Background technique
Coal slime is the by-product of coal washing process, since with fine size, moisture is high, the spy that ash content is big and stickiness is high
Point brings biggish difficulty to its comprehensive utilization.Due to lacking effective utilization technology, many coal mines accumulate coal slime discarded.
If coal slime is stored up for a long time, a large amount of soils are not only taken up, and seriously pollute environment.Coal slime particle is very thin, and dehydration is extremely difficult,
After desiccation, flies upward all over the sky to the wind, meets rainwater and trickle everywhere, it is very big to environmental ecology landscape impact.But coal slime has one
Fixed calorific value, the calorific value of some low ash coal mud are even higher than some low heat value thermal coals, and the existing extensive processing mode of coal slime is made
At great energy waste, with the rapid development of coal washing industry, the slime content that China is discharged every year is also quick therewith
Increase, therefore, the harmless treatment of coal slime and resource utilization are extremely urgent;
With a large amount of drawing-off gas, gas is one of the main source of current China's greenhouse gases effect for coal production, by
In technical restriction, the methane gas 70% generated in coal in China production is all directly discharged in atmosphere, with mining depth plus
Greatly, gas and coal seam risk are prominent, and the Coal Mine Disasters such as gas explosion dominate the situation increasingly severe;
How efficiently to solve coal slime accumulation and reduce the discharge of gas in shaft production, tool is exploited and run to coal mining enterprise
It is of great importance.Coal slime and gas all have certain calorific value, if heat recovery and utilization therein has not only been saved resource, and
And reduce production cost.Coal slime replaces coal-fired as boiler oil and carries out burning to utilize being the preferably square of current processing coal slime
Method.Moisture and ash content and lower calorific value due to high-content, coal slime are not suitable for traditional coal-powder boiler burning.Low heat value
For coal resources using circulating fluidized bed boiler is mainly used, coal slime is widely used in circulating fluidized bed combustion.But current coal slime
Circulating fluidized bed boiler has the following problems: (1) pure coal combustion calorific value is low, low efficiency, generally requires and mixes with high heating value coal
It burns, realizes stable operation;(2) coal slime ash content is big, and partial size is small, and simple coal combustion, flying dust amount is big, and circulating ash quantity is insufficient, needs
Burning fat coal is mixed, circulating fluidization is maintained;(3) coal slime water content is high, and moisture is not easy to control, easily forms clod, often adopts at present
Fed with upper furnace, due to coal slime to access point close to furnace outlet, there are a large amount of coal slimes in the case where no after-flame
It is directly fluidized wind and has gone out burner hearth, into separator, and coal slime granularity is small, and separator is captured less than becoming flying dust, lead
It causes the coal slime residence time insufficient, burns insufficient, efficiency of combustion is low;(4) for circulating fluidized bed boiler, bed endoparticle passes through one
The operation of section time, coarse granule sink to emulsion zone, and fine grained becomes flying dust, and the particle of only certain particle size range becomes stable and follows
Ring ash, for stable bed storage, needs regular deslagging.General bottom deslagging share accounts for 30% or more total ash, causes q6(lime-ash
Physics heat loss) heat loss, reduce boiler thermal efficiency.
Utility model content
Existing coal slime processing unit there are aiming at the problem that, the utility model provides a kind of coal slime total system,
It uses that structure is simple, Reaction Separation unit of efficiency of carbon con version and high combustion efficiency in the processing system, passes through reaction chamber knot
Structure adjustment is capable of providing stable coal slime oxidizing temperature, can handle the low heat value poor quality coal slime that ash content is big, partial size is small, realizes coal
Mud minimizing, harmless treatment and efficient resource utilize.It, can be with pure without mixing burning fat coal when handling coal slime using this system
Coal slime is that raw material carries out oxidation burning recycling heat, and coal slime oxidation efficiency and the device thermal efficiency are high, and processing system can grow week
Phase stable operation.
The utility model provides a kind of coal slime processing system, the coal slime processing system include dewatering unit, drying unit,
Reaction Separation unit, flue and gas purification units, the feeding line successively after dewatering unit and drying unit with react
The connection of separative unit entrance, Reaction Separation unit upper outlet are connected to through pipeline with flue entrance, and flue outlet is through pipeline and gas
The connection of body clean unit entrance;The Reaction Separation unit includes air compartment, reaction chamber, separator, material-returning device and steam generation
Device, the steam generation facility include drum and water-cooling wall, and drum is set to the outer top of reactor, and water-cooling wall is set in reactor
Wall;The reaction chamber is divided into heat-accumulation combustion area, soaking zoneofoxidation and separation back-mixing area from the bottom to top;The air compartment and heat-accumulation combustion
Air distribution plate is equipped between area, the air compartment bottom is provided with First air entrance, and the separation bin of the separator is built in separation and returns
In confounding, separator bottom outlet passes through reacting outdoor wall through refeed line and is connected to material-returning device one end, and the material-returning device is another
One end is connected to through pipeline with heat-accumulation combustion area return port, and the separator top exit is connected to through pipeline with flue.
In coal slime processing system described in the utility model, coal slime dewatering to water content can be not more than by the dewatering unit
35wt%, the dewatering unit can use mechanical dehydration or gravity dehydration, preferably mechanical dehydration, specially filter press, belt pressure
One or more of machine, disk vacuum filter, belt vacuum filter, fold belt vacuum filter.
In coal slime processing system described in the utility model, the drying unit is for will be through dewatering unit treated coal slime
It is further dried to water content no more than 15wt%.The drying unit is dry using thermal energy, can be outer hot indirect type or interior heat
Direct contact type, heat source can be flue gas or steam, specially vertical preferably using self-produced steam as the outer heated drying mode of heat source
One or more of formula, horizontal, rotary steam drying.
In coal slime processing system described in the utility model, heat exchange equipment, the heat exchange equipment foundation are equipped in the flue
One or more of actual demand and purposes, including superheater, economizer and air preheater, the superheater, economizer
It is set in turn in flue with air preheater according to flow of flue gas sequence.
In coal slime processing system described in the utility model, the gas purification units include cleaner, desulphurization plant and
One or more of denitration device, the cleaner, desulphurization plant and denitration device are using the existing equipment in this field
Can, it can be dedusting, desulfurization and denitration separate unit, or the dust removal integrated equipment of desulphurization denitration, those skilled in the art
Member can select suitable equipment according to processing requirement, and this selection is easy to those skilled in the art.Such as
One of gravitational precipitator, inertial dust separator, cyclone dust collectors, sack cleaner and electric precipitator, desulfurization may be selected in dedusting
It handles and dry method, semidry method or wet desulphurization equipment may be selected, denitration can be according to being arranged in flue gas NOx emission behaviour selecting reactor
SNCR denitration, flue are arranged SCR denitration facility and in one or more of subsequent setting supplement oxidation denitration devices of flue.
In coal slime processing system described in the utility model, the heat-accumulation combustion area of the reaction chamber is variable-diameter structure, described equal
Thermal oxide area is equal gauge structures, and the lower part in the separation back-mixing area is variable-diameter structure, and top is to wait gauge structures, wherein separating back-mixing
The outer wall of area lower part variable-diameter structure and the angle α of horizontal plane are not less than the angle of repose of handled material.
In coal slime processing system described in the utility model, heat-accumulation combustion area minimum sectional area is S1, soaking zoneofoxidation
Sectional area is S2, and separation back-mixing area maximum secting area is S3, and the ratio of S1:S2:S3 is 1:3/2 ~ 3:2 ~ 5, preferably 2:3:4.
In coal slime processing system described in the utility model, the volume of the temperature adjustment medium bed of material is accumulation of heat in the heat-accumulation combustion area
The 1/3 ~ 2/3 of combustion zone volume.
In coal slime processing system described in the utility model, the indoor heat-accumulation combustion area of the reaction, soaking zoneofoxidation and
The fluidising air velocity in separation back-mixing area is controlled respectively in 4 ~ 8m/s, 3 ~ 6m/s, 2 ~ 4m/s.
In coal slime processing system described in the utility model, the heat-accumulation combustion area and the setting of soaking zoneofoxidation intersection are secondary
Wind entrance, the following are heat-accumulation combustion areas for Secondary Air entrance.
In coal slime processing system described in the utility model, the Secondary Air entrance top is additionally provided with device in Gas entrance, leads to
Crossing setting device in Gas entrance may be implemented to handle low concentration gas simultaneously.
In coal slime processing system described in the utility model, the material-returning device can be automatic adjustment material-returning device or valve
Type material-returning device.
In coal slime processing system described in the utility model, the temperature adjustment medium bed of material is provided in the heat-accumulation combustion area, it is described
The temperature adjustment medium bed of material is made of temperature adjustment media particles, and the temperature adjustment media particles can be by silica, titanium oxide, aluminium oxide, oxygen
Change one or more of lithium, diatomite, feldspar, quartz, cordierite, mullite etc. to be made.The temperature adjustment media particles
Particle size range 0.5 ~ 10 mm, preferably 1 ~ 6mm, the temperature adjustment media particles shape can for spherical shape, sheet, bulk, jujube shape,
One or more of shapes such as cylindrical body can have cellular structure for solid, hollow, surface fluting or inside.Temperature adjustment
1500 ~ 3000 kg/m of bulk density of media particles3, 700 ~ 2000 kg/m of bulk density3.The temperature adjustment media particles have
Big thermal capacity, high thermal conductivity coefficient, high abrasion, the properties such as anti-oxidant, anticorrosive, thermal expansion coefficient is small.The temperature adjustment media particles
2.6 w/m k of thermal capacity > 1300 J/kg k, thermal coefficient >.
In coal slime processing system described in the utility model, the temperature adjustment medium bed of material includes the tune of two or more different-grain diameters
Warm media particles preferably include the temperature adjustment media particles of three kinds of different-grain diameters.When the temperature adjustment medium including two kinds of different-grain diameters
When grain, one of temperature adjustment media particles partial size is 1 ~ 2mm, and another temperature adjustment media particles partial size is 4 ~ 5mm;When including three kinds
When the temperature adjustment media particles of different-grain diameter, the partial size of three kinds of temperature adjustment media particles is respectively 0.5 ~ 1mm, 2 ~ 3mm, 4 ~ 6mm.
In coal slime processing system described in the utility model, the reaction chamber section can be arbitrary shape, such as rectangular, round,
Polygon etc., it is preferably circular.
In coal slime processing system described in the utility model, baffle plate is set in the separation back-mixing area of the reaction chamber, it is described
Baffle plate is arranged one layer or more, and lowest level arrangement of baffles is in the separation above space of back-mixing area reducer, when two layers of setting or more
When baffle plate, adjacent two layers baffle plate interlaced arrangement.The baffle plate can make the material movement direction moved upwards with flue gas
One or many deflections occur, deflection angle is close to or higher than 180 °, to realize the inertial separation of different-grain diameter particle, baffling
Plate can be one of board-type, inclined plate type, groove profile, inverted V type or a variety of, preferably inverted V type baffle plate.
In coal slime processing system described in the utility model, the separation bin of the separator is built in separation back-mixing area reducer
Top, separator bottom outlet pass through separation back-mixing area reducer outer wall through refeed line and are connected to material-returning device one end.
In coal slime processing system described in the utility model, the separator can be cyclone separator and/or inertial separation
Device, preferably cyclone separator.The incising control dp of the separator is not more than 100 μm, and specific incising control is by temperature adjustment medium
Particle size range determines that control dp is less than the smallest particles degree of temperature adjustment media particles, it is ensured that temperature adjustment media particles pass through material-returning device
Reaction chamber heat-accumulation combustion area is returned to be recycled.The separator can be set one or more according to reactor granules load is taken out of
A, when more than two separators are arranged, separator can connect in parallel or series.
In coal slime processing system described in the utility model, the reactor is equipped with feed inlet, and the feed inlet can be direct
It is arranged on heat-accumulation combustion area side wall, also can be set on the pipeline that material-returning device is connected to heat-accumulation combustion area.
In coal slime processing system described in the utility model, the interior heat collecting device is set in reaction chamber separation back-mixing area, into
One step is preferably disposed on separation back-mixing area inner top.
In coal slime processing system described in the utility model, the outer top of the reaction chamber is arranged drum, in drum and reactor
The water-cooling wall of wall laying is connected.Water in water-cooling wall is heated after generation hot water and steam into drum in reaction chamber, and drum is made
Steam after can be used for industrial production or domestic life, and the water in drum continuously recycles supply water-cooling wall.
In coal slime processing system described in the utility model, heat-accumulation combustion area bottom is also provided with slag-drip opening.
Compared with prior art, coal slime processing system described in the utility model has the advantage that
1, in coal slime processing system described in the utility model, the reaction chamber in Reaction Separation unit be divided into heat-accumulation combustion area,
Variable-diameter structure is arranged in soaking zoneofoxidation and separation back-mixing area, the heat-accumulation combustion area and separation back-mixing area, and matches and fire in accumulation of heat
Burn area in be arranged the temperature adjustment medium bed of material, can be realized in reaction chamber different-grain diameter temperature adjustment media particles back-mixing and interior circulation,
Multizone, multithread field, multicycle material movement state are realized, when for leading to when handling big ash content, fine grain coal slime raw material
Cross temperature adjustment media particles heat-accumulation combustion and equal thermal oxidation, realize the stabilization, fully oxidized of big ash content, fine grained raw material,
Thermal stability is good, and load regulation range is big, and without adding the high-quality coal slime raw material of other bulky grains, it is fine grain that pure burning may be implemented
Coal slime raw material;
2, in coal slime processing system described in the utility model, by using the temperature adjustment medium of different-grain diameter in reaction chamber
Grain, can be better achieved coal slime material particles and temperature adjustment media particles surface and its with the quick update that takes hot wall contact surface, oxygen
It is high to change intensity, heat transfer efficiency is high, and the Thermal load of cross-section of heat-accumulation combustion area and soaking zoneofoxidation is up to 6MW/m2More than;
3, in coal slime processing system described in the utility model, the separation back-mixing area of reaction chamber is variable-diameter structure, is greatly increased
Material is reacting the indoor residence time, keeps material fully oxidized, improves 5% or more than conventional fluidization bed boiler burning rate.Into
Baffle plate is arranged inside separation back-mixing area in one step, makes the direction of motion of material that one or many deflections occur, further increases
The residence time of material, material particles crude separation in separation back-mixing area is realized, the processing for reducing rear end separator is negative
Lotus;
4, in coal slime processing system described in the utility model, separator separation bin is built in the separation back-mixing area of reaction chamber
In, it can be avoided external separator heat loss, external separator is omitted separately sets and take that hot measure, coal slime residence time be longer, coal
Mud particle in separator still preferable oxidizing fire temperature, burning more sufficiently, temperature field it is more balanced, the thermal efficiency is significantly
It improves.The main body separation bin of separator is arranged in above separation back-mixing area reducer, and separator refeed line passes through reducer, due to
Refeed line is thinner, will not influence the rough segmentation effect of reducer, takes full advantage of built in separator main body and expands above separation back-mixing area
The excess room of dilute phase section after diameter, material-returning device are external then easy to maintain;
5, the height ratio of circulating fluid bed reactor reaction chamber described in the utility model is the same as the existing recirculating fluidized bed pot of scale
Furnace can reduce by 20% or more, save device steel consumption, significantly reduce cost.
Specific embodiment
The concrete condition of the utility model is further illustrated below by specific embodiment, but is not limited to following implementation
Example.
In the description of the present invention, it should be noted that term " on ", "lower", "inner", "outside", "top", "bottom"
The orientation or positional relationship of equal instructions is to be based on the orientation or positional relationship shown in the drawings, and being merely for convenience of description, this is practical new
Type and simplified description, rather than the device or element of indication or suggestion meaning must have a particular orientation, with specific orientation
Construction and operation, therefore should not be understood as limiting the present invention.In addition, term " first ", " second " are only used for describing
Purpose is not understood to indicate or imply relative importance.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " is set
Have ", " being placed in ", " connected ", " connection ", " installation " etc. shall be understood in a broad sense, for example, it may be being fixedly connected, being also possible to can
Dismantling connection, or be integrally connected;It can be mechanical connection, be also possible to be electrically connected;It can be directly connected, can also pass through
Intermediary is indirectly connected, and can be the connection inside two elements.For the ordinary skill in the art, can have
Body situation understands the concrete meaning of above-mentioned term in the present invention.
As depicted in figs. 1 and 2, the utility model provides a kind of coal slime processing system, and the coal slime processing system includes de-
Water unit 21, drying unit 22, Reaction Separation unit 23, flue 24 and gas purification units 25, the dewatering unit can be adopted
With mechanical dehydration or gravity dehydration, preferably mechanical dehydration, specially filter press, band press, disk vacuum filter, belt is true
One or more of empty filter, fold belt vacuum filter;The drying unit is dry using thermal energy, can be for outer heat indirectly
Formula or interior hot direct contact type, heat source can be flue gas or steam, preferably using self-produced steam as the outer heated drying mode of heat source, tool
Body is one or more of vertical, horizontal, rotary steam drying.The raw material is through feeding line 20 successively through dewatering unit
21 and drying unit 22 after be connected to 23 entrance of Reaction Separation unit, Reaction Separation unit 23 export through pipeline and 24 entrance of flue
It is connected to, is disposed with superheater 26, economizer 27 and air preheater 28 according to flow of flue gas direction in the flue 24;Cigarette
The outlet of road 24 is connected to through pipeline with 25 entrance of gas purification units;The Reaction Separation unit 23 include reaction chamber 1, separator 2,
Material-returning device 4, air compartment 7, drum 6 and water-cooling wall, drum 6 are set to the outer top of reactor, and water-cooling wall is laid in reactor wall
(water-cooling wall is not drawn into Fig. 2, is those skilled in the art's common knowledge);The reaction chamber 1 be divided into from the bottom to top heat-accumulation combustion area A,
Soaking zoneofoxidation B and separation back-mixing area C;Air distribution plate 8, the wind are equipped between the air compartment 7 and the heat-accumulation combustion area A of reaction chamber
7 bottom of room is provided with First air entrance 11, and the temperature adjustment medium bed of material, the temperature adjustment medium material are provided in the heat-accumulation combustion area A
Layer is made of temperature adjustment media particles, and slag-drip opening 16 is arranged in bottom in heat-accumulation combustion area A, and heat-accumulation combustion area A and soaking zoneofoxidation B are handed over
Secondary Air entrance 12 is set at boundary, and Secondary Air entrance is provided with watt the following are heat-accumulation combustion area A on the side wall of soaking zoneofoxidation B
This gas entrance 13, device in Gas entrance 13 are located at 12 top of Secondary Air entrance, are provided with baffling above separation back-mixing area C reducer
Plate 18, separation back-mixing area C inner top are provided with interior heat collecting device 5, and shown interior heat collecting device 5 can be superheater, the separator 2
Main body separation bin is built in the separation back-mixing area C of reaction chamber 1, and the main body separation bin of further separator 2 is arranged in separation and returns
Above the reducer of confounding C, 2 outlet at bottom of separator passes through reacting outdoor wall through refeed line 3 and is connected to 4 one end of material-returning device,
Further 2 outlet at bottom of separator passes through the reducer outer wall and material-returning device 4 of reaction chamber separation back-mixing area C through refeed line 3
One end connection, 4 other end of material-returning device are connected to the return port 17 of heat-accumulation combustion area A through pipeline, are equipped at the top of separator 2
Material outlet 15, material outlet 15 pass through reactor outer wall by pipeline and are connected to flue 24, and the feed inlet 14 is directly arranged
On heat-accumulation combustion area A side wall, or it is arranged on the refeed line 3 that material-returning device 4 is connected to the heat-accumulation combustion area A of reaction chamber 1.
Feed inlet 14 and return port 17 are lower than overfiren air port 12, and device in Gas entrance 13 is slightly above overfiren air port 12.
When in use, specific work process is as follows for coal slime processing system described in the utility model:
Raw material coal slime first passes around dewatering unit and drying unit and is slightly dehydrated and is dried, coal slime that treated into
Enter Reaction Separation unit, coal slime enters the reaction chamber of Reaction Separation unit from feed inlet, successively in heat-accumulation combustion area, equal thermal oxide
Area and separation back-mixing area internal oxidition burning processing, wherein releasing heat is more in heat-accumulation combustion area, and the heat of generation is by larger
The temperature adjustment media particles accumulation of heat of partial size absorbs;Material and temperature adjustment media particles compared with small particle continue with the flue gas generated after burning
Soaking zoneofoxidation is flowed up into, further occurrence aoxidizes under the supplement of Secondary Air;When material enters separation back-mixing area, by
Increase in gas flow area, flow velocity reduces, and the gas residence time for carrying particle increases, when the ash content in flue gas has enough
Between complete reaction, while baffle plate separation assembly effect under, biggish particles fall, with flue gas realize initial gross separation, due to
The difference of fluidizing velocity forms interior circulation in reaction chamber, enhances the mixing of transverse direction and longitudinal direction.Material and temperature adjustment medium exist
It is sufficiently mixed in flow process, the two constantly collides and rubs, so that larger particles material is under the action of temperature adjustment medium
Gradually be crushed, become smaller, and temperature adjustment medium is due to itself having certain rigidity loss smaller, it is subsequent can be from when flowing through separator
It is separated and recycles in flue gas.Temperature adjustment medium constantly absorbs material and aoxidizes discharged heat, maintains reaction Indoor Temperature
Degree makes newly to be brought rapidly up simultaneously oxidizing fire into the material of reaction chamber at 800 ~ 950 DEG C;Temperature adjustment medium and material are abundant simultaneously
Mixing and fluidisation, by a large amount of heat pass to reaction chamber surrounding water-cooling wall and separate back-mixing area in be arranged take thermal, both will
Heat effective use, and avoid reaction room temperature is excessively high from causing coking and generate thermal NO x.The flue gas of particle is carried from anti-
It is further separated after answering room separation back-mixing area to enter separator, as built in separator, is able to maintain that preferable oxidizing temperature, cigarette
Further oxidation ensures after-flame to carbon residue in separator in gas flying dust, while material particles and temperature adjustment medium are passed through from separator tail portion
Refeed line and material-returning device return in reaction chamber, and the flue gas after separation enters cigarette below from separator outlet discharge reactor
Road;After flue gas enters flue, high-temperature flue gas passes sequentially through the superheater, economizer and air preheater being arranged in flue and carries out
Heat exchange, recovered flue gas thermal energy, flue gas is again after gas purification units are handled out, qualified discharge.