CN209039547U - Copper reclaimer and system is recycled in a kind of cupric cleaning waste water - Google Patents
Copper reclaimer and system is recycled in a kind of cupric cleaning waste water Download PDFInfo
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- CN209039547U CN209039547U CN201821683190.1U CN201821683190U CN209039547U CN 209039547 U CN209039547 U CN 209039547U CN 201821683190 U CN201821683190 U CN 201821683190U CN 209039547 U CN209039547 U CN 209039547U
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- copper
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- tank
- cupric
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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Abstract
The utility model discloses a kind of cupric cleaning waste water, and copper reclaimer and system is recycled, including contained waste liquid storage tank, resin reaction tank and resin regeneration and copper recyclable device, contained waste liquid storage tank connects resin reactor tank, multiple suction resin of copper columns are equipped in resin reaction tank, resin reaction tank connects resin regeneration and copper recyclable device, pass through contained waste liquid storage tank, resin reaction tank and resin regeneration and copper recyclable device are effectively adequately handled contained waste liquid, making treated, waste liquid reaches new discharge standard, copper ion is adsorbed using resin of copper reaction is inhaled, copper can be selectively handled from various metals ion, and copper is effectively recycled by resin regeneration and copper recyclable device, it generates and has valuable copper products, resin reaction tank is set to reply cleaning simultaneously, convenient for wash cycles, it is useless to greatly promote cupric cleaning The processing and utilization efficiency of water, the utility model structure is simple, practical, easy to use and promote.
Description
Technical field
The utility model relates to recyclable device field, specifically a kind of cupric cleaning waste water be recycled copper reclaimer and
System.
Background technique
Because the contamination hazard of copper is big, country and local environmental protection bureaus are tight to the processing emission request of copper-containing wastewater, some places
It is required that discharge index copper≤0.1mg/L after copper-containing wastewater processing, the processing of copper-containing wastewater mostly uses greatly heavy metal chelating agent at present
The precipitation method, but for new wastewater discharge standard, what traditional heavy metal chelating agent precipitation method cannot be stable reaches mark
Standard, and the heavy metal chelating precipitation method can not the single selective processing of metal ion, cannot from various metals ion selectivity
A kind of adsorption treatment copper, it is therefore desirable to new copper-containing wastewater processing equipment.
Summary of the invention
The purpose of this utility model is to provide a kind of cupric cleaning waste water, and copper reclaimer and system is recycled, with solution
Certainly the problems mentioned above in the background art.
To achieve the above object, the utility model provides the following technical solutions:
A kind of cupric cleaning waste water recycling copper reclaimer, including contained waste liquid storage tank, resin reaction tank and resin
Regeneration and copper recyclable device, the contained waste liquid storage tank connect resin reactor tank, are equipped with multiple suction copper in the resin reaction tank
Resin column, water storage tank, the resin reaction tank connection resin regeneration and copper recyclable device in resin reaction tank connection.
As a further solution of the present invention: being equipped with pH detector and conductivity detection in the contained waste liquid storage tank
Instrument.
As a further solution of the present invention, the resin regeneration and copper recyclable device include liquid alkaline storage tank, it is dilute
Sulfuric acid storage tank, cleaning water storage tank, regeneration dope storage tank and cyclone electrolytic cell pond.
The liquid alkaline storage tank, dilute sulfuric acid storage tank, cleaning water storage tank and regeneration as a further solution of the present invention,
Dope storage tank passes through pumping connection resin reactor tank respectively, is stored with liquid alkaline in liquid alkaline storage tank, is stored in dilute sulfuric acid storage tank dilute
Sulfuric acid cleans in water storage tank and is stored with ejected wash water, regenerates in dope storage tank and stores the copper sulphate dope after resin regeneration, regenerates
Dope storage tank connects cyclone electrolytic cell pond, is equipped with swirl electrolysis device in cyclone electrolytic cell pond.
The cyclone electrolytic cell pond connects dilute sulfuric acid storage tank as a further solution of the present invention,.
Blowing plant is installed on the resin reaction tank as a further solution of the present invention,.
The liquid alkaline storage tank, dilute sulfuric acid storage tank, cleaning water storage tank, regeneration as a further solution of the present invention,
Control valve is equipped on the connecting line of dope storage tank and resin reaction tank.
Activity is equipped between the contained waste liquid storage tank and resin reaction tank as a further solution of the present invention,
Charcoal filtering tank
Further object is, proposes that copper recovery system is recycled in a kind of cupric cleaning waste water.
Compared with prior art, the utility model has the beneficial effects that passing through contained waste liquid storage tank, resin reaction tank and tree
Rouge regeneration and copper recyclable device are effectively adequately handled contained waste liquid, and making that treated, waste liquid reaches new discharge mark
Standard can selectively handle copper, and pass through tree using resin of copper reaction absorption copper ion is inhaled from various metals ion
Rouge regeneration and copper recyclable device effectively recycle copper, generate and have valuable copper products, while reply resin reaction tank
Wash cycles are convenient in cleaning, greatly promote the processing and utilization efficiency of cupric cleaning waste water, and the utility model structure is simple, real
With property it is strong, it is easy to use and promote.
Detailed description of the invention
Fig. 1 is the structural schematic diagram that cupric cleans that copper reclaimer and system is recycled in waste water.
Wherein: contained waste liquid storage tank 1, resin reaction tank 2, middle water storage tank 3, liquid alkaline storage tank 4, dilute sulfuric acid storage tank 5, ejected wash water
Storage tank 6, regeneration dope storage tank 7, cyclone electrolytic cell pond 8.
Specific embodiment
The following will be combined with the drawings in the embodiments of the present invention, carries out the technical scheme in the embodiment of the utility model
Clearly and completely describe, it is clear that the described embodiments are only a part of the embodiments of the utility model, rather than whole
Embodiment.Based on the embodiments of the present invention, those of ordinary skill in the art are without making creative work
Every other embodiment obtained, fall within the protection scope of the utility model.
Embodiment 1:
Referring to Fig. 1, in the utility model embodiment, a kind of cupric cleaning waste water is recycled copper reclaimer and is
System, including contained waste liquid storage tank 1, resin reaction tank 2 and resin regeneration and copper recyclable device, the contained waste liquid storage tank 1 pass through
Hose connects resin reactor tank 2, and hose is equipped with pumping.Contained waste liquid storage tank 1 is for storing Korea Spro's contained waste liquid, contained waste liquid storage
Contained waste liquid in tank 1 is extracted by pumping and is delivered in resin reaction tank 2 when working, and is equipped in the resin reaction tank 2
Multiple suction resin of copper columns, inhale resin of copper column in contain a large amount of sodium ion, contained waste liquid in resin reaction tank 2 with resin reaction
Multiple resin columns come into full contact with reaction in tank 2, and ion exchange occurs for the copper in the sodium and waste water in resin column, make copper absorption
On resin, water storage tank 3 in the connection of resin reaction tank 2, the copper after sufficiently reacting in resin reaction tank 2 with resin column contains
Amount is delivered to middle water storage tank 3 less than the waste liquid of 0.1mg/L and stores, and completes the cleaning of contained waste liquid, it is ensured that after contained waste liquid processing
Its copper content is less than 0.1mg/L, reaches discharge standard, and the resin reaction tank 2 connects resin regeneration and copper recyclable device, resin
On the one hand regeneration and copper recyclable device realize the purpose of the recycling to contained waste liquid cleaning, can obtain with economic value
Copper products, on the other hand in resin reaction tank 2 adsorb copper ion resin column timely and effectively cleaned, guarantee resin
Reactor tank 2 is able to carry out repeatedly circulation contained waste liquid cleaning, and in specific works, contained waste liquid is initially stored in contained waste liquid storage
In tank 1, waste liquid is extracted by contained waste liquid storage tank 1 into resin reaction tank 2 by pumping, contained waste liquid is in resin reaction tank 2
It comes into full contact with and reacts with multiple resin columns in resin reaction tank 2, ion exchange, copper occur for the copper in the sodium and waste water in resin
Ionic adsorption has reached the purpose for removing copper ion, the copper content in contained waste liquid is made to decrease below 0.1mg/ on resin
L reaches discharge standard, and treated, and waste liquid is delivered in middle water storage tank 3 is stored, at this point, being recycled by resin regeneration and copper
Device cleans the resin column in resin reaction tank 2, and the copper ion being adsorbed on resin column is sufficiently recycled, and generates
Copper products with economic value, while resin reaction tank 2 being made to can satisfy the purpose of multiple wash cycles, pass through contained waste liquid
Storage tank 1, resin reaction tank 2 and resin regeneration and copper recyclable device are effectively adequately handled contained waste liquid, make to handle
Waste liquid afterwards reaches new discharge standard, using resin of copper reaction absorption copper ion is inhaled, can have choosing from various metals ion
The processing copper of selecting property, and copper is effectively recycled by resin regeneration and copper recyclable device, it generates and has valuable copper production
Product, while resin reaction tank 2 being made to reply cleaning, it is convenient for wash cycles, greatly promotes the processing of cupric cleaning waste water and utilize effect
Rate.
It is equipped with pH detector and electric conductivity detector in the contained waste liquid storage tank 1, is examined by pH detector and conductivity
The design parameter of the contained waste liquid stored in instrument detection contained waste liquid storage tank 1 is surveyed, convenient for accurately opening for contained waste liquid processing work
Exhibition.
The resin regeneration and copper recyclable device include liquid alkaline storage tank 4, dilute sulfuric acid storage tank 5, cleaning water storage tank 6, regeneration it is dense
Liquid storage tank 7 and cyclone electrolytic cell pond 8, the liquid alkaline storage tank 4, dilute sulfuric acid storage tank 5, cleaning water storage tank 6 and regeneration dope storage tank 7 are distinguished
Resin reactor tank 2 is connected by pumping, stores liquid alkaline in liquid alkaline storage tank 4, dilute sulfuric acid, ejected wash water storage are stored in dilute sulfuric acid storage tank 5
Ejected wash water is stored in tank 6, regenerates the copper sulphate dope stored after resin regeneration in dope storage tank 7, the regeneration connection rotation of dope storage tank 7
Electrolytic cell 8 is flowed, is equipped with swirl electrolysis device in cyclone electrolytic cell pond 8, when specific works, to the resin adsorption in resin reaction tank 2
After copper ion saturation, it is conveyed into resin reaction tank 2 by pumping the automatic dilute sulfuric acid for extracting dilute sulfuric acid storage tank 5, dilute sulfuric acid solution
The copper metal being adsorbed on resin is conveyed into tree by pumping the liquid alkaline in automatic extraction liquid alkaline storage tank 4 after resin desorption
In rouge reactor tank 2, resin is made to reply the state before absorption, liquid alkaline completes the purpose of regenerating resin, carries out resin next
Secondary contained waste liquid cleaning, realizes the recycling of resin, is desorbed to resin by dilute sulfuric acid, after liquid alkaline regeneration, passes through pumping
The automatic ejected wash water extracted in cleaning water storage tank 6 is conveyed into resin reaction tank 2, is cleaned remaining impurity in resin, is made subsequent
Adsorption reaction more efficiently carries out, and the copper sulphate dope for having adsorbed copper ion is delivered in regeneration dope storage tank 7 by pumping, then
Raw dope storage tank 7 connects cyclone electrolytic cell pond 8, and copper-bath finally delivers into 8, the cyclone electrolytic cell in cyclone electrolytic cell pond 8
Under the action of device, the copper sulphate dope of 30~40g/L of copper content is electrolysed to copper content 0.5g/L hereinafter, simultaneously output cathode copper
Pipe can have significant economic value with direct marketing.
The cyclone electrolytic cell pond 8 connects dilute sulfuric acid storage tank 5, and the sulfuric acid that cyclone electrolytic cell obtains is completed in cyclone electrolytic cell pond 8
It is delivered in dilute sulfuric acid storage tank 5, is that sulfuric acid realization recycles, saves production and processing cost.
Blowing plant is installed on the resin reaction tank 2, it will be in resin regeneration by blowing plant
It is blown off towards liquid alkaline, dilute sulfuric acid and the ejected wash water in resin reaction tank 2.
The liquid alkaline storage tank 4, dilute sulfuric acid storage tank 5, cleaning water storage tank 6, the company for regenerating dope storage tank 7 and resin reaction tank 2
Adapter tube road is equipped with control valve, recycles the sequence progress of each process for controlling resin regeneration and copper, it is ensured that cupric cleaning
The even running of waste water recycling copper reclaimer.
Embodiment 2:
Referring to Fig. 1, the utility model embodiment is on the basis of embodiment 1, a kind of cupric cleaning waste water circulation is made
Function upgrading is carried out with copper reclaimer and system, specifically:
It is equipped with active carbon filtering tank between the contained waste liquid storage tank 1 and resin reaction tank 2, is equipped in active carbon filtering tank
Multilayer active carbon filter plate effectively filters bulky grain suspended material by multilayer active carbon filter plate, is convenient for resin reaction tank 2
Middle resin is reacted with coming into full contact with for contained waste liquid.
The working principle of the utility model is: contained waste liquid is initially stored in contained waste liquid storage tank 1, by pumping waste liquid
By contained waste liquid storage tank 1 extract into resin reaction tank 2, contained waste liquid in resin reaction tank 2 with it is more in resin reaction tank 2
A resin column comes into full contact with reaction, and ion exchange occurs for the copper in the sodium and waste water in resin, and copper absorption is on resin,
Achieve the purpose that remove copper ion, so that the copper content in contained waste liquid is decreased below 0.1mg/L, reach discharge standard, handles
Waste liquid afterwards is delivered in middle water storage tank 3 and is stored, at this point, by resin regeneration and copper recyclable device in resin reaction tank 2
Resin column cleaned, the copper ion being adsorbed on resin column is sufficiently recycled, generate have economic value copper produce
Product, while resin reaction tank 2 being made to can satisfy the purpose of multiple wash cycles, pass through contained waste liquid storage tank 1, resin reaction tank 2
And resin regeneration and copper recyclable device are effectively adequately handled contained waste liquid, making that treated, waste liquid reaches new row
Standard is put, using resin of copper reaction absorption copper ion is inhaled, copper can be selectively handled from various metals ion, and lead to
It crosses resin regeneration and copper recyclable device effectively recycles copper, generate and have valuable copper products, while making resin reaction tank 2
Cleaning is replied, wash cycles are convenient for, greatly promotes the processing and utilization efficiency of cupric cleaning waste water.
It is obvious to a person skilled in the art that the present invention is not limited to the details of the above exemplary embodiments, and
And without departing substantially from the spirit or essential attributes of the utility model, it can realize that this is practical new in other specific forms
Type.Therefore, in all respects, the present embodiments are to be considered as illustrative and not restrictive, this is practical new
The range of type is indicated by the appended claims rather than the foregoing description, it is intended that containing for the equivalent requirements of the claims will be fallen in
All changes in justice and range are embraced therein.It should not treat any reference in the claims as limiting
Related claim.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (9)
1. a kind of cupric cleaning waste water is recycled copper reclaimer, including contained waste liquid storage tank (1), resin reaction tank (2) and
Resin regeneration and copper recyclable device, which is characterized in that the contained waste liquid storage tank (1) connects resin reactor tank (2), the resin
Multiple suction resin of copper columns, water storage tank (3) in resin reaction tank (2) connection, the resin reaction tank are equipped in reactor tank (2)
(2) resin regeneration and copper recyclable device are connected.
2. copper reclaimer is recycled in cupric cleaning waste water according to claim 1, which is characterized in that the cupric is useless
PH detector and electric conductivity detector are equipped in liquid storage tank (1).
3. copper reclaimer is recycled in cupric cleaning waste water according to claim 1, which is characterized in that the resin is again
Raw and copper recyclable device includes liquid alkaline storage tank (4), dilute sulfuric acid storage tank (5), cleaning water storage tank (6), regeneration dope storage tank (7) and revolves
It flows electrolytic cell (8).
4. copper reclaimer is recycled in cupric cleaning waste water according to claim 3, which is characterized in that the liquid alkaline storage
Tank (4), dilute sulfuric acid storage tank (5), cleaning water storage tank (6) and regeneration dope storage tank (7) pass through pumping connection resin reactor tank respectively
(2), it is stored with liquid alkaline in liquid alkaline storage tank (4), dilute sulfuric acid is stored in dilute sulfuric acid storage tank (5), is stored in cleaning water storage tank (6)
Ejected wash water, regenerates and stores the copper sulphate dope after resin regeneration in dope storage tank (7), and regeneration dope storage tank (7) connects eddy flow
Electrolytic cell (8) is equipped with swirl electrolysis device in cyclone electrolytic cell pond (8).
5. copper reclaimer is recycled in cupric cleaning waste water according to claim 3, which is characterized in that the eddy flow electricity
Xie Chi (8) connection dilute sulfuric acid storage tank (5).
6. copper reclaimer is recycled in cupric cleaning waste water according to claim 1, which is characterized in that the resin is anti-
It answers and blowing plant is installed on tank (2).
7. copper reclaimer is recycled in cupric cleaning waste water according to claim 3, which is characterized in that the liquid alkaline storage
Tank (4), cleaning water storage tank (6), regenerates on the connecting line of dope storage tank (7) and resin reaction tank (2) dilute sulfuric acid storage tank (5)
It is equipped with control valve.
8. copper reclaimer is recycled in cupric cleaning waste water according to claim 1, which is characterized in that the cupric is useless
Active carbon filtering tank is equipped between liquid storage tank (1) and resin reaction tank (2).
9. a kind of cupric cleaning that copper reclaimer is recycled comprising any cupric cleaning waste water of claim 1~8 is useless
Copper recovery system is recycled in water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821683190.1U CN209039547U (en) | 2018-10-17 | 2018-10-17 | Copper reclaimer and system is recycled in a kind of cupric cleaning waste water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821683190.1U CN209039547U (en) | 2018-10-17 | 2018-10-17 | Copper reclaimer and system is recycled in a kind of cupric cleaning waste water |
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| Publication Number | Publication Date |
|---|---|
| CN209039547U true CN209039547U (en) | 2019-06-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201821683190.1U Active CN209039547U (en) | 2018-10-17 | 2018-10-17 | Copper reclaimer and system is recycled in a kind of cupric cleaning waste water |
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| CN (1) | CN209039547U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111635042A (en) * | 2020-06-29 | 2020-09-08 | 江苏净拓环保科技有限公司 | Copper is metal copper recovery unit for waste water purification treatment |
-
2018
- 2018-10-17 CN CN201821683190.1U patent/CN209039547U/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111635042A (en) * | 2020-06-29 | 2020-09-08 | 江苏净拓环保科技有限公司 | Copper is metal copper recovery unit for waste water purification treatment |
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