CN208567497U - A kind of nickelic ternary material sintering rotary furnace - Google Patents

A kind of nickelic ternary material sintering rotary furnace Download PDF

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Publication number
CN208567497U
CN208567497U CN201820895434.6U CN201820895434U CN208567497U CN 208567497 U CN208567497 U CN 208567497U CN 201820895434 U CN201820895434 U CN 201820895434U CN 208567497 U CN208567497 U CN 208567497U
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CN
China
Prior art keywords
boiler tube
nickelic ternary
ternary material
rotary furnace
material sintering
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Expired - Fee Related
Application number
CN201820895434.6U
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Chinese (zh)
Inventor
张保平
于伟
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Fujian Kingsoft Lithium-New Materials Co Ltd
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Fujian Kingsoft Lithium-New Materials Co Ltd
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Priority to CN201820895434.6U priority Critical patent/CN208567497U/en
Application granted granted Critical
Publication of CN208567497U publication Critical patent/CN208567497U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The utility model discloses a kind of nickelic ternary material sintering rotary furnaces, it includes furnace body, the boiler tube for being arranged in the furnace interior, the boiler tube is set as compound boiler tube, the compound boiler tube includes heat resisting steel or high-temperature nickel-base alloy outer layer, inorganic binder middle layer and ceramic inner layer, and its length extending direction is provided with spiral stock guide in the boiler tube;The corrosion of ceramic inner layer alkali resistance, and it will not be with material reaction when contacting with material, this structure of boiler tube, so that the utility model rotary furnace can be used for the sintering of nickelic ternary material, and when being sintered, material rotates in boiler tube, realizes dynamic sinter, to which more energy efficient, production capacity is higher, pollute also fewer;The setting of spiral stock guide can accelerate the sintering velocity of material.

Description

A kind of nickelic ternary material sintering rotary furnace
Technical field
The utility model relates to nickelic ternary material sintering equipment more particularly to nickelic ternary material sintering to turn round Furnace.
Background technique
Tertiary cathode material is because of its energy density with higher, low self-discharge rate, memory-less effect, excellent circulation The advantages that service life and relatively low price, have become the first choice of power battery, especially nickelic tertiary cathode material exists Schedule has been put in application on power battery, nickelic ternary material be expected to be widely used as in the near future lithium from The positive electrode of sub- power battery.
Currently, the nickelic ternary material of industrialization mainly passes through roller kilns or pushed bat kiln sintering, nickelic ternary is being prepared just Oxygen is needed to participate in when the material of pole to complete sintering reaction, when traditional roller kilns or pushed bat kiln are sintered, material is mounted in saggar, Material is stationary state, for static sintering, is sintered the diffusion mainly by oxygen, this sintering processing will lead to material and connect with oxygen Touch insufficient, oxygen diffusion is comparatively more difficult, and the material on saggar surface layer can come into full contact with oxygen, but the object of saggar bottom Expect that the oxygen that touches just than relatively limited, is unfavorable for being sintered, even logical pure oxygen sintering, the charge of material is also very limited, Production capacity is relatively low, and the material property consistency of products obtained therefrom saggar upper and lower level different location is poor, and consumption oxygen is more, sintering Required time is longer, and a large amount of electric energy are consumed in sintering process, and properties of product are not good enough and supervene largely discarded saggar, is It says, energy consumption is high, and production capacity is low, and largely discards saggar and also can cause environmental pollution.
So rotary furnace is the ideal sintering type of furnace, above-mentioned subproblem can solve, but nickelic ternary material exists It is strong basicity environment during sintering, there is oxygen participation, and a large amount of moisture is discharged, existing rotary furnace boiler tube is not resistant to Alkaline corrosion, and be easy and material reacts, can not be sintered so as to cause material, so traditional rotary furnace on the market at present It cannot be used for the sintering of nickelic ternary material.
Utility model content
The purpose of the utility model is to overcome disadvantages mentioned above, provide a kind of nickelic ternary material sintering rotary furnace, It is able to achieve the dynamic sinter of nickelic ternary material, and energy consumption is low, production capacity is high, does not pollute the environment also.
To achieve the above object, the technical scheme adopted by the utility model is
A kind of nickelic ternary material sintering rotary furnace, including furnace body, the boiler tube being arranged in the middle part of the furnace body, the furnace Pipe is set as compound boiler tube, the compound boiler tube include heat resisting steel or high-temperature nickel-base alloy outer layer, inorganic binder middle layer with And ceramic inner layer, and its length extending direction is provided with spiral stock guide in the boiler tube.
The ceramic inner layer and the spiral stock guide are integrally formed.
The ceramic inner layer is set as corundum ceramic internal layer.
Magnetic seal has end cap, and side end cap setting air inlet and feed inlet, another side respectively at the both ends of the boiler tube Lid setting exhaust outlet and discharge port.
The furnace body includes the heater strip being set around outside the boiler tube, covers at refractory fibre outside the heater strip, cover Thermal insulation layer outside the refractory fibre covers at steel shell outside the thermal insulation layer.
The nickelic ternary material sintering rotary furnace further includes support unit, and the furnace body can be connected to the relative rotation Above the support unit.
The nickelic ternary material sintering rotary furnace further includes for controlling the heater strip heating temperature and furnace body The control unit of rotation.
The utility model has the following beneficial effects: the compound boiler tube of the utility model rotary furnace efficiently solves under alkaline environment Material is to the etching problem of boiler tube, so that the utility model rotary furnace can be used for being sintered nickelic tertiary cathode material;In addition, revolution Boiler tube is rotating always when furnace sintered material, i.e. dynamic sinter, this mode, so that material is contacted with oxygen and more filled when sintering Point, thus this problem of the inconsistency of material property of saggar upper and lower level different location when solving traditional static sintering, So that the production capacity for being sintered nickelic ternary material is improved, preparation time is shortened, saves oxygen and electric energy, improves institute The consistency of performance of product is obtained, while saving the usage amount of saggar, reduces pollution;Spiral stock guide is provided with conducive to object Material is pushed ahead in boiler tube rotation according to certain speed, to can not only accelerate the sintering velocity of material, shortens preparation Time further increases production capacity, but also without tilting the boiler tube and furnace body when being discharged after may make material to be sintered.
Detailed description of the invention
Fig. 1 is the schematic diagram of the nickelic ternary material sintering rotary furnace of the utility model;
Fig. 2 is the cross-sectional view that the nickelic ternary material sintering of the utility model turns round furnace body and boiler tube part.
Specific embodiment
As shown in Figure 1, 2, the nickelic ternary material sintering rotary furnace of the utility model includes furnace body 1, is arranged in the furnace The boiler tube 2 at 1 middle part of body, the boiler tube 2 are set as compound boiler tube 2, and the compound boiler tube 2 includes heat resisting steel or high-temperature nickel-base alloy Outer layer 21, inorganic binder middle layer 22 and ceramic inner layer 23, and be provided in the boiler tube 2 along its length extending direction Spiral stock guide 24.
The outer layer of the boiler tube 2 is set as the heat resisting steel or high-temperature nickel-base alloy outer layer 21 of alkali resistance, plays knot to boiler tube 2 Structure supporting role;Middle layer is inorganic bond oxidant layer, can buffer heat resisting steel or high-temperature nickel-base alloy outer layer 21 and ceramic inner layer Equal thermal shocks of expanding with heat and contract with cold between 23, while inorganic binder has good thermal conductivity, can be good at conducting heat;Ceramics The corrosion of 23 alkali resistance of internal layer, and when it is contacted with material, will not be with material reaction.This structure of boiler tube 2, so that this is practical Novel rotation furnace can be used for the sintering of nickelic ternary material;Spiral stock guide 24 is provided with conducive to material when boiler tube 2 rotates It is pushed ahead according to certain speed, to can not only accelerate the sintering velocity of material, shortens preparation time, further increase Production capacity, but also without tilting the boiler tube 2 and furnace body 1 when being discharged after may make material to be sintered.
Preferably, the ceramic inner layer and the spiral stock guide are integrally formed.During actual fabrication, can first it adopt Ceramic inner layer and spiral stock guide is made with connecting method, then firing forms together.
In the present embodiment, the ceramic inner layer 23 is set as corundum ceramic internal layer.
Magnetic seal has end cap 3, and side end cap setting air inlet 31 and feed inlet respectively at the both ends of the boiler tube 2, another Exhaust outlet 32 and discharge port is arranged in side end cap.
The furnace body 1 includes the heater strip 11 being set around outside the boiler tube 2, to cover at fire resisting outside the heater strip 11 fine Dimension 12 covers at thermal insulation layer 13 outside the refractory fibre 12, covers at the steel shell 14 outside the thermal insulation layer 13.Furnace body 1 this Kind structure, enables the generated heat of heater strip 11 farthest all to pass to boiler tube 2, to save electric energy.
The nickelic ternary material sintering rotary furnace of the utility model further includes support unit 4, and the furnace body 1 can relative rotation Ground is connected to 4 top of support unit.
The nickelic ternary material sintering rotary furnace of the utility model further includes for controlling 11 heating temperature of heater strip And the control unit (not shown) that furnace body 1 rotates.
For the sintering temperature of the utility model rotary furnace at 500 to 850 DEG C, difference can be made in furnace body 1 according to actual needs Specification size, compound boiler tube 2 can also be fabricated to different sizes, shape.
The working principle of the utility model are as follows:
Material enters in boiler tube 2 from raw material cabin 5 through a side end cap feed inlet, and oxygen enters in boiler tube 2 from air inlet, boiler tube 2 with furnace body 1 when rotating together, and material rotates in boiler tube 2, and pushes away according to certain speed to the other side along helicla flute Into sintered material is most discharged in feed bin 6 through discharge port afterwards.
As described above, the compound boiler tube 2 of the utility model rotary furnace efficiently solves under alkaline environment material to boiler tube 2 Etching problem, so that the utility model rotary furnace can be used for being sintered nickelic tertiary cathode material;In addition, furnace when rotary furnace sintered material Pipe 2 is rotating always, i.e. dynamic sinter, this mode, so that material contacts more abundant with oxygen when sintering, solves traditional This problem of the inconsistency of material property of saggar upper and lower level different location when static state sintering, so that being sintered nickelic ternary material Production capacity be improved, shorten preparation time, save oxygen and electric energy, improve the consistency of performance of products obtained therefrom, The usage amount for saving saggar simultaneously, reduces pollution.

Claims (7)

1. a kind of nickelic ternary material sintering rotary furnace, including furnace body, it is arranged in the boiler tube of the furnace interior, feature exists In: the boiler tube is set as compound boiler tube, and the compound boiler tube includes heat resisting steel or high-temperature nickel-base alloy outer layer, inorganic binder Middle layer and ceramic inner layer, and its length extending direction is provided with spiral stock guide in the boiler tube.
2. nickelic ternary material sintering rotary furnace according to claim 1, it is characterised in that: the ceramic inner layer and institute It is integrally formed to state spiral stock guide.
3. nickelic ternary material sintering rotary furnace according to claim 1 or 2, it is characterised in that: the ceramic inner layer It is set as corundum ceramic internal layer.
4. nickelic ternary material sintering rotary furnace according to claim 3, it is characterised in that: the both ends of the boiler tube point Other magnetic seal has end cap, and side end cap setting air inlet and feed inlet, another side end cap setting exhaust outlet and discharge port.
5. nickelic ternary material sintering rotary furnace according to claim 1 or 2 or 4, it is characterised in that: the furnace body packet The heater strip being set around outside the boiler tube is included, refractory fibre outside the heater strip is covered at, covers at outside the refractory fibre Thermal insulation layer, cover at steel shell outside the thermal insulation layer.
6. nickelic ternary material sintering rotary furnace according to claim 5, it is characterised in that: it further include support unit, The furnace body can be connected to the relative rotation above the support unit.
7. nickelic ternary material sintering rotary furnace according to claim 6, it is characterised in that: further include for controlling State the control unit of heater strip heating temperature and furnace body rotation.
CN201820895434.6U 2018-06-11 2018-06-11 A kind of nickelic ternary material sintering rotary furnace Expired - Fee Related CN208567497U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201820895434.6U CN208567497U (en) 2018-06-11 2018-06-11 A kind of nickelic ternary material sintering rotary furnace

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Application Number Priority Date Filing Date Title
CN201820895434.6U CN208567497U (en) 2018-06-11 2018-06-11 A kind of nickelic ternary material sintering rotary furnace

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110530147A (en) * 2019-07-30 2019-12-03 佛山市天禄智能装备科技有限公司 A kind of high-temperature rotary furnace for the production of lithium battery anode high-nickel material continuous production
CN112146432A (en) * 2019-06-26 2020-12-29 康荷 Electric heating kiln furnace body structure with built-in spiral track propelling groove
CN112747590A (en) * 2019-10-30 2021-05-04 中国石油化工股份有限公司 Dynamic synthesis device and dynamic synthesis method for ternary materials of lithium ion battery
CN113416086A (en) * 2021-06-18 2021-09-21 湖南金硅科技有限公司 Rotary furnace carbon ceramic furnace tube for CVD carbon vapor deposition, rotary furnace and preparation method of carbon ceramic furnace tube

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112146432A (en) * 2019-06-26 2020-12-29 康荷 Electric heating kiln furnace body structure with built-in spiral track propelling groove
CN112146432B (en) * 2019-06-26 2023-05-02 康荷 Electric heating kiln body structure with built-in spiral track propulsion groove
CN110530147A (en) * 2019-07-30 2019-12-03 佛山市天禄智能装备科技有限公司 A kind of high-temperature rotary furnace for the production of lithium battery anode high-nickel material continuous production
CN112747590A (en) * 2019-10-30 2021-05-04 中国石油化工股份有限公司 Dynamic synthesis device and dynamic synthesis method for ternary materials of lithium ion battery
CN113416086A (en) * 2021-06-18 2021-09-21 湖南金硅科技有限公司 Rotary furnace carbon ceramic furnace tube for CVD carbon vapor deposition, rotary furnace and preparation method of carbon ceramic furnace tube

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Granted publication date: 20190301

Termination date: 20210611