CN209631185U - A kind of bicavate thermochemical method energy storage reaction unit - Google Patents

A kind of bicavate thermochemical method energy storage reaction unit Download PDF

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Publication number
CN209631185U
CN209631185U CN201822104765.6U CN201822104765U CN209631185U CN 209631185 U CN209631185 U CN 209631185U CN 201822104765 U CN201822104765 U CN 201822104765U CN 209631185 U CN209631185 U CN 209631185U
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CN
China
Prior art keywords
reaction chamber
energy storage
exoenergic
bicavate
storage reaction
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Expired - Fee Related
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CN201822104765.6U
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Chinese (zh)
Inventor
龙新峰
徐艳
周思全
楼波
尤坚
郑国�
张明勇
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Zhanjiang Utilities Electric Co Ltd
South China University of Technology SCUT
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Zhanjiang Utilities Electric Co Ltd
South China University of Technology SCUT
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Priority to CN201822104765.6U priority Critical patent/CN209631185U/en
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Abstract

A kind of bicavate thermochemical method energy storage reaction unit, including condenser, reaction chamber, separator disc, vapor supply system, the reaction chamber on separator disc top are energy storage reaction chamber, and the reaction chamber of separator disc lower part is exoenergic reaction chamber;The two sides of energy storage reaction chamber are equipped with calcium hydroxide feed inlet, and absorbing heat disk is installed in energy storage reaction chamber, and absorbing heat disk outer end is stretched out from calcium hydroxide feed inlet;The top of reaction chamber is equipped with for assembling sunlight and reflecting the condenser on the absorbing heat disk in energy storage reaction chamber;Exoenergic reaction is intracavitary to be equipped with coil pipe, gas distribution grid, and coil pipe both ends are respectively thermal fluid inlet and hot fluid outlet ports, and coil pipe both ends are stretched out outside exoenergic reaction chamber, and gas distribution grid is installed below coil pipe.A kind of bicavate thermochemical method energy storage reaction method, using a kind of above-mentioned bicavate thermochemical method energy storage reaction unit.The utility model has many advantages, such as that Matter Transfer utilization rate is high, structure is simple, easy to operate.The utility model solar thermal energy high-temperature storage technical field.

Description

A kind of bicavate thermochemical method energy storage reaction unit
Technical field
A kind of the utility model solar thermal energy high-temperature storage technical field, and in particular to bicavate thermochemical method energy storage reaction Device.
Background technique
With the high speed development of today's society, requirement of the economic growth to the energy increases sharply, and limited fossil fuel is increasingly deficient It is weary, it is not able to satisfy the demand of development of modern industry, and the burning of fossil fuel causes great pressure, generation to ecological environment Boundary is faced with a series of problem of sternnesses such as many energy shortagess, global warming, environmental pollution.Energy resource structure reform New direction is mainly the utilization rate for tapping a new source of energy and improving using new technique fuel.Solar power generation is due to expense Low, the advantages that source is wide, free from environmental pollution and become the ideal alternative energy source of the mankind.Devoting Major Efforts To Developing utilizes solar energy, it will has Effect alleviates the problem of energy shortages, and changes the unreasonable energy resource structure in China, keeps energy supply diversified.However, due to too Sun can have the shortcomings that intermittent, low-density and unstability, be difficult to continue supply, therefore improving thermal energy storage technology is to advise greatly Mould develops the key of solar thermal power generation.
Currently, research application it is most be exactly using heat chemistry energy storage come energy-storage solar.The storage that heat chemistry energy storage has It can the big (100~500kWh/m of density3), it can realize and be stored for a long time without heat waste at ambient temperature, be suitble to long-distance transportation etc. Advantageous properties provide a kind of method of great development prospect for hi-temp hi-effective conversion, storage and the transport of solar thermal energy.Generally The heat chemistry energy storage system of utilization mainly has: the thermal decomposition of metal oxide, the decomposition of oxide and peroxide, calcium hydroxide With the reaction systems such as the conversion of calcium oxide.However the energy storage density of current reactor is low, energy loss is big, and photothermal conversion efficiency is low; Energy storage and exoergic process are provided separately operation, the material demand after energy storage, which is delivered to another component, just can be carried out exoenergic reaction, Structure and process are complex, and energy consumption is higher;Existing reactor is there is also the cyclic utilization rate to material is low, higher cost etc. Disadvantage.
Utility model content
In view of the above-mentioned problems, to provide a kind of bicavate thermochemical method energy storage that Matter Transfer utilization rate is high anti-for the utility model Device is answered, it also has many advantages, such as relatively simple, easy to operate, the achievable control exoenergic reaction rate of structure.
A kind of bicavate thermochemical method energy storage reaction unit, including condenser, reaction chamber, separator disc, vapor supply system It unites, separator disc is installed in reaction chamber, reaction chamber is divided into two by separator disc, and the reaction chamber on separator disc top is energy storage reaction Chamber, the reaction chamber of separator disc lower part are exoenergic reaction chamber;The two sides of energy storage reaction chamber are equipped with calcium hydroxide feed inlet, absorbing heat disk peace Loaded in energy storage reaction chamber, and absorbing heat disk outer end is stretched out from calcium hydroxide feed inlet;The top of reaction chamber is equipped with for assembling too Sunlight simultaneously reflects the condenser on the absorbing heat disk in energy storage reaction chamber;Exoenergic reaction is intracavitary to be equipped with coil pipe, gas distribution grid, disk Pipe both ends are respectively thermal fluid inlet and hot fluid outlet ports, and coil pipe both ends are stretched out outside exoenergic reaction chamber, gas distribution grid installation Below coil pipe;Exoenergic reaction chamber side offers calcium oxide feed inlet, and exoenergic reaction chamber side is equipped with outlet, outlet and outside Screw conveyor connection, the top of screw conveyor is equipped with discharge port, and discharge port is against absorbing heat disk outer end;Vapor supply system System is connected with the bottom of exoenergic reaction chamber.
As a preference, the outlet of exoenergic reaction chamber is connected by output channel with screw conveyor, on output channel Equipped with lateral, lateral is equipped with check-valves, and check-valves also is provided with after lateral on output channel.
As a preference, further include cyclone separator, one end of two cyclone separators respectively with energy storage reaction chamber, release Energy reaction chamber connection, connects after the other end of two cyclone separators is in parallel with water vapor condenser, water vapor condenser and water The connection of steam supply system.
As a preference, being equipped with calcium oxide self-conveyor feed at calcium oxide feed inlet, the installation of calcium oxide charging box is pre- Above calcium oxide self-conveyor feed.
As a preference, separator disc includes the identical radian plate of four specifications, the central angle of radian plate is 90 degree;Four pieces Radian plate is installed in the center point by shaft, is in a complete disk after four pieces of radian plate installations;The opposite radian of central angle Plate is known as a pair of of radian plate, and two pairs of radian plates are arranged in a staggered manner in height;And it is installed on upper pair of radian plate by shaft Hairbrush.
As a preference, energy storage reaction chamber top is equipped with aperture, the upper end of aperture is equipped with secondary condenser, secondary poly- Light device inner wall is polishing mirror surface, and secondary condenser inner wall is coated with reflectance coating.
As a preference, reaction chamber includes successively from outside to inside shell, insulating layer, inner wall, inner wall and shell are all made of Stainless steel material is made, and insulating layer fills heat preserving and insulating material.
As a preference, vapor supply system include steam generator, heater, steam delivery pump, jet chimney, Aqueduct, water pump, steam generator are connected by jet chimney, steam delivery pump with the bottom of exoenergic reaction chamber;Steam hair It is equipped with aqueduct below raw device, aqueduct is connected through water pump with steam generator;Aqueduct is equipped with check-valves, steam pipe Road is equipped with flow control valve.
As a preference, water pump is also connected through heat induction switch, overheat protector with steam generator.
A kind of bicavate thermochemical method energy storage reaction method, using a kind of above-mentioned bicavate thermochemical method energy storage reaction dress It sets, calcium hydroxide is added into energy storage reaction chamber by calcium hydroxide feed inlet, calcium hydroxide glides along absorbing heat disk;Sunlight It through condenser aggregation, reflects on the absorbing heat disk in energy storage reaction chamber, absorbing heat disk absorbs solar energy to heat on absorbing heat disk Calcium hydroxide, calcium hydroxide are thermally decomposed into calcium oxide and vapor, and calcium oxide drops on separator disc;Open separator disc, oxygen Change calcium to fall on gas distribution grid;Water vapour is transported to exoenergic reaction chamber by steam delivery pump, calcium oxide is anti-with water vapour It answers heat release and generates calcium hydroxide, the heat of releasing heats the cold fluid in coil pipe, completes heat exchange, newly-generated hydrogen Calcium oxide is conveyed into energy storage reaction chamber through screw conveyor again, to carry out the reversible reaction of next round.
The utility model has the beneficial effects that
1, using dual-chamber structure, reaction chamber is separated into energy storage reaction chamber and exoenergic reaction chamber using separator disc, and Calcium hydroxide feed inlet is arranged in the two sides of energy storage reaction chamber, opens up outlet in exoenergic reaction chamber, and will outlet and screw conveyor Connection, the discharge port of screw conveyor is against absorbing heat disk, therefore the utility model is able to achieve and realizes hydroxide in a device Calcium/calcium oxide dehydration-hydro-combination process circulate operation, and material can be recycled, energy and material utilization are high, and tie Structure is simple.
2, lateral is set on output channel, and check-valves is set on output channel, lateral, therefore in addition to Material can be realized and be recycled, moreover it is possible in the case where material effective component is low, close the check-valves on output channel, then beat The check-valves on lateral is opened, to enter device for outside material discharge system in order to add new material, realization can be converse That answers is continuous.
3, flow control valve is arranged in the utility model on steam conveying pipe, real by the adjusting to flow rates Now to the adjusting of the reaction rate in exoenergic reaction chamber, and then realize the control to heat exchange rate and efficiency of heating- utilization.
4, the utility model is equipped with secondary condenser on energy storage reaction chamber top, and secondary condenser inner wall is polishing Mirror surface, and secondary condenser inner wall is coated with reflectance coating, therefore more sunlights can be reflected into energy storage reaction chamber It is interior, the efficiency of light energy utilization is further increased, energy storage density is increased, improves photothermal conversion efficiency.
5, separator disc includes the identical radian plate of four specifications, and four radian plates are installed with one heart, and two pairs of radian plates are high Degree is staggered, therefore separates two cavates when radian plate all spreads upper out, convenient for the independent reaction of each chamber, when by top Energy storage material when being delivered to lower part, a pair of of radian plate of lower section is moved to below a pair of of radian of top, in order to material It is delivered to another reaction chamber from a reaction chamber, material transfer is very fast, and process is simple, and it is easy to operate, and cost is relatively low.
Detailed description of the invention
Fig. 1 is the overall structure diagram of the utility model.
Structural schematic diagram when Fig. 2 is the separator disc closure of the utility model.
Fig. 3 is the structural schematic diagram when separator disc of the utility model is opened.
Wherein, the 1- sun;2- condenser;3- secondary condenser;4- hafnium oxide ceramic layer;5- insulating layer;6- cyclonic separation Device;7- check-valves i;8- calcium hydroxide feed inlet;9- absorbing heat disk;10- separator disc;11- hot fluid outlet ports;12- hot fluid inlet; 13- check-valves j;14- steam condenser;15- calcium oxide self-conveyor feed;16- gas distribution grid;17- steam delivery pump; 18- flow control valve;19- temperature controller;20- temperature inductor;21- heater;22- steam generator;23- crosses thermoinduction Switch;24- overheat protector;25- water pump;26- check-valves k;27- screw conveyor;28- discharge outlet;The charging of 29- calcium oxide Case;30- hairbrush;31- exoenergic reaction chamber;32- water vapour supply system;33- shell;34- coil pipe;35- aperture;36- energy storage is anti- Answer chamber;37- check-valves m;38- check-valves n;39- arc panel;40- shaft.
Specific embodiment
The utility model is further illustrated with reference to the accompanying drawing.
A kind of bicavate thermochemical method energy storage reaction unit, it includes condenser, reaction chamber, water vapour supply system;Instead Intracavitary portion is answered to be isolated into two parts by separator disc, top is energy storage reaction chamber, and lower part is exoenergic reaction chamber;Water vapour supply system The lower part (i.e. exoenergic reaction chamber) of system and reaction chamber connects, to provide water vapour for exoenergic reaction.Condenser is groove type solar Condenser.
Reaction chamber top is cylindrical, and reaction chamber bottom is in cone-shaped.Reaction chamber is followed successively by shell, heat preservation from outside to inside Layer, inner wall, inner wall and shell are all made of stainless steel material and are made.Insulating layer is among inner wall and shell, and insulating layer filling is protected Warm heat-barrier material.Separator disc is installed on the middle part of reaction chamber, and reaction chamber is divided into two, and is divided into energy storage reaction chamber and exoenergic reaction Chamber.The top of energy storage reaction chamber is equipped with aperture, and the upper end of aperture is equipped with secondary condenser, and secondary condenser inner wall uses mirror Face polishing, and reflectance coating is coated in secondary condenser inner wall.Absorbing heat disk, which tilts, is installed on the middle and lower part of energy storage reaction chamber, and two Absorbing heat disk is symmetrically arranged on energy storage reaction chamber two sides, and absorbing heat disk tilts down.There are certain distance between the inner end of two absorbing heat disks, In order to which the material after reacting is slipped on separator disc between two absorbing heat disks.Sunlight is emitted into secondary condensation through condenser Device, then via through holes are reflected by secondary condenser and are injected on the absorbing heat disk in energy storage reaction chamber.
The two sides of energy storage reaction chamber offer calcium hydroxide feed inlet, and absorbing heat disk outer end is stretched out from calcium hydroxide feed inlet, And absorbing heat disk and calcium hydroxide feed inlet weld together.The top of absorbing heat disk outer end is equipped with cyclone separator;Cyclone separator One end is connected with the upper end of energy storage reaction chamber, and the cyclone separator other end passes through water vapor condenser and water vapour supply system Connection.The pipeline that the cyclone separator is connected with water vapor condenser is equipped with check-valves i.Moisture content when energy storage reaction chamber reacts By the channel of the upper end of energy storage reaction chamber, then water vapour is delivered to through cyclone separator and is condensed through condenser, be finally delivered to Water vapour supply system.The material being entrained with when reacting is dried cyclone separator, and recycles decentralization extremely collection hot plate outer end, The calcium hydroxide material of drying to recycle is added in energy storage reaction chamber by calcium hydroxide feed inlet.In energy storage reaction chamber Wall is coated with hafnium oxide ceramic layer, and heat-resisting material hafnium oxide fusing point is high, reflectivity with higher, and it is intracorporal anti-to improve chamber Rate is penetrated, conductive heat loss intracavitary when the endothermic reaction is reduced.
Exoenergic reaction is intracavitary to be equipped with coil pipe, gas distribution grid, and coil pipe both ends are from the intracavitary stretching of exoenergic reaction, coil pipe one End is hot fluid inlet, and the coil pipe other end is hot fluid outlet ports.Gas distribution grid is installed below coil pipe, gas distribution grid is used for Accept the calcium oxide of energy storage reaction chamber decentralization;High-temperature vapor and calcium oxide reaction, the heat coil pipe of release, the interior stream of coil pipe Dynamic fluid is in the intracavitary carry out heat exchange of exoenergic reaction.Exoenergic reaction chamber side lower end offers calcium oxide feed inlet, calcium oxide Feed inlet is equipped with calcium oxide self-conveyor feed, and calcium oxide self-conveyor feed is connected with calcium oxide charging box.Calcium oxide charging box Top is equipped with cyclone separator.Cyclone separator one end is connected by pipeline with exoenergic reaction chamber upper end, and cyclone separator is another End is connected by water vapor condenser with water vapour supply system.On the pipeline that the cyclone separator is connected with water vapor condenser Equipped with check-valves j.The material being entrained with when reacting is carried out separation drying by cyclone separator, and is recycled to calcium oxide charging box. Material is conveyed into the intracavitary portion of exoenergic reaction through calcium oxide self-conveyor feed again by calcium oxide charging box.The exoenergic reaction chamber other side Outside is equipped with screw conveyor, and screw conveyor is connected with exoenergic reaction chamber by output channel, and screw conveyor top is equipped with Outlet exports an absorbing heat disk outer end of opposite energy storage reaction chamber.Output channel is equipped with lateral, and lateral is downward, point Branch pipe(tube) is equipped with check-valves m.Check-valves n is equipped on output channel and after lateral.It is reflected from exoenergic reaction chamber The calcium hydroxide come is fed back to energy storage reaction chamber through output channel, then by screw conveyor, to realize the circulation benefit of material With.When calcium hydroxide cannot be recycled, closing check-valves m opens check-valves n, and material is followed by lateral discharge Ring system.It is equipped with discharge outlet in the lower part of exoenergic reaction chamber, the intracavitary extra moisture of exoenergic reaction is discharged.
Water vapour supply system includes steam generator, heater, steam delivery pump, steam delivery pump.Heater is set to In steam generator.Steam generator is connected by jet chimney, steam delivery pump with the bottom of exoenergic reaction chamber, and steam is passed through It is intracavitary that vapor is delivered to exoenergic reaction by jet chimney by the power of delivery pump.Meanwhile steam generator top is also and water Vapour condenser connection, the moisture content that water vapor condenser separates cyclone separator condense.It is equipped with below steam generator Aqueduct, aqueduct are connected through water pump with steam generator, and aqueduct is equipped with check-valves k, and check-valves k is to control Open or close aqueduct.Water pump is also connected through heat induction switch, overheat protector with steam generator, works as steam generator Temperature overstep the extreme limit high level when, opened heat induction switch, overheat protector, to switch off the pump.Jet chimney is equipped with stream Adjustable valve, flow adjusting are also connected through temperature controller with steam generator, and temperature controller is connected with temperature inductor again. When temperature inductor experiences temperature value, temperature value is passed into temperature controller, temperature controller is according to the height of temperature The opening and closing of flow control valve is controlled, the temperature in steam generator is regulated and controled to realize.
Separator disc includes four radian plates, and four pieces of radian plate gauge lattice are consistent, and the central angle of each radian plate is 90 degree.Four pieces Radian plate installs connection by the shaft at center.Opposite a pair of of the radian plate height of central angle is consistent, and two pairs of radian plates one are high One low setting.It is a complete disk after the installation of four blocks of radian plates, overlooks Shi Chengyi round, and four blocks of radian plates is by energy storage The lower part of reaction chamber seals.Be also equipped with hairbrush on separator disc, hairbrush is installed together by shaft and radian plate, brush length and Radian plate radius is identical.When the product calcium oxide that calcium hydroxide in energy storage reaction chamber is thermally decomposed is input to exoenergic reaction chamber, Open separator disc, the opposite radian plate of one pair of them central angle is moved to another pair radian plate in the following, adjacent arc originally at this time Degree plate is overlapped two-by-two, and calcium oxide just falls into that exoenergic reaction is intracavitary from gap, and the radian of slightly higher a pair then will be in hairbrush It is intracavitary that calcium oxide on plate is swept into exoenergic reaction.
The course of work of the utility model:
Operating process in energy storage reaction chamber: calcium hydroxide particle enters energy storage reaction chamber from calcium hydroxide feed opening, stream Through absorbing heat disk;Sunlight is incident in energy storage reaction chamber by groove type solar condenser, heats calcium hydroxide particle, hydroxide Calcium particles by heat resolves into calcium oxide and vapor;Vapor is discharged from the cyclone separator on energy storage reactor top, then through water It is conveyed into vapor supply system after vapour condenser condensation, calcium oxide drops on separator disc.
Operating process in exoenergic reaction chamber: opening separator disc, and calcium oxide is fallen on gas distribution grid;Start vapor to supply System is answered, is delivered water into steam generator, is heated with heater and generates vapor, then uses steam delivery pump by water vapour It is transported to exoenergic reaction chamber, calcium oxide and steam reaction, releases heat;The cold fluid that need to be heated or cold sky are passed through in coil pipe Gas reacts the heat released with calcium oxide with vapor and is heated, and obtains high temperature fluid or high-temperature steam for power generation industries Deng.
After the completion of exoenergic reaction, check-valves n is opened, the calcium hydroxide of generation is transported to calcium hydroxide and added by screw conveyor Material mouth carries out a new round and obtains circular response.The dehydration of high-purity hydrogen calcium oxide and rehydration are 100 times recyclable.Work as calcium hydroxide Activity decline when, open check-valves m be discharged calcium hydroxide, pyrolytic regeneration after, recycling can be sent back to.Again from hydrogen Calcium oxide feed opening is added new or after regeneration calcium hydroxide or inputs calcium oxide from calcium oxide screw conveyor, carries out new The reversible reaction of one wheel.
Above-described embodiment is only the preferable embodiment of the utility model, but the embodiments of the present invention is not by upper State the limitation of embodiment, it is made under other any spiritual essence and principles without departing from the utility model to change, modify, replacing In generation, simplifies combination, should be equivalent substitute mode, is included within the protection scope of the utility model.

Claims (9)

1. a kind of bicavate thermochemical method energy storage reaction unit, it is characterised in that: steamed including condenser, reaction chamber, separator disc, water Gas supply system is equipped with separator disc in reaction chamber, and reaction chamber is divided into two by separator disc, and the reaction chamber on separator disc top is storage Energy reaction chamber, the reaction chamber of separator disc lower part are exoenergic reaction chamber;The two sides of energy storage reaction chamber are equipped with calcium hydroxide feed inlet, inhale Hot plate is installed in energy storage reaction chamber, and absorbing heat disk outer end is stretched out from calcium hydroxide feed inlet;The top of reaction chamber is equipped with and is used for Aggregation sunlight simultaneously reflects the condenser on the absorbing heat disk in energy storage reaction chamber;Exoenergic reaction is intracavitary to be equipped with coil pipe, gas point Fabric swatch, coil pipe both ends are respectively thermal fluid inlet and hot fluid outlet ports, and coil pipe both ends are stretched out outside exoenergic reaction chamber, gas distribution Plate is installed below coil pipe;Exoenergic reaction chamber side offers calcium oxide feed inlet, and exoenergic reaction chamber side is equipped with outlet, outlet Connect with external screw conveyor, the top of screw conveyor is equipped with discharge port, and discharge port is against absorbing heat disk outer end;Vapor Supply system is connected with the bottom of exoenergic reaction chamber.
2. a kind of bicavate thermochemical method energy storage reaction unit according to claim 1, it is characterised in that: exoenergic reaction chamber Outlet is connected by output channel with screw conveyor, and output channel is equipped with lateral, and lateral is equipped with check-valves, Check-valves also is provided on output channel after lateral.
3. a kind of bicavate thermochemical method energy storage reaction unit according to claim 1, it is characterised in that: further include whirlwind point From device, one end of two cyclone separators is connected with energy storage reaction chamber, exoenergic reaction chamber respectively, two cyclone separators it is another It is connected after end is in parallel with water vapor condenser, water vapor condenser is connected with vapor supply system.
4. a kind of bicavate thermochemical method energy storage reaction unit according to claim 1, it is characterised in that: calcium oxide feed inlet Place is equipped with calcium oxide self-conveyor feed, calcium oxide charging box installation pre-oxidation calcium self-conveyor feed top.
5. a kind of bicavate thermochemical method energy storage reaction unit according to claim 1, it is characterised in that: separator disc includes four The identical radian plate of a specification, the central angle of radian plate are 90 degree;Four blocks of radian plates are installed in the center point by shaft, four pieces of arcs It spends after plate installation in a complete disk;The opposite radian plate of central angle is known as a pair of of radian plate, and two pairs of radian plates are in height On be arranged in a staggered manner;And hairbrush is installed by shaft on upper pair of radian plate.
6. a kind of bicavate thermochemical method energy storage reaction unit according to claim 1, it is characterised in that: energy storage reaction chamber top End is equipped with aperture, and the upper end of aperture is equipped with secondary condenser, and secondary condenser inner wall is polishing mirror surface, and secondary condenser Inner wall is coated with reflectance coating.
7. a kind of bicavate thermochemical method energy storage reaction unit according to claim 1, it is characterised in that: reaction chamber is by outside extremely It inside successively include shell, insulating layer, inner wall, inner wall and shell are all made of stainless steel material and are made, and insulating layer fills insulation Material.
8. a kind of bicavate thermochemical method energy storage reaction unit according to claim 1, it is characterised in that: vapor supply system System includes steam generator, heater, steam delivery pump, jet chimney, aqueduct, water pump, and steam generator passes through steam Pipeline, steam delivery pump are connected with the bottom of exoenergic reaction chamber;Aqueduct is equipped with below steam generator, aqueduct is through water Pump is connected with steam generator;Aqueduct is equipped with check-valves, and jet chimney is equipped with flow control valve.
9. a kind of bicavate thermochemical method energy storage reaction unit according to claim 8, it is characterised in that: water pump is also through thermal sensation Inductive switch, overheat protector are connected with steam generator.
CN201822104765.6U 2018-12-14 2018-12-14 A kind of bicavate thermochemical method energy storage reaction unit Expired - Fee Related CN209631185U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109550469A (en) * 2018-12-14 2019-04-02 华南理工大学 A kind of bicavate thermochemical method energy storage reaction unit and method
CN111889056A (en) * 2020-08-03 2020-11-06 博尔滋曼新能源科技(上海)有限公司 Mixing reaction device and method for atomized water and calcium oxide particles
CN113432470A (en) * 2021-07-16 2021-09-24 上海应用技术大学 Sensible heat and thermochemistry coupling heat storage method and device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109550469A (en) * 2018-12-14 2019-04-02 华南理工大学 A kind of bicavate thermochemical method energy storage reaction unit and method
CN109550469B (en) * 2018-12-14 2023-09-29 华南理工大学 Double-cavity thermochemical energy storage reaction device and method
CN111889056A (en) * 2020-08-03 2020-11-06 博尔滋曼新能源科技(上海)有限公司 Mixing reaction device and method for atomized water and calcium oxide particles
CN113432470A (en) * 2021-07-16 2021-09-24 上海应用技术大学 Sensible heat and thermochemistry coupling heat storage method and device

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