CN212403812U - Integrated treatment device for membrane filtration concentrated solution of landfill leachate - Google Patents

Integrated treatment device for membrane filtration concentrated solution of landfill leachate Download PDF

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CN212403812U
CN212403812U CN202020823213.5U CN202020823213U CN212403812U CN 212403812 U CN212403812 U CN 212403812U CN 202020823213 U CN202020823213 U CN 202020823213U CN 212403812 U CN212403812 U CN 212403812U
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reactor
inner cylinder
ozone
landfill leachate
section
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陈善平
王声东
张瑞娜
宋立杰
邰俊
刘庄泉
曹瑞杰
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Shanghai Environmental Sanitation Engineering Design Institute Co ltd
Shanghai Institute for Design and Research on Environmental Engineering Co Ltd
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Shanghai Environmental Sanitation Engineering Design Institute Co ltd
Shanghai Institute for Design and Research on Environmental Engineering Co Ltd
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Abstract

The utility model relates to an integrated treatment device of landfill leachate membrane filtration concentrate, which comprises a dielectric barrier discharge plasma generation section positioned at the upper section of the device and a cooperative ozone pollutant reaction section positioned at the lower section of the device. The upper section of the device is provided with a hydrogen inlet, an insulating clapboard is inserted between the upper section and the lower section, and a plasma hydrogen inlet conduit is arranged. The lower section of the device is provided with an exhaust port, a water sample outlet, an inlet, and an ozone and oxygen inlet. Circulating water for cooling and grounding electrodes is injected between the inner cylinder and the outer cylinder of the reactor. The discharge electrode is inserted into the inner cylinder of the reactor. The microporous aeration head is arranged at the bottom of the inner cylinder of the reactor. The garbage membrane filtration concentrated solution enters the inner cylinder, the mixed gas of ozone and oxygen enters the inner cylinder through microbubble aeration, plasma hydrogen is generated through dielectric barrier discharge and is introduced below the liquid level of the garbage membrane filtration concentrated solution to react with oxygen to generate hydrogen peroxide in situ, the reinforced oxidation treatment of organic matters is realized, and the degradation capability is improved.

Description

Integrated treatment device for membrane filtration concentrated solution of landfill leachate
Technical Field
The utility model belongs to the technical field of the environmental protection engineering garbage leachate processing apparatus, concretely relates to garbage leachate's membrane filters plasma of dense liquid and integrative processing apparatus of ozone in coordination.
Background
At present, the annual clearing and transporting amount of domestic garbage in China reaches two to three hundred million tons, and one hundred million tons of domestic garbage are disposed by an incineration method. The garbage disposal byproduct, namely leachate, which has great harm to the environment is generated in the garbage stacking process. In order to reduce the potential risk of the discharge of the garbage percolate to the whole environment, China requires that matched in-situ percolate treatment equipment is built in an incineration plant or a landfill site so as to ensure that the discharge of the percolate reaches the standard for controlling the pollution of the incineration of the household garbage (GB 18485-2014) and the standard for controlling the pollutants of the landfill site of the household garbage (GB 16889-2008). Since landfill leachate contains high pollutants difficult to biodegrade, the corresponding pollution control requirements are difficult to achieve by adopting conventional biochemical treatment and chemical treatment technologies, and under the background, membrane treatment is widely applied as a physical treatment technology with low operation cost.
However, the membrane treatment can produce concentrated liquor which is 20-30% of the volume of the percolate, the concentrated liquor of the membrane filtration is rich in various pollutants in the percolate before the membrane filtration, the humus and the salt content of the concentrated liquor are high, and the further treatment difficulty is high. At present, most of membrane filtration concentrated solutions of landfill sites are treated by methods such as evaporation concentration and the like, most of membrane filtration concentrated solutions of incineration plants are sprayed back to an incinerator, the treatment cost is very high, and according to estimation in the industry, each ton of membrane filtration concentrated solutions to be treated at least needs to consume heat equivalent to 600 degrees of electricity. Therefore, how to reduce the cost of the membrane filtration concentrate of the landfill leachate becomes an industrial hotspot problem. The advanced oxidation method has attracted attention as a technique that can improve the biochemical property of refractory wastewater and create conditions for the concentrated solution to flow back to a front end biochemical system after being treated.
The ozone oxidation technology has strong oxidation capability, not only has good effect on organic matters and inorganic matters, but also has the functions of deodorization, disinfection, sterilization and the like, and is applied to the treatment of percolate to a certain degree as a green and friendly technology. Patent document CN206570116U discloses a treatment device for multistage catalytic ozonation for advanced treatment, in which ozone is catalyzed by a catalyst to improve the utilization efficiency of ozone, thereby further improving the degradation effect. Patent document CN201910554317.2 discloses a method for treating leachate with calcium peroxide in combination with ozone to improve the utilization efficiency of ozone. However, the above methods all need to introduce new reagents, and at the same time, 85% -90% of oxygen is mixed in the reaction device during the ozone reaction, which means that the problem of large oxygen consumption of the ozone system still cannot be solved.
Therefore, it is very important to construct a cooperative ozone integrated device which is mainly used for synchronously improving the utilization rate of oxygen and ozone in the field of landfill leachate treatment.
Disclosure of Invention
In order to solve the problem of low oxygen consumption and ozone utilization rate in the prior ozone technology, the utility model provides a plasma and ozone integrated treatment device for membrane filtration concentrated solution of garbage leachate, which has the basic principle that ozone is rapidly contacted with organic matters after entering from the bottom of a reactor, and the organic matters are directly or indirectly oxidized to realize the one-time utilization of ozone; the residual large amount of oxygen combines with active hydrogen in a plasma device at the upper section of the reactor to generate hydrogen peroxide in situ, and reacts with ozone to generate hydroxyl radicals, so that secondary utilization of the ozone is realized. The treatment device synchronously and efficiently improves the utilization rate of oxygen and ozone and the degradation capability of the oxygen and ozone to organic matters, and achieves a more ideal treatment effect.
The technical solution of the utility model is as follows:
an integrated treatment device for membrane filtration concentrated solution of landfill leachate, which consists of a dielectric barrier discharge plasma generation section positioned at the upper section of the device and a cooperative ozone pollutant reaction section positioned at the lower section of the device, and comprises a reactor inner cylinder, a reactor outer cylinder, a discharge electrode, a metal current lead-out wire and a microporous aeration head;
the reactor inner cylinder is a main body of the whole reactor and is a vertical cylindrical piece with a sealed bottom end, an insulating sealing cover is arranged at an opening at the upper end of the reactor inner cylinder, and a hydrogen inlet is arranged on the side wall of the upper section of the reactor inner cylinder of the device, which is higher than the reactor outer cylinder; a horizontal insulating partition plate is inserted between the upper section and the lower section of the device, and a plasma hydrogen inlet conduit is arranged in the center of the partition plate; the side wall of the upper end of the lower section of the device is provided with an air outlet and a water sample outlet, the side wall of the lower end of the lower section of the device is provided with a water sample inlet, and the bottom end of the lower section of the device is provided with an ozone and oxygen inlet;
the reactor outer cylinder is positioned at the upper section of the device, and circulating water for cooling and grounding electrodes is injected into the area between the reactor inner cylinder and the reactor outer cylinder from bottom to top;
the discharge electrode is inserted into the inner cylinder of the reactor from the center of the insulating sealing cover, and the partial electrode of the discharge electrode extending out of the insulating sealing cover upwards is connected with the high voltage of the alternating-current step-up transformer;
the other end of the metal current lead-out wire is connected with a ground wire outside the outer cylinder of the reactor;
the microporous aeration head is arranged at the bottom of the reactor inner barrel and is connected with an external ozone generator through an ozone inlet pipe.
The micropore aeration head is an umbrella-shaped or flat plate aeration head, the aperture of the micropore aeration head is 0.22-0.45 mu m, and the size of the generated micro-bubbles is less than 50 mu m.
The plasma hydrogen inlet conduit is positioned between 1/4 and 1/3 at the upper end of the lower section of the reactor inner cylinder, and the lower end of the plasma hydrogen inlet conduit is positioned below the liquid level of the membrane filtration concentrated solution.
The hydrogen inlet is provided with an air inlet pipe.
The exhaust port is provided with an exhaust pipe, and the exhaust pipe is located below the horizontal insulating partition plate.
And a condensed water inlet and a condensed water outlet are formed in the side wall of the outer barrel of the reactor.
And a sealing material is arranged at the joint of the insulating sealing cover and the upper end of the inner cylinder of the reactor.
The utility model discloses mainly be in order to solve ozone generator at the in-process that produces ozone, along with a large amount of oxygen get into reaction unit jointly, however oxygen is not by make full use of's problem. For solving the problem, the utility model discloses a processing apparatus adopts plasma generating device and pollutant reaction unit two sections, and a large amount of oxygen generate oxygen active material hydrogen peroxide with active hydrogen reaction in plasma generating device section, and hydrogen peroxide can further catalyze the hydroxyl free radical that ozone generation oxidation performance is stronger, realizes improving oxygen and ozone utilization ratio in step, realizes the high-efficient degradation efficiency of processing system to the pollutant.
The utility model discloses a plasma of landfill leachate membrane filtration concentrate cooperates integrative processing apparatus of ozone to take place the section and be located the ozone pollutant reaction section constitution of hypomere by the dielectric barrier discharge's that is located the upper segment plasma, including spare parts such as reactor inner tube, reactor urceolus, discharge electrode, metal current conductance line and microbubble aeration head. The garbage membrane filtration concentrated solution enters the lower-section inner cylinder of the reactor through the side wall at the bottom end, the mixed gas of ozone and oxygen enters the lower-section inner cylinder of the reactor from the bottom through microbubble aeration, plasma hydrogen is generated through dielectric barrier discharge at the upper section of the reactor and is introduced below the liquid level of the garbage membrane filtration concentrated solution to react with oxygen to generate hydrogen peroxide in situ, and the enhanced oxidation treatment of organic matters is realized. The utility model provides high ozone and surplus oxygen's utilization efficiency, ozone is reinforceed to the hydrogen peroxide that the normal position produced, has increased OH output, has effectively improved the degradation ability to difficult degradation organic matter in the concentrated liquid is strained to the rubbish membrane, is the environmental protection technology who has good development prospect.
Compared with the prior art, the utility model discloses following beneficial effect has been obtained: the original empty oxygen is utilized in a plasma mode, so that the oxygen utilization rate and the ozone utilization rate are both improved by more than 20%, the removal rate of the membrane filtration concentrated solution of the landfill leachate is improved by more than 25% compared with that of a single ozone treatment system, and the membrane filtration concentrated solution has a higher removal effect on humus substances; meanwhile, the reaction treatment device has the characteristics of small occupied area, high operation efficiency and the like.
Drawings
Fig. 1 is the structure schematic diagram of the integrated treatment device for membrane filtration concentrated solution of landfill leachate of the utility model.
Reference numerals:
1 is an ozone and oxygen inlet, 2 is a microporous aerator, 3 is a hydrogen inlet, 4 is an exhaust port, 5 is a reactor outer cylinder, 6 is an inner cylinder medium or a discharge medium, 7 is a reactor inner cylinder, 8 is a condensed water inlet, 9 is a condensed water outlet, 10 is an insulating seal cover, 11 is a discharge electrode, 12 is a sealing material, 13 is a metal current leading-out wire, 14 is a plasma hydrogen inlet conduit, 15 is a wastewater inlet, 16 is a wastewater outlet, 17 is a membrane filtration concentrated solution, and 18 is a horizontal insulating partition plate.
Detailed Description
The present invention will be described in detail with reference to the accompanying drawings and examples.
Referring to fig. 1, the utility model provides a plasma of landfill leachate membrane filtration concentrate cooperates with integrative processing apparatus of ozone, and it comprises the plasma generation section that is located the dielectric barrier discharge of device upper segment and the cooperation ozone pollutant reaction section that is located the device hypomere, is equipped with spare parts such as reactor inner tube 7, reactor urceolus 5, discharge electrode 11, metal current derivation line 13 and micropore aeration head 2.
The reactor inner cylinder 7 is the main body of the whole reactor and is a vertical cylinder with a sealed bottom end, and an insulating sealing cover 10 is arranged at the opening of the upper end of the reactor inner cylinder. The joint of the insulating cover 10 and the upper end of the reactor inner cylinder 7 is provided with a sealing material 12. The side wall of the upper section of the device, which is higher than the part of the inner cylinder 7 of the reactor than the outer cylinder 5 of the reactor, is provided with a hydrogen inlet 3. The hydrogen inlet 3 is provided with an air inlet pipe, and the volume concentration of the hydrogen input by the air inlet pipe is less than 4.1 percent. The hydrogen and ozone/oxygen ratios are limited to the explosive limits of hydrogen.
A horizontal insulating baffle 18 is interposed between the upper and lower sections of the apparatus and a plasma hydrogen inlet conduit 14 is provided centrally in the baffle. The position of the plasma hydrogen inlet conduit 14 is positioned between the upper ends 1/4-1/3 of the lower section of the reactor inner cylinder 7, and the lower end of the plasma hydrogen inlet conduit 14 is positioned below the liquid level of the membrane filtration concentrated solution 17.
The side wall of the upper end of the lower section of the device is provided with an air outlet 4 and a water sample outlet. The exhaust port 4 is provided with an exhaust pipe which is located below the horizontal insulating partition 18. The exhaust pipe is made of an insulating material. The side wall of the lower end of the lower section of the device is provided with a water sample inlet. The water sample inlet is provided with a waste water inlet 15, and the water sample outlet is provided with a waste water outlet 16. The bottom end of the lower section of the device is provided with an ozone and oxygen inlet 1.
The reactor outer cylinder 5 is positioned at the upper section of the device, and circulating water for cooling and grounding electrodes is injected into the area between the reactor inner cylinder 7 and the reactor outer cylinder 5 from bottom to top. The side wall of the outer cylinder 5 of the reactor is provided with a condensed water inlet 8 and a condensed water outlet 9. The reactor inner vessel 7 can be provided with an inner vessel medium or discharge medium 6. The height-diameter ratio of the inner barrel 7 of the reactor is between 8 and 50. The ratio of the upper section to the lower section of the inner barrel 7 of the reactor is 1/8-1/2. The diameter ratio of the inner reactor cylinder 7 to the outer reactor cylinder 5 is 1/2-1/5.
The discharge electrode 11 is inserted into the reactor inner tube 7 from the center of the insulating cover 10. The partial electrode of the discharge electrode 11 extending upwards out of the insulation cover 10 is connected with the high voltage of the alternating current step-up transformer. The discharge electrode 11 is a metal wire having a diameter to the reactor inner vessel 7 ratio of 1/30-1/15. The discharge electrode 11 is made of copper, tungsten, stainless steel containing nickel and titanium, or an alloy containing a trace amount of rare element oxide, wherein the rare element includes scandium, yttrium, and lanthanoid.
The part of the metal current lead-out wire 13 arranged in the area between the reactor inner cylinder 7 and the reactor outer cylinder 5 is contacted with the circulating water, and the other end of the metal current lead-out wire 13 is connected with the ground wire outside the reactor outer cylinder 5. The ratio of the diameter of the metal current lead-out line 13 to the diameter of the discharge electrode 11 is between 1 and 10. The metal current lead-out wire 13 is made of copper, tungsten, stainless steel containing nickel and titanium or alloy added with trace rare element oxides, wherein the rare elements comprise scandium, yttrium and lanthanide.
The microporous aeration head 2 is arranged at the bottom of the reactor inner cylinder 7, and the microporous aeration head 2 is connected with an external ozone generator through an ozone inlet pipe. The microporous aeration head 2 is an umbrella-shaped or flat plate aeration head, the aperture of the microporous aeration head 2 is 0.22-0.45 μm, and the size of the generated micro-bubbles is less than 50 μm. The material of the microporous aeration head 2 is titanium.
The inner reactor cylinder 7 and the outer reactor cylinder 5 are made of one or more mixed insulating materials of quartz, glass, ceramics and corundum. The plasma hydrogen inlet conduit 14 is made of silica gel, polyvinyl chloride, polytetrafluoroethylene or perfluoroalkoxy resin.
The utility model discloses a plasma of landfill leachate membrane filtration concentrate is in coordination with integrative processing apparatus of ozone has adopted following mounting means and working process in practical application:
as shown in figure 1, the reactor inner cylinder 7 is the main body of the whole reactor, and is a vertical cylindrical piece with a sealed bottom end, the opening of the upper end is sealed by an insulating sealing cover 10 and sealed by a sealing material 12, and a hydrogen inlet 3 is arranged on the side wall of the inner cylinder at the upper section of the device, which is higher than the outer cylinder part. A horizontal insulating baffle 18 is inserted between the upper and lower sections of the device, and a plasma hydrogen inlet conduit 14 is provided in the center of the baffle. The upper end of the lower section of the device is provided with an exhaust port 4 and a waste water outlet 16, the lower end is provided with a waste water inlet 15, and the bottom end is provided with an ozone and oxygen inlet 1. The outer reactor barrel 5 is positioned at the upper section of the device. Circulating water used as a cooling and grounding electrode is injected between the inner cylinder and the outer cylinder of the reactor from bottom to top.
The discharge electrode 11 is a metal wire, inserted into the reactor inner cylinder 7 from the center of the insulating cover 10, and the part extending out of the insulating cover 10 is connected with the high voltage of the AC step-up transformer. One end of the metal current lead-out wire 13 is contacted with the circulating water between the inner and outer cylinders of the reactor, and the other end is connected with the ground wire outside the outer cylinder 5 of the reactor. The microporous aeration head 2 is arranged at the bottom of the reactor inner cylinder 7 and is connected with an external ozone generator through an ozone inlet pipe of the ozone and oxygen inlet 1.
During operation, the garbage leachate membrane filtration concentrated solution 17 enters the lower section of the reactor inner cylinder 7 of the device through a pump through a wastewater inlet 15 positioned on the side wall of the bottom end of the device, and ozone and oxygen mixed gas generated by an ozone generator forms micro-bubbles through a microporous aeration head 2 and enters the inner section of the lower section of the reactor inner cylinder 7 of the device through a conduit of an ozone and oxygen inlet 1 at the bottom of the device. Plasma hydrogen is generated by dielectric barrier discharge at the upper section of the reactor, and is introduced below the liquid level of the landfill leachate membrane filtration concentrated solution 17 through the plasma hydrogen inlet conduit 14 to react with oxygen to generate hydrogen peroxide in situ. The microbubble ozone and the in-situ generated hydrogen peroxide strengthen the contact reaction of the ozone section and the landfill leachate membrane concentrated solution, fully utilize the residual oxygen, improve the conversion efficiency of the ozone and generate more active free radicals. The membrane filtration concentrated solution of the treated landfill leachate is the concentrated solution intercepted by membranes such as nanofiltration, reverse osmosis and the like after biochemical treatment of the leachate, and COD is 3000-20000 mg/L.
The following provides the utility model discloses a plasma of landfill leachate membrane filtration concentrate cooperates with the embodiment of integrative processing apparatus of ozone in concrete processing work.
Example 1:
the treatment object is leachate nanofiltration membrane liquid (COD is 3000 mg/L) of a domestic garbage landfill, the treatment is carried out by adopting a process device shown in figure 1, and the main process parameters are as follows: the treated water amount is 3L, the inner and outer cylinders of the reactor are made of quartz glass, the height-diameter ratio of the inner sleeve is 8, the upper-lower section ratio of the inner cylinder is 1/3, and the diameter ratio of the inner and outer cylinders is 1/2. The adopted discharge electrode and the metal current lead-out wire are all copper wires with the diameters of 0.5cm and 2cm respectively, and the discharge power is 10W. An umbrella-shaped aeration head made of titanium is adopted, and the aperture is 0.22-0.45 mu m. The volume concentration of hydrogen is 2%, the concentration of ozone is 80mg/L, the flow is 1L/min, the reaction treatment is carried out for 120min, the utilization rate of oxygen is improved by 21.5%, the utilization rate of ozone is improved by 20.3%, and the final removal rate of COD can reach 78.8%.
Example 2:
the treatment object is leachate nanofiltration membrane liquid (COD is 10000 mg/L) of a domestic garbage landfill, the treatment is carried out by adopting a process device shown in figure 1, and the main process parameters are as follows: the treated water amount is 3L, the inner and outer cylinders of the reactor are made of quartz glass, the height-diameter ratio of the inner sleeve is 20, the ratio of the upper section to the lower section of the inner cylinder is 1/4, and the ratio of the diameter of the inner cylinder to the outer cylinder is 1/2. The adopted discharge electrode and the metal current lead-out wire are all copper wires with the diameters of 0.5cm and 2cm respectively, and the discharge power is 10W. An umbrella-shaped aeration head made of titanium is adopted, and the aperture is 0.22-0.45 mu m. The volume concentration of hydrogen is 2%, the concentration of ozone is 80mg/L, the flow is 1L/min, the reaction treatment is carried out for 120min, the utilization rate of oxygen is improved by 19.8%, the utilization rate of ozone is improved by 18.2%, and the final removal rate of COD can reach 75.4%.
Example 3:
the treatment object is a domestic garbage landfill leachate nanofiltration membrane liquid (COD is 20000 mg/L), the treatment is carried out by adopting the process device shown in figure 1, and the main process parameters are as follows: the treated water amount is 3L, the inner and outer cylinders of the reactor are made of quartz glass, the height-diameter ratio of the inner sleeve is 50, the ratio of the upper section to the lower section of the inner cylinder is 1/4, and the ratio of the diameter of the inner cylinder to the outer cylinder is 1/2. The adopted discharge electrode and the metal current lead-out wire are all copper wires with the diameters of 0.5cm and 2cm respectively, and the discharge power is 10W. An umbrella-shaped aeration head made of titanium is adopted, and the aperture is 0.22-0.45 mu m. The volume concentration of hydrogen is 2%, the concentration of ozone is 80mg/L, the flow is 1L/min, the reaction treatment is carried out for 120min, the utilization rate of oxygen is improved by 18.8%, the utilization rate of ozone is improved by 16.4%, and the final removal rate of COD can reach 65.8%.
To sum up, the utility model discloses an integrated processing apparatus of concentrated liquid is strained to landfill leachate membrane adopts plasma generating device and pollutant reaction unit two sections, and a large amount of oxygen generate oxygen active material hydrogen peroxide with active hydrogen reaction in plasma generating device section, and hydrogen peroxide can further catalyze ozone and generate the stronger hydroxyl radical of oxidation property, realizes improving oxygen and ozone utilization ratio in step, has effectively improved the degradation ability to difficult degradation organic matter in the concentrated liquid is strained to the landfill leachate membrane, and it is little to have area simultaneously, characteristics such as operating efficiency height.
Of course, those skilled in the art should recognize that the above-described embodiments are merely illustrative of the present invention and are not intended to be limiting, and that changes, modifications, etc. to the above-described embodiments are intended to fall within the scope of the appended claims, provided they fall within the true spirit of the present invention.

Claims (7)

1. The utility model provides an integrated processing apparatus of landfill leachate membrane filtration concentrate which characterized in that: the device consists of a dielectric barrier discharge plasma generation section positioned on the upper section of the device and a cooperative ozone pollutant reaction section positioned on the lower section of the device, and comprises a reactor inner cylinder (7), a reactor outer cylinder (5), a discharge electrode (11), a metal current lead-out wire (13) and a microporous aeration head (2);
the reactor inner cylinder (7) is a main body of the whole reactor and is a vertical cylindrical piece with a sealed bottom end, an insulating sealing cover (10) is arranged at an opening at the upper end of the reactor inner cylinder, and a hydrogen inlet (3) is arranged on the side wall of the part of the reactor inner cylinder (7) at the upper section of the device, which is higher than the reactor outer cylinder (5); a horizontal insulating partition plate (18) is inserted between the upper section and the lower section of the device, and a plasma hydrogen inlet conduit (14) is arranged in the center of the partition plate; the side wall of the upper end of the lower section of the device is provided with an exhaust port (4) and a water sample outlet, the side wall of the lower end of the lower section of the device is provided with a water sample inlet, and the bottom end of the lower section of the device is provided with an ozone and oxygen inlet (1);
the reactor outer cylinder (5) is positioned at the upper section of the device, and circulating water for cooling and grounding electrodes is injected into a region between the reactor inner cylinder (7) and the reactor outer cylinder (5) from bottom to top;
the discharge electrode (11) is inserted into the reactor inner cylinder (7) from the center of the insulating sealing cover (10), and the partial electrode of the discharge electrode (11) which upwards extends out of the insulating sealing cover (10) is connected with the high voltage of the alternating current step-up transformer;
the metal current lead-out wire (13) is arranged in a part of a lead-out wire in the area between the reactor inner cylinder (7) and the reactor outer cylinder (5) and is contacted with circulating water, and the other end of the metal current lead-out wire (13) is connected with a ground wire outside the reactor outer cylinder (5);
the microporous aeration head (2) is arranged at the bottom of the reactor inner cylinder (7), and the microporous aeration head (2) is connected with an external ozone generator through an ozone inlet pipe.
2. The integrated treatment device of the landfill leachate membrane concentrate of claim 1, wherein: the microporous aeration head (2) is an umbrella-shaped or flat plate aeration head, the aperture of the microporous aeration head (2) is 0.22-0.45 mu m, and the size of the generated micro-bubbles is less than 50 mu m.
3. The integrated treatment device of the landfill leachate membrane concentrate of claim 1, wherein: the position of the plasma hydrogen inlet conduit (14) is positioned between the upper ends 1/4-1/3 of the lower section of the reactor inner cylinder (7), and the lower end of the plasma hydrogen inlet conduit (14) is positioned below the liquid level of the membrane filtration concentrated solution (17).
4. The integrated treatment device of the landfill leachate membrane concentrate of claim 1, wherein: the hydrogen inlet (3) is provided with an air inlet pipe.
5. The integrated treatment device of the landfill leachate membrane concentrate of claim 1, wherein: the exhaust port (4) is provided with an exhaust pipe which is positioned below the horizontal insulating partition plate (18).
6. The integrated treatment device of the landfill leachate membrane concentrate of claim 1, wherein: and a condensed water inlet (8) and a condensed water outlet (9) are formed in the side wall of the outer reactor barrel (5).
7. The integrated treatment device of the landfill leachate membrane concentrate of claim 1, wherein: and a sealing material (12) is arranged at the joint of the insulating sealing cover (10) and the upper end of the reactor inner cylinder (7).
CN202020823213.5U 2020-05-18 2020-05-18 Integrated treatment device for membrane filtration concentrated solution of landfill leachate Active CN212403812U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114684994A (en) * 2022-04-26 2022-07-01 江苏大学 RO (reverse osmosis) membrane module and low-temperature plasma organic wastewater degradation system and method
CN115520936A (en) * 2022-11-25 2022-12-27 福建省粤华环保科技有限公司 Advanced treatment process and equipment for landfill leachate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114684994A (en) * 2022-04-26 2022-07-01 江苏大学 RO (reverse osmosis) membrane module and low-temperature plasma organic wastewater degradation system and method
CN115520936A (en) * 2022-11-25 2022-12-27 福建省粤华环保科技有限公司 Advanced treatment process and equipment for landfill leachate

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