CN220977172U - Electrolytic cell with gasket and high-voltage electrolytic tank - Google Patents
Electrolytic cell with gasket and high-voltage electrolytic tank Download PDFInfo
- Publication number
- CN220977172U CN220977172U CN202322476977.8U CN202322476977U CN220977172U CN 220977172 U CN220977172 U CN 220977172U CN 202322476977 U CN202322476977 U CN 202322476977U CN 220977172 U CN220977172 U CN 220977172U
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- Prior art keywords
- sealing gasket
- electrolytic
- electrode plate
- electrode
- sealing
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- 238000007789 sealing Methods 0.000 claims abstract description 81
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 239000003792 electrolyte Substances 0.000 claims description 3
- 239000002390 adhesive tape Substances 0.000 claims description 2
- 238000003466 welding Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 238000007747 plating Methods 0.000 claims 1
- 239000001301 oxygen Substances 0.000 abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 abstract description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 6
- 239000001257 hydrogen Substances 0.000 abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000012528 membrane Substances 0.000 description 8
- 239000011324 bead Substances 0.000 description 7
- 230000008878 coupling Effects 0.000 description 5
- 238000010168 coupling process Methods 0.000 description 5
- 238000005859 coupling reaction Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005524 ceramic coating Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The utility model relates to an electrolysis unit with a sealing gasket and a high-voltage electrolysis tank formed by the electrolysis unit, and belongs to the technical field of pressure electrolysis tanks. When the pair of electrode plates forming the cathode electrode and the anode electrode are oppositely attached and the electrolytic diaphragm is clamped in the middle, the first convex ring on the sealing gasket and the two side surfaces of the electrolytic diaphragm form two circles of line seals which are staggered with each other, so that the plane seals between the conventional sealing gasket and the electrolytic diaphragm and the electrode plates are respectively changed into line seals, and the high-pressure hydrogen and oxygen production without leakage can be realized by using the electrolytic unit and the high-pressure electrolytic tank.
Description
Technical Field
The utility model relates to an electrode plate structure for a high-voltage electrolytic tank, an electrolytic unit structure formed by the electrode plate and a high-voltage electrolytic tank formed by the electrolytic unit structure, and belongs to the technical field of pressure electrolytic tanks.
Background
Chinese patent publication No. CN219032404U discloses an electrolyzer for producing high pressure hydrogen and oxygen, as shown in fig. 1. The electrolytic cell comprises three regular polygon planar pieces, namely a polar plate, a sealing gasket and a diaphragm, wherein the polar plate, the sealing gasket and the diaphragm are in planar contact, and each electrolytic cell group is formed by overlapping and closely contacting a first sealing gasket 103, an anode plate 104, the first sealing gasket 103, a diaphragm 105, a second sealing gasket 106, a cathode plate 107, a second sealing gasket 106 and the diaphragm 105. Since the plates, gaskets and diaphragms of the electrolysis cell stack all lie flat against each other, a flat seal is formed between the compressed plates, gaskets and diaphragms. However, in the subsequent experiments for manufacturing the electrolytic cell, the inventors of the above patent found that when the electrolytic cell gradually forms high pressure as the electrolytic reaction continuously generates gases (hydrogen and oxygen), gas-liquid leakage occurs between the polar plate, the sealing gasket and the diaphragm, that is, the sealing becomes ineffective. For this reason, the inventors of the above-mentioned patent have intensively studied the assembly sealing structure of the electrolytic cell group and made further improvements thereto.
Disclosure of Invention
The utility model aims to solve the technical problems that: the above patent discloses an electrode plate of an electrolytic cell and its constituent structure are improved to meet the requirement of high-pressure electrolytic sealing, and an electrolytic cell with reliable sealing are formed to realize high-pressure hydrogen and oxygen production.
The first technical scheme provided by the utility model for solving the technical problems is as follows: the electrolytic unit with the sealing gasket comprises a pair of electrode plates, the sealing gasket which is attached to the front side surface and the back side surface of the electrode plates, and an electrolytic diaphragm which is clamped between the opposite side surfaces of the pair of electrode plates, wherein one electrode plate is connected with a positive electrode of a power supply and the other electrode plate is connected with a negative electrode of the power supply; the outer side surfaces of the sealing gaskets are provided with convex rings, and the diameters of the two convex rings of the two sealing gaskets on the two opposite side surfaces of the pair of electrode plates are different; the convex ring of the sealing gasket on one electrode plate of the pair of electrode plates is abutted against one side surface of the electrolytic diaphragm to form a first coil wire seal, and the convex ring of the sealing gasket on the other electrode plate is abutted against the other side surface of the electrolytic diaphragm to form a second coil wire seal; the first coil seal and the second coil seal are staggered from each other on the circumference; the sealing gasket forms radial limit relative to the electrode plate.
The second technical scheme provided by the utility model for solving the technical problems is as follows: the high-voltage electrolytic tank is formed by stacking and pressing a plurality of electrolytic units in the second technical scheme, the liquid inlet holes and the corresponding film openings are used for allowing electrolyte to enter and fill the electrolytic areas on the front side and the back side of the electrode plate, and the two liquid outlet holes and the corresponding film openings are used for respectively leading out gas and liquid after the electrolytic reaction on the cathode side and the anode side.
The inventor of the present patent application studied intensively the above-mentioned assembly sealing structure of the existing electrolytic cell group: 1. the flat seal is formed among the pole plate, the sealing gasket and the diaphragm after the compression, the flatness of the sealing surfaces of the pole plate, the sealing gasket and the diaphragm is difficult to achieve high precision due to the processing precision, when the gas-liquid is gradually generated in the electrolytic reaction area to form high pressure, a large pressure difference is formed between the gas-liquid and the outside, and under the action of the large pressure difference, the sealing failure among the pole plate, the sealing gasket and the diaphragm is easy to be caused; 2. because the plane seal is formed among the polar plate, the sealing gasket and the diaphragm, the axial stress is applied to form constraint after the compression, but the constraint is not effective in the radial direction, the polar plate, the sealing gasket and the diaphragm are easy to generate tiny movement on the plane under the action force of high-pressure gas and liquid generated in an electrolytic reaction area, and the sealing among the polar plate, the sealing gasket and the diaphragm is easy to lose efficacy.
The beneficial effects of the utility model are as follows: because the sealing gaskets are designed and filled between the side surfaces of the pair of electrode plates, when the pair of electrode plates forming the cathode electrode and the anode electrode are oppositely attached and the electrolytic membrane is clamped between the pair of electrode plates, the two sealing gaskets on the opposite side surfaces of the pair of electrode plates are respectively staggered with the two side surfaces of the electrolytic membrane (the first coil of wire sealing and the second coil of wire sealing), the plane sealing between the conventional sealing gaskets and the electrolytic membrane and the electrode plates is changed into the two coil of wire sealing, the sealing performance is greatly improved, and the pressure difference between an electrolytic reaction area and the outside is greatly resisted without leakage. As for the pressure difference between the corresponding liquid inlet hole of the inner ring of the electrolytic diaphragm and the membrane opening hole of the liquid outlet hole, the sealing of the outer ring of the electrolytic diaphragm is ensured, so that the gas-liquid pressure difference of the inner ring of the electrolytic diaphragm gradually balances itself and disappears. When the high-pressure electrolytic tank is formed by the electrolytic unit, the high-pressure electrolytic tank and the electrolytic unit thereof can reach the required high pressure after continuous electrolysis without worrying about leakage, thereby realizing the high-pressure hydrogen-to-oxygen production without leakage, namely producing high-pressure hydrogen and oxygen.
Further, annular grooves are formed in the peripheral edges of the electrolytic area on the front side surface and the back side surface of the electrode plate, and all or part of the sealing gasket is filled into the annular grooves to form radial limit between the sealing gasket and the side surface of the electrode plate.
Further, the surface of the sealing gasket, which is in contact with the electrode plate, is provided with grains, and when friction force is formed on the surface of the sealing gasket, which is in contact with the electrode plate, radial limit is formed between the sealing gasket and the side surface of the electrode plate.
Further, the surfaces of the sealing gasket, which are in contact with the electrode plates, are respectively provided with a protrusion and a groove which are nested with each other, so that radial limit is formed between the sealing gasket and the side surfaces of the electrode plates.
Further, a baffle is arranged on the outer peripheral side of the sealing gasket, and the baffle and the electrode plate form fixed connection so as to form radial limit between the sealing gasket and the side surface of the electrode plate.
Through the improvement and variation, the sealing gasket can be limited to slide outwards in the radial direction, so that the leakage of the inner ring sealing gasket on the side surface of the electrode plate due to radial movement is avoided.
Further, the fixed coupling is a bolt coupling, a weld, a key-to-keyway coupling, or a pin-to-pinhole coupling.
Further, the bead is an O-ring or other shape in cross-section.
Further, the bead is an adhesive strip adhered to the outward-facing hollow side of the gasket.
Further, the bead is a coating formed on the hollow side of the gasket facing outward.
Drawings
The electrolytic cell with a gasket and the high-pressure electrolytic cell according to the present utility model will be further described with reference to the accompanying drawings.
FIG. 1 is a schematic view of a conventional electrolytic cell seal assembly for producing high pressure hydrogen and oxygen.
FIG. 2 is a schematic view showing the structure of an electrolytic cell according to the first embodiment.
Fig. 3 is a sectional view taken along A-A in fig. 2.
Fig. 4 is an enlarged view of a portion of the circle marked B in fig. 2.
FIG. 5 is a schematic view showing the structure of an electrolytic cell according to the second embodiment.
Fig. 6 is a cross-sectional view taken along the direction C-C in fig. 5.
Fig. 7 is an enlarged view of a portion of the circle marked D in fig. 5.
FIG. 8 is a schematic view showing a partial structure of a variation of the electrolytic unit of FIG. 7.
FIG. 9 is a schematic view showing the structure of an electrolytic cell according to the third embodiment.
Fig. 10 is an enlarged view of a portion of the circle marked E in fig. 9.
FIG. 11 is a schematic view showing the structure of an electrolytic cell in the third embodiment.
Fig. 12 is a cross-sectional view taken along the direction F-F in fig. 11.
Fig. 13 is an enlarged view of a portion of the circle marked G in fig. 11.
Fig. 14 is a schematic diagram of the explosion of the structure of a high-voltage electrolytic cell in the fourth embodiment.
Detailed Description
Example 1
The present embodiment provides an electrolysis unit with gaskets, as shown in fig. 2, which is composed of a pair of electrode plates 1, gaskets 6 attached to the opposite sides of the electrode plates 1, and an electrolysis diaphragm 10 interposed between the opposite sides of the pair of electrode plates 1, the electrolysis diaphragm 10 being also interposed between the opposite gaskets 6; in order to show the positional relationship among the electrode plate 1, the gasket 6 and the electrolytic membrane 10 clearly, fig. 2 is not to scale, for example, the thickness of the gasket 6 is relatively large. One electrode plate 1 of the pair of electrode plates 1 is used as an anode electrode when being connected with a positive electrode of a power supply, and the other electrode plate 1 is used as a cathode electrode when being connected with a negative electrode of the power supply. As shown in FIG. 3, the middle part of the front and back sides of the electrode plate 1 is provided with an electrolysis area 100 which participates in the electrolysis reaction, and a liquid inlet hole 2, two liquid outlet holes 3-1, 3-2 and a plurality of small through holes 4 are formed in the area. The electrolytic diaphragm 10 is respectively attached to the opposite side surfaces of the pair of electrode plates 1, covers the electrolytic area 100 and is clamped between the two opposite sealing gaskets 6, and the electrolytic diaphragm 10 is provided with a diaphragm opening corresponding to the liquid inlet hole 2 and the liquid outlet holes 3-1 and 3-2.
As shown in fig. 4, the outward side of the gasket 6 is formed with a bead 8, and the diameters of the two beads 8 of the two gaskets 6 on the opposite sides of the pair of electrode plates 1 respectively forming the cathode electrode plate and the anode electrode plate are different; the convex ring 8 of the sealing gasket 6 on one electrode plate 1 of the pair of electrode plates 1 is abutted against one side surface of the electrolytic diaphragm 10 to form a first coil seal 5-1, and the convex ring 8 of the sealing gasket 6 on the other electrode plate 1 is abutted against the other side surface of the electrolytic diaphragm 10 to form a second coil seal 5-2; the first coil seal 5-1 and the second coil seal 5-2 are offset from each other on the circumference.
The surface of the sealing gasket 6 contacted with the electrode plate 1 is provided with grains, and when the surface of the sealing gasket 6 contacted with the electrode plate 1 forms friction force, radial limit is formed between the sealing gasket 6 and the side surface of the electrode plate 1.
Example two
This embodiment provides an electrolytic cell with a gasket, as shown in fig. 5, 6 and 7, which is a modified variation on the basis of the electrolytic cell of the first embodiment, except that the difference is as follows: annular grooves 7 are formed in the peripheral edges of the electrolysis area 100 on the front side and the back side of the surrounding electrode plate 1, and all sealing gaskets 6 are filled into the annular grooves 7 to form radial limit between the sealing gaskets 6 and the side of the electrode plate 1.
Of course, only a part of the gasket 6 may be filled in the annular groove 7, so that a radial limit is formed between the gasket 6 and the side surface of the electrode plate 1, as shown in fig. 8.
Example III
This embodiment provides an electrolytic cell with a gasket, as shown in fig. 9 and 10, which is a modified variation on the basis of the electrolytic cell of the first embodiment, except that the difference is as follows: the surfaces of the gasket 6 contacting the electrode plate 1 are respectively formed with protrusions 9 and grooves 11 nested with each other. Thereby forming a radial limit between the gasket 6 and the side of the electrode plate 1.
Example IV
This embodiment provides an electrolytic cell with a gasket, as shown in fig. 11, 12 and 13, which is a modified variation on the basis of the electrolytic cell of the first embodiment, except that the difference is as follows: the periphery side of the sealing gasket 6 is provided with a baffle plate 12, and the baffle plate 12 is fixedly connected with the electrode plate 1; the fixed connection is through a bolt 13. Of course, the bolt 13 coupling may be changed to welding. Thereby forming a radial limit between the gasket 6 and the side of the electrode plate 1.
The bead 8 of the first to fourth embodiments may be modified as follows:
1) The convex ring 8 is an adhesive tape adhered to the outward empty side surface of the sealing gasket 6;
2) The bead 8 is a coating such as a ceramic coating or the like formed on the hollow side surface of the gasket 6 facing outward;
3) The convex ring 8 is a convex ring strip which is integrally manufactured with the sealing gasket 6, namely, the convex ring 8 is a part of the same material of the sealing gasket 6;
4) The cross-sectional shape of the collar may be formed of any reasonable shape other than O-shape, for example: triangles, quadrilaterals, etc.;
5) The number of collars 8 used as seals may be increased to form a third, fourth or more collar seal.
Example five
The embodiment provides a high-voltage electrolytic tank, as shown in fig. 14, which is formed by stacking and pressing a plurality of electrolytic units of the first embodiment, the second embodiment, the third embodiment or the fourth embodiment, wherein the liquid inlet hole 2 and the second opening 20 on the corresponding electrolytic membrane 10 are used for allowing electrolyte to enter and fill the electrolytic areas 100 on the front side and the back side of the electrode plate, and the two liquid outlet holes 3-1, 3-2 and the membrane openings 10-1, 10-2 on the corresponding electrolytic membrane 10 are used for respectively leading out gas and liquid after the electrolytic reaction on the cathode side and the anode side.
In addition, the electrolytic unit and other prior arts of the electrolytic tank related to the above embodiments are referred to the chinese patent or similar publications mentioned in the background art, and the present utility model will not be repeated.
The foregoing description is only of the preferred embodiments of the utility model, but the utility model is not limited thereto, and all equivalents and modifications according to the concept of the utility model and the technical solutions thereof are intended to be included in the scope of the utility model.
Claims (10)
1. The electrolytic unit with the sealing gasket comprises a pair of electrode plates, the sealing gasket which is attached to the front side surface and the back side surface of the electrode plates, and an electrolytic diaphragm which is clamped between the opposite side surfaces of the pair of electrode plates, wherein one electrode plate is connected with a positive electrode of a power supply and the other electrode plate is connected with a negative electrode of the power supply; the method is characterized in that: the outer side surfaces of the sealing gaskets are provided with convex rings, and the diameters of the two convex rings of the two sealing gaskets on the two opposite side surfaces of the pair of electrode plates are different; the convex ring of the sealing gasket on one electrode plate of the pair of electrode plates is abutted against one side surface of the electrolytic diaphragm to form a first coil wire seal, and the convex ring of the sealing gasket on the other electrode plate is abutted against the other side surface of the electrolytic diaphragm to form a second coil wire seal; the first coil seal and the second coil seal are staggered from each other on the circumference; the sealing gasket forms radial limit relative to the electrode plate.
2. The electrolysis cell of claim 1, wherein: annular grooves are formed in the peripheral edges of the electrolytic area on the front side surface and the back side surface of the electrode plate, and all or part of the sealing gasket is filled into the annular grooves to form radial limit between the sealing gasket and the side surface of the electrode plate.
3. The electrolysis cell of claim 1, wherein: the surface of the sealing gasket, which is in contact with the electrode plate, is provided with grains, and radial limit is formed between the sealing gasket and the side surface of the electrode plate when friction force is formed on the surface of the sealing gasket, which is in contact with the electrode plate.
4. The electrolysis cell of claim 1, wherein: the surface of the sealing gasket, which is contacted with the electrode plate, is respectively provided with a protrusion and a groove which are nested with each other, so that radial limit is formed between the sealing gasket and the side surface of the electrode plate.
5. The electrolysis cell of claim 1, wherein: the periphery side of the sealing gasket is provided with a baffle, and the baffle and the electrode plate form fixed connection so as to form radial limit between the sealing gasket and the side surface of the electrode plate.
6. The electrolysis cell according to any one of claims 1 to 5, wherein: the male ring is an O-ring.
7. The electrolysis cell according to any one of claims 1 to 5, wherein: the convex ring is adhered to the adhesive tape on the outward empty side surface of the sealing gasket.
8. The electrolysis cell according to any one of claims 1 to 5, wherein: the convex ring is provided with a circle of plating layer on the outward empty side surface of the sealing gasket.
9. The electrolysis cell of claim 5, wherein: the fixed connection is a bolt connection, a welding, a key-key slot connection or a pin-pin hole connection.
10. A high voltage electrolytic cell, characterized in that: the electrolytic cell is formed by stacking and pressing a plurality of electrolytic cells according to any one of claims 1-5, wherein the liquid inlet holes and the corresponding film openings are used for allowing electrolyte to enter and fill the electrolytic areas on the front side and the back side of the electrode plate, and the two liquid outlet holes and the corresponding film openings are used for respectively leading out gas and liquid after the electrolytic reaction on the cathode side and the anode side.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202322476977.8U CN220977172U (en) | 2023-09-12 | 2023-09-12 | Electrolytic cell with gasket and high-voltage electrolytic tank |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN202322476977.8U CN220977172U (en) | 2023-09-12 | 2023-09-12 | Electrolytic cell with gasket and high-voltage electrolytic tank |
Publications (1)
Publication Number | Publication Date |
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CN220977172U true CN220977172U (en) | 2024-05-17 |
Family
ID=91056536
Family Applications (1)
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CN202322476977.8U Active CN220977172U (en) | 2023-09-12 | 2023-09-12 | Electrolytic cell with gasket and high-voltage electrolytic tank |
Country Status (1)
Country | Link |
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CN (1) | CN220977172U (en) |
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2023
- 2023-09-12 CN CN202322476977.8U patent/CN220977172U/en active Active
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