CN214581009U - Waste heat recovery system and boiler system - Google Patents
Waste heat recovery system and boiler system Download PDFInfo
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- CN214581009U CN214581009U CN202120607266.8U CN202120607266U CN214581009U CN 214581009 U CN214581009 U CN 214581009U CN 202120607266 U CN202120607266 U CN 202120607266U CN 214581009 U CN214581009 U CN 214581009U
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Abstract
The utility model relates to a waste heat recovery system and boiler system. The heat exchanger comprises a first heat exchanger and a second heat exchanger which are sequentially arranged on a flue, wherein the first heat exchanger is an air-water heat exchanger made of common materials, the second heat exchanger is an air-water heat exchanger made of corrosion-resistant materials, a plate-type third heat exchanger is arranged between the two heat exchangers, a first heat exchange medium sequentially flows through the second heat exchanger, the first heat exchange medium flows through the first heat exchanger, the second heat exchanger exchanges heat with flue gas in the first heat exchanger, the third heat exchanger exchanges heat with steam introduced into a boiler system, and a temperature control module is arranged to control the temperature of the first heat exchange medium in the first heat exchanger within a set temperature range slightly higher than dew point temperature, so that the water vapor in the flue gas can not be condensed on the surface of the first heat exchanger but is condensed on the surface of the second heat exchanger, so that the flue gas has good corrosion resistance on the premise of efficient heat exchange, and the whole cost is low.
Description
Technical Field
The utility model relates to a waste heat recovery system and boiler system.
Background
With the continuous deepening of the policy of energy conservation and emission reduction in China, the original coal-fired boiler for providing steam for enterprises or residents is gradually replaced by a gas-fired boiler taking natural gas as fuel, taking a certain industrial park as an example, 3 gas-fired boilers can generate 150 tons of steam per hour, the consumption capacity is huge, the temperature of the combusted tail gas is around 110-150 ℃, the main component of the natural gas is methane CH4, and according to the combustion chemical formula: CH4+2O2 ═ CO2+2H2O, 1m3After full combustion of the natural gas, the heating value is about 35.88MJ without regard to condensation. When considering the condensation exotherm, the heating value can be as high as 39.82MJ due to the large exotherm produced by the condensation of water vapor, and it can be seen that the combustion tail gas contains a large amount of heat energy.
According to the 50t/h evaporation capacity and the 4586.48Nm3/h fuel gas consumption of a single boiler, the generated water vapor is about: 1.6137kg/s, the heat power released due to condensation is about 1827kW and the heat power released in the tail gas is about 1015kW, which is calculated according to the saturated humidity tail gas cooled to 50 ℃, and the total is about 2850kW by inquiring the enthalpy value table. The power can raise the temperature of water at 50t/h (13.88kg/s) to 2850/(13.88 multiplied by 4.2) to 48.9K, namely if the feed water temperature is 20 ℃, hot water at about 70 ℃ can be directly obtained by a waste heat recovery system. According to economic analysis, the 2850kW waste heat recovery energy source is 2.85MJ/s, namely 2.85/35.88 is equivalent to 0.079m3The calorific value released by the natural gas. The saving of 0.079X 3600 ═ 284.4m per hour3Natural gas. According to 2.5 yuan/m3The natural gas value of (2.5 x 0.079 x 3600) is calculated to be equivalent to saving fuel cost of 714.9 yuan per hour. When the device is operated for 20 hours every day, 714.9X 20 is saved, namely 14298 yuan/day. On the other hand, if carbon emissions are considered, the carbon emissions can be reduced by 8.2 tons per day.
Therefore, the significance of improving the recovery utilization rate of the heat energy of the tail gas is great.
However, in the prior art, the recovery efficiency of tail gas waste heat recovery is low, if the heat exchange efficiency is improved, the temperature of a heat exchange medium needs to be reduced, so that a large amount of water vapor in the tail gas is condensed on the surface of a heat exchanger, a corrosive acid solution is formed, the acid solution can cause the outer surface of the heat exchanger to be seriously corroded and rusted, and a channel for the tail gas to pass through on the heat exchanger can be blocked by a rusty oxide, so that the ventilation is not smooth; however, if the corrosion problem is to be solved, the investment is huge, so that the economy is poor, the steam supply unit considers the cost problem, the waste heat recovery system is not good, and the popularization of the waste heat recovery system is severely limited.
SUMMERY OF THE UTILITY MODEL
The utility model aims to provide a waste heat recovery system which can not only effectively prevent corrosion, but also obviously improve the heat exchange efficiency and has low cost investment; an object of the utility model is also to provide an use above-mentioned waste heat recovery system's boiler system.
The utility model discloses a waste heat recovery system's technical scheme as follows:
a waste heat recovery system comprising:
the first heat exchanger is arranged in the flue and is an air-water heat exchanger, a first internal pipeline is arranged in the first heat exchanger, and the first internal pipeline is provided with a first water inlet and a first water outlet; the first heat exchanger is made of common carbon steel;
the second heat exchanger is arranged in the flue and is positioned at the downstream of the first heat exchanger along the flow direction of the flue gas, the second heat exchanger is an air-water heat exchanger and is provided with a second internal pipeline, and the second internal pipeline is provided with a cooling water inlet and a cooling water outlet;
the third heat exchanger is a plate heat exchanger for water-water heat exchange, a hot end pipeline and a cold end pipeline which are mutually crossed and attached are arranged in the third heat exchanger, an inlet of the cold end pipeline is communicated with the cooling water outlet, and an outlet of the cold end pipeline is communicated with the first water inlet; the inlet of the hot end pipeline is used for being communicated with a steam pipeline of output steam of the boiler system;
the first heat exchange medium flows in from the cooling water inlet, sequentially flows through the second internal pipeline, the cold end pipeline and the first internal pipeline, and flows out from the first water outlet; the third heat exchanger is made of corrosion-resistant metal or nonmetal;
the temperature control module comprises a temperature detection sensor arranged at a position between an outlet of the cold end pipeline and the first water outlet, a regulating valve arranged on the pipeline in front of an inlet of the hot end pipeline and a controller in control connection with the temperature detection sensor and the regulating valve, wherein the regulating valve is controlled by feedback of the temperature detection module to control the temperature of the first heat exchange medium to be within a set temperature range in a mode of controlling the flow of steam entering the hot end pipeline, and the lowest temperature of the set temperature range is greater than the dew point temperature of the steam in the flue gas when the steam is condensed on the outer surface of the first heat exchanger.
On the basis of the scheme, the waste heat recovery system is further improved as follows, the waste heat recovery system further comprises a fourth heat exchanger which is arranged in the flue and is located on the downstream of the second heat exchanger along the flow direction of flue gas so as to be used for regenerative heating of the flue gas, the fourth heat exchanger is an air-water heat exchanger and is provided with a fourth internal pipeline, the fourth internal pipeline is provided with a fourth water inlet and a fourth water outlet, the first water outlet is communicated with the fourth water inlet, and the fourth water outlet is communicated with a water inlet pipeline of the boiler system.
On the basis of the scheme, the cross section of the first inner pipeline of the first heat exchanger is oval, and the length direction of the oval is arranged along the flow direction of the flue gas.
On the basis of the scheme, the heat exchanger is further improved as follows, and the first heat exchanger is a finned tube heat exchanger.
On the basis of the scheme, the heat exchanger is further improved in the following mode, and the second heat exchanger is a light pipe heat exchanger.
The utility model discloses a boiler system's technical scheme as follows:
the utility model provides a boiler system, includes boiler body, the flue and the inlet channel that link to each other with boiler body, still includes the steam pipeline of outside output steam, still includes:
the first heat exchanger is arranged in the flue and is an air-water heat exchanger, a first internal pipeline is arranged in the first heat exchanger, and the first internal pipeline is provided with a first water inlet and a first water outlet; the first heat exchanger is made of common carbon steel;
the second heat exchanger is arranged in the flue and is positioned at the downstream of the first heat exchanger along the flow direction of the flue gas, the second heat exchanger is an air-water heat exchanger and is provided with a second internal pipeline, and the second internal pipeline is provided with a cooling water inlet and a cooling water outlet;
the third heat exchanger is a plate heat exchanger for water-water heat exchange, a hot end pipeline and a cold end pipeline which are mutually crossed and attached are arranged in the third heat exchanger, an inlet of the cold end pipeline is communicated with the cooling water outlet, and an outlet of the cold end pipeline is communicated with the first water inlet; the inlet of the hot end pipeline is used for being communicated with a steam pipeline of output steam of the boiler system;
the first heat exchange medium flows in from the cooling water inlet, sequentially flows through the second internal pipeline, the cold end pipeline and the first internal pipeline, and flows out from the first water outlet; the third heat exchanger is made of corrosion-resistant metal or nonmetal;
the temperature control module comprises a temperature detection sensor arranged at a position between an outlet of the cold end pipeline and the first water outlet, a regulating valve arranged on the pipeline in front of an inlet of the hot end pipeline and a controller in control connection with the temperature detection sensor and the regulating valve, wherein the regulating valve is controlled by feedback of the temperature detection module to control the temperature of the first heat exchange medium to be within a set temperature range in a mode of controlling the flow of steam entering the hot end pipeline, and the lowest temperature of the set temperature range is greater than the dew point temperature of the steam in the flue gas when the steam is condensed on the outer surface of the first heat exchanger.
On the basis of the scheme, the waste heat recovery system is further improved as follows, the waste heat recovery system further comprises a fourth heat exchanger which is arranged in the flue and is located on the downstream of the second heat exchanger along the flow direction of flue gas so as to be used for regenerative heating of the flue gas, the fourth heat exchanger is an air-water heat exchanger and is provided with a fourth internal pipeline, the fourth internal pipeline is provided with a fourth water inlet and a fourth water outlet, the first water outlet is communicated with the fourth water inlet, and the fourth water outlet is communicated with a water inlet pipeline of the boiler system.
On the basis of the scheme, the cross section of the first inner pipeline of the first heat exchanger is oval, and the length direction of the oval is arranged along the flow direction of the flue gas.
On the basis of the scheme, the heat exchanger is further improved as follows, and the first heat exchanger is a finned tube heat exchanger.
On the basis of the scheme, the heat exchanger is further improved in the following mode, and the second heat exchanger is a light pipe heat exchanger.
The utility model has the advantages that: the utility model has the advantages that the heat recovery efficiency is high, and the energy utilization rate can be improved as much as possible, firstly, the temperature of the first heat exchange medium in the first heat exchanger is controlled to be as low as possible under the premise that the temperature is higher than the dew point and the corrosion is not easy to occur, so that the heat exchange efficiency is higher when the first heat exchange is carried out with tail gas; secondly, as the first heat exchanger is controlled by the medium temperature without corrosion, the first heat exchanger can be made of common carbon steel, so that the aim of low cost is fulfilled; moreover, the second heat exchanger is used as a set condensation position, so that water vapor in the flue gas can be concentrated at the second heat exchanger for severe phase change of condensation heat exchange, not only can the moisture in the flue gas be removed, but also the heat in the flue gas is recovered, and the finished anticorrosion requirement can be realized only by carrying out concentrated anticorrosion treatment on the second heat exchanger; the two-stage heat exchange of the first heat exchanger and the second heat exchanger further improves the heat exchange efficiency and the heat recovery rate; the heated first heat exchange medium can be used as raw material water of the gas boiler, so that the fuel quantity required by the gas boiler when heating the first heat exchange medium is obviously reduced compared with the fuel quantity required by the original cooling water used as a raw material, namely, the energy dissipation during subsequent long-distance conveying is avoided, and the starting point temperature of the gas boiler during steam production is increased, so that the energy utilization rate is increased; therefore, the utility model discloses have very high heat recovery efficiency, improved the utilization ratio of fuel, the overall cost is lower moreover, and the system is simple, has very good anticorrosive, prevents that the ash is stifled effect moreover.
Furthermore, the system has a self-whitening function due to the arrangement of the fourth heat exchanger, the occurrence of white fog in the smoke discharged into the chimney subsequently is remarkably reduced, and the corrosion of the inner wall of the chimney is avoided.
Furthermore, the first heat exchanger adopts finned tubes with oval cross sections, and the heat exchange efficiency is further improved because the width of the finned tubes in the wind direction is wider on the premise of meeting the requirement of smaller wind resistance, and therefore, the heat exchange time is longer, the heat exchange area is larger; in addition, because the first heat exchanger can not be condensed, the heat exchanger with the fins is selected, the heat exchange efficiency of the fins is higher, and the heat recovery efficiency is also improved.
Further, the second heat exchanger adopts the light pipe heat exchanger, and because the second heat exchanger is the place of the concentrated condensation of design, the adoption of the light pipe heat exchanger is convenient for condensation on the one hand, and the acid liquor formed by the convenient condensation is discharged, is convenient for cleaning, and is structurally corrosion-resistant as far as possible, and because the second heat exchanger is the place of the concentrated condensation, the condensation is the process of violent phase change, and the finned tube heat exchanger is not needed to be adopted to improve the heat exchange efficiency.
Drawings
Fig. 1 is a schematic view of the working principle of embodiment 1 of the waste heat recovery system of the present invention;
FIG. 2 is a front view of a first heat exchanger and a second heat exchanger;
FIG. 3 is a left side view of FIG. 2;
fig. 4 is a schematic view of the working principle of embodiment 2 of the waste heat recovery system of the present invention;
in the figure: 1-a first heat exchanger, 11-a first water inlet, 12-a first water outlet, 4-a spray pipe, 41-a nozzle, 42-a spray water inlet, 43-a water outlet, 44-a water collecting tank, 5-a second heat exchanger, 51-a cooling water inlet, 52-a cooling water outlet, 6-a third heat exchanger and 7-a fourth heat exchanger; 8-first heat exchange medium, 40-shell.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more clearly understood, the present invention is further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the invention, i.e., the described embodiments are only some, but not all embodiments of the invention. The components of embodiments of the present invention, as generally described and illustrated in the figures herein, may be arranged and designed in a wide variety of different configurations.
Thus, the following detailed description of the embodiments of the present invention, presented in the accompanying drawings, is not intended to limit the scope of the invention, as claimed, but is merely representative of selected embodiments of the invention. Based on the embodiment of the present invention, all other embodiments obtained by the person skilled in the art without creative work belong to the protection scope of the present invention.
It is noted that relational terms such as "first" and "second," and the like, may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
The features and properties of the present invention are described in further detail below with reference to examples.
A waste heat recovery system comprising:
the first heat exchanger is arranged in the flue and is an air-water heat exchanger, a first internal pipeline is arranged in the first heat exchanger, and the first internal pipeline is provided with a first water inlet and a first water outlet; the first heat exchanger is made of common carbon steel;
the second heat exchanger is arranged in the flue and is positioned at the downstream of the first heat exchanger along the flow direction of the flue gas, the second heat exchanger is an air-water heat exchanger and is provided with a second internal pipeline, and the second internal pipeline is provided with a cooling water inlet and a cooling water outlet;
the third heat exchanger is a plate heat exchanger for water-water heat exchange, a hot end pipeline and a cold end pipeline which are mutually crossed and attached are arranged in the third heat exchanger, an inlet of the cold end pipeline is communicated with the cooling water outlet, and an outlet of the cold end pipeline is communicated with the first water inlet; the inlet of the hot end pipeline is used for being communicated with a steam pipeline of output steam of the boiler system;
the first heat exchange medium flows in from the cooling water inlet, sequentially flows through the second internal pipeline, the cold end pipeline and the first internal pipeline, and flows out from the first water outlet; the third heat exchanger is made of corrosion-resistant metal or nonmetal;
the temperature control module comprises a temperature detection sensor arranged at a position between an outlet of the cold end pipeline and the first water outlet, a regulating valve arranged on the pipeline in front of an inlet of the hot end pipeline and a controller in control connection with the temperature detection sensor and the regulating valve, wherein the regulating valve is controlled by feedback of the temperature detection module to control the temperature of the first heat exchange medium to be within a set temperature range in a mode of controlling the flow of steam entering the hot end pipeline, and the lowest temperature of the set temperature range is greater than the dew point temperature of the steam in the flue gas when the steam is condensed on the outer surface of the first heat exchanger.
The waste heat recovery system further comprises a fourth heat exchanger which is arranged in the flue and located on the downstream of the second heat exchanger along the flow direction of flue gas so as to be used for regenerative heating of the flue gas, the fourth heat exchanger is an empty water heat exchanger and is provided with a fourth internal pipeline, the fourth internal pipeline is provided with a fourth water inlet and a fourth water outlet, the first water outlet is communicated with the fourth water inlet, and the fourth water outlet is communicated with a water inlet pipeline of the boiler system. The cross section of a first inner pipeline of the first heat exchanger is oval, and the oval length direction is arranged along the flow direction of flue gas. The first heat exchanger is a finned tube heat exchanger. The second heat exchanger is a light pipe heat exchanger.
The utility model discloses an embodiment 1 of waste heat recovery system:
the waste heat recovery system is used for waste heat recovery of tail gas of a gas boiler or a coal-fired boiler, and the waste heat recovery system is provided with a shell 40, the shell 40 is in a pipeline shape and is connected in series in a tail gas pipeline, namely, two ends of the shell are in sealed butt joint with a tail gas pipe respectively, so that the tail gas of the boiler can pass through the waste heat recovery system, the tail gas is discharged after heat exchange is carried out, heat in the tail gas is transferred to a heat transfer medium of the waste heat recovery system, heat of the heat transfer medium is utilized to heat or a water inlet pipeline of a leading-in boiler system is utilized, and secondary utilization of the heat is realized. More specifically:
as shown in fig. 1 to 3, the waste heat recovery system includes a housing 40, and a first heat exchanger 1, a second heat exchanger 5, and a third heat exchanger 6 installed in the housing 40. Wherein:
the first heat exchanger 1 is a tube fin type air-water heat exchanger made of common carbon steel, tube fins of the first heat exchanger are elliptical finned tubes, the windward side of the first heat exchanger is small, the heat exchange area is large, the wind resistance outside the tubes can be fully reduced on the premise of ensuring the heat exchange efficiency, the overall structure better conforms to the field synergy principle, and the heat transfer coefficient of the first heat exchanger is superior to that of a common circular finned tube. Meanwhile, in order to ensure the corrosion resistance of the heat exchanger in the area, the outside of the finned tube is galvanized. Through high-temperature hot galvanizing, the fins and the base pipe are wrapped by the zinc layer at the same time, and the protection of the zinc layer can ensure that the fin and the base pipe have antirust and anticorrosive performances while the high-efficiency heat transfer between metals is kept. The following table is a table of performance parameters of the elliptical finned tube heat exchanger (first heat exchanger 1):
the body of the first heat exchanger 1 has inside an internal pipe with a first water inlet 11 and a first water outlet 12.
The second heat exchanger 5 is a light pipe type air-water heat exchanger made of stainless steel, a cooling water inlet 51 and a cooling water outlet 52 are formed in the body of the heat exchanger and used for heating cooling water (called as a first heat exchange medium) for the first time, the first heat exchange medium enters the first heat exchanger for heat exchange after being heated by the second heat exchanger, the first heat exchange medium serves as an output medium and can be used for heating or a water supply system of a gas boiler after being heated, and therefore some fuel can be consumed less when the gas boiler produces steam. In the second heat exchanger 5, because the temperature of the first heat exchange medium in the second heat exchanger is lower than the dew point temperature, a large amount of heat is released through condensation of water vapor in the flue gas, and the heating power during the whole condensation can account for about 11% of the full heat value of the natural gas at most. In order to ensure reliable construction, a certain margin is reserved, and the flue gas temperature is recovered to 50 ℃. In the second heat exchanger 5, since the flue gas is mainly saturated steam, a large amount of heat is released along with condensation, and a large amount of condensed water is separated out. At this time, a large amount of acidic solution is generated outside the heat exchange tube.
The second-stage heat exchanger is a condensation heat exchange core area, and because the phase change of condensation heat exchange is severe and the heat exchange amount is large, the heat exchange efficiency is not required to be increased by adopting fins, and the light tube made of stainless steel or glass is directly adopted in consideration of the requirements on cost and corrosion resistance. The following table is a table of performance parameters for the bare tube heat exchanger (second heat exchanger 5):
as shown in fig. 2 and 3, since the acid solution is formed on the surface of the second heat exchanger 5, the acid solution is unfavorable to the heat exchanger on the surface of the heat exchanger, and dust is easily accumulated, a spray pipe 4 is disposed between the first heat exchanger 1 and the second heat exchanger 5, a plurality of spray nozzles 41 are disposed at intervals on the spray pipe 4, the spray nozzles 41 are disposed toward the second heat exchanger 5, high-pressure water is supplied by an external water supply pump, supplied to the spray pipe 4 through a spray water inlet 42, high-pressure water mist is sprayed out through the spray nozzles 41 in a tapered range to wash off the outer surface of the second heat exchanger 5 on-line, so as to wash off the dust and the acid solution on the surface of the second heat exchanger 5, a water collection tank 44 structure similar to a funnel is disposed at the lower portion of the housing 40 corresponding to the second heat exchanger 5, a water discharge port 43 is disposed at the lower portion of the water collection tank structure for discharging the washed off water, and since the washed water contains the acid solution, it is therefore contemplated that the acidic solution may be filtered, purified, etc. to form a more pure acidic solution for subsequent use. In other embodiments, the material of the light pipe may be replaced by a corrosion-resistant material such as glass or ceramic. In other embodiments, an online cleaning system such as a shower pipe may not be provided, and self-cleaning may be achieved only by flowing of condensed water.
Meanwhile, due to the separation of the condensed water, dust and impurities are very easily polluted in the area, so that the drawer type core body is adopted in the design, the maintenance and the cleaning are convenient, and the efficiency of the heat exchange tube and the cleanliness in the area are improved.
As shown in fig. 1, the flowing directions of the first heat exchange medium and the tail gas are opposite, the tail gas sequentially passes through the first heat exchanger and the second heat exchanger, the first heat exchange medium is opposite, and passes through the second heat exchanger first and then passes through the first heat exchanger, on one hand, the heat exchange efficiency is improved, on the other hand, when the first heat exchanger flows inside, the temperature of the first heat exchange medium is ensured to reach the temperature higher than the dew point, and therefore the problem that the corrosion is caused due to the fact that acid liquor is formed by condensation on the outer surface of the first heat exchanger is solved.
The third heat exchanger 6 is used for controlling the temperature of the first heat exchange medium before entering the first heat exchanger, so that the temperature of the first heat exchange medium is kept in a temperature range slightly higher than the dew point temperature, so as to prevent the water vapor in the tail gas from condensing on the outer surface of the first heat exchanger to generate acid liquor, the third heat exchanger is an auxiliary heat exchanger, it adopts a plate heat exchanger with a multi-layer plate lamination structure, is a water-water heat exchanger, does not participate in heat exchange with tail gas, is internally provided with two flow passages which respectively form a cold end pipeline and a hot end pipeline, wherein the water inlet of the cold end pipeline is communicated with the cooling water outlet of the second heat exchanger, the water outlet of the cold end pipeline is communicated with the first water inlet of the first heat exchanger, after flowing out of the second heat exchanger, the first heat exchange medium can flow through the cold end pipeline of the third heat exchanger and then flow into the internal pipeline of the first heat exchanger. And the hot end pipeline of the third heat exchanger is communicated with a deaerator or a steam distributing cylinder of the boiler system (namely connected with a pipeline outlet of the boiler system for leading out steam), so that high-temperature steam produced by the boiler system can be led into the hot end pipeline of the third heat exchanger, and the first heat exchange medium flowing in the cold end pipeline is heated.
In particular, in order to realize the accurate control of the temperature of the first heat exchange medium before entering the first heat exchanger, a temperature detection sensor is arranged on a pipeline between the third heat exchanger and the first heat exchanger or on an internal pipeline of the first heat exchanger for detecting the temperature of the first heat exchange medium, a regulating valve is arranged on a pipeline between the boiler system and a hot end pipeline of the third heat exchanger, the regulating valve can be an electromagnetic valve, the real-time temperature detected by a temperature detection sensor is compared with the temperature range preset by a controller, for example, a temperature range of 60-63 c is set, when the real-time measured temperature is lower than 60 c, the valve port of the controller which receives the feedback of the temperature sensor and controls the opening of the regulating valve through logic processing is larger, thereby improving the flow of the high-temperature steam in the hot end pipeline and further improving the temperature of the first heat exchange medium; and conversely, when the detected actual temperature is higher than 63 ℃, the regulating valve is controlled to be opened slightly or closed directly, so that the temperature of the first heat exchange medium is reduced.
The temperature is controlled to be slightly higher than the dew point temperature, so that the water vapor in the tail gas is prevented from condensing on the surface of the first heat exchanger, and the heat exchange efficiency of the first heat exchanger is improved as much as possible.
It should be noted that: the reason why the water vapor in the exhaust gas is prevented from condensing on the outer surface of the first heat exchanger 1 is that the exhaust gas contains a large amount of nitrogen oxides and water vapor after the natural gas is sufficiently combusted. When the tail gas passes through the first heat exchanger 1, if the temperature of the first heat exchange medium 8 in the first heat exchanger 1 is lower than the dew point temperature, water vapor in the tail gas is separated out due to condensation and is combined with nitrogen oxides to generate a nitric acid solution. Due to the structural action of the fins, the acidic corrosive solution collects liquid drops outside the fin tubes of the heat exchanger, so that the fins are gradually corroded to generate metal oxides (rust). The fluffy oxides are accumulated outside the first heat exchanger 1, so that an air channel is gradually blocked, the air outlet resistance in the pipeline is increased, the performance working point of the tail gas fan is changed, and the air volume is obviously reduced. And the utility model discloses a scheme makes the temperature control of first heat transfer medium 8 at the temperature that is a little higher than the dew point through setting up of accuse temperature pipeline and third heat exchanger 6 for 1 surface of first heat exchanger can not condense out acid corrosion solution, thereby has avoided the corrosion problems of first heat exchanger 1 to take place, of course, in order to ensure the accident, the surface of first heat exchanger 1 has also carried out hot-galvanize or electroplating treatment, thereby has the corrosion resisting property of certain degree.
High anticorrosive material, for example stainless steel or the heat exchange tube of taking special cladding can effectively be able to bear the corrosion of rare nitric acid, but because its price is more expensive, if all use high anticorrosive material to make the heat exchanger, probably lead to the heat exchanger investment cost far beyond the budget. Considering the cost, first heat exchanger 1 itself can choose ordinary carbon steel material not corrosion-resistant for use, owing to avoided first heat exchanger 1 surface corrosion through 8 temperature's of first heat transfer medium control, does not worry again under the prerequisite of anticorrosive problem, chooses for use the heat exchanger that the cross section is oval fin tube structure for the purpose of improving heat exchange efficiency. In other words, the temperature of the entire flow field of the exhaust gas as it passes through the condenser is calculated according to software simulation. And in different temperature intervals, different materials are selected for use as the heat exchange tube material, so that the heat exchanger structure with the heat exchange tube material coupled with the temperature field is realized. In the high temperature region of condenser, because no moisture analysis goes out, can adopt the finned tube of ordinary material to combine general antiseptic measure to restrain the acid corrosion in the scheme of the utility model, we adopt this kind of low windage anticorrosive heat exchange tube of oval finned tube to design the condenser of manufacturing high temperature region. In the low temperature region, a large amount of dilute nitric acid solution is formed because a large amount of water is separated out. Therefore, in this region, stainless steel light pipes, which are corrosion resistant but costly, are selected for the design of the condenser module in which the region is fabricated (see below for further details).
On the other hand, the system is also provided with a water leakage alarm module and a water shortage alarm module, and when water leakage of a pipeline or water shortage in the heat exchanger is detected, alarm prompts are respectively carried out so as to ensure that maintenance personnel can timely collect message prompts.
When in use: as shown in fig. 1, high temperature exhaust gas (about 150 ℃) discharged from a gas boiler after combustion flows in a flue and firstly passes through the outer surface of a finned tube of a first heat exchanger 1 to exchange heat with a first heat exchange medium 8 flowing in the finned tube, at this time, the temperature of the exhaust gas is reduced to about 60 ℃, the temperature of the first heat exchange medium 8 is increased to about 87 ℃, then the exhaust gas (60 ℃) passes through the outer surface of a light tube of a second heat exchanger 5 to exchange heat with a first heat exchange medium (cooling water of 20 ℃) in the second heat exchanger 5, a large amount of heat is discharged due to condensation (the dew point is about 60 ℃), the temperature of the exhaust gas is reduced to about 50 ℃, and the temperature of the first heat exchange medium is increased to about 50 ℃; meanwhile, high-temperature steam in the boiler system flows through a hot end pipeline of the third heat exchanger, the first heat exchange medium flows out of the second heat exchanger and then also flows through a cold end pipeline of the third heat exchanger, the first heat exchange medium (about 50 ℃) exchanges heat with the high-temperature steam, so that the temperature of the first heat exchange medium is raised to be slightly higher than the dew point temperature (60-63 ℃), the real-time temperature detected by the temperature detection sensor is compared with the preset temperature range of the controller, for example, the set temperature range is 60-63 ℃, when the real-time measured temperature is lower than 60 ℃, the controller receives the feedback of the temperature sensor and controls the opening of the regulating valve to be larger through logic processing, so that the flow of the high-temperature steam in the hot end pipeline is increased, and the temperature of the first heat exchange medium is increased; and conversely, when the detected actual temperature is higher than 63 ℃, the regulating valve is controlled to be opened slightly or closed directly, so that the temperature of the first heat exchange medium is reduced. The first heat exchange medium heated for three times can be led into a water supply pipeline of the boiler system, so that the gas consumption of the gas boiler is reduced, and the first heat exchange medium can also be led into an urban heating pipeline to realize heating and can also be used for other purposes. And the steam passing through the hot end pipeline of the third heat exchanger can be continuously used for the second time.
The utility model discloses a waste heat recovery system has following characteristics:
1. the heat recovery efficiency is high, the energy utilization rate of the gas boiler can be improved as much as possible, firstly, the temperature of the first heat exchange medium 8 in the first heat exchanger 1 is controlled to be as low as possible on the premise that the temperature is higher than the dew point and the first heat exchange medium is not easy to corrode, so that the heat exchange efficiency is higher when the first heat exchange is carried out on the first heat exchange medium and the tail gas; secondly, the first heat exchanger 1 adopts finned tubes with oval cross sections, and the heat exchange efficiency is further improved because the width of the finned tubes in the wind direction is wider on the premise of meeting the requirement of smaller wind resistance, and the heat exchange time is longer and the heat exchange area is larger; in addition, the first heat exchanger 1 does not condense, so that a heat exchanger with fins is selected, the heat exchange efficiency of the fins is high, and the heat recovery efficiency is improved; moreover, the first heat exchange medium 8 also realizes heat exchange with high-temperature steam through the third heat exchanger 6, so that the temperature of the first heat exchange medium serving as an output product is further increased, and the heat recovery efficiency is further improved; more importantly, the heated first heat exchange medium 8 is used as raw material water of the gas boiler, so that the fuel quantity required by the gas boiler when heating the first heat exchange medium 8 is obviously reduced compared with the fuel quantity required by the original cooling water used as raw material, namely, the energy dissipation during subsequent long-distance conveying is avoided, and the starting point temperature of the gas boiler during steam production is increased, so that the energy utilization rate is improved; therefore, the utility model discloses a waste heat recovery system has very high heat recovery efficiency, can improve gas boiler's energy utilization as far as possible.
2. The anti-corrosion and anti-wind channel blockage method comprises the steps that firstly, for a first heat exchanger 1, the temperature of a first heat exchange medium 8 in the first heat exchanger is adjusted to be higher than the dew point temperature of water vapor condensation in tail gas, so that the water vapor can not be condensed at the first heat exchanger 1, and common anti-corrosion schemes such as hot galvanizing or electroplating are adopted on the outer surface of the first heat exchanger 1, so that the anti-corrosion purpose of the first heat exchanger 1 is realized, the finned tube heat exchanger made of common carbon steel can be selected safely, and no condensation can occur, so that an acid solution can not be formed, the surface of the first heat exchanger 1 can not rust, and the problem of preventing the flue blockage is solved; secondly, for the second heat exchanger 5, because the second heat exchanger 5 is in a low-temperature region, the temperature of the first heat exchange medium in the second heat exchanger 5 is still lower, so that the second heat exchanger 5 is a core region for condensation heat exchange, and a large amount of condensed water is inevitably generated on the outer surface of the second heat exchanger 5, so that a large amount of dilute nitric acid solution can be formed, therefore, the second heat exchanger 5 is a core region which is corroded, and the corrosion resistance of the second heat exchanger is well achieved, and the second heat exchanger 5 is integrally made of corrosion-resistant materials such as stainless steel and the like to play a main corrosion resistance role; in addition, in order to prevent the acid solution from being accumulated on the surface of the second heat exchanger 5, a smooth-surface non-groove light pipe heat exchanger is selected, so that the acid solution cannot be accumulated on the surface of the heat exchanger for a long time; furthermore, in order to prevent the acidic solution from bonding to the surface of the second heat exchanger 5 after being combined with the dust, the spraying pipe 4 is arranged, and the water outlet 43 is also arranged at the lower part of the spraying pipe, so that the outer surface of the second heat exchanger 5 is regularly washed, the dust and the acidic solution are washed down and discharged from the water outlet 43, and the corrosion of the outer surface of the second heat exchanger 5 and the inner wall surface of the flue is avoided; the design of the above anticorrosion measures has the advantages of excellent anticorrosion and flue blockage prevention on the premise of low cost, simple structure and high heat exchange efficiency; the corrosion of the waste heat recovery device is mainly electrochemical corrosion, the contents of the discharged gases of various boilers and gas turbines are different, the environmental pressures are different, the dew points (condensation-generating temperatures) are different, when the temperature of a certain point of the heat exchange device is lower than the condensation temperature, dew condensation can be generated, so that the heat exchanger is corroded, all the temperatures of the heat exchanger are higher than the dew point temperature by controlling the temperature of a cold-side medium of the heat recovery device, and the heat recovery quantity of a common heat exchanger can be reduced to the maximum extent by using common materials.
3. The finned tube heat exchanger is low in cost, if the finned tube heat exchanger is complex in structure and made of high-corrosion-resistant materials such as stainless steel, the cost is high, the finned tube heat exchanger is made of common carbon steel with low cost, and corrosion is prevented by increasing the temperature of a heat exchange medium, so that the corrosion prevention problem of the first heat exchanger is solved; the second heat exchanger adopts a light pipe heat exchanger, and the light pipe heat exchanger has a simple structure, so that the overall cost is not high even if the light pipe heat exchanger is processed by high-cost stainless steel materials, and even if the light pipe heat exchanger is adopted, the light pipe heat exchanger can completely adopt non-metal materials such as glass, ceramics and the like, so that a large amount of equipment cost can be further saved; in addition, for temperature control before the first heat exchange medium enters the first heat exchanger, steam produced by the boiler system is directly adopted, the temperature of the first heat exchange medium can be controlled only by controlling one regulating valve, a heat source does not need to be additionally arranged, and the cost is further reduced.
On the basis of the two characteristics, the novel energy-saving environment-friendly energy-saving device has the advantages of long service life of products, long service life, good economical efficiency and capability of reducing the investment recovery period.
The utility model discloses an embodiment 2 of waste heat recovery system: as shown in fig. 4, the difference from embodiment 1 is that a fourth heat exchanger 7 is further provided after the second heat exchanger 5 to solve the whitening problem, specifically: the fourth heat exchanger 7 is an empty water heat exchanger, because there is no condensation basically, so the heat exchanger processed by common carbon steel plus galvanization can be adopted to reduce the cost, the water inlet of the fourth heat exchanger is communicated with the first water outlet of the first heat exchanger, the water outlet of the fourth heat exchanger is communicated with the water supply pipeline of the boiler system, namely, the first heat exchange medium 8 flows out of the first heat exchanger and then flows through the fourth heat exchanger, in other embodiments, the first heat exchange medium flowing out of the first heat exchanger can be divided into two paths, one path is led into the fourth heat exchanger, the other path is led into the water supply pipeline of the boiler system, reverse heating of the tail gas can be realized through the leading of the first heat exchange medium, the heat regeneration is for short, and the tail gas whitening effect can be realized after the heat regeneration.
The working principle of the whitening here is as follows: after passing through the second heat exchanger 5, most of moisture in the tail gas is condensed and separated out, the temperature of the tail gas is about 40 ℃, if the tail gas is directly discharged through a chimney, because the temperature of the tail gas is lower (lower than the dew point), when the tail gas is contacted with the inner wall of the chimney, because the temperature of the inner wall of the chimney is lower, saturated water vapor can be further condensed, so that an acid solution can be generated on the inner wall of the chimney, the corrosion of the inner wall of the chimney is easily caused, and when the tail gas is positioned near a smoke exhaust port of the chimney, the tail gas is contacted with cold air and is condensed to form white fog; in the scheme, the fourth heat exchanger 7 is arranged behind the second heat exchanger 5, so that part or all of the heated first heat exchange medium 8 can be guided to be heated by the tail gas, the temperature of the tail gas is higher than the dew point temperature (about 50 ℃ or higher), namely, the temperature of the tail gas is higher than the dew point temperature when the temperature of the tail gas is close to smoke exhaust ports of a chimney and the chimney, condensation cannot occur, and after the tail gas is further diffused into the atmosphere, although the temperature of the tail gas is lower than the dew point temperature, water vapor after diffusion is relatively dispersed, water mist cannot be formed, and accordingly, white mist cannot occur, and the aim of whitening is achieved. According to the scheme, additional energy is not required to be utilized for heating the tail gas, the temperature of the tail gas is utilized to be reversely heated for the tail gas after heat exchange, and therefore whitening is achieved.
It should be noted that: in the scheme, the tail gas is heated to be higher than 60 ℃ through regenerative heating after being reduced from 150 ℃ to 40 ℃, the regenerative process is not a repeated process, and the scheme is different from the scheme that the tail gas is directly reduced from 150 ℃ to 60 ℃, because the tail gas is a large amount of condensation processes carried out at the second heat exchanger 5 in the process of reducing the temperature to 40 ℃, most of water vapor in the tail gas is condensed and separated out in the process, therefore, the air is only heated in the subsequent regenerative process, the energy consumption of heating is low, and the humidity of the tail gas can be effectively reduced. It can be seen that the reduction from 60 ℃ to 40 ℃ and the heating from 40 ℃ to 60 ℃ in this solution are irreversible processes, since the moisture content in the exhaust gas is different in the two processes, the former having a large energy variation, and the latter having a small energy variation due to the phase transition process involving little water. This is also an ingenious aspect of the present solution.
Through this scheme, can realize protecting rear end chimney internal face material not corroded, reduce the humidity of discharging fume, prevent that vapor from appearing, and realize taking off white. In addition, the scheme achieves the extreme effect of heat recovery, and increases the utilization rate of heat as much as possible on the premise of meeting the requirement of whitening.
In use, as shown in fig. 4, the difference from example 1 is that the first heat exchange medium (about 87 ℃) having passed through the first heat exchanger is not directly introduced into the steam boiler feed water, but the exhaust gas (about 40 ℃ and about 100% humidity) is heated by the fourth heat exchanger 7 to obtain an exhaust gas temperature of about 50 ℃ and a humidity of about 70%, while the temperature of the first heat exchange medium is lowered to about 75 ℃, and the first heat exchange medium (about 75 ℃) is subsequently introduced into the steam boiler feed water.
The first embodiment described above was compared for operational economy:
(1) basic principle of thermodynamics:
by the chemical equation: CH4+2O2 is CO2+2H2O, and it is known that 1mol of methane is combusted, and 2mol of oxygen is consumed, and 1mol of carbon dioxide and 2mol of water vapor are produced.
According to the current field real-time measurement of the oxygen content of the flue gas to be 0.3 percent and the mole number of oxygen in the common ambient air to be 20.95 percent, the volume ratio of the natural gas at the inlet of the boiler to the air is about 1: 11.5.
(2) Original design and this application new thermal behavior after reforming transform design contrast:
the original design air-out temperature is 55 ℃, the air-out temperature after the new transformation of the application can be lower than 50 ℃, and the specific air-out temperature is shown in the following table:
index (I) | Original design | The scheme of the application | Unit of |
Temperature of outlet air | 55 | 50 | ℃ |
Temperature of inlet air | 155 | 155 | ℃ |
Amount of condensate precipitated | 0.31 | 0.74 | Kg/s |
Sensible heat recovery | 1622 | 1703 | Kw |
Latent heat recovery | 792.6 | 1893 | Kw |
Total heat recovery | 2414.6 | 3596.2 | Kw |
Boiler energy efficiency | 99.29 | 101.54 | % |
As can be seen from the above table, the waste heat recovery system of the present application can recover 3596.2-2414.6 ═ 1181.6kw more than the waste heat recovery system in the original design ideal state, and the energy efficiency of the boiler after modification can reach 101.51% by bringing the newly added energy into the energy efficiency data of the original boiler.
(3) Performance comparison and investment cycle analysis before and after corresponding transformation of the application
At present, the air outlet temperature of the original equipment is 70 ℃, the air outlet temperature after the scheme of the application is transformed can be lower than 50 ℃, and the following concrete steps are as follows:
it can be seen from the above table that, according to the calculation of the current fuel utilization condition, the recovery and reconstruction investment cost can be realized within half a year through the fuel cost saved after the reconstruction in the state of 50% of the utilization rate of the boiler after the reconstruction.
(4) Analysis of overall waste heat recovery performance and economic benefit after transformation
The waste heat recovery pair at different inlet air temperatures after modification is as follows:
the utility model discloses a boiler system's embodiment: take gas boiler system as an example, the system includes boiler body, water softener, water tank, oxygen-eliminating device, steam-distributing cylinder, feed pump, oxygen pump, continuous blowdown flash tank, combustor, flue, pipeline and waste heat recovery system, and waste heat recovery system's specific structure is the same with the structure in the above-mentioned embodiment, no longer explains repeatedly.
The above description is only for the preferred embodiment of the present invention, and the present invention is not limited thereto, the protection scope of the present invention is defined by the claims, and all structural changes equivalent to the contents of the description and drawings of the present invention should be included in the protection scope of the present invention.
Claims (6)
1. A waste heat recovery system, comprising:
the first heat exchanger is arranged in the flue and is an air-water heat exchanger, a first internal pipeline is arranged in the first heat exchanger, and the first internal pipeline is provided with a first water inlet and a first water outlet; the first heat exchanger is made of common carbon steel;
the second heat exchanger is arranged in the flue and is positioned at the downstream of the first heat exchanger along the flow direction of the flue gas, the second heat exchanger is an air-water heat exchanger and is provided with a second internal pipeline, and the second internal pipeline is provided with a cooling water inlet and a cooling water outlet;
the third heat exchanger is a plate heat exchanger for water-water heat exchange, a hot end pipeline and a cold end pipeline which are mutually crossed and attached are arranged in the third heat exchanger, an inlet of the cold end pipeline is communicated with the cooling water outlet, and an outlet of the cold end pipeline is communicated with the first water inlet; the inlet of the hot end pipeline is used for being communicated with a steam pipeline of output steam of the boiler system;
the first heat exchange medium flows in from the cooling water inlet, sequentially flows through the second internal pipeline, the cold end pipeline and the first internal pipeline, and flows out from the first water outlet; the third heat exchanger is made of corrosion-resistant metal or nonmetal;
the temperature control module comprises a temperature detection sensor arranged at a position between an outlet of the cold end pipeline and the first water outlet, a regulating valve arranged on the pipeline in front of an inlet of the hot end pipeline and a controller in control connection with the temperature detection sensor and the regulating valve, wherein the regulating valve is controlled by feedback of the temperature detection module to control the temperature of the first heat exchange medium to be within a set temperature range in a mode of controlling the flow of steam entering the hot end pipeline, and the lowest temperature of the set temperature range is greater than the dew point temperature of the steam in the flue gas when the steam is condensed on the outer surface of the first heat exchanger.
2. A waste heat recovery system according to claim 1, further comprising a fourth heat exchanger for being arranged in the flue, downstream of the second heat exchanger in the flue gas flow direction for recuperating heat to the flue gas, the fourth heat exchanger being an air-water heat exchanger, the fourth heat exchanger having a fourth inner conduit with a fourth water inlet and a fourth water outlet, the first water outlet being in communication with the fourth water inlet, the fourth water outlet being in communication with a water inlet conduit of the boiler system.
3. A waste heat recovery system according to claim 1 or 2, characterized in that the cross section of the first internal pipe of the first heat exchanger is oval, and the length direction of the oval is arranged along the flow direction of the flue gas.
4. A waste heat recovery system according to claim 3 wherein the first heat exchanger is a finned tube heat exchanger.
5. A waste heat recovery system as claimed in claim 4, wherein the second heat exchanger is a light pipe heat exchanger.
6. A boiler system comprising a boiler body, a flue and a water inlet pipe connected to the boiler body, and further comprising a steam pipe for outputting steam to the outside, characterized by further comprising a waste heat recovery system as claimed in any one of claims 1 to 5.
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