CN2700312Y - Chlorine dioxide generator - Google Patents

Chlorine dioxide generator Download PDF

Info

Publication number
CN2700312Y
CN2700312Y CN 200320115368 CN200320115368U CN2700312Y CN 2700312 Y CN2700312 Y CN 2700312Y CN 200320115368 CN200320115368 CN 200320115368 CN 200320115368 U CN200320115368 U CN 200320115368U CN 2700312 Y CN2700312 Y CN 2700312Y
Authority
CN
China
Prior art keywords
reactor
chlorine dioxide
dioxide generator
temperature
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN 200320115368
Other languages
Chinese (zh)
Inventor
艾雪莉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Qili Water Treatment Science & Technology Co., Ltd.
Original Assignee
艾雪莉
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 艾雪莉 filed Critical 艾雪莉
Priority to CN 200320115368 priority Critical patent/CN2700312Y/en
Application granted granted Critical
Publication of CN2700312Y publication Critical patent/CN2700312Y/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Abstract

The utility model relates to a chlorine dioxide generator which comprises a feeding system, a heating water tank, a tubular pre-reactor and a high-temperature reactor, wherein the high-temperature reactor is formed by connecting in series a plurality of tubular reactors, and each of reactors is respectively provided with a cushioning aerator and a water jetting device. The utility model has the advantages of low manufacture cost, low operating cost, high raw material conversion rate which can reach above 95%, high chlorine dioxide preparing purity which can reach above 95%, simple device structure, convenient operation, high automation level, etc., is widely used for the treatments of purifying, bleaching and sanitizing of drinking water, industrial water, hospital wastewater, printing wastewater and paper making wastewater, and is a novel purifying device for environmental protection.

Description

Chlorine dioxide generator
Technical field
The utility model relates to a kind of water disinfection and treating plant, particularly chlorine dioxide generator.
Background technology
Adopt chemical process to produce dioxide peroxide at present both at home and abroad, be divided into Textone method and sodium chlorate method according to the starting material difference, its preparation apparatus mostly is the monomer reaction device, as jar, cylinder etc., the material reaction concentration that this reactor exists in the reactor is low, defectives such as temperature of reaction is low, and speed of response is slow and incomplete.Produce dioxide peroxide with Textone, cost of material height, cost of water treatment height.Get dioxide peroxide with the sodium chlorate legal system, cost of material is low, but that this method exists feed stock conversion is low, and generally about 70%~80%, the purity of chlorine dioxide of generation is low, has only 50%~60%.
Summary of the invention
The purpose of this utility model is to overcome the deficiency that above-mentioned prior art exists, a kind of simple in structure, easy to operate, manufacturing cost and the low chlorine dioxide generator of working cost are provided, because sufficient reacting, the feed stock conversion height, the purity of chlorine dioxide height of producing is a kind of novel environmental protection purifying equipment.
Invention main points of the present utility model are, a kind of chlorine dioxide generator comprises the high-temperature reactor that a plurality of reactors in series that pre-reactor, tubing that feeder system, heating water tank, tubing are made are made form, water sprayer, above-mentioned pre-reactor places in the low temperature pool of heating water tank, high-temperature reactor places in the high temperature pool of heating water tank, and each reactor that constitutes high-temperature reactor all is equipped with the buffering aerator.
The low cost of manufacture of this chlorine dioxide generator, working cost is lower by 70% than existing chlorine dioxide generator, and feed stock conversion can reach more than 95%, and purity of chlorine dioxide can reach more than 95%.This automation degree of equipment height, operate continuously.Can be widely used in purification, bleaching, disinfection processing of tap water, process water, hospital sewage, printing and dyeing, papermaking wastewater etc.
Description of drawings
Accompanying drawing 1 is the chlorine dioxide generator structural representation.
Accompanying drawing 2 is chlorine dioxide generator buffering aerator sectional views.
Shown in Figure 1, single card microcomputer controller 1, volume pump 2, heating water tank 3, low temperature pool 4, high temperature pool 5, pre-reactor 6, reactor 7, buffering aerator 8, pipe connecting 9, pipe connecting 10, water sprayer 11.
Shown in Figure 2, on manage 12, middle pipe 13, manage 14 down.
Embodiment
Below with reference to the accompanying drawing description detailed in addition to the utility model:
Feeder system is made up of single card microcomputer controller 1, volume pump 2,4~20mA signal that 4~20mA signal that the processed water flow instrument provides and chlorine dioxide sensor provide, be input to carry out calculation process in the single card microcomputer 1 after, output 0~100 subpulse signal is to volume pump 2, thereby reach the dosage of control material, make an amount of material continuously supply with pre-reactor 6 and reactor 7.Heating water tank 3 is divided into low temperature pool 4 and high temperature pool 5 by a dividing plate.Pre-reactor 6 is 20~50mm by diameter, length is 1000~5000mm, its material is made crooked shape for the pvc pipe material and is formed, it is inserted in the low temperature pool 4 of heating water tank 3, its water temperature is controlled at 45~55 ℃, the front end of pre-reactor 6 is connected with feeder system, and end is connected with the first reactor 7 of high-temperature reactor.Because pre-reactor 6 is made curved shape, its length is increased, increase warm up time, makes material temperature be preheating to the temperature in low temperature pool, enters in the reactor 7 again, created good temperature of reaction condition.Four tubular reactors 7, each is 50~300mm by diameter all, and length is that its material of 200~600mm is made for CPVC tubing, is connected into high-temperature reactor by pipe connecting 9 between each reactor, and it is inserted in the high temperature pool 5 of heating water tank 3, water temperature is controlled at 60~90 ℃.The end of last reactor of high-temperature reactor is connected with water sprayer 11 by pipe connecting 10.Four reactors 7 all are equipped with buffering aerator 8.Material after pre-reactor 6 preheatings enters in each reactor of high-temperature reactor, just begin reaction and generate dioxide peroxide, water sprayer 11 work back generation negative pressure are released the dioxide peroxide that generates and are dissolved in the cold water, form the dioxide peroxide finished fluid and enter in the processed water again.
As shown in Figure 2, buffering aerator 8 is by last pipe 12, middle pipe 13, manages 14 down and constitute.The upper end open of last pipe 12 is in atmosphere, and the lower end is connected with the upper end of middle pipe 13, and following 14 the upper end of managing is connected with the lower end of middle pipe 13, the lower end of following pipe be opening and place in the reactor 7.Last pipe 12 diameters are 20~30mm, and length is 200mm, and middle pipe 13 diameters are 50~80mm, and length is 100mm, and following pipe diameter is 20~30mm, and length is 500~600mm.Last pipe, middle pipe are the pvc pipe material, and following pipe is a CPVC tubing.Middle pipe 13 has bigger spatial volume.Produce negative pressure when water sprayer 11 work, air enters into reactor 7 from upper orifice, and its effect has two, the one, the generation dioxide peroxide is diluted, guarantee dioxide peroxide not to be decomposed and set off an explosion that it two is that reaction mass is played stirring action, makes reaction more abundant.When water sprayer 11 quit work, no negative pressure produced, and the material in each reactor will enter in the pipe 13 that respectively cushions aerator, and when water sprayer was started working, each cushioned in the aerator material and playbacks again and react in each reactor, plays buffer protection function.

Claims (5)

1, a kind of chlorine dioxide generator, comprise feeder system, heating water tank, pre-reactor, high-temperature reactor, water sprayer, it is characterized in that pre-reactor is to be made by tubing, it is inserted in the low temperature pool of heating water tank, the reactors in series that high-temperature reactor is made by a plurality of tubing forms, and be placed in the high temperature pool of heating water tank, each reactor all is equipped with the buffering aerator.
2, chlorine dioxide generator according to claim 1 is characterized in that pre-reactor makes curved shape with tubing.
3, chlorine dioxide generator according to claim 1 is characterized in that pre-reactor is to be made by the pvc pipe material.
4, chlorine dioxide generator according to claim 1 is characterized in that high-temperature reactor is to be in series by four tubular reactors.
5, chlorine dioxide generator according to claim 1 is characterized in that each reactor in the high-temperature reactor is made by CPVC tubing.
CN 200320115368 2003-12-12 2003-12-12 Chlorine dioxide generator Expired - Lifetime CN2700312Y (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200320115368 CN2700312Y (en) 2003-12-12 2003-12-12 Chlorine dioxide generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200320115368 CN2700312Y (en) 2003-12-12 2003-12-12 Chlorine dioxide generator

Publications (1)

Publication Number Publication Date
CN2700312Y true CN2700312Y (en) 2005-05-18

Family

ID=34762250

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200320115368 Expired - Lifetime CN2700312Y (en) 2003-12-12 2003-12-12 Chlorine dioxide generator

Country Status (1)

Country Link
CN (1) CN2700312Y (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100424004C (en) * 2006-01-12 2008-10-08 王丛若 Chlorine dioxide generator
CN102167287A (en) * 2011-05-19 2011-08-31 李达 Multifunctional high-efficiency and energy-saving chlorine dioxide generator
CN107617412A (en) * 2017-08-31 2018-01-23 四川齐力绿源水处理科技有限公司 A kind of chlorine dioxide preparation apparatus and preparation method
US10501345B2 (en) 2017-08-17 2019-12-10 Ecolab Usa Inc. Low risk chlorine dioxide onsite generation system
US11130677B2 (en) 2017-03-24 2021-09-28 Ecolab Usa Inc. Low risk chlorine dioxide onsite generation system
US11535541B2 (en) 2017-02-27 2022-12-27 Ecolab Usa Inc. Method for onsite production of chlorine dioxide
US11970393B2 (en) 2019-07-03 2024-04-30 Ecolab Usa Inc. Decomposition mediation in chlorine dioxide generation systems through sound detection and control

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100424004C (en) * 2006-01-12 2008-10-08 王丛若 Chlorine dioxide generator
CN102167287A (en) * 2011-05-19 2011-08-31 李达 Multifunctional high-efficiency and energy-saving chlorine dioxide generator
CN102167287B (en) * 2011-05-19 2016-01-20 李达 Multifunction efficient energy-saving chlorine dioxide generator
US11535541B2 (en) 2017-02-27 2022-12-27 Ecolab Usa Inc. Method for onsite production of chlorine dioxide
US11130677B2 (en) 2017-03-24 2021-09-28 Ecolab Usa Inc. Low risk chlorine dioxide onsite generation system
US10501345B2 (en) 2017-08-17 2019-12-10 Ecolab Usa Inc. Low risk chlorine dioxide onsite generation system
US11225421B2 (en) 2017-08-17 2022-01-18 Ecolab Usa Inc. Low risk chlorine dioxide onsite generation system
CN107617412A (en) * 2017-08-31 2018-01-23 四川齐力绿源水处理科技有限公司 A kind of chlorine dioxide preparation apparatus and preparation method
US11970393B2 (en) 2019-07-03 2024-04-30 Ecolab Usa Inc. Decomposition mediation in chlorine dioxide generation systems through sound detection and control

Similar Documents

Publication Publication Date Title
RU2268241C2 (en) Method for preparing chlorine dioxide
US20050186131A1 (en) Process for production of chlorine dioxide
CN101132990A (en) Wastewater treatment equipment and method of wastewater treatment
CN2700312Y (en) Chlorine dioxide generator
CN101880029B (en) Continuous production device of composite chlorine dioxide and technology
CN216073237U (en) Constructed wetland with hydrogen peroxide oxygenation and denitrification capability improvement function
CN201158590Y (en) Chlorine dioxide generator
CN1230517A (en) Chlorine dioxide generating method and apparatus
AU2005214291B2 (en) Process for production of Chlorine Dioxide
EP1819635B1 (en) Chemical process and production unit
CN1062715C (en) Method for preparing chlorine dioxide and its generation equipment
CN201495121U (en) Multifunctional chlorine dioxide disinfection device
CN205874093U (en) Caprolactam waste water preprocessing device
CN100424004C (en) Chlorine dioxide generator
CN205892749U (en) Full -automatic chlorine dioxide generator of integral type
CN204803191U (en) Waste water purification treatment system
CN102992480A (en) Device and process for carrying out autotrophic denitrification treatment on nitrate nitrogen in sewage based on non-foaming hydrogen supply
CN113461222A (en) Industrial wastewater enhanced oxidation treatment method
CN201777880U (en) Composite chlorine dioxide continuous production equipment
CN2460516Y (en) Generation device of chlorine dioxide composition disinfectant
CN105060616A (en) Waste water purification treatment system
CN2417158Y (en) Practical type chlorine dioxide generator
CN2813580Y (en) Chlorine dioxide generator
CN103754827A (en) Method and special equipment for mixed chlorine dioxide
CN2709418Y (en) Chlorine dioxide generator

Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: CHENGDU WATER TREATMENT TECHNOLOGY CO.

Free format text: FORMER OWNER: AI XUELI

Effective date: 20050610

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20050610

Address after: 5 2 units, 611830 Taiping shopping center, Taiping Street, Sichuan, Chengdu, Dujiangyan

Patentee after: Chengdu Qili Water Treatment Science & Technology Co., Ltd.

Address before: 5 2 units, 611830 Taiping shopping center, Taiping Street, Sichuan, Chengdu, Dujiangyan

Patentee before: Ai Xueli

PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of utility model: ClO2 generator with initial reactor

Effective date of registration: 20110211

Granted publication date: 20050518

Pledgee: Chengdu Productivity Promotion Center

Pledgor: Chengdu Qili Water Treatment Science & Technology Co., Ltd.

Registration number: 2011990000044

C17 Cessation of patent right
CX01 Expiry of patent term

Expiration termination date: 20131212

Granted publication date: 20050518