CN210560795U - Hydrogen generating device - Google Patents

Hydrogen generating device Download PDF

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Publication number
CN210560795U
CN210560795U CN201920905697.5U CN201920905697U CN210560795U CN 210560795 U CN210560795 U CN 210560795U CN 201920905697 U CN201920905697 U CN 201920905697U CN 210560795 U CN210560795 U CN 210560795U
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China
Prior art keywords
plate
water
water flow
titanium fiber
electrolytic
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CN201920905697.5U
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Chinese (zh)
Inventor
李晓浩
宋云超
王海
李晓飞
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Shenzhen Facai Technology Co ltd
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Shenzhen Facai Technology Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

The embodiment of the utility model discloses a hydrogen generating device, including water tank and electrolysis trough, the electrolysis trough includes first fixed plate, first insulating plate, positive pole electrolysis board, first titanium fibreboard, ionic membrane, second titanium fibreboard, negative pole electrolysis board, second insulating board and the second fixed plate that sets gradually, the one side that positive pole electrolysis board faced negative pole electrolysis board is equipped with the rivers groove, be equipped with the gib block of vertical trend in the rivers groove, the lower part and the water inlet intercommunication of rivers groove, upper portion and delivery port intercommunication, the upper surface of gib block is equal to the border of rivers groove; the cathode electrolytic plate is provided with an air outlet which is communicated with the first titanium fiber plate; the water tank is connected with the water inlet and the water outlet through a conduit, and the connecting position of the conduit connected with the water inlet and the water tank is lower than the connecting position of the conduit connected with the water outlet and the water tank. When the electrolytic cell works, the cathode electrolytic plate is connected with the negative electrode of the direct current power supply, and the anode electrolytic plate is connected with the positive electrode of the direct current power supply. Adopt the utility model discloses, can generate hydrogen reliable and stable, small, compact structure.

Description

Hydrogen generating device
Technical Field
The utility model relates to a civilian hydrogen preparation field especially relates to a hydrogen generates device.
Background
The existing electrolytic hydrogen production device is mainly characterized in that an electrolyzer is immersed in water, hydrogen and oxygen are generated in an electrolytic mode, and then the hydrogen is collected. The structure occupies a large space and is inconvenient to carry. When hydrogen and oxygen are generated, the gases can accumulate on the electrolytic sheets of the electrolyzer, affecting the contact area of the electrolytic sheets with water and thus the electrolysis efficiency.
SUMMERY OF THE UTILITY MODEL
The embodiment of the utility model provides a technical problem that will solve lies in, provides a hydrogen generating device, can generate hydrogen reliable and stable, and is small, compact structure.
In order to solve the technical problem, an embodiment of the present invention provides a hydrogen generation device, including a water tank and an electrolytic cell, where the electrolytic cell includes a first fixing plate, a first insulating plate, an anode electrolytic plate, a first titanium fiber plate, an ionic membrane, a second titanium fiber plate, a cathode electrolytic plate, a second insulating plate and a second fixing plate, which are sequentially arranged, one surface of the anode electrolytic plate facing the cathode electrolytic plate is provided with a water flow groove, a guide strip with a vertical trend is arranged in the water flow groove, a lower portion of the water flow groove is communicated with a water inlet, an upper portion of the water flow groove is communicated with a water outlet, and an upper surface of the guide strip is level with an edge of the water flow groove; the cathode electrolytic plate is provided with an air outlet which is communicated with the first titanium fiber plate; the water tank is connected with the water inlet and the water outlet through a conduit, and the connecting position of the conduit connected with the water inlet and the water tank is lower than the connecting position of the conduit connected with the water outlet and the water tank. When the electrolytic cell works, the cathode electrolytic plate is connected with the negative electrode of the direct current power supply, and the anode electrolytic plate is connected with the positive electrode of the direct current power supply.
As an improvement of the above scheme, the four guide strips are transversely arranged at a predetermined distance to form a water flow supporting unit, two groups of water flow supporting units are transversely arranged in the water flow groove, and the distance between the two groups of water flow supporting units is greater than the distance between adjacent guide strips in a single water flow supporting unit.
As an improvement of the above scheme, three groups of water flow supporting units are longitudinally arranged in the water flow groove, and the three groups of water flow supporting units are arranged according to a preset interval.
As an improvement of the above scheme, the peripheries of the first titanium fiber plate, the ionic membrane and the second titanium fiber plate are provided with silica gel sealing frames, when the first fixing plate and the second fixing plate apply pressure to the first conducting plate and the second conducting plate, the first conducting plate and the second conducting plate compress the silica gel sealing frames tightly, and a sealing space is formed between the first conducting plate and the second conducting plate; the first conducting plate is connected with the first titanium fiber plate in an abutting mode, the second conducting plate is connected with the second titanium fiber plate in an abutting mode, and the first titanium fiber plate and the second titanium fiber plate evenly clamp the ionic membrane.
As an improvement of the above scheme, the ionic membrane extends out from the peripheral edges of the first titanium fiber plate and the second titanium fiber plate and is clamped by the silica gel sealing frame; a sealed water flow containing cavity is formed among the anode electrolytic plate, the silica gel sealing frame and the ionic membrane, and a sealed hydrogen containing cavity is formed among the cathode electrolytic plate, the silica gel sealing frame and the ionic membrane.
As an improvement of the scheme, a cover is arranged at the top of the water tank and is provided with a water-stopping ventilation cavity; and a lower vent hole and an upper vent hole are arranged in the water stopping vent cavity, a plug is arranged between the lower vent hole and the upper vent hole, and the plug is connected with the spring.
As an improvement of the scheme, an air guide column is arranged below the upper vent hole; in an initial state, a gap is reserved between the plug and the air guide column, a conical part is arranged on the lower end face of the plug, and the conical part extends into the lower air vent.
As an improvement of the scheme, the top of the cover is provided with a handheld part higher than the plane of the cover, and the top surface of the handheld part is in a ridge shape; the upper vent hole is arranged on the top surface of the handheld part.
Implement the embodiment of the utility model provides a, following beneficial effect has:
the utility model discloses a border at first fixed plate and second fixed plate sets up the bolt in bank, applys even pressure to the multiple panel between first fixed plate and the second fixed plate. Under the pressure, a sealing chamber is formed between the anode electrolytic plate and the ionic membrane and between the cathode electrolytic plate and the ionic membrane through a rubber sealing frame; arranging a first titanium fiber board and a second titanium fiber board with smooth surfaces in the sealed chamber, and ensuring that the surfaces of the ionic membranes are continuously covered by water and the generated gas can be discharged from the first titanium fiber board and the second titanium fiber board in time by utilizing the hydrophobicity and the air permeability of the first titanium fiber board and the second titanium fiber board; by utilizing the conductivity of the first titanium fiber board and the second titanium fiber board, a uniform electric field is formed on two sides of the ionic membrane, and the stable proceeding of electrolytic reaction is ensured; by utilizing the physical characteristics of large strength, compact inner hole and smooth and fine surface of the first titanium fiber plate and the second titanium fiber plate, all parts of the ionic membrane are clamped tightly, the ionic membrane is prevented from repeatedly expanding and contracting due to the periodic force in the electrolytic process, and the service life of the ionic membrane is prolonged.
The main water flow channel is formed between the two groups of water flow supporting units of the utility model, which can rapidly supplement water for the first titanium fiber board; an auxiliary water flow channel is formed between the adjacent guide strips, generated oxygen bubbles are guided to be collected to the water outlet to be discharged, and the generated oxygen bubbles are prevented from being gathered on the water flow groove too fast to become large bubbles to block the flow of water flow. The small bubbles in the auxiliary water flow channel move upwards, and meanwhile, the water flow is provided with power flowing upwards, so that the water flow can enter from the water inlet and flow out from the water outlet spontaneously only by directly communicating the water inlet with the water outlet and the water tank without arranging active power devices such as a water pump.
Drawings
FIG. 1 is a schematic view of a hydrogen generating apparatus according to the present invention;
FIG. 2 is a schematic view of an assembled state of an electrolyzer of a hydrogen generating apparatus of the present invention;
FIG. 3 is an exploded view of an electrolyzer for a hydrogen generating apparatus of the present invention;
FIG. 4 is a schematic view of an anode electrolytic plate of a hydrogen generating apparatus according to the present invention;
fig. 5 is a schematic structural diagram of a cover of a hydrogen generating apparatus according to the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention clearer, the present invention will be described in further detail with reference to the accompanying drawings. Only this statement, the utility model discloses the upper and lower, left and right, preceding, back, inside and outside etc. position words that appear or will appear in the text only use the utility model discloses an attached drawing is the benchmark, and it is not right the utility model discloses a concrete restriction.
As shown in fig. 1-5, an embodiment of the present invention provides a hydrogen generation device, including a water tank 1 and an electrolytic cell 2, the electrolytic cell 2 includes a first fixing plate 21, a first insulating plate 22, an anode electrolytic plate 23, a first titanium fiber plate 24, an ionic membrane 25, a second titanium fiber plate 26, a cathode electrolytic plate 27, a second insulating plate 28, and a second fixing plate 29, which are sequentially disposed, one side of the anode electrolytic plate 23 facing the cathode electrolytic plate 27 is provided with a water flow groove 231, a vertically-oriented guide strip 232 is disposed in the water flow groove 231, a lower portion of the water flow groove 231 is communicated with a water inlet 233, an upper portion of the water flow groove is communicated with a water outlet 234, and an upper surface of the guide strip 232 is level with an edge of the water flow groove 231; the cathode electrolytic plate 27 is provided with an air outlet hole 271, and the air outlet hole 271 is communicated with the first honeycomb aluminum plate 24; the first fixing plate 21 and the second fixing plate 29 may be made of aluminum alloy, the first insulating plate 22 and the second insulating plate 28 may be silicon rubber plates, and the anode electrolytic plate 23 is made of TA1 titanium. The cathode electrolyte plate 27 may be a general conductive metal plate, and the ion membrane 25 may be an N117 surface-coated or plated noble metal catalyst, such as a platinum catalyst. The water tank 1 is connected with the water inlet 233 and the water outlet 234 through a conduit, and the connecting position of the conduit connected with the water inlet 233 and the water tank 1 is lower than the connecting position of the conduit connected with the water outlet 234 and the water tank 1. In operation, the cathode plate 27 is connected to the negative pole of the DC power source, and the anode plate 23 is connected to the positive pole of the DC power source. The cathode electrolytic plate 27 transfers the electric field to the second titanium fiber plate 26, the anode electrolytic plate 23 transfers the electric field to the first titanium fiber plate 24, so that a potential difference is formed between two sides of the ionic membrane 25, hydrogen ions and cations in water move directionally under the action of the potential difference, hydrogen is generated on one side of the ionic membrane 25, oxygen is generated on the other side of the ionic membrane, the generated hydrogen is transmitted back to the cathode electrolytic plate 27 through the second honeycomb aluminum plate 26, and the generated oxygen is transmitted back to the anode electrolytic plate 23 through the first titanium fiber plate 24.
The utility model discloses a set up the bolt 3 in bank at the border of first fixed plate 21 and second fixed plate 29, exert even pressure to the multiple panel between first fixed plate 21 and the second fixed plate 29. Under the pressure, a sealed chamber is formed between the anode electrolytic plate 23 and the ionic membrane 25 and between the cathode electrolytic plate 27 and the ionic membrane 25 through the silica gel sealing frame 20; arranging a first titanium fiber plate 24 and a second titanium fiber plate 26 with flat surfaces in the sealed chamber, and ensuring that the surface of the ionic membrane 25 is continuously covered by water and the generated gas can be timely discharged from the first honeycomb aluminum plate 24 and the second honeycomb aluminum plate 26 by utilizing the hydrophobicity and the air permeability of the first titanium fiber plate 24 and the second titanium fiber plate 26; by utilizing the conductivity of the first titanium fiber plate 24 and the second titanium fiber plate 26, a uniform electric field is formed on two sides of the ionic membrane 25, and the stable proceeding of the electrolytic reaction is ensured; by utilizing the physical characteristics of the first titanium fiber plate 24 and the second titanium fiber plate 26, such as high strength, compact inner hole and smooth and flat surface, each part of the ionic membrane 25 is clamped, so that the ionic membrane 25 is prevented from repeatedly expanding and contracting due to the periodic force in the electrolytic process, and the service life of the ionic membrane 25 is prolonged.
At the anode reaction end, it is ensured that the water and the ionic membrane 25 are in full contact, and the generated oxygen can be discharged in time. For this, in the present embodiment, four guide bars 232 are transversely arranged at a predetermined distance to form a water flow supporting unit a, and two groups of water flow supporting units a are transversely arranged in the water flow groove 231, and the distance between the two groups of water flow supporting units a is greater than the distance between adjacent guide bars 232 in a single water flow supporting unit a. A main water flow channel 233 is formed between the two groups of water flow supporting units A and is used for rapidly supplementing water for the first titanium fiber plate 24; a secondary water flow channel 234 is formed between the adjacent guide strips 232 to guide the generated oxygen bubbles to be collected to the water outlet 234 to be discharged, so that the generated oxygen bubbles are prevented from being rapidly gathered on the water flow groove 231 to become large bubbles to block the flow of water flow. The small bubbles in the auxiliary water flow channel 234 move upward and simultaneously bring upward flowing power to the water flow, so that the water flow can spontaneously enter from the water inlet 233 and flow out from the water outlet 234 without arranging active power devices such as a water pump and the like by only directly communicating the water inlet 233 and the water outlet 234 with the water tank 1.
Preferably, three groups of water flow supporting units a are longitudinally arranged in the water flow groove 231, and the three groups of water flow supporting units a are arranged at a predetermined interval. Between the water flow supporting units a arranged in the longitudinal direction, the water flow and the air bubbles can move in the lateral direction, preventing the water flow from failing to flow in the entire longitudinal area due to the blockage of one of the sub-water flow passages 234 or preventing the abnormal increase of the gas pressure.
As described above, in order to make the electrolysis reaction of water in the first titanium fiber sheet 24, the ionic membrane 25 and the second titanium fiber sheet 26 rapid and stable, it is necessary to ensure that the first titanium fiber sheet 24 and the second titanium fiber sheet 26 are uniformly forced against the surface of the ionic membrane 25 and provide a watertight and airtight environment for them. For this purpose, the peripheries of the first titanium fiber plate 24, the ionic membrane 25 and the second titanium fiber plate 26 are provided with a silica gel sealing frame 20, when the first fixing plate 21 and the second fixing plate 29 apply pressure to the anode electrolytic plate 23 and the cathode electrolytic plate 27, the anode electrolytic plate 23 and the cathode electrolytic plate 27 press the silica gel sealing frame 20 tightly, and a sealing space is formed between the anode electrolytic plate 23 and the cathode electrolytic plate 27; the anode electrolytic plate 23 abuts against the first titanium fiber plate 24, the cathode electrolytic plate 27 abuts against the second titanium fiber plate 26, and the first titanium fiber plate 24 and the second titanium fiber plate 26 uniformly clamp the ionic membrane 25. The ionic membrane 25 extends from the peripheral edges of the first titanium fiber plate 24 and the second titanium fiber plate 26 and is clamped by the silica gel sealing frame 20; a sealed water flow cavity is formed among the anode electrolytic plate 23, the rubber sealing frame 20 and the ionic membrane 25, and a sealed hydrogen cavity is formed among the cathode electrolytic plate 27, the silica gel sealing frame 20 and the ionic membrane 25. Through the structure, the clinging degree of the first titanium fiber plate 24, the ionic membrane 25 and the second titanium fiber plate 26 is not influenced by the assembling precision, the peripheral sealing is completed by the elastic silica gel sealing frame 20, the requirement on the tolerance precision of each element is reduced, and the assembling is facilitated.
The oxygen generated by the electrolyzer re-enters the water tank 1 with the water outlet 234, and therefore the water tank 1 must have a venting function. In addition, in order to improve portability of the present apparatus, the water tank 1 should be able to prevent water from being poured out from the back while exhausting air. For this purpose, a cover 11 is arranged on the top of the water tank 1, and the cover 11 is provided with a water-stop ventilation cavity 111; a lower vent hole 112 and an upper vent hole 113 are arranged in the water-stopping vent cavity 111, a plug 114 is arranged between the lower vent hole 112 and the upper vent hole 113, and the plug 114 is connected with a spring 115. Specifically, an air guide column 116 is arranged below the upper vent hole 113; in an initial state, a gap is left between the plug 114 and the air guide column 116, a tapered portion 117 is arranged on the lower end face of the plug 114, and the tapered portion 117 extends into the lower vent hole 112. When the air pressure in the water tank 1 is greater than the ambient air pressure, the air in the water tank 1 pushes the plug 114 to move upwards, and the air in the water tank 1 enters the air guide column 116 from the gap between the plug 114 and the air guide column 116 and is discharged through the upper vent hole 113. According to the scheme, the conical part extends into the lower vent hole 112 to serve as the guide of the plug 114, so that the defect that gas cannot be discharged timely when the plug 114 is blocked in operation in the guide groove due to the fact that the guide groove is formed above the plug 114 in the conventional structure is overcome. When the water tank 1 is poured, water enters through the lower vent hole 112, the plug 114 is pushed to move towards the air guide column 116, the plug 114 is plugged on the air guide column 116 because the viscosity and resistance of the water are greater than those of the air, the water cannot enter the air guide column 116, and therefore the water cannot flow out of the upper vent hole 113.
Preferably, the top of the cover 11 is provided with a handheld part 118 higher than the plane of the cover, and the top surface of the handheld part 118 is ridge-shaped; the upper vent 113 is disposed on a top surface of the handle 118. In daily use, dust is not easy to accumulate on the top surface of the handheld part 118 higher than the plane of the handheld part, and the ridge-shaped top surface is not easy to be completely covered by sundries, so that the upper vent hole 113 arranged on the handheld part is not easy to be blocked, and the use reliability is ensured.
The foregoing is a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, a plurality of improvements and decorations can be made without departing from the principle of the present invention, and these improvements and decorations are also considered as the protection scope of the present invention.

Claims (8)

1. A hydrogen generating device comprises a water tank and an electrolytic tank, and is characterized in that the electrolytic tank comprises a first fixing plate, a first insulating plate, an anode electrolytic plate, a first titanium fiber plate, an ionic membrane, a second titanium fiber plate, a cathode electrolytic plate, a second insulating plate and a second fixing plate which are sequentially arranged, wherein a water flow groove is formed in one surface of the anode electrolytic plate, which faces the cathode electrolytic plate, a guide strip in a vertical direction is arranged in the water flow groove, the lower part of the water flow groove is communicated with a water inlet, the upper part of the water flow groove is communicated with a water outlet, and the upper surface of the guide strip is level to the edge of the water flow groove; the cathode electrolytic plate is provided with an air outlet hole which is communicated with the first honeycomb aluminum plate;
the water tank is connected with the water inlet and the water outlet through a conduit, and the connecting position of the conduit connected with the water inlet and the water tank is lower than the connecting position of the conduit connected with the water outlet and the water tank.
2. The hydrogen generator according to claim 1, wherein four of said guide strips are arranged laterally at a predetermined distance to form a water flow supporting unit, and two water flow supporting units are arranged laterally in said water flow channel, and the distance between said two water flow supporting units is greater than the distance between adjacent guide strips in a single water flow supporting unit.
3. A hydrogen generating apparatus as defined in claim 2, wherein three sets of water flow supporting units are arranged longitudinally in the water flow tank, and the three sets of water flow supporting units are arranged at predetermined intervals.
4. A hydrogen generating apparatus as defined in any of claims 2 or 3, wherein the first titanium fiber plate, the ion membrane and the second titanium fiber plate are provided at their peripheries with a silicone sealing frame, and when the first fixing plate and the second fixing plate apply pressure to the first conductive plate and the second conductive plate, the first conductive plate and the second conductive plate press the rubber sealing frame to form a sealed space between the first conductive plate and the second conductive plate; the first conducting plate is connected with the first titanium fiber plate in an abutting mode, the second conducting plate is connected with the second titanium fiber plate in an abutting mode, and the first titanium fiber plate and the second titanium fiber plate evenly clamp the ionic membrane.
5. A hydrogen generating apparatus as defined in claim 4, wherein said ionic membrane extends from the peripheral edges of the first titanium fiber plate and the second titanium fiber plate and is held by a silicone sealing frame; a sealed water flow containing cavity is formed among the anode electrolytic plate, the silica gel sealing frame and the ionic membrane, and a sealed hydrogen containing cavity is formed among the cathode electrolytic plate, the rubber sealing frame and the ionic membrane.
6. A hydrogen generation device in accordance with claim 1, wherein a lid is provided on the top of the water tank, said lid being provided with a water stop vent chamber; and a lower vent hole and an upper vent hole are arranged in the water stopping vent cavity, a plug is arranged between the lower vent hole and the upper vent hole, and the plug is connected with the spring.
7. A hydrogen generation device in accordance with claim 6, wherein a gas-conducting column is provided below said upper vent; in an initial state, a gap is reserved between the plug and the air guide column, a conical part is arranged on the lower end face of the plug, and the conical part extends into the lower air vent.
8. A hydrogen generating device as defined in claim 7, wherein the top of said cover is provided with a hand-held portion higher than the plane of said cover, and the top surface of said hand-held portion is ridge-shaped; the upper vent hole is arranged on the top surface of the handheld part.
CN201920905697.5U 2019-06-14 2019-06-14 Hydrogen generating device Active CN210560795U (en)

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CN201920905697.5U CN210560795U (en) 2019-06-14 2019-06-14 Hydrogen generating device

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Application Number Priority Date Filing Date Title
CN201920905697.5U CN210560795U (en) 2019-06-14 2019-06-14 Hydrogen generating device

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CN210560795U true CN210560795U (en) 2020-05-19

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110295373A (en) * 2019-06-14 2019-10-01 深圳市珐彩科技有限公司 A kind of hydrogen generating device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110295373A (en) * 2019-06-14 2019-10-01 深圳市珐彩科技有限公司 A kind of hydrogen generating device

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