CN207995835U - Water purification system - Google Patents

Water purification system Download PDF

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Publication number
CN207995835U
CN207995835U CN201820195670.7U CN201820195670U CN207995835U CN 207995835 U CN207995835 U CN 207995835U CN 201820195670 U CN201820195670 U CN 201820195670U CN 207995835 U CN207995835 U CN 207995835U
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China
Prior art keywords
water
ion
bubble
gas
micro
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Expired - Fee Related
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CN201820195670.7U
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Chinese (zh)
Inventor
吴正新
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Guangdong Wate Soil Remediation Research Center Co Ltd
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Guangdong Wate Soil Remediation Research Center Co Ltd
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Priority to CN201820195670.7U priority Critical patent/CN207995835U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/80Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
    • Y02A40/81Aquaculture, e.g. of fish

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Abstract

The utility model provides a kind of water purification system, including:Electrolysis installation, Liqiud-gas mixing device, electric cabinet and pressure adjust tank.A kind of water purification system described in the utility model, by generating the micro-nano air-bubble containing electrolytic ion and the micro-nano air-bubble containing electrolytic ion being input in the water body for needing to purify, electrolytic ion is set to be combined into the solid content mode that organism in water can not absorb with the heavy metal ion in water body, it is deposited in bottom of pond, reduce the content of beary metal in water body, meanwhile in micro-nano bubbles burst release oxygen to water body, increasing water body oxygen content.In addition, method and system described in the utility model can also reduce the disease of fishes and shrimps, the bilgy odour of the flesh of fish is removed.

Description

Water purification system
Technical field
The utility model is related to water purification technology field more particularly to a kind of water purification systems.
Background technology
Soil protection environment is maintaining ecological balance and promotes the important content of ecological construction, and be related to social economy can Sustainable development.But in the past, due to the extensive development of industry, the soil environment situation in many areas causes anxiety, some areas pollution Seriously.
Soil pollution can be divided into heavy metal pollution and Petrochemical pollution air.Non-ferrous metal metallurgy, PETROLEUM PROCESSING, chemical industry, coking, Plating, process hides, bleaching and dyeing, wiring board, Treatment of Metal Surface, medical manufacture, lead-acid accumulator, waste and old electric dismantling, hazardous waste Processing etc. will produce soil pollution, and pollutant is discharged through exhaust gas, the propagation of surface water and groundwater, cause soil dirt nearby Dye.
However, rehabilitating soil pollution is a complex art, generally comprise:Engineering measure, chemical harnessing measure, agricultural are raw State reclamation activities, animal reparation, phytoremediation, microorganism remediation etc..During heavy metal pollution of soil, especially farmland is dirty Dye, since pollutant is from the exhaust gas and irrigation water nearby discharged, into farmland after dissociate heavy metal ion be easy diffusion, lead It causes to repair difficulty reinforcement.
Water pollution, the especially heavy metal pollution of pool water quality, endanger bigger, be free in heavy metal in pool from Son can directly be absorbed by fishes and shrimps or other aquatic animals and plants so that fishes and shrimps, aquatic animals and plants content of beary metal are exceeded, and soil Fishy smell aggravates.
Utility model content
For this purpose, technical problem to be solved in the utility model is:A kind of water purification system is provided, to reduce in water body Content of beary metal, repair water quality, remove earthy taste of fresh water fish.
Then, the utility model provides a kind of water purification system, including:It is electrolysis installation, Liqiud-gas mixing device, automatically controlled Case and pressure adjust tank, and water is input in electrolysis installation and in electrolysis installation Inner electrolysis into hydrogen ion, hydroxyl ion or carbonic acid The electrolytic ionic water of radical ion, part hydrogen ion, which is attached on hydrone, to be lost in flow, after part hydrogen ion is merged into hydrogen Soluble in water, the water containing electrolytic ion enters Liqiud-gas mixing device, and is combined with air in Liqiud-gas mixing device and generate bubble, Electrolytic ion is attached to the surface layer of bubble in bubble generation process, generates the micro-nano air-bubble containing electrolytic ion, containing electrolysis from The micro-nano air-bubble of son enters pressure regulating tank and is exported to the water body for needing to purify through control valve after dischargeing excessive gas In.
Wherein, the Liqiud-gas mixing device is equipped with the cooling gas check valve entered for air, and the pressure adjusts on tank Equipped with the solenoid valve for discharging excessive gas, the output pressure range that pressure adjusts tank is 0.1 to 0.5Mpa.
The electric cabinet is that electrolysis installation is powered in a manner of pulse DC electricity, and electric cabinet is additionally operable to fill for gas-liquid mixed It sets, pressure adjusts tank power supply and the time for flow valve and pressure provides control.
The pulses range of the electric cabinet is 1 to 200 Hz.
The electric cabinet, electrolysis installation, Liqiud-gas mixing device and pressure adjust tank concentrated setting in a packaged type system In system.
A kind of water purification system described in the utility model, by generating the micro-nano air-bubble containing electrolytic ion and inciting somebody to action Micro-nano air-bubble containing electrolytic ion is input in the water body for needing to purify, and makes electrolytic ion and the heavy metal ion in water body It is combined into the solid content mode that organism in water can not absorb, is deposited in bottom of pond.Reduce the content of beary metal in water body, meanwhile, In micro-nano bubbles burst release oxygen to water body, water body oxygen content is increased.In addition, electrolytic ion, especially hydrogen-oxygen from Son itself has apparent bacteriostasis to fungi and mould, it is possible to reduce the disease of organism in water, especially fishes and shrimps.In addition, light After the fish gill of water fish absorbs micro-nano bubble, hydroxyl ion on bubble is to the geosmin and ammonia nitrogen that are attached on fish gill organ All there is decomposition, the bilgy odour of the flesh of fish can be effectively removed.
Description of the drawings
Fig. 1 is the structural schematic diagram of water purification system described in the utility model embodiment.
Specific implementation mode
In the following, the utility model is described in detail in conjunction with attached drawing.
As shown in Figure 1, present embodiments providing a kind of water purification system 30, it is built up in by pond 31.In pond 31 Water enter a packaged type system 35 through filter plant 32 and water pump 34.Packaged type system 35 includes:Electrolysis installation 36, gas Liquid mixing arrangement 38, pressure adjustment tank 42 and electric cabinet 48.Wherein, Liqiud-gas mixing device 38 is equipped with the gas for inputting gas Body check valve 40, pressure adjust tank 42 equipped with the solenoid valve 44 for discharging excessive gas, and electrolysis installation 36 is internally provided with Positive 36A and cathode 36B.
Water generates instant cell reaction when through electrolysis installation 36, generates micromolecular water and electrolytic ion.Water is set in electrolysis Cathode 36B in standby 36 generates hydrogen ion, and part hydrogen ion is attached on hydrone, is lost in flow.Part hydrogen ion merges Soluble in water as hydrogen, positive 36A of the water in electrolysis installation 36 generates hydroxyl ion.Therefore water generates after cell reaction For electrolytic ion based on the hydroxyl ion of negative electricity valence, this causes the water body for flowing through electrolysis installation, pH value slightly to increase.
Water containing electrolytic ion enters the water inlet end of Liqiud-gas mixing device 38.On the other hand, it is controlled by cooling gas check valve 40 Air processed enters the inlet end of Liqiud-gas mixing device 38.The two rapidly stirs in Liqiud-gas mixing device 38, cuts and mixes It closes.Electrolytic ion is attached to during bubble generates on the surface layer of bubble.It is generated in gas-liquid mixing process containing electrolysis The micro-nano air-bubble of ion.
Micro-nano bubble generates diameter in 50 microns of micro-bubbles between tens nanometer when referring to that bubble occurs. Common blister residence time in water body is very short, is rapidly reached the water surface and swelling fracture disappears.Micro-nano bubble is micro- due to volume It is small and residence time is long in water body, but be under pressure and gas molecule is constantly dissolved in water and reduces, it may finally be complete It is dissolved in the water.
Micro-nano bubble containing electrolytic ion refers to electrolytic ion in such a way that electrostatic attaches, and is distributed in micro-nano bubble Surface.Electrolytic ion is based on the hydroxyl ion of negatively charged valence.If electrolysis installation 16 generated in electrolytic process carbonate from Son, carbanion can be also attached on the bubble surface of generation.With the electrolytic ion that electrolysis installation 36 discharges, contain electricity to generate The micro-nano bubble that ion attaches is solved, the concentration ratio of bubble surface electrolytic ion is not with the bubble table by electrolysis installation 36 Face electrolytic ion concentration is higher by 5 to 150 times, and gap is apparent.This enables there are many micro-nano air-bubbles containing electrolytic ion Using.
The air-bubble that Liqiud-gas mixing device 38 generates initially enters pressure adjustment tank 42, extra in pressure adjustment tank 42 Gas hoard the top that tank 42 is adjusted in pressure, periodically start the solenoid valve 44 being arranged above pressure adjustment tank 42, can be with The gas hoarded in pressure adjustment tank 42 is discharged.When solenoid valve 44 is closed, pressure adjusts tank 42 by the air-bubble in it It is output in pipeline 46 by control valve 41 again.
The output of Liqiud-gas mixing device 38, via the flow control of control valve 41, to adjust Liqiud-gas mixing device 38 and pressure Power adjusts the output pressure of tank 42.The output pressure range of preferred pressure adjustment tank 42 is 0.1 to 0.5MPa.
Water in pipeline 46 is filled with micro-nano bubble, and electrolytic ion is attached on most micro-nano bubble.Electricity Control case 48 provides the electric power that entire packaged type system 35 needs and to the time control of solenoid valve 44 and to control valve 41 Pressure controls.The hydrogen ion that water is generated in 36 cell reaction of electrolysis installation is lost in except the hydrogen ion of a part is attached on hydrone Outside flow, a part can be also attached on micro-nano bubble, form the micro-nano bubble containing positive electricity price.But this micro-nano gas Steep it is unstable, pressure adjustment 42 implosion of tank decompose.Two hydrogen ions are combined into hydrogen and the gas of arc bubble release fills The top that tank 42 is adjusted in pressure is denounceed, when opening moving electromagnetic valve 44, from discharge in pressure adjustment tank 42.
Another mode of production that can increase electrolytic ion is that electric cabinet 48 supplies electricity to be electrolysed in a manner of pulse DC electricity Equipment 36.Pulse DC electricity is mainly discontinuous power supply, can reduce the accumulation of foreign matter on cathode 36B and anode 36A in this way.Arteries and veins It is 1 to 200 Hz to rush frequency range, and preferred range is 5 to 150 Hz.And pulse voltage is determined according to electrolyte content, is led to Often it is no more than 24V.
When the micro-nano air-bubble containing electrolytic ion enters in the water body for needing to purify, the air in water body can be increased Content, and the electrolytic ion of band especially hydroxyl ion on bubble, in needing the water body that purifies, encounter different heavy metals from The period of the day from 11 p.m. to 1 a.m, it will most heavy metal ion solid.Herein by taking copper, zinc, nickel, chromium, lead, arsenic, cadmium as an example.
If hydroxyl ion and copper ion meet, the solid content of Kocide SD is formed, water is slightly soluble in.If hydroxyl ion and zinc from Son meets, and forms the solid content of zinc hydroxide, not soluble in water.If hydroxyl ion and nickel ion meet, consolidating for nickel hydroxide is formed Shape object, it is not soluble in water.If hydroxyl ion and trivalent chromic ion meet, the solid content of chromium hydroxide is formed, it is not soluble in water.If hydrogen-oxygen Ion and lead ion meet, and form the solid content of lead hydroxide, are slightly soluble in water.If hydroxyl ion and arsenic ion meet, hydrogen is formed The solid content of arsenic oxide arsenoxide, it is not soluble in water.If hydroxyl ion and cadmium ion meet, hydrogen can be formed under no ammonia and nitrate anion interference The solid content of cadmium oxide, it is not soluble in water.
In aquaculture, packaged type system 35 generates the micro-nano air-bubble containing electrolytic ion, and 46 gradually by the road The diffusion in pond 31.Micro-nano bubble ratio common blister has a relatively large total surface area, the air in micro-nano bubble, outside The current potential that aerating bubble surface hydroxyl ion charge generates shows good absorption in cultivation water to the suspended matter in water Effect and efficient removal rate, to the COD in pond 31(Chemical Oxygen Demand, COD), ammonia nitrogen and Total phosphorus also has preferable removal effect.
Micro-nano bubble in liberal supply dissolved oxygen into water can inhibit the sludge in entire pond to increase, and digestion storage is dirty Mud builds good ecologic breeding environment.Micro-nano bubble can enhance aerobic microbiological in water, planktonic organism and aquatic animal Bioactivity accelerates its biodegradation process to pollutant in water body and bed mud, realizes purification of water quality purpose.Nano bubble sheet Body provides the hydroxyl ion adhered on more oxygen and bubble, all has decomposition to organic pollution, to purify water.It is rich Oxygen environment is vigorous one of the condition of fish metabolism, as human body directly can quickly absorb oxygen molecule one by digestive system Sample equally can directly be that the digestive organs of fish are absorbed with the micro-nano bubble of oxygen, be supplied to each organ of fish body.
If have heavy metal ion, heavy metal ion and micro-nano bubble contact in water body, that is, it is attracted to bubble surface, Solid type heavy metal compound is formed with hydroxyl ion, does not dissolve in or is slightly soluble in water, be deposited in bottom of pond, directly reduce heavy metal Pollution to fish.
In addition, electrolytic ion, especially hydroxyl ion itself have apparent bacteriostasis to fungi and mould.Therefore the fish gill When absorbing the micro-nano air-bubble containing hydroxyl ion, in addition to absorbing oxygen, hydroxyl ion has the disease of the fish gill a degree of Inhibiting effect.If fish obtains gill disease, it may appear that have difficulty in breathing, without appetite.
The bilgy odour of fresh-water fishes, mainly fish absorb the earthy that actinomyces secrete in bed mud by the gill or gastrointestinal tract Element, cyanobacteria and other substances.The mud decrement in entire pond, reduces the geosmin of pond sludge naturally.In respiratory In, the fish gill absorbs micro-nano bubble, and the hydroxyl ion on bubble all has the geosmin and ammonia nitrogen being attached on gill organ Decomposition, directly embodiment is the bilgy odour removal of the flesh of fish.
In water purification system 30, water generates cell reaction by electrolysis installation 36, and then electrolytic ion is attached immediately On the surface of micro-nano bubble, in water body conductance substance or dissolved solids the more, the amount of the hydroxyl ion after cell reaction The more, the also opposite raising of pH value and in water body.
In addition, electric cabinet, electrolysis installation, Liqiud-gas mixing device and pressure adjust tank concentrated setting at one in the present embodiment In packaged type system, it can also be not provided in a system according to actual demand.The system can be mobile, also may be used To be fixed.
Using above-mentioned water purification system 30, the present embodiment additionally provides a kind of method for purifying water, including:
Water is input in electrolysis installation, water be electrolyzed to produce the electrolysis of hydrogen ion, hydroxyl ion or carbanion from Sub- water, part hydrogen ion, which is attached on hydrone, to be lost in flow, and part hydrogen ion is merged into soluble in water after hydrogen;
Water containing electrolytic ion is input in Liqiud-gas mixing device, water is combined and produced with air in Liqiud-gas mixing device Anger is steeped, and electrolytic ion is attached to the surface layer of bubble in bubble generation process, generates the micro-nano air-bubble containing electrolytic ion;
By the micro-nano air-bubble containing electrolytic ion be input to pressure regulating tank discharge it is defeated through control valve after excessive gas Go out into the water body for needing to purify.
Wherein, after the micro-nano air-bubble containing electrolytic ion enters in water body, bubble increases air content in water body, electricity Solution ion is combined the solid content to form organism in water and can not absorb with the heavy metal ion in water body, is deposited in bottom of pond.
In order to reduce accumulation of the foreign matter on the positive 36A and cathode 36B of electrolysis installation 36, by what is powered for electrolysis installation Electric cabinet 48 is set as powering in a manner of pulse DC electricity, and electric cabinet 48 is additionally operable to adjust tank for Liqiud-gas mixing device 38, pressure 42 power supplies and the time for flow valve and pressure provide control.
In conclusion a kind of method for purifying water and system described in the present embodiment, pass through and generate the micro-nano containing electrolytic ion Micro-nano air-bubble containing electrolytic ion is simultaneously input in the water body for needing to purify by rice air-bubble, makes electrolytic ion and water body In heavy metal ion be combined into the solid content mode that organism in water can not absorb, reduce the content of beary metal in water body, together When, micro-nano bubbles burst discharges in oxygen to water body, increases water body oxygen content.In addition, electrolytic ion, especially hydrogen-oxygen Ion itself has apparent bacteriostasis to fungi and mould, it is possible to reduce the disease of organism in water, especially fishes and shrimps.In addition, After the fish gills of fresh-water fishes absorbs micro-nano bubble, hydroxyl ion on bubble is to the geosmin and ammonia that are attached on fish gill organ Nitrogen all has decomposition, can effectively remove the bilgy odour of the flesh of fish.
The above is only the preferred embodiment of the utility model only, is not intended to limit the utility model, all at this Within the spirit and principle of utility model, any modification, equivalent replacement, improvement and so on should be included in the utility model Protection domain within.

Claims (4)

1. a kind of water purification system, which is characterized in that including:Electrolysis installation, Liqiud-gas mixing device, electric cabinet and pressure adjustment Tank, the electrolytic ionic water that hydrogen ion, hydroxyl ion or carbanion are electrolyzed to produce in electrolysis installation enter gas-liquid mixed Device, and enter pressure after being combined generation micro-nano air-bubble of the bubble formation containing electrolytic ion with air in Liqiud-gas mixing device Power adjusts tank, and is exported into the water body for needing to purify through control valve after dischargeing excessive gas.
2. water purification system according to claim 1, which is characterized in that the Liqiud-gas mixing device is equipped with for sky The cooling gas check valve that gas enters, the pressure adjustment tank are equipped with the solenoid valve for discharging excessive gas, and pressure adjusts tank Output pressure range is 0.1 to 0.5Mpa.
3. water purification system according to claim 1, which is characterized in that the electric cabinet is electrolysis installation with pulsed Direct current mode is powered, electric cabinet be additionally operable to for Liqiud-gas mixing device, pressure adjust tank power supply and be flow valve time and Pressure provides control.
4. water purification system according to claim 3, which is characterized in that the pulses range of the electric cabinet is 1 To 200 Hz.
CN201820195670.7U 2018-02-05 2018-02-05 Water purification system Expired - Fee Related CN207995835U (en)

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Application Number Priority Date Filing Date Title
CN201820195670.7U CN207995835U (en) 2018-02-05 2018-02-05 Water purification system

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CN201820195670.7U CN207995835U (en) 2018-02-05 2018-02-05 Water purification system

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108094302A (en) * 2018-02-05 2018-06-01 广东威特宝土壤修复科研中心有限公司 Method for purifying water and system and earthy taste of fresh water fish minimizing technology
CN111646548A (en) * 2020-05-28 2020-09-11 天津市得欣环保科技有限公司 Electrolytic sterilization washing water and preparation method and application thereof
CN114797521A (en) * 2022-03-29 2022-07-29 江苏海狮机械股份有限公司 Micro-nano hydrogen bubble water generation system and operation control method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108094302A (en) * 2018-02-05 2018-06-01 广东威特宝土壤修复科研中心有限公司 Method for purifying water and system and earthy taste of fresh water fish minimizing technology
CN111646548A (en) * 2020-05-28 2020-09-11 天津市得欣环保科技有限公司 Electrolytic sterilization washing water and preparation method and application thereof
CN114797521A (en) * 2022-03-29 2022-07-29 江苏海狮机械股份有限公司 Micro-nano hydrogen bubble water generation system and operation control method thereof
CN114797521B (en) * 2022-03-29 2024-02-06 江苏海狮机械股份有限公司 Micro-nano hydrogen bubble generation system and operation control method thereof

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Granted publication date: 20181023

Termination date: 20220205