CN221164034U - Degradable high-barrier food packaging box - Google Patents

Degradable high-barrier food packaging box Download PDF

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Publication number
CN221164034U
CN221164034U CN202322580913.2U CN202322580913U CN221164034U CN 221164034 U CN221164034 U CN 221164034U CN 202322580913 U CN202322580913 U CN 202322580913U CN 221164034 U CN221164034 U CN 221164034U
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layer
barrier
waterproof
base material
adhesive layer
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CN202322580913.2U
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陈正勇
黄维捷
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Jiangsu Juhong Material Technology Co ltd
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Jiangsu Juhong Material Technology Co ltd
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Abstract

The utility model discloses a degradable high-barrier food packaging box, which comprises a box body and a soft film cover, wherein the box body is provided with a containing space and an opening communicated with the containing space, the box body is used for containing food, the box body is made of PGA modified materials, the soft film cover is matched with the opening in size, the soft film cover comprises a base material layer, a barrier layer, a waterproof layer and an adhesive layer, the barrier layer and the waterproof layer are respectively formed on two sides of the base material layer, the adhesive layer is formed on one side, away from the base material layer, of the barrier layer or the waterproof layer, the soft film cover is adhered to the box body in a mode that the adhesive layer corresponds to the opening, and the base material layer is made of degradable materials, and can block gas and prevent water. The utility model can be degraded, can effectively block gas, has better barrier property than common packaging boxes, and can greatly prolong the preservation time of foods.

Description

Degradable high-barrier food packaging box
Technical Field
The utility model relates to a packaging box, in particular to a degradable high-barrier food packaging box.
Background
When fresh perishable foods, particularly primary meat products, are packaged, it is often necessary to select a food package having a certain gas barrier function to prevent the invasion of external gases such as oxygen from affecting the shelf life of the food. Such food packages with higher barrier properties typically include a rigid barrier casing and a flexible barrier film that closes the food within the rigid barrier casing by covering the opening of the rigid barrier casing.
At present, a hard barrier box body and a soft barrier film commonly used in the market are designed in a multi-layer mode by taking EVOH as a barrier material, wherein adhesive layers are arranged on two sides of the EVOH layer of the hard barrier box body and are respectively bonded with a PP layer or a PE layer through the adhesive layers, PE layers are arranged on two sides of the EVOH layer of the soft barrier film or are respectively bonded with the PE layers, and the soft barrier film is bonded to the hard barrier box body through the PE layers or the adhesive layers through a hot pressing process.
Materials having gas barrier properties similar to EVOH also include PVDC, MXD6, PEN, PVA, non-degradable substrates electroplated with silica or aluminized, etc., none of which is degradable, and therefore food packages made therefrom are also non-degradable. In addition, for instance, in the case of EVOH, the oxygen transmission rate of a conventional food package having an EVOH layer as a barrier layer is 1-5cm 3/(m2. 24 h.0.1 MPa, and the storage time of the food package for foods is not long enough, and the barrier performance is still required to be improved.
Disclosure of utility model
One advantage of the present utility model is to provide a degradable high barrier food package that can be degraded and is more environmentally friendly to use than conventional packages.
The utility model has the advantages that the degradable high-barrier food packaging box is provided, the gas can be effectively blocked, and compared with the packaging box made of common blocking materials, the packaging box has better blocking performance, and the storage time of food can be greatly prolonged.
To achieve at least one of the above advantages, the present utility model provides a degradable high barrier food package comprising:
A case having an accommodation space and an opening communicating with the accommodation space, the case being for accommodating food, the case being implemented as a PGA-modified material;
The size of the soft film cover is matched with the size of the opening, the soft film cover comprises a base material layer, a blocking layer, a waterproof layer and an adhesive layer, the blocking layer and the waterproof layer are respectively formed on two sides of the base material layer, the adhesive layer is formed on one side, away from the base material layer, of the blocking layer or the waterproof layer, the soft film cover is adhered to the box body in a mode that the adhesive layer corresponds to the opening, the base material layer is made of degradable materials, and the blocking layer can block gas and is waterproof.
According to an embodiment of the utility model, the substrate layer is implemented as a cellophane material.
According to an embodiment of the present utility model, the barrier layer is implemented as a silicon dioxide material formed on the surface of the substrate layer by electroplating.
According to an embodiment of the present utility model, the waterproof layer is implemented as a silicon dioxide material formed on the surface of the substrate layer through electroplating treatment.
According to an embodiment of the utility model, the waterproof layer is implemented as a waterproof material applied to the surface of the substrate layer.
According to an embodiment of the present utility model, the adhesive layer is formed on a side of the barrier layer away from the substrate layer, and when the flexible film cover is covered on the box body, the substrate layer, the barrier layer, the waterproof layer, and the adhesive layer are sequentially arranged in the order of the adhesive layer, the barrier layer, the substrate layer, and the waterproof layer, with reference to a direction of the accommodating space toward the opening.
According to an embodiment of the present utility model, the adhesive layer is formed on a side of the waterproof layer away from the substrate layer, and when the flexible film cover is covered on the box body, the substrate layer, the barrier layer, the waterproof layer, and the adhesive layer are sequentially arranged in the order of the adhesive layer, the waterproof layer, the substrate layer, and the barrier layer, with reference to a direction of the accommodating space toward the opening.
According to an embodiment of the present utility model, the adhesive layer and the waterproof layer are integrally formed and integrally implemented as a waterproof adhesive layer, the waterproof adhesive layer and the barrier layer are respectively located at two sides of the substrate layer, and when the soft film cover is covered on the box body, the waterproof adhesive layer, the barrier layer and the substrate layer are sequentially arranged along the direction of the accommodating space towards the opening as a reference, and the waterproof adhesive layer, the substrate layer and the barrier layer are sequentially arranged.
According to one embodiment of the utility model, the thickness of the box body is 0.3-1.5mm.
According to an embodiment of the present utility model, the thickness of the substrate layer is 0.02-0.06mm, the thickness of the adhesive layer is 0.003-0.015mm, and the overall thickness of the soft film cover is 0.03-0.08mm.
Drawings
Fig. 1 shows a schematic structural view of the degradable high-barrier food package of the present utility model.
Fig. 2 shows a schematic partial structure of the degradable high-barrier food package according to the utility model.
Figure 3 shows another partial structural cross-sectional view of the degradable high barrier food package of the present utility model.
Figure 4 shows a structural cross-sectional view of one embodiment of the degradable high barrier food package of the present utility model.
Figure 5 shows a structural cross-sectional view of another embodiment of the degradable high barrier food package of the present utility model.
Detailed Description
The following description is presented to enable one of ordinary skill in the art to make and use the utility model. The preferred embodiments in the following description are by way of example only and other obvious variations will occur to those skilled in the art. The basic principles of the utility model defined in the following description may be applied to other embodiments, variations, modifications, equivalents, and other technical solutions without departing from the spirit and scope of the utility model.
It will be appreciated by those skilled in the art that in the present disclosure, the terms "longitudinal," "transverse," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," etc. refer to an orientation or positional relationship based on that shown in the drawings, which is merely for convenience of description and to simplify the description, and do not indicate or imply that the apparatus or elements referred to must have a particular orientation, be constructed and operated in a particular orientation, and therefore the above terms should not be construed as limiting the present utility model.
It will be understood that the terms "a" and "an" should be interpreted as referring to "at least one" or "one or more," i.e., in one embodiment, the number of elements may be one, while in another embodiment, the number of elements may be plural, and the term "a" should not be interpreted as limiting the number.
Referring to fig. 1 to 2, a degradable high barrier food package according to a preferred embodiment of the present utility model will be described in detail below, the degradable high barrier food package comprising a case 10, the case 10 having a receiving space 101 and an opening 102 communicating with the receiving space 101, the case 10 for receiving food. The cartridge 10 is implemented as a PGA-modified material.
Preferably, the thickness of the case 10 is 0.3-1.5mm.
It should be noted that the thickness of the case 10 is positively related to the weight of the food, that is, the heavier the weight of the food, the greater the thickness of the case 10, so as to effectively avoid the case 10 being too thin and the food being too heavy, which results in the case 10 being unable to effectively bear the food and being broken. In addition, the thickness of the case 10 is positively correlated with the size of the accommodating space 101, that is, the larger the size of the accommodating space 101 is, the larger the thickness of the case 10 is, so that the case 10 cannot effectively bear food and is broken due to excessive food accommodated in the accommodating space 101 is effectively avoided.
Preferably, the PGA modified material is prepared by blending PGA or PGLA, a toughening material, inorganic powder, an auxiliary agent and the like. Preferably, 70-95 parts of PGA or PGLA, 5-30 parts of toughening material, 0.1-15 parts of inorganic powder and 0.1-5 parts of auxiliary agent.
It will be appreciated by those skilled in the art that PGA is polyglycolic acid or polyglycolide and PGLA is a copolymer of glycolic acid and lactic acid or a copolymer of glycolide and lactide or polyglycolide-lactide, with GA being the predominant component.
Preferably, the toughening material includes, but is not limited to, one or more combinations of PBAT, PCL, PHA and degradable materials such as PBS.
Preferably, the inorganic powder includes, but is not limited to, glass fibers, calcium carbonate, calcium sulfate, magnesium sulfate, ceramic whiskers, and the like, and the auxiliary includes, but is not limited to, antioxidants, heat stabilizers, lubricating plasticizers, crosslinking agents, and the like.
It will be appreciated by those skilled in the art that the PGA and PGLA are gas-barrier and degradable, and the toughening material has a predetermined strength so that the case 10 can be degraded and the preservation time of the food can be prolonged, and the case 10 can also effectively support the food in the accommodating space 101.
Preferably, the case body 10 is formed by processing the PGA modified material through a casting process and a plastic sucking process in sequence.
As a deformability, the case body 10 is injection-molded from the PGA-modified material.
Referring to fig. 1 and 3, the degradable high-barrier food package further includes a flexible film cover 20, the size of the flexible film cover 20 is adapted to the size of the opening 102, and the flexible film cover 20 is mounted on the case 10 in such a manner as to cover the opening 102.
Referring to fig. 3, the flexible film cover 20 includes a base layer 21, a barrier layer 22, a waterproof layer 23, and an adhesive layer 24, wherein the barrier layer 22 and the waterproof layer 23 are formed on two sides of the base layer 21, and the adhesive layer 24 is formed on one side of the barrier layer 22 or the waterproof layer 23 away from the base layer 21. The bladder cover 20 is adhered to the case 10 in such a manner that the adhesive layer 24 corresponds to the opening 102.
The substrate layer 21 is implemented as a degradable material and the barrier layer 22 is capable of gas barrier and water resistance. In this way, the design of the base material layer 21 is used to improve the degradability of the soft film cover 20; due to the design of the barrier layer 22, the flexible film cover 20 seals the opening 102 to separate the food in the case 10 from the external air, so as to extend the preservation time of the food, and the barrier layer 22 and the waterproof layer 23 are combined to be double waterproof, so that the situation that the use effect of the flexible film cover 20 is affected due to the penetration of the liquid into the flexible film cover 20 is prevented, and the situation that the liquid penetrates into the flexible film cover 20 and finally into the case 10 is prevented, so that the quality of the food in the case 10 is affected.
Preferably, the substrate layer 21 is implemented as a cellophane material. As will be appreciated by those skilled in the art, cellophane is a regenerated cellulose film, is formed from natural cellulosic materials, is degradable by household composting and has high transparency; and is resistant to high temperature, and is suitable for electroplating on the surface. In this way, the soft film cover 20 made of the base material layer 21 implemented as a cellophane material can be seen through, and the cartridge 10 made of the PGA modified material is opaque, so that the interior of the cartridge 10 can be seen through the use of the soft film cover 20 in combination with the base material layer.
In another embodiment, the substrate layer 21 may also be implemented as a degradable material with low transparency or opacity, such as a modified blend of PGA and PBAT, etc., where internal visualization of the cartridge 10 is not required.
Preferably, the barrier layer 22 is implemented as a silicon dioxide material formed on the surface of the substrate layer 21 through an electroplating process. It will be appreciated by those skilled in the art that the barrier layer 22, which is implemented as a silicon dioxide material, can block gas to block food within the case 10 from the outside gas when the soft film cover 20 covers the case 10, so as to extend the preservation time of the food.
Preferably, the waterproof layer 23 is made of a silicon dioxide material formed on the surface of the substrate layer 21 through electroplating treatment, and cooperates with the barrier layer 22 made of a silicon dioxide material to perform double-sided waterproof on the substrate layer 21, so as to prevent the substrate layer 21 made of cellophane material from expanding when encountering water to affect the use of the soft film cover 20, and increase the stability of the use of the soft film cover 20. In addition, when both the barrier layer 22 and the waterproof layer 23 are implemented as a silicon dioxide material, the soft film cover 20 has dual barrier properties to improve the gas barrier properties of the soft film cover 20.
It will be appreciated by those skilled in the art that silica is inorganic and does not affect the degradation properties of the piate cover 20. In addition, the waterproof layer 23, which is made of a silica material, is transparent, thereby improving the transparency of the soft film cover 20.
Based on the fact that the box body 10 is made of the PGA modified material, the barrier layer 22 and the waterproof layer 23 are made of silicon dioxide material, the oxygen transmittance of the degradable high-barrier food packaging box is 0.1-0.5cm 3/(m2 & 24h & 0.1MPa, and compared with the packaging box made of common barrier materials, the barrier performance is better, and the preservation time of food can be greatly prolonged. In addition, based on the case 10 being implemented as the PGA modified material, the base material layer 21 of the flexible film cover 20 is implemented as a degradable material so that the entire household compost can be degraded, without being intensively recovered for industrial compost degradation, the recovery load and the burden of industrial compost degradation are reduced, and the use is more environment-friendly than the conventional packing box.
In one embodiment, the waterproof layer 23 is implemented as a waterproof material coated on the surface of the base material layer 21, and the waterproof material includes, but is not limited to, PBAT, to cooperate with the barrier layer 22 implemented as a silica material to double-sided waterproof the base material layer 21, so as to prevent the base material layer 21 implemented as a cellophane material from swelling in water to affect the use of the soft film cover 20. In addition, the waterproof layer 23 can be degraded to improve the overall degradation performance of the soft film cover 20.
Preferably, the waterproof material is implemented as a transparent PBAT to improve transparency of the soft film cover 20.
Preferably, the adhesive layer 24 is implemented as an adhesive material, and in practical applications, the thickness of the adhesive layer 24 is small, and does not affect the degradation performance of the whole soft film cover 20.
Preferably, the adhesive layer 24 can be implemented as a degradable adhesive material to enhance the overall degradability of the soft film cover 20.
Preferably, the adhesive layer 24 is transparent, and the waterproof layer 23 is transparent, and the barrier layer 22 is transparent based on the substrate layer 21, which is implemented as a cellophane material, and is implemented as a silica material, so as to further improve the transparency of the soft film cover 20 and the effect of the internal perspective of the case 10.
Referring to fig. 4, the adhesive layer 24 is preferably formed on a side of the barrier layer 22 remote from the substrate layer 21. When the flexible film cover 20 is covered on the box body 10, the arrangement sequence of the substrate layer 21, the barrier layer 22, the waterproof layer 23 and the adhesive layer 24 is that of the adhesive layer 24, the barrier layer 22, the substrate layer 21 and the waterproof layer 23 sequentially, taking the direction of the accommodating space 101 towards the opening 102 as a reference.
Referring to fig. 5, as a deformability, the adhesive layer 24 is formed at a side of the waterproof layer 23 remote from the base material layer 21. When the flexible film cover 20 is covered on the box body 10, the arrangement sequence of the substrate layer 21, the barrier layer 22, the waterproof layer 23 and the adhesive layer 24 is that of the adhesive layer 24, the waterproof layer 23, the substrate layer 21 and the barrier layer 22 sequentially, taking the direction of the accommodating space 101 towards the opening 102 as a reference.
As a deformability, the adhesive layer 24 and the waterproof layer 23 are integrally formed and integrally implemented as a waterproof adhesive layer, which is respectively located at both sides of the base material layer 21, and the barrier layer 22. When the flexible film cover 20 is covered on the box body 10, the waterproof adhesive layer, the barrier layer 22 and the substrate layer 21 are sequentially arranged along the direction of the accommodating space 101 towards the opening 102, and the waterproof adhesive layer, the substrate layer 21 and the barrier layer 22 are sequentially arranged.
In one embodiment, the thickness of the substrate layer 21 is 0.02-0.06mm, the thickness of the adhesive layer 24 is 0.003-0.015mm, the thickness of the barrier layer 22 and the waterproof layer 23 implemented as silica materials is 5-100nm, and the overall thickness of the soft film cover 20 is 0.03-0.08mm.
In another embodiment, the thickness of the base material layer 21 is 0.02-0.06mm, the thickness of the adhesive layer 24 is 0.003-0.015mm, the thickness of the barrier layer 22 implemented as a silicon dioxide material is 5-100nm, the thickness of the waterproof layer 23 implemented as the waterproof material is 0.015-0.02mm, and the overall thickness of the soft film cover 20 is 0.03-0.08mm.
It will be appreciated by persons skilled in the art that the embodiments of the utility model described above and shown in the drawings are by way of example only and are not limiting. The advantages of the present utility model have been fully and effectively realized. The functional and structural principles of the present utility model have been shown and described in the examples and embodiments of the utility model may be modified or practiced without departing from the principles described.

Claims (10)

1. The degradable high-barrier food packaging box is characterized in that the degradable high-barrier food packaging box comprises:
A case having an accommodation space and an opening communicating with the accommodation space, the case being for accommodating food, the case being implemented as a PGA-modified material;
The size of the soft film cover is matched with the size of the opening, the soft film cover comprises a base material layer, a blocking layer, a waterproof layer and an adhesive layer, the blocking layer and the waterproof layer are respectively formed on two sides of the base material layer, the adhesive layer is formed on one side, away from the base material layer, of the blocking layer or the waterproof layer, the soft film cover is adhered to the box body in a mode that the adhesive layer corresponds to the opening, the base material layer is made of degradable materials, and the blocking layer can block gas and is waterproof.
2. The degradable high barrier food package of claim 1, wherein the substrate layer is implemented as cellophane material.
3. The degradable high barrier food package according to claim 1 or 2, characterized in that the barrier layer is implemented as a silicon dioxide material formed on the surface of the substrate layer by an electroplating process.
4. A degradable high barrier food package according to claim 3, characterised in that the water barrier layer is implemented as a silicon dioxide material formed on the surface of the substrate layer by an electroplating process.
5. A degradable high barrier food package according to claim 3, characterised in that the water-repellent layer is embodied as a water-repellent material applied to the surface of the substrate layer.
6. A degradable high-barrier food package according to claim 3, wherein the adhesive layer is formed on a side of the barrier layer away from the base material layer, and the base material layer, the barrier layer, the base material layer and the waterproof layer are arranged in this order with reference to the direction of the accommodating space toward the opening when the flexible film cover is covered on the case.
7. The degradable high-barrier food packaging box according to claim 3, wherein the adhesive layer is formed on one side of the waterproof layer away from the base material layer, and when the soft film cover is covered on the box body, the base material layer, the barrier layer, the waterproof layer and the adhesive layer are sequentially arranged in the order of the adhesive layer, the waterproof layer, the base material layer and the barrier layer along the direction of the accommodating space toward the opening.
8. The degradable high-barrier food packaging box according to claim 3, wherein the adhesive layer and the waterproof layer are integrally formed and integrally implemented as a waterproof adhesive layer, the waterproof adhesive layer and the barrier layer are respectively located at two sides of the base material layer, when the soft film cover is covered on the box body, the direction of the accommodating space towards the opening is taken as a reference, and the arrangement sequence of the waterproof adhesive layer, the barrier layer and the base material layer is the waterproof adhesive layer, the base material layer and the barrier layer in sequence.
9. The degradable high barrier food package of claim 1, wherein the thickness of the casing is 0.3-1.5mm.
10. The degradable high barrier food package of claim 1, wherein the thickness of the substrate layer is 0.02-0.06mm, the thickness of the adhesive layer is 0.003-0.015mm, and the overall thickness of the flexible film cover is 0.03-0.08mm.
CN202322580913.2U 2023-09-21 2023-09-21 Degradable high-barrier food packaging box Active CN221164034U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202322580913.2U CN221164034U (en) 2023-09-21 2023-09-21 Degradable high-barrier food packaging box

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202322580913.2U CN221164034U (en) 2023-09-21 2023-09-21 Degradable high-barrier food packaging box

Publications (1)

Publication Number Publication Date
CN221164034U true CN221164034U (en) 2024-06-18

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202322580913.2U Active CN221164034U (en) 2023-09-21 2023-09-21 Degradable high-barrier food packaging box

Country Status (1)

Country Link
CN (1) CN221164034U (en)

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