CN209438365U - A kind of organic exhaust gas adsorption electrolysis unit - Google Patents

A kind of organic exhaust gas adsorption electrolysis unit Download PDF

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Publication number
CN209438365U
CN209438365U CN201920126542.1U CN201920126542U CN209438365U CN 209438365 U CN209438365 U CN 209438365U CN 201920126542 U CN201920126542 U CN 201920126542U CN 209438365 U CN209438365 U CN 209438365U
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absorption
activated carbon
electrolytic cell
spray
cellular activated
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CN201920126542.1U
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查红平
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Abstract

The utility model embodiment discloses a kind of organic exhaust gas adsorption electrolysis unit, described device includes the sequentially connected carbon dust slurry spray absorption in front and back and electrolysis installation section, the absorption of runner cellular activated carbon and electrolysis installation section and lye spray-absorption equipment section, and above three equipment section is installed in the shell being made of lower groove body and top cover, wherein carbon dust slurry spray absorption and electrolysis installation section include the first electrolytic cell of multiple groups spray tube, packing layer and lower part;The runner cellular activated carbon absorption and electrolysis installation section include multiple cellular activated carbon vacuum chuck turntables;The lye spray-absorption equipment section includes multiple groups spray tube, packing layer and the collecting tank of lower part.The device collects to solve existing organic exhaust gas, the deficiency in controlling device, the needs of absorption and sorption of organic exhaust gas and medium electrochemical degradation, regeneration are organically combined, while meeting whole process operation stability, safety, economy and administering validity.

Description

A kind of organic exhaust gas adsorption electrolysis unit
Technical field
The utility model relates to industrial waste gas processing technology fields, and in particular to a kind of organic exhaust gas adsorption electrolysis unit.
Background technique
The industries such as petrochemical industry, coating, printing, rubber generate organic exhaust gas in containing benzene,toluene,xylene, ethyl acetate, The organic compounds such as acetone, formaldehyde, methanol, these pernicious gas majorities are inflammable, explosive, a large amount of to discharge not only localized region Ecological environment has some impact on, and can also generate serious harm to entire earth environment, be cause Atmospheric Photochemical Smog, One of the reason of greenhouse effects and depletion of the ozone layer, has become the source of atmospheric pollution that our state keys are administered at present.
There are two main classes for existing VOCs treatment device: one kind is recyclable device, and another kind of is cancellation element.Recycling Device mainly applies charcoal absorption, pressure-variable adsorption, condensation method and membrane separation technique, recyclable device be by physical method, with temperature, The means such as pressure, selective absorbent and permoselective membrane separate organic pollutant.Cancellation element has thermal oxide, catalysis Burning, biological oxidation and integrated technology;Cancellation element mainly passes through chemistry or biochemical reaction, with heat, catalyst and microorganism Organic matter is transformed into CO2And water.The two in terms of VOCs treatment exist be not easy continuous and steady operation, be also easy to produce it is secondary Pollution, initial investment is big, operating cost is high, changes the problems such as adaptability is not strong to organic exhaust gas concentration and composition.
Utility model content
The complexes for being designed to provide a kind of organic exhaust gas adsorption electrolysis of the utility model embodiment, to solve Deficiency in existing organic exhaust gas collection, controlling device, by the absorption and sorption of organic exhaust gas and medium electrochemical degradation, regeneration The needs of organically combining, while meeting whole process operation stability, safety, economy and administering validity.
To achieve the above object, the utility model embodiment provides a kind of organic exhaust gas adsorption electrolysis unit, described device Including the slurry spray absorption of the sequentially connected carbon dust in front and back and electrolysis installation section, the absorption of runner cellular activated carbon and electrolysis installation section with And lye spray-absorption equipment section, and above three equipment section is installed in the shell being made of lower groove body and top cover In, wherein
Carbon dust slurry spray absorption and electrolysis installation section include multiple groups first unit in upper lid body in tandem and First electrolytic cell of lower part, every group of first unit include the first spray tube and the first packing layer that front and back is arranged successively;Described turn The absorption of wheel cellular activated carbon and electrolysis installation section include multiple bees in top cover and the second electrolytic cell of lower part in tandem Nest activated carbon adsorption turntable, these cellular activated carbon vacuum chuck turntables are connected across the center of circle by drive shaft and drive rotation, the drive Moving axis is at least stretched out from a side body;The lye spray-absorption equipment section includes the multiple groups second in upper lid body in tandem The collecting tank of unit and lower part, every group of second unit include the second spray tube and the second packing layer that front and back is arranged successively.
Further, the carbon dust slurry spray absorption and electrolysis installation section are equipped with first also after last group of first unit Inclined tube demisting layer;The lye spray-absorption equipment section is equipped with the second inclined tube demisting layer also after last group of second unit;With/ Or the runner cellular activated carbon absorption and electrolysis installation section are equipped with third also after the last one cellular activated carbon vacuum chuck turntable Inclined tube demisting layer.
The inclined tube demisting layer is equipped with multiple inclined tube through-holes in the level vertical with airflow direction, so that entrained liquids When passing through inclined tube demisting layer, the fine droplet of Vapor Entrainment collides on inclined tube inner wall, converges gas phase, forms larger drop, And fallen in lower channel downwards along inclined tube inner wall, to complete demisting effect.
Further, each first unit is equipped with the first water conservancy diversion also between the first spray tube and the first packing layer Plate;Each second unit is equipped with the second deflector also between the second spray tube and the second packing layer;And first bee Third deflector is additionally provided with before nest activated carbon adsorption turntable.The deflector is for filling packing layer/vacuum chuck turntable and cover Between gap, prevent organic exhaust gas short stream in cover, thus influence absorption and filter effect.
Further, first electrolytic cell, the second electrolytic cell and collecting tank are square groove, and outside is sequentially connected, internal Independently of each other;Top cover internal run-through above three equipment section, cross section are semicircle, the connection of cover front end Air inlet pipe, cover rear end connect delivery pipe.
Above-mentioned first electrolytic cell, the second electrolytic cell and the setting of collecting tank internal independence, can be according to organic exhaust gas adsorption electricity The different phase and spray liquid of solution and the variety classes of electrolyte are adapted to respectively and independent operating, can also be set according to above three The variations such as quantity, the size of standby intersegmental part component and flexible configuration, realize modularization management.Top cover is in above three equipment Internal run-through at section, the delivery pipe of air inlet pipe and rear end together with front end form the complete gas circuit of organic exhaust gas, above-mentioned spray Pipe, packing layer, deflector, cellular activated carbon vacuum chuck turntable, inclined tube demisting layer shape be adapted with mask body shape so that organic Exhaust gas is basically by said modules.By the complete process of above three equipment section, the gas for meeting discharge standard is carried out Discharge.
Further, it is equipped in first electrolytic cell and is evenly distributed with the first three-dimensional filled electrode bed, second electrolytic cell It is inside equipped with and is evenly distributed with the second three-diemsnional electrode bed;The cathode and anode of the second three-diemsnional electrode bed are also evenly distributed on the multiple Between cellular activated carbon vacuum chuck turntable.It is logical to be just met for cellular activated carbon vacuum chuck turntable for anode and cathode spacing in second electrolytic cell It crosses, and realizes regenerating active carbon under electrochemical action.Uniformly distributed three-dimensional filled electrode bed can accelerate organic matter in electrolytic cell Electrolytic process improves regeneration effect.Electrode bed anode and cathode uses coating titanium net, and surface covering is according to building rings such as analysis chlorine, analysis oxygen Border needs to customize.
Further, first electrolytic cell, the second electrolytic cell and collect trench bottom further respectively have the first liquid outlet, Third liquid outlet and second liquid outlet, for connecting liquid circulation pump and/or supersonic generator;The liquid circulation pump Outlet docked with the entrance of the spray tube and/or the circulation stirring pipe of electrolytic cell.The liquid circulation pump is every for recycling Liquid working substance in a equipment section;The supersonic generator is used to be passed to ultrasonic wave into liquid working substance, to improve liquid work The electrolytic process of organic matter in matter accelerates electrolyte to flow through hole, improves adsorbing medium regeneration effect.
Further, it is sealed at the top cover and lower groove body docking using gasket;The deflector relative to Packing layer or cellular activated carbon vacuum chuck turntable radially protruding 5-10cm later;And the deflector with later packing layer or bee The spacing of nest activated carbon adsorption turntable is 1cm.
The cover of every section of control waste gas flow direction is sealed with the lower half groove body place of docking using gasket, and reduction is leaked out;Every section The deflector of 5~10cm is protruded in packing layer or the installation of turntable windward side side backwards to drive shaft, and deflector apart from packing layer or Turntable spacing 1cm or so prevents exhaust gas along the short stream in cover wall gap, fails effectively to adsorb.
Lye spray-absorption equipment section is to remove former sections of sprays and the issuable sour gas of electrolytic process, further By lye spray-absorption, the small water droplet blown away with air-flow is collected through inclined tube demisting layer and flows back to bottom collection slot.
Further, drive shaft stretching shell side is also connected with transmission system;First electrolytic cell and second Electrolytic cell is also connected with electrolyte monitoring system and automatic medicament feeding system.The transmission system is used for connecting power device, is used for Power is provided and drives drive shaft turns, cellular activated carbon vacuum chuck turntable is further driven to and is rotated in shell.Drive shaft can both ends Through shell, the adjustable revolving speed in the case where external motor and transmission system drive.The electrolyte monitoring system and automatic medicament feeding system For monitoring the state of electrolyte in the first electrolytic cell and the second electrolytic cell in real time, and in insufficient electrolyte to above-mentioned electrolytic cell Middle automatic electrolyte.
Further, the cellular activated carbon vacuum chuck turntable with a thickness of 3-5cm, quantity is 2-5.In an embodiment party In case, the revolving speed of the cellular activated carbon vacuum chuck turntable is that 2-10 turns/day.
3~5cm cellular activated carbon is fixed in thick round pie support for rotary disc, and bracket can make honeycomb active with drive shaft turns Charcoal vacuum chuck turntable alternately enters electrolytic regeneration in the second electrolytic cell of lower part, then returns to top and continues to absorb organic exhaust gas.It can root According to needing to design 2~5 groups of cellular activated carbon vacuum chuck turntables, hole is towards airflow direction, and some resistance is small, adsorption capacity is big; 2~10 turn/day of vacuum chuck turntable revolving speed is adjustable, when the active carbon after making absorption organic exhaust gas has sufficiently long regeneration in the electrolytic solution Between, it is ensured that regeneration is abundant;Second electrolytic cell cathode-anode plate spacing just allows vacuum chuck turntable to pass through, and the mating spray liquid of electrolytic cell follows The auxiliary equipment such as ring pump and supersonic generator, promote liquid in cellular activated carbon hole inner transmission matter, regeneration;It is conductive in electrolyte The parameters such as type, additive amount, pH and the current strength of salt, ultrasonic intensity can determine optimization, centralized control according to test.
Further, the spray liquid in first spray tube include be configured to by Powdered Activated Carbon spray active carbon Slurry, while adding sodium chloride, ferrous sulfate, hydrogen peroxide and/or sulfuric acid.Above-mentioned spray liquid flourishing, specific surface using pore structure The Powdered Activated Carbon that product is big, absorption property is strong is configured to that active carbon slurry can be sprayed, while adding sodium chloride, ferrous sulfate, dioxygen Water, sulfuric acid etc. improve waste water electric conductivity, generate living radical and active powdered carbon is accelerated to be adsorbed with the decomposition of machine object and powdered carbon regeneration;Electricity Solving the auxiliary equipment such as the mating spray liquid circulating pump of slot and supersonic generator promotes liquid in active powdered carbon hole inner transmission matter;Activity The parameters such as charcoal slurry, the type of conductive salt, additive amount, pH and current strength, spraying intensity can be according to processing Exhaust gas species test It determines, centralized control addition.
The utility model embodiment has the advantages that
1, the device is using combination measures such as active carbon slurry absorption electrolysis+runner activated carbon adsorption electrolytic regeneration+Alkali absorptions It realizes organic exhaust gas economy, stabilization, efficiently administer.
2, each segment length, solution parameter, spraying intensity, current parameters etc. can change according to the concentration and composition of organic exhaust gas Adjustment has the ability of modularization installation.
3, scientific structure, rationally, the organic exhaust gas generated for industries such as petrochemical industry, coating, printing, rubber can be effective for setting Remove various organic compounds.
Detailed description of the invention
Fig. 1 is the structural schematic diagram for the organic exhaust gas adsorption electrolysis unit that the utility model embodiment 1 provides.
Wherein appended drawing reference are as follows:
1, air inlet pipe;2, cover;3, the first spray tube;3 ', second spray tube;4, the first deflector;4 ', second water conservancy diversion Plate;4 ", third deflector;5, the first packing layer;5 ', second packing layer;6, the first inclined tube demisting layer;6 ', second inclined tube demisting Layer;7, cellular activated carbon vacuum chuck turntable;8, delivery pipe;9, drive shaft;10, the first three-dimensional filled electrode bed;10 ", second is three-dimensional Electrode bed;11, the first liquid outlet;11 ', second liquid exports;11 ", third liquid outlet;12, groove body.
Specific embodiment
The embodiments of the present invention is illustrated by particular specific embodiment below, those skilled in the art can be by this Content disclosed by specification understands other advantages and effect of the utility model easily.
It should be clear that this specification structure depicted in this specification institute accompanying drawings, ratio, size etc., only to cooperate specification to be taken off The content shown is not intended to limit the utility model enforceable restriction item so that those skilled in the art understands and reads Part, therefore do not have technical essential meaning, the modification of any structure, the change of proportionate relationship or the adjustment of size are not influencing Under the effect of the utility model can be generated and the purpose that can reach, should all still it fall in the revealed technology of the utility model In the range of Rong get Neng is covered.Meanwhile cited such as "upper", "lower", " left side ", the right side in this specification ", the use of " centre " Language is merely convenient to being illustrated for narration, rather than to limit the enforceable range of the utility model, the change of relativeness or Adjustment, under the content of no substantial changes in technology, when being also considered as the enforceable scope of the utility model.
Embodiment 1
As shown in Figure 1, it is shown that for the knot for the organic exhaust gas adsorption electrolysis unit that the utility model one embodiment provides Structure schematic diagram.
The device includes carbon dust slurry spray absorption and electrolysis installation section (3,4,5,6);The absorption of runner cellular activated carbon and electricity It solves equipment section (4 ", 7);Lye spray-absorption equipment section (3 ', 4 ', 5 ', 6 ');Drive shaft 9;Control cover 2, the slot of waste gas flow direction Body 12, air inlet pipe 1, delivery pipe 8, electrolyte monitoring system (not shown), automatic medicament feeding system (not shown) etc..Organic exhaust gas from Air inlet pipe 1 enters absorption electrolysis unit, sprays by carbon dust slurry spray absorption and 3 nozzle of electrolysis installation Duan Shiyu spray tube thin Droplet shape adsorbing medium is mixed absorption in semicircle packing layer 5, and organic exhaust gas is transferred to liquid phase from gas phase and realizes the It is primary to absorb;Collision is in surface aggregation at big liquid when drop after being entrained to packing layer 5 with exhaust gas encounters the first inclined tube demisting layer 6 It drips and flows back to this section of groove body 12 (the first electrolytic cell);The first three-dimensional filled electrode bed 10 is three-diemsnional electrode group in the first electrolytic cell At cathode-anode plate uses titanium net coated electrode, and central filler is conducive to improve the filler of electrolytic efficiency, is conducive to living radical Generation, improve powdered carbon absorption organic matter degradation and adsorption capacity regeneration;In addition, the first electrolytic cell passes through the first liquid outlet The auxiliary equipment (not shown) such as the mating spray liquid circulating pump (not shown) of 11 connections and supersonic generator guarantees spray flow quantity With the liquid circulation flow in electrolytic cell, accelerate the mass transport process between solid liquid phase such as free radical, organic matter, improves electrolysis effect Rate.
Organic exhaust gas after charcoal starches spray absorption enters the absorption of runner cellular activated carbon and electrolysis installation section, and 3~5cm is thick Cellular activated carbon, which is fixed in round pie bracket, constitutes cellular activated carbon vacuum chuck turntable 7, by honeycomb activity when organic exhaust gas passes through The cellular activated carbon absorption loaded in charcoal vacuum chuck turntable 7, the turntable 7 for having adsorbed organic exhaust gas are slow under the action of drive shaft 9 It is transferred in lower groove body 12 (the second electrolytic cell), the anode and cathode of titanium net coating in the second three-diemsnional electrode bed 10 " of the second electrolytic cell Plate is located just at 7 two sides of turntable, and the living radical generated in electrolytic process under ultrasound cooperation is quickly through in active carbon Cavity and adsorption channel, realize degradation and the regenerating active carbon of organic matter, the cellular activated carbon after regeneration is in drive shaft 9 The lower slowly rotation of effect, which returns, absorbs organic exhaust gas in top cover 2, design 2~5 groups of cellular activated carbon absorption as needed and turn Disk 7, hole is towards airflow direction, and some resistance is small, adsorption capacity is big;Vacuum chuck turntable 7 revolving speed, 2~10 turns/day are adjustable, make to inhale Active carbon after attached organic exhaust gas has enough reproduction times in the electrolytic solution, it is ensured that regeneration is abundant;This section of lower half portion second 10 " cathode-anode plate spacing of three-diemsnional electrode bed just allows turntable 7 to pass through, and the second electrolytic cell is connected by third liquid outlet 11 " The auxiliary equipment such as mating electrolyte circulating pump and supersonic generator promote liquid in cellular activated carbon hole inner transmission matter, regeneration; The parameters such as the type of conductive salt, additive amount, pH value and current strength, ultrasonic intensity can be determined according to test in electrolyte Optimization, centralized control.
Last exhaust gas makes alkaline absorption by the second spray tube 3 ' and the second packing layer 5 ' through lye spray-absorption equipment section Liquid and exhaust gas, which come into full contact with, to be flowed back to groove body 12 (collecting tank), realizes the first two sections suctions for generating acid mist and part soluble organic exhaust It receives, the final qualified discharge for realizing organic exhaust gas, the second inclined tube demisting layer 6 ' of cooperation reduces fluid loss.
Each segment length of equipment, solution parameter, spraying intensity, current parameters etc. can become according to the concentration and composition of organic exhaust gas Change adjustment, has the ability of modularization installation.9 both ends of drive shaft of cellular activated carbon vacuum chuck turntable 7 are driven to run through shell, outside Adjustable revolving speed under portion's motor and transmission system drive.The cover 2 of every section of control waste gas flow direction is adopted with 12 place of docking of lower half groove body It is sealed with gasket, reduction is leaked out;Every section of packing layer 5 or the installation of turntable 7 windward side side are backwards to drive shaft 7 relative to thereafter Packing layer 5 or turntable 7 protrude the deflector 4 of 5~10cm, 4 ', 4 ", and with 7 distance 1cm of packing layer 5 or turntable or so thereafter, It prevents exhaust gas along the short stream in cover wall gap, fail effectively to adsorb.
The active carbon slurry spray unlimited active carbon meal component of adsorbing medium that the utility model uses, particle size meet spray The inorganic adsorbents media such as leaching, the active oxidation aluminium powder of absorption demand, zeolite powder also can be used;Other common liquid liquid that are suitable for are handed over The absorption tower changed is also applied for the utility model.The medicament added in active carbon slurry spray adsorbent solution is not limited to sodium chloride, sulphur Sour ferrous iron, hydrogen peroxide, sulfuric acid etc. determine that the ingredient that oxidation regeneration efficiency can be improved is contemplated that according to test.Runner honeycomb The medicament added in the electrolyte of activated carbon adsorption and electrolysis installation section is not limited to sodium chloride, ferrous sulfate, hydrogen peroxide, sulfuric acid Deng;Adsorbing medium is also not necessarily limited to cellular activated carbon, other low windages, stable in physicochemical property porous adsorbing medium can also be used for turning Disk filler.Meanwhile the utility model be improve electrolytic cell efficiency using enhancements be not limited to it is ultrasound-enhanced, it is possible to use or increase Microwave etc. is added to strengthen.
Although above having made detailed description to the utility model with generality explanation and specific embodiment, On the basis of the utility model, it can be made some modifications or improvements, this is apparent to those skilled in the art 's.Therefore, these modifications or improvements on the basis of without departing from the spirit of the present invention, belong to the utility model and want Seek the range of protection.

Claims (9)

1. a kind of organic exhaust gas adsorption electrolysis unit, which is characterized in that described device includes the sequentially connected carbon dust slurry spray in front and back Leaching absorption and electrolysis installation section, the absorption of runner cellular activated carbon and electrolysis installation section and lye spray-absorption equipment section, and on Three equipment sections are stated to be installed in the shell being made of lower groove body and top cover, wherein
The carbon dust slurry spray absorption and electrolysis installation section include multiple groups first unit and the lower part in upper lid body in tandem The first electrolytic cell, every group of first unit includes the first spray tube and the first packing layer that are arranged successively of front and back;The runner bee Nest activated carbon adsorption and electrolysis installation section include that multiple honeycombs in top cover and the second electrolytic cell of lower part in tandem are living Property charcoal vacuum chuck turntable, these cellular activated carbon vacuum chuck turntables pass through the center of circle by drive shaft and connect and drive rotation, the drive shaft At least stretched out from a side body;The lye spray-absorption equipment section includes the multiple groups second unit in upper lid body in tandem With the collecting tank of lower part, every group of second unit includes the second spray tube and the second packing layer that front and back is arranged successively.
2. the apparatus according to claim 1, which is characterized in that the carbon dust slurry spray absorption and electrolysis installation section are also most The first inclined tube demisting layer is equipped with after later group first unit;The lye spray-absorption equipment section is also in last group of second unit It is equipped with the second inclined tube demisting layer afterwards;And/or the runner cellular activated carbon absorption and electrolysis installation section are also in the last one honeycomb Third inclined tube demisting layer is equipped with after activated carbon adsorption turntable.
3. the apparatus of claim 2, which is characterized in that each first unit is also in the first spray tube and first The first deflector is equipped between packing layer;Each second unit is equipped with the also between the second spray tube and the second packing layer Two deflectors;And third deflector is additionally provided with before first cellular activated carbon vacuum chuck turntable.
4. device according to claim 3, which is characterized in that using sealing at the top cover and lower groove body docking Pad sealing;The deflector is relative to packing layer or cellular activated carbon vacuum chuck turntable radially protruding 5-10cm later;And it is described The spacing of deflector and packing layer or cellular activated carbon vacuum chuck turntable later is 1cm.
5. device according to claim 3, which is characterized in that first electrolytic cell, the second electrolytic cell and collecting tank are Square groove, outside are sequentially connected, internal mutually indepedent;Top cover internal run-through above three equipment section, it is horizontal Section is semicircle, and cover front end connects air inlet pipe, and cover rear end connects delivery pipe.
6. device according to claim 5, which is characterized in that be equipped in first electrolytic cell and uniformly distributed first three-dimensional is filled out Electrode bed is filled, be equipped in second electrolytic cell and is evenly distributed with the second three-diemsnional electrode bed;The cathode of the second three-diemsnional electrode bed and Anode is also evenly distributed between the multiple cellular activated carbon vacuum chuck turntable.
7. device according to claim 6, which is characterized in that first electrolytic cell, the second electrolytic cell and collecting tank bottom Portion further respectively has the first liquid outlet, third liquid outlet and second liquid outlet, for connecting liquid circulation pump and/or surpassing Sonic generator;It is docked with the entrance of circulation stirring pipe in the spray tube and/or electrolytic cell the outlet of the liquid circulation pump.
8. the apparatus according to claim 1, which is characterized in that the drive shaft stretches out shell side and is also connected with power train System;First electrolytic cell and the second electrolytic cell are also connected with electrolyte monitoring system and automatic medicament feeding system.
9. the apparatus according to claim 1, which is characterized in that the cellular activated carbon vacuum chuck turntable with a thickness of 3-5cm, Quantity is 2-5.
CN201920126542.1U 2019-01-24 2019-01-24 A kind of organic exhaust gas adsorption electrolysis unit Expired - Fee Related CN209438365U (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109603486A (en) * 2019-01-24 2019-04-12 查红平 A kind of organic exhaust gas adsorption electrolysis unit

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109603486A (en) * 2019-01-24 2019-04-12 查红平 A kind of organic exhaust gas adsorption electrolysis unit
CN109603486B (en) * 2019-01-24 2024-04-05 查红平 Organic waste gas adsorbs electrolytic device

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