selected from in next the group latex: diene latex, polychloroprene latex, ABS resin latex, acrylic latex, urethane latex and the mixture between them between natural rubber latex, vinylbenzene polyvinyl butadiene rubber breast, polyvinyl butadiene rubber breast, different the eleventh of the twelve Earthly Branches.
15, according to claim 8 described a kind of methods, coating composition wherein still contains a kind of fibrous material and is selected from one group of following raw material: the titanate fiber of vinylon, nylon, trevira, polypropylene fibre, alkali resistant glass fiber, asbestos, mineral fibre, metal, wollastonite, and the mixture between them.
The trade(brand)name of the light weight concrete that concrete product, sand oar goods, foam plastic product, Siliaa Licite(hot-pressing processing are crossed), wall, ground and top ceiling in metal products, glasswork and the buildings 16, according to claim 8 described a kind of methods, substrate wherein is selected from the following thing group:.
17, according to claim 8 described a kind of methods, coating composition wherein is that coated is to certain substrate and form a kind ceramic coating.
18, according to claim 17 described a kind of methods, be coated with again on the class ceramic coating wherein, provide the coating that a kind of outward appearance and character are similar to pottery therefrom can form a kind of coating compound of transparent gloss layer.
19, according to a kind of method of claim 8, coating composition wherein be by the spraying method coated on substrate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59099719A JPS60244375A (en) | 1984-05-19 | 1984-05-19 | Formation of ceramic coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN85103491A true CN85103491A (en) | 1986-11-12 |
Family
ID=14254879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN198585103491A Pending CN85103491A (en) | 1984-05-19 | 1985-05-18 | The coating that can form the class ceramic coating is formed and the preparing such coating method for compositions |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS60244375A (en) |
| KR (1) | KR850008474A (en) |
| CN (1) | CN85103491A (en) |
| ZA (1) | ZA853711B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1070827C (en) * | 1998-12-21 | 2001-09-12 | 冶金工业部钢铁研究总院 | High-temp ceramic extrusion coating for outside wall of oxygen lance for electric furnace steel smelting |
| CN104529343A (en) * | 2014-12-10 | 2015-04-22 | 国家电网公司 | Gatepost decoration material |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62105943A (en) * | 1985-10-30 | 1987-05-16 | ダイセル化学工業株式会社 | Formed product for wall or roof |
| JPH01126254A (en) * | 1986-09-25 | 1989-05-18 | Buchtal Gmbh | Production of plate-shape ceramic molded body having spot resistance on visible side |
| KR20020038211A (en) * | 2000-11-17 | 2002-05-23 | 강종구 | preparation material with hardenability |
| KR20030073920A (en) * | 2002-03-14 | 2003-09-19 | 중앙산업 (주) | Ceramics composition of rebirth and new pipe inside lining for water and sewage pipe |
| KR101357014B1 (en) * | 2012-04-02 | 2014-02-05 | 손복자 | A composite of coating material asphalt pavement |
| JP6171377B2 (en) * | 2013-02-08 | 2017-08-02 | 宇部興産株式会社 | Construction method for concrete structures |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5139887B2 (en) * | 1973-06-23 | 1976-10-30 | ||
| JPS5354516A (en) * | 1976-10-21 | 1978-05-18 | Kubota Ltd | Hollow float |
| JPS5920636B2 (en) * | 1977-04-21 | 1984-05-14 | 三洋化成工業株式会社 | Penetrating waterproofing composition |
| JPS5466932A (en) * | 1977-11-09 | 1979-05-29 | Shinnitsutou Kougiyou Kk | Coating material |
| JPS6038355B2 (en) * | 1979-05-28 | 1985-08-31 | 中部工業株式会社 | Surface finishing method for lightweight foam concrete |
| JPS5857985A (en) * | 1981-10-01 | 1983-04-06 | Canon Inc | Printer |
-
1984
- 1984-05-19 JP JP59099719A patent/JPS60244375A/en active Pending
-
1985
- 1985-05-15 ZA ZA853711A patent/ZA853711B/en unknown
- 1985-05-18 CN CN198585103491A patent/CN85103491A/en active Pending
- 1985-05-18 KR KR1019850003419A patent/KR850008474A/en not_active Application Discontinuation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1070827C (en) * | 1998-12-21 | 2001-09-12 | 冶金工业部钢铁研究总院 | High-temp ceramic extrusion coating for outside wall of oxygen lance for electric furnace steel smelting |
| CN104529343A (en) * | 2014-12-10 | 2015-04-22 | 国家电网公司 | Gatepost decoration material |
Also Published As
| Publication number | Publication date |
|---|---|
| KR850008474A (en) | 1985-12-18 |
| ZA853711B (en) | 1986-01-29 |
| JPS60244375A (en) | 1985-12-04 |
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