CN216972345U - Tempered glass product and electronic equipment shell - Google Patents

Tempered glass product and electronic equipment shell Download PDF

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CN216972345U
CN216972345U CN202220362669.5U CN202220362669U CN216972345U CN 216972345 U CN216972345 U CN 216972345U CN 202220362669 U CN202220362669 U CN 202220362669U CN 216972345 U CN216972345 U CN 216972345U
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compressive stress
glass article
strengthened glass
depth
stress layer
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裴郁蕾
盖琪莹
赵倩情
崔静娜
张家鑫
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BYD Co Ltd
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BYD Co Ltd
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Abstract

The application provides a tempered glass article and an electronic device shell, wherein the tempered glass article comprises a first surface and a second surface which are oppositely arranged, a first pressure stress layer extending from the first surface to a certain depth in the tempered glass article, and a second pressure stress layer extending from the second surface to a preset depth in the tempered glass article, wherein the first surface is a frosted surface, the second surface is a non-frosted surface, and one side, far away from the second surface, of the second pressure stress layer is wavy and is provided with a plurality of wave crests and a plurality of wave troughs which are alternately distributed. The strengthened glass product can give consideration to both good frosting effect and better mechanical property.

Description

Tempered glass product and electronic equipment shell
Technical Field
The application relates to the technical field of glass, in particular to a tempered glass product and an electronic equipment shell.
Background
Frosted glass is a kind of decorative glass developed in recent years, and is obtained by etching a glass substrate with a frosted liquid, and the glass surface can present a certain convex structure, so that the glass has a hazy and beautiful appearance effect and a certain anti-glare function, and is particularly suitable for being used as a decorative shell (such as a cover plate) of electronic equipment. Chemical strengthening (i.e., ion exchange) is a common means for improving the mechanical properties of glass, and frosted glass has certain damage on the surface, so that the high mechanical properties are difficult to endow to the frosted glass by ordinary chemical strengthening. Therefore, there is a need to provide a new strengthened frosted glass product with excellent mechanical properties.
SUMMERY OF THE UTILITY MODEL
In view of this, the present application provides a strengthened glass product, which can achieve both good frosting effect and superior mechanical properties.
A first aspect of the present disclosure provides a strengthened glass article, including a first surface and a second surface disposed opposite to each other, a first compressive stress layer extending from the first surface to a predetermined depth, and a second compressive stress layer extending from the second surface to a depth in the strengthened glass article, wherein the first surface is a frosted surface, the second surface is a non-frosted surface, and a side of the second compressive stress layer away from the second surface is wavy and has a plurality of peaks and a plurality of valleys alternately distributed.
In the tempered glass product, one side surface is a frosted surface, the other side surface is a non-frosted surface, the pressure stress layers on the two side surfaces are different and are distributed asymmetrically, the depth of the pressure stress layer on the non-frosted surface side is different, and the pressure stress layer on the non-frosted surface side is in a periodic trend of alternately high depth and shallow depth in the direction parallel to the non-frosted surface, so that if a crack exists in a tension pressure area clamped between the two asymmetric pressure stress layers, the expansion of the crack can be fully inhibited, particularly, the special structure of the pressure stress layer on the non-frosted surface side greatly increases the contact area of the crack which can be obstructed, further greatly reduces the influence of the crack on the strength of the glass product, and improves the mechanical properties of the crack threshold, bending strength, impact resistance and the like.
A second aspect of the present application provides an electronic device housing comprising a strengthened glass article as described in the first aspect of the present application.
The electronic equipment shell containing the tempered glass product is fashionable in appearance and good in mechanical property, and the appearance change force and the product competitiveness of electronic equipment can be improved.
Drawings
Fig. 1 is a schematic cross-sectional structural view of a strengthened glass article provided in an embodiment of the present disclosure.
Fig. 2 is another schematic structural view of the strengthened glass article of fig. 1.
Fig. 3 is a schematic view of another configuration of the strengthened glass article of fig. 1.
FIG. 4 is a schematic cross-sectional view of a strengthened glass produced in comparative example 1.
Detailed Description
The technical solutions of the embodiments of the present application are described below with reference to the drawings.
Fig. 1 is a schematic cross-sectional structural view of a strengthened glass article provided in an embodiment of the present disclosure. As shown in fig. 1, the strengthened glass article 100 includes a first surface 10a and a second surface 10b disposed opposite to each other, a first compressive stress layer 101 extending from the first surface 10a to a predetermined depth in the strengthened glass article 100, and a second compressive stress layer 102 extending from the second surface 10b to a predetermined depth in the strengthened glass article 100, wherein the first surface 10a is a frosted surface, the second surface 10b is a non-frosted surface, and a side of the second compressive stress layer 102 away from the second surface 10b is wavy and has a plurality of peaks and a plurality of valleys alternately (i.e., a side of the second compressive stress layer 102 away from the second surface 10b has a plurality of peaks spaced apart from each other, and a valley exists between two adjacent peaks). Wherein the wave crests correspond to the maximum depth of the second compressive stress layer 102 and the wave troughs correspond to the minimum depth of the second compressive stress layer 102.
One side surface of the strengthened glass product is a frosted surface, the other side surface of the strengthened glass product is a non-frosted surface, the compression stress layers on the two side surfaces are different and are in asymmetric distribution, the depth of the compression stress layer 102 on the non-frosted surface side is different, and the compression stress layer has a periodic trend of alternately high depth and shallow depth in the direction parallel to the non-frosted surface (namely, the x direction in fig. 1), so that if a crack exists in a tension pressure area clamped between the two asymmetric compression stress layers, the expansion of the crack can be fully inhibited, and particularly, the special structure of the compression stress layer on the non-frosted surface side greatly increases the contact area of the crack which can be blocked, thereby greatly reducing the influence of the crack on the strength of the glass product, and improving the mechanical properties such as the fracture threshold, bending strength, impact resistance and the like.
In the present application, the distance between the peak and the second surface 10b is denoted as H1The distance of the trough from the second surface 10b is denoted as H2It is understood that H1Greater than H2. Wherein H2May be H1Can be, for example, 25%, 30%, 35%, 40%, 50%, 55%, 60%, 70%, 75%, etc., and in some embodiments, H is present in an amount of about 20-80%, or more specifically about 25%, 30%, 35%, 40%, 50%, 55%, 60%, 70%, or 75%, etc2May be H130-60 percent of the total weight of the powder. This may cause the side of the second layer 102 remote from the second surface 10b to be substantially wavy, which may be more clearly distinguished from the first layer 101. In some embodiments of the present application, the distance H of the peak from the second surface 10b1Greater than or equal to 100 μm. E.g. H1Is 100 μm to 200 μm. The distance H of the trough from the second surface 10b2Greater than or equal to 50 μm. E.g. H2Is 50-160 μm.
Further, referring to fig. 2, the second compressive stress layer 102 includes a first compressive stress region 1021 extending from the second surface 10b into the strengthened glass article, and a second compressive stress region 1022 extending from the second surface 10b into the strengthened glass article, wherein the first compressive stress region 1021 includes one of the peaks, and the second compressive stress region 1022 includes one of the valleys, and the first compressive stress region 1021 and the second compressive stress region 1022 are distributed at intervals and are adjacent to each other along a direction (x direction in the drawing) parallel to the second surface 10 b. Is defined between the trough and the crestAny plane parallel to the second surface 10b is a boundary plane of the first compressive stress region 1021 and the second compressive stress region 1022 (its distance from the second surface is denoted as H)x) At any same depth between the horizontal plane in which the trough lies and the bounding surface (i.e. at a depth between H2And HxAt any same depth therebetween), the compressive stress of the first compressive stress region 1021 is greater than the compressive stress of the second compressive stress region 1022.
As shown in fig. 2, a projection of an intersection point of the defining surface and the first compressive stress region 1021 on the second surface is A, B, and a projection of an intersection point of the defining surface and the second compressive stress region 1022 on the second surface is B, C, then a horizontal distance between A, B is a width of the first compressive stress region 1021, and a horizontal distance between B, C is a width of the second compressive stress region 1022.
Since the first compressive stress region 1021 includes a peak and the second compressive stress region 1022 includes a valley, it will be appreciated that the maximum depth of the first compressive stress region (i.e., the distance of the peak from the second surface) is greater than the maximum depth of the second compressive stress region. The above-mentioned defining surfaces may be at equal distances from the peak and the trough, or may be close to the peak or close to the trough, and preferably, the defining surfaces are close to the trough (i.e. the distance from the trough to the defining surfaces is less than the distance from the peak). It will be appreciated that when the depth of the valleys of the second layer 102 is different, the defining surface is selected primarily for adjacent peaks and valleys.
In the present embodiment, the distance from the second surface 10b is 0 to a third depth (denoted as H)3) At any same depth within the range of (a), the compressive stress of the first compressive stress region 1021 is substantially equal to the compressive stress of the second compressive stress region 1022; wherein the third depth H3Less than the distance H of the trough from the second surface 10b2And the third depth H3Not exceeding 50 μm. By "substantially equal" is meant that the compressive stress F of the first compressive stress section 1021 is1Compressive stress F with the second compressive stress region 10222Does not exceed 1%, i.e., the degree of deviation k ═ F1-F2|/F1K is less than or equal to 1 percent. Alternatively, k is 0.5%, in some cases k is 0.1%, and even k is 0. In other words, the second compressive stress layer 102 includes a second extension from the second surface 10b to a depth H3A uniform compressive stress layer (as shown in fig. 3). The uniform compressive stress layer is a stress layer with substantially equal compressive stress in the same depth, and is mainly formed by secondary chemical strengthening.
In addition, the depth of the second compressive stress layer is greater than the H3The compressive stress in the second compressive stress layer decreases with increasing depth. Specifically, the first compressive stress region 1021 is deeper than H3To H1In the range of (1), the compressive stress thereof decreases with increasing depth; the second compressive stress region 1022 is deeper than H3To HxIn the range of (1), the compressive stress thereof decreases with increasing depth. At this time, in FIG. 2, the third depth H is set between3At any depth from the above-mentioned bounding surface (i.e. depth between H)3And HxAt any same depth therebetween), the compressive stress of the first compressive stress region 1021 is greater than the compressive stress of the second compressive stress region 1022.
Optionally, the compressive stress of the second compressive stress layer 102 at a depth of 50 μm from the second surface 10b is greater than or equal to 10 MPa.
In the present embodiment, the surface compressive stress of the second compressive stress layer 102 at the second surface 10b is equal to the surface compressive stress of the first compressive stress layer 101 at the first surface 10 a. Wherein the surface compressive stress of the second compressive stress layer 102 at the second surface 10b is greater than or equal to 550MPa, such as at 550-1000 MPa.
In the present application, the depth of the first compressive stress layer 101 is substantially constant along the x-direction in fig. 1. In the present embodiment, the depth of the first compressive stress layer 101 may be equal to the maximum depth of the second compressive stress layer 102 (i.e., the distance H of the peak from the second surface 10 b)1) As shown in fig. 3. Similarly, the first compressive stress layer 101 also has a depth H extending from the first surface 10a to the inside3' a uniform compressive stress layer. H is made of3' with the above H3And are equal. Wherein the surface of the first compressive stress layer 101The surface compressive stress is greater than or equal to 550MPa, for example, in the range of 550MPa to 1000 MPa.
In the embodiment of the present application, the thickness of the tempered glass product may be 0.3mm to 5 mm. Specifically, the thickness may be 0.4mm, 0.5mm, 0.6mm, 0.8mm, 1mm, 1.2mm, 2mm, 3mm, 4mm, or the like. In some embodiments, the thickness may be 0.4mm to 2 mm. At the moment, the electronic equipment shell adopting the tempered glass product is lighter and thinner, and the mechanical property of the electronic equipment shell is better.
In an embodiment of the present application, the strengthened glass product has a flexural strength of 800MPa or more. The higher bending strength reflects the better toughness and less tendency to crack of the strengthened glass product. In some embodiments, the flexural strength is 800-1200Mpa, and further may be 900-1200 Mpa.
In an embodiment of the present application, the strengthened glass article has an impact energy of 0.5J or more. The larger impact strength reflects the strong impact resistance of the tempered glass and is not easy to break. In some embodiments, the impact energy is 0.6J or greater, such as 0.6J to 3J.
The strengthened glass article can be produced by the following method. Specifically, the following steps may be included:
(1) arranging protective layers on other surfaces of the glass body except the surface to be frosted (such as a first surface), then placing the glass body in a frosting solution to convert the first surface into a frosted surface (namely, obtaining frosted glass), and removing the protective layers;
(2) locally shielding a second surface opposite to the frosting surface, and then chemically strengthening the glass body after local shielding for the first time;
(3) removing the shielding pattern, and performing a second chemical strengthening to obtain the strengthened glass product.
In the step (1), the protective layer is typically an acid-resistant polymer film (such as polyethylene terephthalate (PET), or an ink layer, etc. the protective layer can be removed by physical removal such as sanding, polishing, etc., or chemical removal such as alkali etching, etc.
In the step (2), the shielding pattern may be formed on the surface of the glass body through a screen printing process, a coating process (such as spraying), a plating process, or an exposure and development process. The masking pattern is typically a high temperature resistant material. The shielding pattern may include a plurality of shielding layers distributed at intervals, and the shape of the shielding layers (specifically, the projection shape thereof on the glass substrate) may include a regular shape such as a circle, an ellipse, a triangle, a rectangle, a polygon, or an irregular shape. The existence of the shielding pattern can block ion exchange between ions in the strengthened molten salt and the glass part shielded by the shielding pattern, and further the strengthened glass with the asymmetric pressure stress layer can be formed. Optionally, the total coverage of the shielding pattern on the second surface of the glass body is 10% -50%. This reduces distortion caused by asymmetrical stress distribution on the surfaces on both sides of the glass. In the step (3), the removal of the shielding pattern can be realized by at least one of a mechanical polishing technology and a soaking method in the liquid medicine.
The molten salt used for the first chemical strengthening can be only a sodium salt or a mixture of the sodium salt and a potassium salt. The molten salt used for the second chemical strengthening can be only potassium salt or a mixture of sodium salt and potassium salt. The molten salt used for the two-step chemical strengthening can be determined according to the specific material of the glass body. Typically, the glass body is lithium aluminosilicate glass.
Embodiments of the present application also provide an electronic device housing that includes a strengthened glass article as described previously herein.
The electronic device adopting the electronic device shell can be various consumer electronic products, such as mobile phones, tablet computers, notebook computers, wearable devices (such as smart watches and smart bracelets), Virtual Reality (VR) terminal devices, Augmented Reality (AR), electronic readers, televisions, camcorders, projectors and other electronic products.
For the case that the electronic device is a portable electronic device such as a mobile phone, a tablet computer, a wearable product, etc., the electronic device housing may be a display screen cover plate specifically assembled on the front side of the electronic device, and the display screen cover plate is covered on the display module; a rear cover assembled to the rear side of the electronic apparatus is also possible. In some embodiments, when the electronic device is an electronic device with a camera function (e.g., a mobile phone or a digital camera), the electronic device housing may also be a camera protection cover.
The strengthened glass product is used as a shell of electronic equipment, can meet the light and thin requirements of the electronic equipment, and has good mechanical properties.
The present application is further illustrated by the following specific examples.
Example 1
A method of making a strengthened glass article, comprising the steps of:
(1) taking the lithium aluminosilicate glass with the size of 160mm in length, 80mm in width and 0.6mm in thickness, arranging an ink protective layer on the other surfaces except the surface (such as the first surface) to be frosted, then soaking the lithium aluminosilicate glass in a frosting solution to obtain frosted glass with one frosted surface, and removing the ink protective layer.
(2) The frosted glass is cleaned, a second surface opposite to the frosted surface is partially shielded, a plurality of shielding layers distributed at intervals are formed on the non-frosted surface of the glass in a silk screen printing mode, the shielding layers are circular with the diameter of 1mm, the distance between centers of circles is 2mm, and the total coverage rate of the shielding layers on the second surface is 23%. And then, performing first chemical strengthening on the frosted glass after the partial shielding.
(3) And removing the shielding layer, performing secondary chemical strengthening on the frosted glass, and cleaning to obtain a strengthened glass product.
A schematic of the structure of the strengthened glass article of example 1 is shown in figure 1, described above. The strengthened glass article includes a first surface 10a (which is a frosted surface) and a second surface 10b (which is a non-frosted surface) disposed opposite to each other, a first compressive stress layer 101 extending from the first surface 10a to a certain depth in the strengthened glass article 100, and a second compressive stress layer 102 extending from the second surface 10b to a predetermined depth, wherein a side of the second compressive stress layer 102 away from the second surface 10b is wavy and has a plurality of peaks and a plurality of valleys alternately distributed.
Wherein the distance H of the wave peak from the second surface 10b1About 150 μmThe distance H of the trough from the second surface 10b2About 55 μm. The first compressive stress layer 101 includes a depth H extending from the first surface 10a3A uniform compressive stress layer of about 20 μm; the second compressive stress layer 102 includes a second surface 10b extending to a depth H3About 20 μm, and the second compressive stress layer 102 has the same compressive stress at the same depth within the range of less than or equal to 20 μm. The surface compressive stress of the second compressive stress layer 102 is equal to the surface compressive stress of the first compressive stress layer 101 and is about 800 MPa; the second compressive stress layer 102 has a compressive stress of about 15Mpa at a depth of 50 μm from the second surface.
Example 2
A strengthened glass article, which is prepared by a method different from that of example 1: the shielding layers are squares with 1mm side length, the center distance is 2mm, and the total coverage rate of the plurality of shielding layers on the second surface is 23%.
The structure of the strengthened glass article of example 2 is schematically shown in fig. 1, and the overall structural features thereof are substantially the same as those of example 1. Wherein the distance H of the wave peak from the second surface 10b1About 180 μm, the distance H of the wave trough from the second surface 10b2About 70 μm. The first compressive stress layer 101 includes a depth H extending from the first surface 10a3' A uniform compressive stress layer of about 10 μm, the second compressive stress layer 102 includes a second surface 10b extending to a depth H3A uniform compressive stress layer of about 10 μm, the compressive stress at any same depth within the range of 10 μm or less being substantially equal. The surface compressive stress of the second compressive stress layer 102 is equal to the surface compressive stress of the first compressive stress layer 101 and is about 830 MPa; the second compressive stress layer 10 has a compressive stress of about 20MPa at a depth of 50 μm from the second surface.
Example 3
A strengthened glass article, which is prepared by a method different from that of example 1: the masking layer is circular with a diameter of 1mm, the center-to-center distance is 1.5mm, and the total coverage of the multiple masking layers on the second surface is 40%.
The structure of the strengthened glass article of example 3 is schematically shown in fig. 1, and the overall structural features thereof are substantially the same as those of example 1. Wherein, the waveDistance H of peak from second surface 10b1About 130 μm, the distance H of the wave trough from the second surface 10b2About 70 μm. The first compressive stress layer 101 includes a depth H extending from the first surface 10a3' a uniform compressive stress layer of about 35 μm; the second compressive stress layer 102 includes a second surface 10b extending to a depth H3A uniform compressive stress layer of about 35 μm, the compressive stress at any same depth within the range of less than 35 μm being substantially equal. The surface compressive stress of the second compressive stress layer 102 is equal to the surface compressive stress of the first compressive stress layer 101 and is about 750 MPa; the second compressive stress layer 10 has a compressive stress of about 25MPa at a depth of 50 μm from the second surface.
In order to highlight the beneficial effects of the embodiments of the present application, the following comparative examples are provided:
comparative example 1
A strengthened glass article prepared by a method different from that of example 1, comprising: after one side surface of the glass body is subjected to frosting treatment, the surface opposite to the frosting surface of the glass body is not subjected to local shielding, and the first chemical strengthening and the second chemical strengthening are directly and sequentially carried out.
A schematic structural view of the strengthened glass article of comparative example 1 is shown in fig. 4. The strengthened glass article includes a first surface 10a (which is a frosted surface) and a second surface 10b (which is a non-frosted surface) disposed opposite one another, but the first compressive stress layer 101 extending inward to a depth from the first surface 10a and the second compressive stress layer 102 extending inward to a depth from the second surface 10b are substantially identical and symmetrically distributed. The thickness of the two pressure stress layers is 150 μm, and the surface pressure stress is 800 MPa.
To support the benefits of the examples of the present application, the four-point bending test and the ball drop impact test were performed on the strengthened glass articles of the examples and comparative examples above, and the results are summarized in table 1 below.
The four-point bending test method comprises the following steps: each glass sample was placed in a bending jig with a distance between the upper support rods of 20mm, a distance between the lower support rods of 40mm, and a pressing speed of 10 mm/min. The glass is pressed to break and the maximum pressure p (n) is recorded. Width w (mm) and thickness t (mm) of combined glass sample) The flexural strength of the sample was calculated: bending strength 3P x (40-20)/(2 xw x t)2)。
The method for testing falling ball impact comprises the following steps: and smashing the central point of the glass sample by using a steel ball with the weight of 65 g. And starting the test from the falling ball height of 25cm, increasing the falling ball height in a gradient of 5cm, recording the corresponding falling ball height when the glass sample is broken, and calculating the impact resistance energy of the sample. Wherein the impact energy is mgh, wherein m is the weight (kg) of the falling ball, g is the acceleration of gravity 10m/s, and h is the height (m) of the falling ball.
TABLE 1
Flexural Strength (MPa) Impact energy (J)
Example 1 1050 0.65
Example 2 970 0.62
Example 3 1130 0.62
Comparative example 1 700 0.26
As can be seen from table 1 above, the strengthened glass articles provided in the examples of the present application have better mechanical properties, and are significantly better than the strengthened glass of the comparative examples in terms of bending strength, impact strength, and the like.
The above-mentioned embodiments only express the exemplary embodiments of the present application, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present application. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the concept of the present application, which are considered to be within the scope of the present application.

Claims (12)

1. A strengthened glass article comprising first and second oppositely disposed surfaces, a first compressive stress layer extending from the first surface to a predetermined depth in the strengthened glass article, and a second compressive stress layer extending from the second surface to a depth in the strengthened glass article, wherein the first surface is frosted and the second surface is non-frosted, and wherein a side of the second compressive stress layer remote from the second surface is wavy having a plurality of peaks and a plurality of valleys alternating therewith.
2. The strengthened glass article of claim 1, wherein the second compressive stress layer comprises a first compressive stress region extending from the second surface into the strengthened glass article and a second compressive stress region extending from the second surface into the strengthened glass article, the first compressive stress region comprising one of the peaks and the second compressive stress region comprising one of the valleys, the first compressive stress region and the second compressive stress region being disposed in spaced, abutting relation in a direction parallel to the second surface;
and defining any plane which is positioned between the wave crests and the wave troughs and is parallel to the second surface as a defining surface, and if the plane is positioned at any same depth between the horizontal plane of the wave troughs and the defining surface, the compressive stress of the first compressive stress region is greater than that of the second compressive stress region.
3. The strengthened glass article of claim 2, wherein the compressive stress of the first compressive stress region is substantially equal to the compressive stress of the second compressive stress region from any same depth within a range from 0 to a third depth from the second surface; wherein the third depth is less than the distance of the trough from the second surface, and the third depth is no more than 50 μm.
4. The strengthened glass article of claim 1, wherein the distance of the trough from the second surface is 20-80% of the distance of the peak from the second surface.
5. The strengthened glass article of claim 4, wherein the peak is at a distance greater than or equal to 100 μ ι η from the second surface.
6. The strengthened glass article of claim 4, wherein the valleys are greater than or equal to 50 μ ι η from the second surface.
7. The strengthened glass article of any one of claims 1 to 6, wherein the second compressive stress layer has a compressive stress at a depth of 50 μ ι η from the second surface of greater than or equal to 10 MPa.
8. The strengthened glass article of any one of claims 1 to 6, wherein the second compressive stress layer has a surface compressive stress greater than or equal to 550 MPa.
9. The strengthened glass article of claim 8, wherein a surface compressive stress of the second compressive stress layer is equal to a surface compressive stress of the first compressive stress layer.
10. The strengthened glass article of claim 1, wherein the strengthened glass article has a thickness of 0.3mm to 5 mm.
11. The strengthened glass article of claim 1, wherein the strengthened glass article has a flexural strength of greater than or equal to 800 MPa.
12. An electronic device housing comprising the strengthened glass article of any one of claims 1-11.
CN202220362669.5U 2022-02-22 2022-02-22 Tempered glass product and electronic equipment shell Active CN216972345U (en)

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