CN208292875U - A kind of selfreparing multifunctional glass - Google Patents

A kind of selfreparing multifunctional glass Download PDF

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Publication number
CN208292875U
CN208292875U CN201820749347.XU CN201820749347U CN208292875U CN 208292875 U CN208292875 U CN 208292875U CN 201820749347 U CN201820749347 U CN 201820749347U CN 208292875 U CN208292875 U CN 208292875U
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glass
selfreparing
resin layer
base
self
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CN201820749347.XU
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秦世明
赵光勇
赵洁
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Feiyao Technology Zhejiang Co ltd
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Zhejiang Xixi Glass Co Ltd
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Abstract

The utility model relates to a kind of glass, more particularly, to a kind of selfreparing multifunctional glass.The selfreparing multilayer insulation glass includes several glass-bases, and the glass-base upper and lower end faces are coated with self-repair resin layer, is additionally provided with one layer of silica aerogel among the glass-base that adjacent two panels is coated with self-repair resin layer;In the glass-base coated with self-repair resin layer, one layer of super-hydrophobic coat is additionally provided on the outside of the self-repair resin layer in outermost glass-base.The utility model has the following beneficial effects: cullet will not be made to fall after (1) glass breaking;(2) glass glue will not be cured in advance, to can repair in time after broken;(3) use vdiverse in function that can satisfy in a variety of situations.

Description

A kind of selfreparing multifunctional glass
Technical field
The utility model relates to a kind of glass, more particularly, to a kind of selfreparing multifunctional glass.
Background technique
Glass is amorphous inorganic non-metallic material, and usually with a variety of inorganic minerals, (such as quartz sand, borax, boric acid, weight are brilliant Stone, barium carbonate, lime stone, feldspar, soda ash etc.) it is primary raw material, it additionally incorporates made of a small amount of auxiliary material.It it is main at It is divided into silica and other oxides.The chemical composition of simple glass is Na2SiO3, CaSiO3, SiO2 or Na2OCaO 6SiO2 etc., main component are silicate double salt, are a kind of non-crystalline solids of random structure.It is widely used in building, uses To belong to mixture every wind light transmission.The usual matter of glass is hard and crisp, often chipping when being hit, to threaten The life security of user, and its it is chipping after can not often repair, be merely able to be replaced, to increase use Cost.
Selfreparing (Self-repairing) material is a branch of intellectual material, it simulates biological bulk damage and reviews one's lessons by oneself Multiple mechanism carries out self-regeneration to the damage that material generates in use.In numerous self-repair materials, it can protect Substrate and can assign substrate property coatings research and development have become scientific circles concern hot spot, it is leading The fields such as electrocoat, corrosion-inhibiting coating, scratch resistant coatings have a wide range of applications, and especially have harsh conditions some, it is difficult to The extraordinary adhesive coating applied in the high leading-edge field of maintenance such as aerospace and military ocean, marine drilling platform and ground The fields such as the corrosion-inhibiting coatings such as lower petroleum pipeline suffer from urgent demand.
Coatings mainly include that Intrinsical coatings and foreign aid's type review one's lessons by oneself overcoating by Type division is repaired at present Layer.
Intrinsical selfreparing is to be not required to additional reparation system, but coating material itself contains special chemical bond or other Physicochemical properties such as reversible covalent bonds, non-covalent bond, molecule diffusion etc. realize self-repair function.This method is independent of reparation Agent eliminates the complex steps such as preparatory renovation agent embedding techniques, and small on substrate performance influence, but to coated substrate material molecule Structure design is the ultimate challenge that this method faces.
Foreign aid's type coatings refer in coated substrate by introducing extraneous component such as containing the micro- of renovation agent system Capsule, carbon nanotube, microvascular, glass fibre or nanoparticle etc. realize self-repair function, and this method need to be by various renovation agents System embeds in advance, is then added in matrix, when damage of material, under environmental stimuli (power, pH value, temperature etc.) effect Cause the renovation agent of damage field to discharge, to realize selfreparing, has become research emphasis at present.
So if self-repair technology can be introduced into glass, enable glass can be certainly in the case where fragmentation I repairs, and can not only effectively reduce economic expenditure, can more ensure the life security of user.
Such as a kind of disclosed in the Chinese patent literature a kind of screen glass and preparation method of selfreparing, application are public Cloth number is CN106746746A, and the screen glass of selfreparing includes the figure and glass glue of glass board material, micron level, glass The figure of micron level is made on one of face of glass plate material, fills full glass glue in other figure in the micron-scale, so The figure of the micron level on glass board material is subjected to Seal treatment to form closed cavity afterwards.Adhesive of the invention is direct It is stored in the microcavity of glass matrix, when crackle generates, due to siphonage, the adhesive of mobility can reach in time to be split Line position can obtain good calking effect, and then play excellent self-repair function.Spontaneous identification can be achieved in the invention The function of screen glass micro-crack and spontaneous reparation micro-crack, is able to extend the service life of screen glass, is also able to solve screen The problem of curtain glass is also easy to produce crackle and then broken screen in use.But there is also its shortcomings for the invention, such as Its glass board material is single layer structure, is easy after being crushed so that glass fragment is fallen, to can not repair, furthermore glass glue It is easy solidification in the case where no protection, so that the effect of reparation is not achieved, and its function is more single, is unable to satisfy a variety of In the case of use.
Utility model content
The utility model be in order to overcome in the prior art selfreparing glass cullet after broken be easy to fall, thus nothing Method is repaired in time, and glass glue is easy to be cured in advance, is unable to reach the purpose of reparation, and function is more single, can not The problem of meeting the use in a variety of situations, providing after one kind enables to glass breaking will not make cullet fall, glass Adhesive will not be cured in advance, to can repair in time after broken, and vdiverse in function can satisfy in a variety of situations Use.
To achieve the goals above, the utility model uses following technical scheme:
A kind of selfreparing multifunctional glass, the selfreparing multilayer insulation glass includes several glass-bases, described Glass-base upper and lower end faces are coated with self-repair resin layer, are coated with the glass base of self-repair resin layer in adjacent two panels Layer is intermediate to be additionally provided with one layer of silica aerogel;In the glass-base coated with self-repair resin layer, it is in outermost glass One layer of super-hydrophobic coat is additionally provided on the outside of the self-repair resin layer of glass base.
It ensure that glass coated with self-repair resin layer using on two end faces of glass-base in the utility model Base can effectively play repair after rupturing, and whichever face has occurred fragmentation resin for restoration and can seep Enter to be repaired.Furthermore aerogel layer is set, the utility model is enabled to have the effect of heat-insulating sound-insulating, increases its application Type.One layer of super-hydrophobic coat is additionally provided on the outside of the self-repair resin layer of outermost glass-base enables to selfreparing simultaneously Resin layer is completely cut off with oxygen, to prevent the oxidative cure of active principle in resin for restoration layer, ensure that its validity, Super-hydrophobic coat, which is arranged, simultaneously enables to dirt not to be adhered on glass, to ensure that the cleaning of glass.
Preferably, being additionally provided with a microcorrosion layer on described two end faces of glass-base.
Preferably, in the glass-base in microcorrosion layer containing inside oriented glass-base to the corrosion of lower recess Hole, the downward cup depth of the etch pit are 5-50 μm.
Setting microcorrosion layer can effectively make glass-base and self-repair resin layer be in close contact, and increase two layers Bond strength, while capsule of nano can be also accommodated in etch pit, thus the photosensitive resin after fragmentation in capsule of nano It can fill up in crack at once, achieve the purpose that reparation.
Preferably, the self-repair resin layer includes binding resin layer, it is equipped with inside the binding resin layer close Like the capsule of nano of spherical shape.
Preferably, the capsule of nano includes the silica gel outer shell that can completely cut off ultraviolet light, and it is encapsulated in silicon Photosensitive resin inside glue outer shell.
Silica gel outer shell in the utility model have the function of obstruct ultraviolet light, can protection packaging in silica gel outer shell Internal photosensitive resin will not be cured because of daily solar irradiation, to influence repairing performance.
Preferably, the diameter of the capsule of nano is 5000-10000nm.
Preferably, the capsule of nano can be effectively in etch pit.
Therefore, the utility model has the following beneficial effects: cullet will not be made to fall after (1) glass breaking;(2) glass Glass adhesive will not be cured in advance, to can repair in time after broken;(3) vdiverse in function to can satisfy a variety of situations Under use.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of the utility model.
Fig. 2 is the structural schematic diagram of the glass-base of the utility model.
Fig. 3 is the microcorrosion layer micro-structure diagram of the utility model.
Fig. 4 is the structural schematic diagram of the self-repair resin layer of the utility model.
Fig. 5 is the structural schematic diagram of the utility model capsule of nano.
Wherein: glass-base 1, self-repair resin layer 2, silica aerogel 3, super-hydrophobic coat 4, microcorrosion layer 5, etch pit 6, Binding resin layer 7, capsule of nano 8, silica gel outer shell 9, photosensitive resin 10.
Specific embodiment
The utility model is further described with specific embodiment with reference to the accompanying drawing.
In embodiment as shown in Figs. 1-5, a kind of selfreparing multifunctional glass, the selfreparing multilayer insulation glass bag Several glass-bases 1 are included, 1 upper and lower end faces of glass-base are coated with self-repair resin layer 2, apply in adjacent two panels It is covered among the glass-base 1 of self-repair resin layer 2 and is additionally provided with one layer of silica aerogel 3;Described is coated with self-repair resin layer 2 Glass-base 1 in, one layer of super-hydrophobic coat 4 is additionally provided on the outside of the self-repair resin layer 1 in outermost glass-base 2.
It is additionally provided with a microcorrosion layer 5 on described 1 two end faces of glass-base, contains in the microcorrosion layer 5 oriented To the etch pit of lower recess 6 inside glass-base 1, the downward cup depth of etch pit 6 is 5-50 μm.
The self-repair resin layer 2 includes binding resin layer 7, and approximate spherical shape is equipped with inside the binding resin layer Capsule of nano 8,8 diameter of capsule of nano be 5000-10000nm comprising the silica gel of ultraviolet light can be completely cut off Outer shell 9, and it is encapsulated in the photosensitive resin 10 inside silica gel outer shell, the capsule of nano can be effectively embedded in corruption In borrosion hole.

Claims (7)

1. a kind of selfreparing multifunctional glass, characterized in that the selfreparing multilayer insulation glass includes several glass-bases, The glass-base upper and lower end faces are coated with self-repair resin layer, are coated with self-repair resin layer in adjacent two panels One layer of silica aerogel is additionally provided among glass-base;In the glass-base coated with self-repair resin layer, in outermost One layer of super-hydrophobic coat is additionally provided on the outside of the self-repair resin layer of the glass-base of side.
2. a kind of selfreparing multifunctional glass according to claim 1, characterized in that described two end faces of glass-base On be additionally provided with a microcorrosion layer.
3. a kind of selfreparing multifunctional glass according to claim 1 or 2, characterized in that micro- in the glass-base Containing, to the etch pit of lower recess, the downward cup depth of the etch pit is 5-50 μm inside oriented glass-base in corrosion layer.
4. a kind of selfreparing multifunctional glass according to claim 1, characterized in that the self-repair resin layer includes Binding resin layer, the binding resin layer inside are equipped with the capsule of nano of approximate spherical shape.
5. a kind of selfreparing multifunctional glass according to claim 4, characterized in that the capsule of nano includes energy Enough completely cut off the silica gel outer shell of ultraviolet light, and is encapsulated in the photosensitive resin inside silica gel outer shell.
6. a kind of selfreparing multifunctional glass according to claim 4 or 5, characterized in that the capsule of nano Diameter is 5000-10000nm.
7. a kind of selfreparing multifunctional glass according to claim 6, characterized in that the capsule of nano can have Effect is embedded in etch pit.
CN201820749347.XU 2018-05-18 2018-05-18 A kind of selfreparing multifunctional glass Active CN208292875U (en)

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CN201820749347.XU CN208292875U (en) 2018-05-18 2018-05-18 A kind of selfreparing multifunctional glass

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Application Number Priority Date Filing Date Title
CN201820749347.XU CN208292875U (en) 2018-05-18 2018-05-18 A kind of selfreparing multifunctional glass

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CN208292875U true CN208292875U (en) 2018-12-28

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111908810A (en) * 2020-06-23 2020-11-10 江苏铁锚玻璃股份有限公司 Liquid self-repairing hydrophobic glass based on negative pressure technology
CN112216206A (en) * 2019-07-09 2021-01-12 陕西坤同半导体科技有限公司 Glass cover plate, flexible display screen and display device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112216206A (en) * 2019-07-09 2021-01-12 陕西坤同半导体科技有限公司 Glass cover plate, flexible display screen and display device
CN111908810A (en) * 2020-06-23 2020-11-10 江苏铁锚玻璃股份有限公司 Liquid self-repairing hydrophobic glass based on negative pressure technology

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GR01 Patent grant
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Effective date of registration: 20220507

Address after: No. 128, doumenba, Xigang village, Yuyue Town, Deqing County, Huzhou City, Zhejiang Province, 313213

Patentee after: Zhejiang Taiming Glass Technology Co.,Ltd.

Address before: 313200 No. 505, hanghai Road, Yuyue Town, Deqing County, Huzhou City, Zhejiang Province

Patentee before: ZHEJIANG XIXI GLASS Co.,Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20221212

Address after: No. 20-1, Lingang Avenue, Daixi Town, Wuxing District, Huzhou City, Zhejiang Province 313000

Patentee after: Feiyao Technology (Zhejiang) Co.,Ltd.

Address before: No. 128, doumenba, Xigang village, Yuyue Town, Deqing County, Huzhou City, Zhejiang Province, 313213

Patentee before: Zhejiang Taiming Glass Technology Co.,Ltd.

TR01 Transfer of patent right